Mains 5

7/7/2015
QuestionRevision
Question1.
IfthepHofasolutionis11,calculatethenumberofhydrogenionspresentpermlofthesolution.
[A]
[B]
[C]
[D]
Question2.
Aweak,monoproticacidisdissociatedtotheextentof3%in0.02Msolution.Calculatetheextentofitsdissociationin0.05Msolution.T
=298K.
[A]
[B]
[C]
[D]
1.39%
2.19%
2.32%
1.93%
Question3.
AmixtureofCO 2(g),CO (g)andC(s)aremaintainedatequilibriumat
gaseousmixtureis
[A]
[B]
[C]
[D]
inaonelitreflask.Ifthemeanmolarmassofthe
.Whatisthecompositionofthegasmixture.
1:1
1:2
2:1
3:2
Question4.
Whenincreasingpressureisappliedtotheequilibriumsystem,
[A]
[B]
[C]
[D]
,whichofthefollowingwillhappen?
Moreicewillevaporate
Waterwillevaporate
Morewaterwillbeformed
Anyoftheabovedependingonthetemperatureofthesystem
Question5.
Acertainmonoproticweakacidshowsenthalpyofneutralization=
degreeofionizationtobe0.25.For
.Calculateitsenthalpyofionizationassumingits
neutralization,enthalpyvalue=
[A]
[B]
[C]
[D]
Question6.
.Thedissociationprocesses:
I.
and
II.
energyofthe
absorb265kcal/moland
respectively.Calculatethebond
bond.
http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff80808149bc8a9d0149e637cba017f5&tName=2016%20JEE%20
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[A]
[B]
[C]
[D]
QuestionRevision
+93kcal
+73kcal
Question7.
Theelectrostaticforceofattractionbetween
[A]
[B]
[C]
[D]
isgreaterthanthatof
because:
Nahashigherionizationenergy
Nadoesnothavefilleddorbitals
Na+hassmallersizethanCs +
Cs +ismorereactivethanNa+
Question8.
AmoleculeofthetypeAX4withsp3d2hybridizationwillhave:
[A]
[B]
[C]
[D]
willdependonelectronegativityofAandX
willdependondirectionoflonepairofelectrons
Question9.
Thestructureandhybridizationof
[A]
[B]
[C]
[D]
is:
Linear,sp3d2
Angular,sp2
Linear,sp3d
Angular,sp3d
Question10.
Statement1:NCl3hasverysmalldipolemomentwhileNH3hasalargedipolemoment.
Statement2:TheelectronegativitydifferencebetweenNandClisverysmallandthatbetweenNandHisverylarge.
[A]
[B]
[C]
[D]
Statement1isTrue,Statement2isTrueStatement2isacorrectexplanationforStatement1
Statement1isTrue,Statement2isTrueStatement2isNOTacorrectexplanationforStatement1
Statement1isTrue,Statement2isFalse
Statement1isFalse,Statement2isTrue
Question11.
Statement1:Fortheheterogeneousequilibrium:
,thereactioncanbemadetoshiftin
forwarddirectionbyincreasingthevolumeofcontainer.
Statement2:Withanincreaseinvolumeofcontainer,theconcentrationofCO 2decreases.
[A]
[B]
[C]
[D]
Question12.
Statement1:LiClisanioniccompound,withgoodcovalentcharacter.
Statement2:Forcovalentcharacter,cationsizeshouldbesmalleranionsizeshouldbelargerwhichresultsingreaterpolarization.
[A]
[B]
[C]
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[D]
QuestionRevision
Question13.
Statement1:Thefirstmemberofpblockelementswhencomparedtothatofsubsequentmembersinthesamegroupshows
differentchemicalbehaviour.
Statement2:Theothermembersofagrouphavevacantdorbitals.
[A]
[B]
[C]
[D]
Question14.
TheformalchargeonnitrogenbondedtooxygeninthemoleculeN2Ois:
[A]
[B]
[C]
[D]
+1
Question15.
Agaseoushydrocarbonrequires6timesitsownvolumeofO 2forcompleteoxidationandproduces4timesitsvolumeofCO 2atsameP
andT.Themolecularformulaofgasis:
[A]
[B]
[C]
[D]
C4H10
C4H8
CH2
C8H14
Question16.
