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QuestionRevision
Question1.
When1moleofanidealgasiscompressedtohalfofitsinitialvolume,itstemperaturebecomesdouble.Thenthechangeinentropy
wouldbe:
[A]
[B]
[C]
[D]
Question2.
Theprecipitateof
isobtainedwhenequalvolumesofthefollowingaremixed:
[A]
[B]
[C]
[D]
Question3.
Thegeometrywithrespecttothecentralatomofthefollowingmoleculesare:
[A]
[B]
[C]
[D]
Planar,pyramidal,planar
Planar,pyramidal,pyramidal
Pyramidal,pyramidal,pyramidal
Pyramidal,planar,pyramidal
Question4.
Amongst
thecompoundswithgreatestandleastioniccharacterrespectivelyare:
[A]
[B]
[C]
[D]
Question5.
Oxygenismoreelectronegativethansulphur,yet
isacidicinnaturewhile
[A]
moleculeareassociatedduetointermolecularhydrogenbonding
[B]
hashigherboilingpointthan
[C]
bondisweakerthan
[D]
isneutral,because:
bond
isgasatordinarytemperaturewhile
isliquid
Question6.
FromseparatesolutionoffoursodiumsaltsNaW,NaX,NaYandNaZhadpH7.0,9.0,10.0and11.0respectively.Wheneachsolution
was0.1M,thestrongestacidis:
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[A]
[B]
[C]
[D]
QuestionRevision
HW
HX
HY
HZ
Question7.
AsampleofanidealgaswithinitialpressurePandvolumeVistakenreversiblythroughanisothermalprocessduringwhichentropy
changeisfoundtobe
.TheuniversalgasconstantisR.Thentheworkdonebythegasisgivenby:
[A]
[B]
[C]
[D]
Question8.
Sodiumperoxideisusedtopurifytheairinsubmarinesandconfinedspacesbecause:
[A]
Itremoves
andproduces
[B]
Itdecomposestoform
[C]
[D]
Itreactswithoxygentoformsodiumsuperoxide
Allofthese
Question9.
ThespecieshavingbondorderdifferentfromthatinCOis:
[A]
[B]
[C]
[D]
Question10.
AnammoniaammoniumchloridebufferhasapHvalueof9with
KOHbeaddedto200mLbuffersolution
[A]
[B]
[C]
[D]
.ByhowmuchthepHwillchangeif75mLof0.1M
0.2
0.3
0.1
0.4
Question11.
When200mLof1MNaOHsolutionismixedwith100mLof1MHCland100mLof1M
temperature,thetemperaturesoftwomixturesriseby
solutionsseparatelyataconstant
oC.Then,
[A]
[B]
[C]
[D]
Unpredictable
Question12.
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Thetwoequilibria
aresimultaneouslywithequilibriumconstant
respectively.theratioof
inthesolutionis:
[A]
Directlyproportionaltotheconcentrationof
[B]
Inverselyproportionaltotheconcentrationof
[C]
Directlyproportionaltothesquareoftheconcentrationof
[D]
Inverselyproportionaltothesquareoftheconcentrationof
Question13.
Selectthecorrectstatement:
[A]
Perxenateionis
withoctahedralgeometry
isbentmoleculewith3lonepairs(I.p)
[B]
allcontainsonelonepaironly
[C]
[D]
Noneofthese
Question14.
Thermalstabilityof
isinorder:
[A]
[B]
[C]
[D]
Question15.
Whichofthefollowingrepresentscorrectrelationshipofbondlengths?
[A]
[B]
[C]
[D]
Question16.
Calculatetheratioof
and
inamixtureof
and0.1MHF
:
[A]
[B]
[C]
[D]
Question17.
Assumethatareactionhas
.Atwhattemperaturerangewillitchangefromspontaneousto
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nonspontaneous?
[A]
[B]
[C]
[D]
Question18.
TheratioofdissociationconstantoftwoweakacidsHAandHBis4.Atwhatmolarconcentrationratio,thetwoacidswillhavesamepH:
[A]
[B]
[C]
[D]
2
0.5
4
0.25
Question19.
Amongthefollowing,theparamagneticcompoundis:
[A]
[B]
[C]
[D]
Question20.
Thepairofcompoundswhichcannotexisttogetherinsolutionis:
[A]
[B]
[C]
[D]
Question21.
When1moleofgasisheatedatconstantvolume,temperatureisraisedfrom298to308K.Heatsuppliedtothegasis500J.Thenwhich
statementiscorrect?
