LMN No.: 150534823
This booklet contains 24 printed pages.
PAPER - 1: MATHEMATICS, PHYSICS & CHEMISTRY
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SEAL ds
PART A — MATHEMATICS
A complex number z is said to be
unimodular if |z|=1. Suppose z, and 2)
m — 2m
are complex numbers such that ="
2-2
is unimodular and z, is not unimodular.
Then the point z; lies on a :
aX
ww
(2) _ straight line parallel to x-axis.
(1) circle of radius J2
(3) straight line parallel to y-axis.
(4) circle of radius 2.
‘The normal to the curve, 22+21y—3y?=0,
at (1, 1) :
(1) meets the curve again in the fourth
quadrant.
(2) does not meet the curve again.
(3) meets the curve again in the second
quadrant,
(4) meets the curve again in the third
quadrant.
The sum of first 9 terms of the series
PeP SSeS yok
1+3 14345
q@) 192 .
~
Qn Wee
s
9 wie
f) % mie
(4) 142
4,
5.
6.
/ @Dy
Let f(x) be a polynomial of degree four
having extreme values at x=1 and x=2.
if tim|1 + £2] - 3, is
tn 2 then f(2) is equal
to:
qi) 4
(2) -8
(3) -4
@) 0
The negation of ~s v (~r as) is equivalent
to:
A) sar
Q) sanr
Q) sagas)
(4) sv@v~s)
[ee ey
If A=|2 1 -2 |is a matrix satisfying
[a 2° tb
the equation AAT=91, where [ is 3x3
identity matrix, then the ordered pair
{a, b) is equal to ad 10,
nd
/ ay (~2,-1) Met ot
v 4.8
(2) @ -1)
+
3) (-2) 4 dx
7. The integral [4% __ equals :
Jaa +14
1
[tty ,
AD ae
o (F +1
7
i? x
@) (ttt +
ae
@ -Gtiy+e
8. If m is the A.M. of two distinct real
numbers I and n (1, n > 1) and Gy, Gy and
G, are three geometric means between |
and n, then G} + 2G3+ G4 equals.
(1) 4 Pmtn?
(2) 4Pmn
Q) 4 Inn
(4) 4 tmn?
9. Let y(x) be the solution of the differential
equation
d
(x logx) = + y =2r logx, (x > 1).
Then y(e) is equal to
(Q) 2
Qe
(3) 0
(4)
10.
11.
12.
‘The number of integers greater than 6,000
that can be formed, using the digits 3, 5, 6,
7 and 8, without repetition, is :
(1) 72 ape a%
4,5
(2) 216” i
) 192 ol
4
@ 120-7
The number of points, having both
co-ordinates as integers, that lie in the
interior of the triangle with vertices (0, 0),
(0, 41) and (41, 0), is : e
AD 780
fo i
io
2) 901
(3) 861 NN
(4) 820
Let @ and B be the roots of equation <
x?—6x~2=0. If a,=a"—B", for n>1, ay
then the value of “10 —?88 js equal to
2ag
Oh a8 Oe
Q) 6
(@) -6
(@) 3
SPACE FOR ROUGH WORK 13.
where |x| < € Then a value of y is :
ax tx?
Q Trae
3x- x9
2 1- 3x7
5 3x +x?
® Ta
3x-x3
4)
® Tra2
14. The distance of the point (1, 0, 2) from the
point of intersection of the line
= = nee “sf and the plane
x-ytz=16, is:
Al) 13
2) 2via
@® 8
(4) svar
15. The area (in sq. units) of the region
described by
((u y) sy? < 2x and y > 4x - Nis:
as
az
o 2
® 2
16.) Let O be the vertex and Q be any point on
the parabola, x?=8y. If the point P divides
the line segment OQ internally in the ratio
1:3, then the locus of P is :
A) tary
@ May agg
@) Pex
@
yen2x
| #7. The mean of the data set comprising of 16
observations s 16. If one of the observation
valued 16 is deleted and three new
observations valued 3, 4 and 5 are added
to the data, then the mean of the resultant
data, is
fy 40
2) 16.8
(3) 16.0
(4) 158
C/Page 4
SPACE FOR ROUGH WORK 18.
19.
20.