Thegivencurveshowsthevariationof
[A]
[B]
[C]
[D]
asafunctionofTforafixedmassandPofanidealgas.Itfollowsfromthecurvethat:
P1=P2=P3
P1>P2>P3
P1<P2<P3
Nothingcanbepredictedaboutthepressures
Question17.
Onahumiddayinsummer,themolefractionofgaseousH2O(watervapour)intheairat
totalpressureof0.95atm,whatisthepartialpressureofdryair?
[A]
[B]
[C]
[D]
canbeashighas0.02.Assuminga
0.95atm
0.93atm
0.02atm
0.97atm
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Question18.
X,YandZreactinthe1:1:1stoichiometricratio.
TheconcentrationofX,YandZwherefoundtovarywithtimeasshowninthefigurebelow:
Whichofthefollowingequilibriumreactionrepresentsthecorrectvariationofconcentrationwithtime.
[A]
[B]
[C]
[D]
Question19.
Thevalueoftheequilibriumconstant(Kc )fortheequilibriumrepresentedinabovesketchwillbe:
[A]
[B]
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[C]
[D]
Question20.
Ifaboveequilibriumisestablishedina2.0LcontainerbytakingreactantsinsufficientamountthenhowmanymolesofcomponentY
musthavereactedtoestablishtheequilibrium?
[A]
[B]
[C]
[D]
0
6
12
8
Question21.
TwogramsofgasAareintroducedinaevacuatedflaskat
.Thepressureofthegasis1atm.Now3gofanothergasBis
introducedinthesameflaskthetotalpressurebecomes1.5atm.TheratioofmolecularmassofAandBis:
[A]
[B]
[C]
[D]
3/1
1/3
1/4
2/3
Question22.
TheoxidationofSO 2byO 2toSO 3isanexothermicprocess.TheyieldofSO 3ismaximumif:
I.TemperatureisincreasedII.Temperatureisreduced
III.PressureisincreasedIV.Temperatureandpressurebothareincreased
Thecorrectoptionis:
[A]
[B]
[C]
[D]
I,II
I,III
II,III
II,III,IV
Question23.
AtacertaintemperatureT,acompoundAB4(g)dissociatesas
withadegreeofdissociationx,
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whichisnegligiblecomparedwithunity.TheexpressionofKpintermsofxandtotalpressurePis:
[A]
[B]
[C]
[D]
8P3x 5
256P333x 5
4Px 2
Noneofthese
Question24.
WhichofthefollowingcanactasLewisacids?
I.
II.
III.
IV.
Thecorrectoptionis:
[A]
[B]
[C]
[D]
I,II
II,III
II,III,IV
III,IV
Question25.
Byobservingadjacentgraphwhatcanbesaidabouttherelationshipbetweenvanderwaal'sconstantbofHeandH2atthesame
temperature?
[A]
[B]
[C]
[D]
Nothingcanbepredictedbetweenthevaluesof
and
Question26.
IfthebonddissociationenergiesofXY,
formationofXYis
and
(alldiatomicmolecules)areintheratioof1:1:0.5and
.Thebonddissociationenergyof
forthe
willbe:
[A]
[B]
[C]
[D]
Noneofthese
Question27.
Thevalueofenthalpychange
forthereaction
at27oCis
.Thevalueofinternalenergychangefortheabovereactionatthistemperaturewillbe:
[A]
[B]
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[C]
[D]
Question28.
Whichofthefollowingis/nottrueforathermochemicalreaction?
[A]
atconstantpressure
[B]
atconstantvolume
[C]
when
iszero
[D]
when
iszero
Question29.
Whichofthefollowingis(are)Extensiveproperties:
I.InternalenergyII.Specificheat
III.EnthalpyIV.Boilingpoint
Thecorrectoptionis:
[A]
[B]
[C]
[D]
I,II
I,III
I,II,III
II,IV
Question30.
WhichofthefollowingcanactasBronstedLowryacids?
I.
II.
IV.
V.
III.
Thecorrectoptionis:
[A]
[B]
[C]
[D]
I,IV,V
I,III,IV,V
I,II,III,IV,V
I,IV
Question31.
Twoparticleshavingmassration:1areinterconnectedbyalightinextensiblestringthatpassesoverasmoothpulley.Ifthesystemis
released,thentheaccelerationofthecentreofmassofthesystemis:
[A]
[B]
[C]
[D]
Question32.
Ablockofmassmispushedtowardsamovablewedgeofmass2mandheighthwithavelocityu.