[A]
[B]
[C]
[D]
Question22.
WhichofthefollowingstatementisincorrectforH3BO 3?
[A]
[B]
[C]
[D]
ItisaLewisacid
ItisatriproticArrheniusacid
Itinvolves
backbonding
Boronhasincompleteoctetofelectrons
Question23.
Whichofthefollowingalkalineearthmetalhydroxidesistheleastsolubleinwater?
[A]
[B]
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QuestionRevision
[C]
[D]
Question24.
isanunstableyelloworangesolidand
The
bondlengthin
and
isacolourlessliquid,bothhave
bond.
respectivelyis:
[A]
[B]
[C]
[D]
Question25.
Toacertainvolumeofaweakmonobasicacid,when20mLofNaOHsolutionisadded,pHoftheresultingsolutionwasfoundtobe3.7
whereaswhen30mLofthesameNaOHisaddedtothesamevolumeoftheacidfromsamestock,pHwasfoundtobe4.18.Determine
oftheacid.
[A]
[B]
[C]
[D]
Question26.
Forapuresubstance,aplotofGibb'sfreeenergy(G)againsttemperatureatconstantpressureis:
[A]
[B]
[C]
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[D]
Question27.
Onemoleofnonidealgasundergoesachangeofstate
internalenergy
[A]
[B]
[C]
[D]
to
withachangein
.ThechangeinenthalpyoftheprocessinLatm:
43
57
42
38
Question28.
Thecorrectsolubilityorderis(are):
[A]
[B]
[C]
[D]
Question29.
Amongst
,thenonplanarspeciesare:
[A]
[B]
[C]
[D]
Question30.
AnidealmonatomicgasistakenroundthecycleABCDAasshowninfigure.Theworkdoneduringcycleis:
[A]
[B]
PV
2PV
[C]
[D]
Zero
Question31.
Athickropeofdensity
andlengthLishungfromarigidsupport.Theincreaseinlengthoftheropeduetoitsownweightis:(Yis
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theYoung'smodulus)
[A]
[B]
[C]
[D]
Question32.
Young'smodulusofbrassandsteelare
and
respectively.Abrasswireandasteelwireofthe
samelengthareextendedby1mmunderthesameforce.TheradiiofthebrassandsteelwiresareRBandRS,respectively.Then:
[A]
[B]
[C]
[D]
Question33.
Twoblocksofmasses1kgand2kgareconnectedbyametalwiregoingoverasmoothpulleyasshowninthefigure.Thebreaking
stressofthemetalis
If
,thenwhatshouldbetheminimumradiusofthewireusedifitisnot
tobreak?
[A]
[B]
[C]
[D]
0.5mm
1mm
1.5mm
2mm
Question34.
TwometallicspheresS1andS2aremadeofthesamematerialandhavegotidenticalsurfacefinish.
ThemassofS1isthricethatofS2.Boththespheresareheatedtothesamehightemperatureandplacedinthesameroomhavinglower
temperaturebutarethermallyinsulatedfromeachother.TheratiooftheinitialrateofcoolingofS1tothatofS2is:
[A]
[B]
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[C]
[D]
Question35.
Adiatomicgasiscompressedadiabaticallyto
ofitsinitialvolume.IfinitialtemperatureisTKandfinaltemperatureisaTKthenthe
valueofais:
[A]
[B]
[C]
[D]
2
3
4
Noneofthese
Question36.
Startingwiththesameinitialconditions,anidealgasexpandsfromvolumeV1toV2inthreedifferentways,theworkdonebythegasis
W1iftheprocessispurelyisothermal,W2ifpurelyisobaricandW3ifpurelyadiabatic,then:
[A]
[B]
[C]
[D]
Question37.
Initially,thespringisunstretched.Thegasisallowedtoexpand.Atequilibrium,thecompressionofthespringis
gasisW,changeininternalenergyis
.Workdonebythe
.Then:
[A]
[B]
[C]
[D]
Question38.
Asealedtankcontainingaliquidofdensity
betweentwopointsAandBwillbe:
moveswithhorizontalaccelerationaasshowninthefigure.Thedifferenceinpressure
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[A]
[B]
[C]
[D]
Question39.
Ametalpieceofmass160gliesinequilibriuminsideaglassofwater.Thepiecetouchestheglassatsmallnumberofpoints.Ifthe
densityofthemetalis8000kg/m3,thenthenormalforceexertedbythebottomoftheglassonthemetalpieceis:
[A]
[B]
[C]
[D]
2N
8N
0.16N
1.4N
Question40.