‘The area (in sq. units) of the quadrilateral
formed by the tangents at the end points
of the latera recta to the ellipse
Bb ao:
oy F
2 +L -1,is:
o 6
() 27
7
a 2
3) 18
@ 2
The equation of the plane containing the
line 2x-5y+z=3; x+y+4
parallel to the plane, x +3y +6:
(1) 2x+6y+122=-13
(2) 2x+6y+122=13
The number of common tangents to the
circles x?+y?—4x-—6y-12=0 and
xtty!+ 6x+18y+26=0, is :
a 4
Q 4
(3) 2
@) 3
21;
22.
23,
The set of all values of \ for which the
system of linear equations
2xy—2xy+45=Axy
2x —3xy +244 = Ax
Hxt2 = hy
has a non-trivial solution,
(1) contains more than two elements.
(2) isan empty set. \
(3) isa singleton.
(4) contains two elements. ~
If 12 identical balls are to be placed in 3
identical boxes, then the probability that
one of the boxes contains exactly 3 balls
goo 0
The sum of coefficients of integral powers
of x in the binomial expansion of
(1 ave)” is:
a 3% +1)
a e+)
(4)
C/Page 5
SPACE FOR ROUGH WORK 24,
25.
‘The integral
4 2
laa
zlog x? + log (36 - 12x + x?)
is equal to :
ay 6
Q) 2
@) 4
@a
If the function.
kWe¥1 , 05x53
B(x) =
mx+2 ,3
26. Locus of the image of the point (2, 3) in | 30 Let @, b and ¢ bethreenon-zero vectors
the line (2v-3y +4) +k (x-2y+3)=0, such that no two of them are collinear and
came) (ax byx C=TIAT. 10 is the
(1) circle of radius /3.
(2) agement Une pacallsiiio = sie angle between vectors b and ¢, then a
(3) _ straight line parallel to y-axis, anwaneadie
(4) circle of radius /2
(1)
27, tim (1 ) is equal to
1390 eg Q)
ny
a 8)
2) 4
@) 3 ee
2 3
C/Page 6
SPACE FOR ROUGH WORK eit) aye b-
2) aly at
aah vss wy Be
Be ote
wie! Sub
PART B PHYSICS i, | 33.
o
31.
2 3h
aM
In the circuit shown, the current in the 19
resistor is : re
we
.
(ly 0.13 A, from P
ie eee eee
ee
qe 1.99
2) 13.A, from P to Q
‘
bagig) OM ane
w ot [=
ae 6 013 A, fromQtoP ~
ah
we
“Ve
ane
32. Distance of the centre of mass of a solid
uniform cone from its vertex is zy. If the
radius of its base is R and its height is h
34.
then zp is equal to
gh?
oe
wR
@ ae
3h
eo >
Sh
OF
Match List - (Fundamental Experiment)
with List - II (its conclusion) and select
the correct option from the choices given
below the list
List-1 List - IT
Particle nature
lof light
Discrete energy
levels of atom
[Franck-Hertz |
a }@
Al
(ay Experiment. 2
[Photo-electric
(B)]
lexperiment,
(ii)
Wave nature of|
lelectron
[Davison - Germer
experiment i
Structure of
vy Jatom
©-@
(©- Gi)
(C)- Gti)
(© - (ili)
a)
®
(3)
co)
(A) -@v)
(A)-
(B) - (ii)
(B) - (iv)
(B) - (iv)
(B)-@)
A
(A) - Gi)
(A) - Gi)
The period of oscillation of a simple
pendulum is T= 2m, £ - Measured value
8
of L is 20.0 cm known to 1 mmm accuracy
and time for 100 oscillations of the
pendulum is found to be 90s using a wrist
watch of Is resolution. ‘The accuracy in
the determination of g is
pe tem
100 90
SPACE FOR ROUGH WORK 35.
36.
Ared LED emits light at 0.1 watt uniformly
around it. The amplitude of the electric
field of the light at a distance of 1 m from
the diode is :
(1) 7.75 V/m
QQ) 1.73 V/m
(@) 245 V/m
(4) 5.48 V/m
In the given circuit, charge Q, on the 2uF
capacitor changes as C is varied from 1yF
to 3uF. Q) as a function of ‘C’ is given
properly by: (iguresare drawn schematically
and are not to scale)
di
Hie
ue
4
()
(2)
37.