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Allsurfacesaresmooth.Theminimumvalueofuforwhichtheblockwillreachthetopofthewedgeis:
[A]
[B]
[C]
[D]
Question33.
Abodydroppedfromaheight'H'reachesthegroundwithaspeedof
[A]
[B]
[C]
[D]
Calculatetheworkdonebyairfriction.
Zero
0.28mgH
0.72mgH
0.28mgH
Question34.
Aballisprojectedfromgroundwithavelocityvatanangle
andreturnstoground.Thetotaltimeofflightoftheballis:
tothevertical.Onitspathitmakesanelasticcollisionwithaverticalwall
[A]
[B]
[C]
[D]
Question35.
Displacementofaparticleofmass2kgmovinginastraightlinevarieswithtimeass=(2t3+2)m
Impulseoftheforceactingontheparticleoveratimeintervalbetweent=0andt=1sis:
[A]
[B]
[C]
[D]
10Ns
12Ns
8Ns
6Ns
Question36.
Awireoflengthlandmassmisfirstbentinacircle,theninasquareandtheninanequilateraltriangle.Themomentofinertiainthese
threecasesaboutanaxisperpendiculartotheirplanesandpassingthroughtheircentersofmassare
respectively.
Thenmaximumofthemis:
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[A]
[B]
[C]
[D]
Datainsufficient
Question37.
Auniformcirculardiscofradiusrplacedonaroughhorizontalplanehasinitialvelocityv 0andanangularvelocity
disccomestorestaftermovingsomedistanceinthedirectionofmotion.Theninitially:
[A]
[B]
[C]
asshown.The
Thefrictionforceactsintheforwarddirection
Thepointofcontactofdiscwithgroundhaszerovelocity
[D]
Question38.
TwoparticlesofequalmassmatAandBareconnectedbyarigidlightrodAB,lyingonasmoothhorizontaltable.AnimpulseJis
appliedatAintheplaneofthetableandperpendiculartoAB.ThenthevelocityofparticleatAis:
[A]
[B]
[C]
[D]
Zero
Question39.
Adiscofradiusrrollswithoutslippingonaroughhorizontalfloor.
Ifvelocityofitscentreofmassisv 0,thenvelocityofpointP,asshowninthefigure(OP=r/2and
),is:
[A]
[B]
[C]
[D]
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Question40.
TheaccelerationaoftheplankPrequiredtokeepthecentreCofasolidcylinderinafixedpositionduringthemotionis:(Noslipping
takesplacebetweencylinderandplank)
[A]
[B]
[C]
[D]
Question41.
AuniformrodABofmassmandlength2aisfallingfreelywithoutrotationundergravitywithABhorizontal.SuddenlytheendAisfixed
whenthespeedoftherodisv.Theangularspeedwithwhichtherodbeginstorotateis:
[A]
[B]
[C]
[D]
Question42.
ArodofmassmandlengthlishingedatoneofitsendAasshowninfigure.
AforceFisappliedatadistancexfromA.Theaccelerationofcentreofmass'a'varieswithxas:
[A]
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[B]
[C]
[D]
Question43.
AnimpulseJisappliedonadiscofmassmalongalinepassingthroughitscentreO.Thediscisplacedonaroughhorizontalsurface.
Thelinearvelocityofcentreofdisconceitstartsrollingwithoutslippingis:
[A]
[B]
[C]
[D]
J/2m
2J/3m
J/4m
J/3m
Question44.
AtimevaryingforceF=2tisappliedonaspoolasshowninfigure.
Theangularmomentumofthespoolattimetaboutbottommostpointis:
[A]
[B]
[C]
[D]
Dataisinsufficient
Question45.
Ablockweighing10NtravelsdownasmoothcurvedtrackABjoinedtoaroughhorizontalsurface(figure).Theroughsurfacehasa
frictioncoefficientof0.20withtheblock.Iftheblockisreleasedfromrestonthetrackfromapoint1.0mabovethehorizontalsurface,
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thedistanceitwillmoveontheroughsurfaceis:
[A]
[B]
[C]
[D]
5.0m
10.0m
15.0m
20.0m
Question46.
Figureshowsablockslidingonafrictionlesstrackwhichterminatesinastraighthorizontalsection.Iftheblockstartsslippingfromthe
pointA,howfarawayfromthetrackwilltheblockhittheground?