38.
eo)
Two long current carrying thin wires, both
with current I, are held by insulating
threads of length L and are in equilibrium
as shown in the figure, with threads
making an angle ‘é’ with the vertical. If
wires have mass per unit length then the
value of Lis :
(g =gravitational acceleration)
frag
tan®
(1)
(2) sin8
4) 2
A particle of mass m moving in the
x direction with speed 20 is hit by another
particle of mass 2m moving in the
y direction with speed v. If the collision is
perfectly inelastic, the percentage loss in
the energy during the collision is close to :
() 62% Ay
2) 44% _\)
Q) 50% -
(4) 56%
SPACE FOR ROUGH WORK 39.
40.
Given in the figure are two blocks A and B
of weight 20 N and 100 N, respectively.
‘These are being pressed against a wall by
a force F as shown. If the coefficient of
friction between the blocks is 0.1 and
between block B and the wall is 0.15, the
frictional force applied by the wall on block
Bis:
vt) 150 4 7a
@) 100N aq?
ant oe 120 :
(4) 120Nt ‘ yoo #0
Consider an ideal gas confined in an
isolated closed chamber. As the gas
undergoes an adiabatic expansion, the
average time of collision between
molecules increases as V", where V is the
volume of the gas. The value of q is
(-2)
a
g 2
@ 2
@ 2
41.
A rectangular loop of sides 10 em and
5 cm carrying a current | of 12 A is placed
in different orientations as shown in the
figures below :
4
@ 2
we
If there is a uniform magnetic field of
03 T in the positive z direction, in which
orientations the loop would be in (i) stable
equilibrium and (ii) unstable equilibrium ?
(1) (b) and (0), respectively
_ (@)and (b), respectively (a
(3) @) and (0), respectively )
(4) (b) and (4), respectively
C/Page 9
SPACE FOR ROUGH WORK 42.
43.
C/Page 10
Consider a spherical shell of radius R at
temperature T. The black body radiation
inside it can be considered as an ideal gas
of photons with internal energy per unit
us ? «T* and pressure
volume
1/2). if the shell now undergoes
3lv —
an adiabatic’ expansion the relation
between T and Ris:
Te -
@ i
@ Taek *
@) Texe3k
1
@ Tes
As an electron makes a transition from an
excited state to the ground state of a
hydrogen - like atom/ion :
(1) kinetic energy and total energy
decrease but potential energy
increases
(2) its kinetic energy increases but
potential energy and total energy
decrease
(3) Kinetic energy, potential energy and
total energy decrease
(4) kinetic energy decreases, potential
energy increases but total energy
remains same
44. Ona hot summer night, the refractive
index of air is smallest near the ground and
increases with height from the ground.
Whena light beam is directed horizontally,
the Huygens’ principle leads us to conclude
that as it travels, the light beam :
(1) bends upwards
(2) becomes narrower
(3) goes horizontally without any
deflection
(4) bends downwards
45. Froma solid sphere of mass M and radius
R
R, a spherical portion of radius > is
removed, as shown in the figure. Taking
gravitational potential V=0 at r= x, the
potential at the centre of the cavity thus
formed is :
(G = gravitational constant)
@y 226M
R
- GM
Chere
=GM
eo
(@)
v
SPACE FOR ROUGH WORK 46. Monochromatic light is incident on a glass
prism of angle A. If the refractive index of
the material of the prism is yw, a ray,
incident at an angle 0, on the face AB
would get transmitted through the face AC
of the prism provided :
os oom
2) oie (a- sin! 2)
@) ecos"! [rsin(a+ sin”!
D
47.
Two stones are thrown up simultaneously
from the edge of a cliff 240 m high with
initial speed of 10 m/s and 40 m/s
respectively. Which of the following graph
best represents the time variation of
relative position of the second stone with
respect to the first ?
(Assume stones do not rebound after
hitting the ground and neglect air
resistance, take g=10 m/s?)
(The figures are schematic and not drawn to
scale)
2-1) m
240
qa) i
siz)
aQ2-n)m
240} a
iz
16s)
(yay) m
(4) i
¢ os )
C/Page 11 SPACE FOR ROUGH WORK 48.
49.
Fora simple pendulum, a graph is plotted
between its kinetic energy (KE) and
potential energy (PE) against its
displacement d. Which one of the
following represents these correctly ?
(graphs are schematic and not drawn to scale)
A train is moving on a straight track with
speed 20 ms~!. It is blowing its whistle at
the frequency of 1000 Hz. The percentage
change in the frequency heard by a person
standing near the track as the train passes
him is (speed of sound =320 ms~!) close
to
Q) 24%
2) 6%
@ 12% ae
(4) 18%
50.
An LCR circuit is equivalent to a damped
pendulum. In an LCR circuit the capacitor
is charged to Qy and then connected to
the L and R as shown below :
Ifa student plots graphs of the square of
maximum charge (Qpj,.) on the capacitor
with time(|) for two different values L and
Ly (Ly>Lq) of L then which of the following,
represents this graph correctly ? (plots are
schematic and not drawn to scale)
ei
‘Max! Qy (For both L; and
@ d ‘Land L3)
ot AUREREEESS Pe
Fe
2) ce
Qe Ne
fl] Ke
@) aan
Ue
2
Qs Ly
) \
C/Page 12
SPACE FOR ROUGH WORK 51. A solid body of constant heat capacity
1J/°C is being heated by keeping it in
contact with reservoirs in two ways
() Sequentially keeping in contact with
2 reservoirs such that each reservoir
supplies same amount of heat.
Sequentially keeping in contact with
8 reservoirs such that each reservoir
cc)
supplies same amount of heat
In both the cases body is brought from
initial temperature 100°C to final
temperature 200°C. Entropy change of the
body in the two cases respectively is
(1) 2tn2, 8In2
(2) n2, 4in2
(3) Ind, n2
(4) Ind, 2nd
C/Page 13
52.
53.
An inductor (L=0.03H) and a resistor
(R=0.15 kQ) are connected in series to a
battery of 15V EMF in a circuit shown
below. The key K, has been kept closed
for along time. Then at t=0, K, is opened
and key K, is closed simultaneously.
At t=1ms, the current in the circuit will
be : (e°2150)
03H
3H 015 ko.
Ke
(1) (0.67 mA
(2) 100 mA
@) 67 mA
(3) 6.7 mA
A uniformly charged solid sphere of radius,
R has potential Vp (measured with respect
to ®) on its surface. For this sphere the
equipotential surfaces with potentials
Ry Ry and R, sespectively. Then
Yo
id [> have radius Ry
a
(2) R,=0and R, > (R,-R,)
IR (Ry-Ry)
0 and Ry < (Ry- Ry)
‘SPACE FOR ROUGH WORK 54.
A long cylindrical shell carries positive
surface charge o in the upper half and
negative surface charge —o in the lower
half. The electric field lines around the
cylinder will look like figure given in :
(figures are schematic and not drazon to scale)
@)
2)
7 $e
55.
56.
Assuming human pupil to have a radius
of 0.25 cm and a comfortable viewing
distance of 25 cm, the minimum separation
between two objects that human eye can
resolve at 500 nm wavelength is :
(1) 300 pm
2) 1am
3) 30 um
(4) 100 pm
A signal of 5 kHz frequency is amplitude
modulated on a carrier wave of frequency
2MHz. The frequencies of the resultant
signal is/are :
(1) 2000 kHz and 1995 kHz
(2) 2MHz only
(3) 2005 kHz, and 1995 kHz
(4) 2005 kHz, 2000 kHz and 1995 kHz
C/Page 14
SPACE FOR ROUGH WORK Sasa
Th
‘Two coaxial solenoids of different radii
carry current I in the same direction. Let
57.
F,_be the magnetic force on the inner
solenoid due to the outer one and F be
the magnetic force on the outer solenoid
due to the inner one. Then :
F, is radially outwards and F, =0
i-i EH)
F, is radially inwards and B is
@
4
8)
radially outwards
(4) Fis radially inwards and F =0
‘A pendulum made of a uniform wire of
cross sectional area A has time period T.
When an additional mass M is added to
its bob, the time period changes to Tyy. If
the Young’s modulus of the material of the
58.
1
wire is Y then
ravitational acceleration)
is equal to:
59,
60.
From a solid sphere of mass M and radius
Ra cube of maximum possible volume is
cut. Moment of inertia of cube about an
axis passing through its center and
perpendicular to one of its faces is :
SPACE FOR ROUGH WORK
ay amr?
ae
Na *
©
wes wot
ws
©) 32m Z
s
NY
2 ye
She
©) 6m
i 4M?