[A]
[B]
[C]
[D]
Atahorizontaldistanceof1mfromtheendofthetrack
Atahorizontaldistanceof2mfrotheendofthetrack
Atahorizontaldistanceof3mfromtheendofthetrack
Insufficientinformation
Question47.
Ablockofmassmisattachedtotwounstretchedspringsofspringconstantsk 1andk 2asshowninfigure.Theblockisdisplaced
towardsrightthroughadistancexandisreleased.Findthespeedoftheblockasitpassesthroughthemeanposition:
[A]
[B]
[C]
[D]
Noneofthese
Question48.
Abodyofmassmdroppedfromacertainheightstrikesalightverticalfixedspringofstiffnessk.
Theheightofitsfallbeforetouchingthespringifthemaximumcompressionofthespringisequalto
is:
[A]
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[B]
[C]
[D]
Question49.
Aparticleismovedfrom(0,0)to(a,a)underaforce
fromtwopaths.Path1isOPandpath2isOQP.LetW1andW2
betheworkdonebythisforceinthesetwopaths.Then,
[A]
[B]
[C]
[D]
W1=W2
W1=2W2
W2=2W1
W2=4W1
Question50.
Ablockofmass50kgisprojectedhorizontallyonaroughhorizontalfloor.Thecoefficientoffrictionbetweentheblockandtheflooris
0.1.Theblockstrikesalightspringofstiffnessk=100N/mwithavelocity2m/s,themaximumcompressionofthespringis:
[A]
[B]
[C]
[D]
1m
2m
3m
4m
Question51.
Twoparticles1and2areallowedtodescendontwofrictionlesschordsOPandOQfromO.Theratioofthespeedsoftheparticles1
and2respectivelywhentheyreachonthecircumferenceis:
[A]
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QuestionRevision
[B]
[C]
[D]
Question52.
Abodyismovedfromrestalongastraightlinebyamachinedeliveringconstantpower.Theratioofdisplacementandvelocity(s/v)
varieswithtimetas:
[A]
[B]
[C]
[D]
Question53.
Auniformrodoflengthliskeptverticallyonaroughhorizontalsurfaceatx=0.Itisrotatedslightlyandreleased.Whentherodfinally
fallsonthehorizontalsurface,thelowerendwillremainat:
[A]
[B]
[C]
[D]
x=l/2
x>l/2
x<l/2
x=0
Question54.
Fourparticlesofmassesm1=2m,m2=4m,m3=mandm4areplacedatfourcornersofasquare.Whatshouldbethevalueofm4,so
thatthecentreofmassofallthefourparticlesareexactlyatthecentreofthesquare?
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[A]
[B]
[C]
[D]
QuestionRevision
2m
8m
6m
Noneofthese
Question55.
Whatisthepoweroutputofa
usableenergy?(Avogadronumber
[A]
[B]
[C]
[D]
reactorifittakes16daystouseup864gmsoffuelandifeachfissionproduces235MeVof
/mol)
10MW
60MW
600MW
100MW
Question56.
Ifaballmovingwithvelocityuovertakesanotherballoftwiceitsownmassmovingwithoneseventhofitsvelocityandifthecoefficient
ofrestitutionbetweenthemis
[A]
[B]
[C]
[D]
,thevelocityofthefirstballafterstrikingthesecondballis:
u/2
Zero
u/4
3u/4
Question57.
Aballfallsvertically2sandhitsaplaneinclinedat30otothehorizontal.Ifcoefficientofrestitutionis5/8,thenfindthetimeafterwhichit
hitstheplaneagain(g=10m/s 2)
[A]
[B]
[C]
[D]
2s
4s
2.5s
5s
Question58.
Aparticleofmass0.5kgmovesalongaliney=x2(x,yinmetres)withaconstantspeed6m/s.Angularmomentumoftheparticle
abouttheorigin,inmagnitude,is:
[A]
kgm2/s
[B]
[C]
4kgm2/s
kgm2/s
[D]
kgm2/s
Question59.
AuniformsolidcylinderofradiusrstartsrollingwithoutslippingdownfromthetopofafixedsphereofradiusR.Theangularvelocityof
thecylinderatthemomentitbreaksoffthespherewillbe:
[A]
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QuestionRevision
[B]
[C]
[D]
Question60.
Asolidsphereisrotatinginfreespace.Iftheradiusofsphereisincreasedkeepingmasssamewhichoneofthefollowingwillnotbe
affected?