O ofan
When 5V potential difference is applied
across a wire of length 0.1 m, the drift
speed of electrons is 2.5x1074 ms“). If
the electron density in the wire is
8x 10° m~3, the resistivity of the material“ \,
is close to :
(1) 1610-5 Om
(2) 1.6x10-8§ Om
a
(3) 1.6x10-7 Om Ty!
ke
(4) 1.6x10-6 Om ae 61.
62.
63.
64.
PART C — CHEMISTRY
The vapour pressure of acetone at 20°C is
185 torr. When 1.2 g of a non-volatile
substance was dissolved in 100 g of acetone
at 20°C, its vapour pressure was 183 torr.
The molar mass (g mol ~}) of the substance
is:
(1) 488
(2) 32
@) 64,
(4) 128
3 g of activated charcoal was added to
50 mL. of acetic acid solution (0,06N) in a
flask. After an hour it was filtered and
the strength of the filtrate was found to be
0.042 N. The amount of acetic acid
adsorbed (per gram of charcoal) is
(1) 54mg
(2) 18mg
(@) 36mg
(@) 42mg
Which of the following is the energy of a
possible excited state of hydrogen ?
(1) +68 ev
(2) +13.6 eV
Q) -68 ev
(@) -34ev,
Which among the following is the most
reactive ?
q) ia
“@ a,
@) By.
® b
65.
66.
67.
Which polymer is used in the manufacture
of paints and lacquers ?
(1) Poly vinyl chloride
(2) Bakelite
(3) Glyptal
(4) Polypropene
The molecular formula of a commercial
resin used for exchanging ions in water
softening is CgH,SO3Na (Mol. wt. 206).
What would be the maximum uptake of
Ca?* ions by the resin when expressed in
mole per gram resin ?
Ym
1
@ ae
1
© as
2
© ss
In Carius method of estimation of
halogens, 250 mg of an organic compound
gave 141 mg of AgBr. The percentage of
bromine in the compound is :
(at. mass Ag =108; Br =80)
(1) 60
(2) 24
(3) 36
(4) 48
C/Page 16
SPACE FOR ROUGH WORK 68. Assertion : Nitrogen and Oxygen are the
main components in the
atmosphere but these do not
react to form oxides of nitrogen.
Reason : The reaction between nitrogen
and oxygen requires high
temperature.
(1) Both the assertion and reason are
incorrect
(2) Both assertion and reason are
correct, and the reason is the correct
explanation for the assertion
(3) Both assertion and reason are
correct, but the reason is not the
correct explanation for the assertion
(4) The assertion is incorrect, but the
reason is correct
69. The following reaction is performed at
298 K.
2NO(®) + O2(g) = 2NO2(g)
The standard free energy of formation of
NO(g) is 86.6 kJ/mol at 298 K. What is
the standard free energy of formation of
NO,(g) at 298 K? (kK, =1.6x 102)
(1) 0.5[2% 86,600 —R(298) In(1.6 x 10!)]
(2) R(298) In(1.6 x 102) 86600
(3) 86600 + R(298) In(1.6x10!2)
In (1.6 x 10")
(8) 86600 = 8)
C/Page 17
70. Which one of the following alkaline earth
‘metal sulphates has its hydration enthalpy
greater than its lattice enthalpy ?
(1) S180,
2) CaSO,
@) BeSO,
(4) BaSO,
71. The number of geometric isomers that can
exist for square planar [Pt (Cl) (py) (NH)
(NH,OH)]* is (py = pyridine) :
@ 6
Q) 2
&) 3
@ 4
72. The synthesis of alkyl fluorides is best
accomplished by
(1) Swarts reaction
(2) Free radical fluorination
(3) Sandmeyer’s reaction
(4) Finkelstein reaction
73. The intermolecular interaction that is
dependent on the inverse cube of distance
between the molecules is :
pil be
() hydrogen bond «= ROA
(2) ion - ion interaction
_ 3) ion - dipole interaction
(4) London force
SPACE FOR ROUGH WORK 74,
75.
76.
77.
In the context of the Hall - Heroult process
for the extraction of Al, which of the
following statements is false ?