[A]
[B]
[C]
[D]
Angularvelocity
Angularmomentum
Momentofinertia
Rotationalkineticenergy
Question61.
Iftwocurveswhoseequationsare
and
intersectinfourconcyclicpoints,then:
[A]
[B]
[C]
[D]
Question62.
Tangentsaredrawnto
fromanyarbitrarypointsPontheline
.Thecorrespondingchordofcontact
passesthroughafixedpointwhosecoordinatesare
[A]
[B]
[C]
[D]
Question63.
Thenumberofcommontangentstothecircles
[A]
[B]
[C]
[D]
and
is:
0
1
3
4
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Question64.
Circlesaredrawnthroughthepoints(2,0)tocutinterceptoflength5unitsonthexaxis.Iftheircentreslieinthefirstquadrant,thentheir
equationis:
[A]
[B]
[C]
[D]
Question65.
Therangeofvaluesofrforwhichthepoint
,cutoffbytheline
isaninteriorpointofthemajorsegmentofthecircle
,is:
[A]
[B]
[C]
[D]
Noneofthese
Question66.
TangentsPAandPBaredrawnto
fromthepointP(4,4).AreaofthetriangleOAB,'O'beingtheorigin,isequalto:
[A]
[B]
[C]
[D]
Question67.
Locusofmidpointofchordsof
thatpassthroughtheorigin,is:
[A]
[B]
[C]
[D]
Question68.
TangentsPAandPBdrawnto
fromanyarbitrarypoint'P'ontheline
.LocusofmidpointofchordABis:
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QuestionRevision
[A]
[B]
[C]
[D]
Noneofthese
Question69.
Thedomainofthefunction,
[A]
[B]
[C]
[D]
Question70.
Therangeofthefunction
is:
[A]
[B]
[C]
[D]
Noneofthese
Question71.
Afunctionwhosegraphissymmetricalabouttheyaxisisgivenby:
[A]
[B]
[C]
[D]
sin(sin(sinx))
Question72.
If
[A]
thendomainoff(x)is:
R
[B]
[C]
[D]
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Question73.
If
[A]
[B]
[C]
[D]
isafunctionsatisfyingtheproperty
,thentheperiodoff(x)is:
2
4
8
12
Question74.
thenthenumberofsolutionsof
[A]
[B]
[C]
[D]
is:
1
2
3
4
Question75.
f:
where
,(where[.]denotestheG.I.F.),isanoddfunction.Complete
setofvaluesof'a'is:
[A]
[B]
[C]
[D]
Question76.
Theminimumvalueof
[A]
[B]
[C]
[D]
isequalto:
1
2
3
Zero
Question77.
Let
.Then:
[A]
[B]
[C]
[D]
Noneofthese
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QuestionRevision
Question78.
Ifthefunctionf(x)isdefinedby
and
(repeatedrtimes),then
isequalto:
[A]
[B]
[C]
[D]
Question79.
Thevalueof
[A]
[B]
[C]
[D]
is:
1
0
Question80.
Letzandwbetwononzerocomplexnumbersuchthat
[A]
[B]
[C]
and
.Thenzequal
w
w
[D]
Question81.
If
,wherezisacomplexnumber,thenvaluesof
is:
[A]
[B]
[C]
[D]
12
18
54
6
Question82.
Let
,anda,b,c,x,y,zbenonzerocomplexnumberssuchthat:
,
Thenthevalueof
[A]
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[B]
[C]
[D]
QuestionRevision
2
3
4
Question83.
If
thenvalueof
cannotexceed:
[A]
[B]
[C]
[D]
Question84.
If
then
equals:
[A]
[B]
[C]
[D]
1
0
Question85.
If
aretherootsof
,and
isacuberootofunity,thenvalueof
is:
[A]
[B]
3q
[C]
[D]
Question86.
If
isanimaginarycuberootofunity,thenthevalueof
is:
[A]
[B]
[C]
[D]
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Question87.
If
[A]
[B]
[C]
[D]
arecomplexnumberssuchthat
.Then
is:
Equalto1
Lessthan1
Greaterthan3
Equalto3
Question88.
Complexnumber
isequalto:
[A]
[B]
[C]
[D]
Question89.
If
[A]
[B]
[C]
[D]
,then
reducesto:
2
3
4
5
Question90.
If
[A]
[B]
[C]
[D]
,forx>2thenf(11)isequalto:
7/6
5/6
6/7
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