(1) NajAIF, serves as the electrolyte
(2) CO and CO, are produced in this
process
(@)_Al,; is mixed with CaF, which
lowers the melting point of the
mixture and_ brings conductivity
(4) Al* is reduced at the cathode to
form Al
Which of the following compounds will
exhibit geometrical isomerism ?
x
q
(1) 1,1- Diphenyl - 1 - propane
(2) 1-Phenyl-2-butene ¥ &
oO
@) 3-Phenyl-1-butene
@) 2-Phenyl-1-butene +
*
VU
The ionic radii (in A) of N?~, 02~ and F~
are respectively : 5
1) 171, 1.36 and 1.40 Duce’
@ and RS:
(2) 1.36, 1.40 and 1.71 te # <
(@) 136, 1.71 and 1.40 %
eS
(4) 171, 1.40 and 1.36 xe
From the following statements regarding
H,O,, choose the incorrect statement :
(2) Ithas to be kept away from dust,
(2) Itcan act only as an oxidizing agent
(3) _ It decomposes on exposure to light,
(4) Ithas to be stored in plastic or wax
lined glass bottles in dark v
78.
to:
eo)
ee
@)
@
Higher order (>3) reactions are rare due
loss of active species on collision
low probability of simultaneous
collision of all the reacting species
increase in entropy and activation
energy as more molecules are
involved
shifting of equilibrium towards
reactants due to elastic collisions
79. Match the catalysts to the correct
processes
Catalyst Process
(A) TiCl; (i) Wacker process
(8) PaCl, (ii) Ziegler - Natta
polymerization
(©) CuCl, _ fill) Contact process
(D) V,0;" (iv) Deacon's process
(yy (A)- (ii) (B) - (, (©) - (ii), (D) - Gv)
(2) (A)= (ii) B)- GH, (=v), O)-
aA (3) (A)- Gi), (B)- @, © - @), (D) - (iti)
(4) (A)- (ii), (B) - il), (© - Gv), (D)-
80. Which one has the highest boiling point ?
a
oy
0)
@
Xe
He +
Ne ©
Kr
C/Page 18
SPACE FOR ROUGH WORK |
81.
82.
C/Page 19
In the reaction
NEI
NANOYHE p_CHENAC 5 y,
cH,
the product E is =
cH,
ao
COOH
°
@
cH,
@ MeLODXLO ohh
CN
@)
CH;
Which of the following compounds is not
colored yellow ?
(1) BaCrO,
(2) Zms[Fe(CN),]
(3) Ks[Co(NO,)]
(4) (NH4)s [As (Mos Oj)4)
Sodium metal crystallizes ina body centred
cubic lattice with a unit cell edge of 4.29A.
The sodium atom is
approximately
radius of
(2) 0.934,
me
(3) 3.22A
1.86A
(4) 5.72
gles?
84. The standard cing ae at
300 K for the reaction 2A = B+C is
2494.2 J. Ata given time, the composition
of the reaction mixture is [A] = >, [B]=2
1
and [C]= >. The reaction proceeds in
the: [R=8.314 J/K/mol, e=2.718]
@ (0) teverse direction because Q < K.
(2) forward direction because Q > K,
aS) -
(4) forward direction because Q < K.
reverse direction because Q > K,
SPACE FOR ROUGH WORK 85. Which compound would give
5 - keto - 2 - methyl hexanal upon
ozonolysis ?
cH,
8
CH
os
CH :
8)
‘CH;
Cly
£
86. Which of the following compounds is not
an antacid ?
(1) Ranitidine
(2) Aluminium hydroxide
(3) Cimetidine
(4) Phenelzine
87. In the following sequence of reactions :
Totuene KMHOL, 4 252.5 p HYPE,
the product Cis :
D> CcHsCHO
(2) CgHsCOOH
(3) CgHsCH
(4) CyH,CH,OH
88. Which of the vitamins given below is water
soluble ?
a
2
®
@
Vitamin K
Vitamin C
Vitamin D
Vitamin E
89. The color of KMnO, is due to :
@
2)
A
@)
v — o* wansition
M — L charge transfer transition
d = d transition
L— M charge transfer transition
90. Two Faraday of electricity is passed
through a solution of CuSO,. The mass of
copper deposited at the cathode is
(at, mass of Cu =63.5 amu)
QQ) 127 gv
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