AhollowsphereofmassM=50kgandradius
isimmersedinatankofwater(density
).
ThesphereistiedtothebottomofatankbytwowiresAandBasshown.TensioninwireAis:
[A]
[B]
[C]
125N
[D]
250N
Question41.
InacylindricalwatertanktherearetwosmallholesQandPonthewallatadepthof
of
fromtheupperlevelofwaterandataheight
fromthelowerendofthetank,respectively,asshowninthefigure.Watercomingoutfromboththeholesstrikethegroundat
thesamepoint.Theratioof
and
is:
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[A]
[B]
[C]
QuestionRevision
1
2
[D]
Question42.
Anidealfluidatthepipeasshowninthefigure.Thepressureinthefluidatthebottom
velocityofthetop
[A]
[B]
[C]
[D]
.Thentheratioofareas
isthesameasitisatthetop
the
is:
2:1
4:1
8:1
4:3
Question43.
AcylindricaltankofheightHisopenatthetopendandithasaradiusr.waterisfilledinituptoaheightofh.Thetimetakentoempty
thetankthroughaholeofradius
initsbottomis:
[A]
[B]
[C]
[D]
Noneofthese
Question44.
Apieceofmaterialweighing50.0giscoatedwith6.3gofwaxofspecificgravity0.9.Ifthecoatedpieceweighs16.3ginwater,thenthe
densityofthematerialis:
[A]
[B]
[C]
[D]
1.5
2.1
2.35
4.6
Question45.
AUtubeofuniformcrosssectionispartiallyfilledwithmercury.Waterispouredintoonelimbsothatmercurylevelgoesdownby1cm
onthatside.Theheightofthewatercolumnis:
[A]
[B]
[C]
[D]
13.6cm
27.2cm
0.136cm
0.272cm
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QuestionRevision
Question46.
Aconicalbodyofheighthisfloatinginbetweentwoliquidlayershavingdensity
theheight
.If
isthedensityofthecone,then
inthetopliquid:
[A]
[B]
[C]
[D]
Question47.
Atankfilledwithwaterhasfiveholesonitssides,spacedequallysuchthat1isatthetopand5isatbottom.Thetankisplacedona
standofequalheightasthetank.Whenthetankisfull,therangeonthegroundismaximumforoutflowfrom:
[A]
[B]
[C]
[D]
5
4
3
2or1
Question48.
Awoodenblockwithbaseareaaandheight
isfloatingonwaterinawatertankwithlength
Theblockcarriesnidenticalstoneseachofvolume
immersed.
timesthevolumeoftheblock.
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Thevalueofncanbe:
[A]
[B]
[C]
[D]
600
700
800
900
Question49.
Awoodenblockwithbaseareaaandheight
isfloatingonwaterinawatertankwithlength
Theblockcarriesnidenticalstoneseachofvolume
immersed.
timesthevolumeoftheblock.
Whenoneamongthenstoneswasdroppedintothewater,thedepthofimmersionoftheblockbecomes:
[A]
[B]
[C]
[D]
Question50.
Twoadiabaticexpansionsofnmoleofsamegasareshown.If
then
is
[A]
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[B]
[C]
[D]
Question51.
AandBaretwoidenticalcylinders,thefirstwithamovablesmoothpistonandthesecondwithafixedone.Bothcontainthesame
amountofanidealmonoatomicgasat27oC.Whenequalamountofheatisgiventoeach,itisfoundthattheriseintemperatureofthe
gasinAisT.NowthetemperatureofBis:
[A]
[B]
[C]
[D]
T
Zero
Question52.
Theratioofrmsvelocityofmoleculesoftwosystemsofmonoatomicgaseschangesfrom1:2to3:4whenthefirstadiabatically
compressedandthesecondsystemisisothermallyexpanded.Theratiooffinaltoinitialvolumesintheadiabaticprocessis:
[A]
[B]
[C]
[D]
Question53.
IfworkdoneinprocessABisW,workdoneinprocessABCAis:
[A]
[B]
[C]
0.3W
0.7W
[D]
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QuestionRevision
Question54.
Onemoleofanidealgas(monoatomic)attemperature
expandsslowlyaccordingtolaw
(cisconstant).Iffinaltemperatureis
.Heatsuppliedtogasis:
[A]
[B]
[C]
[D]
Question55.
TheworkdonebyonemolegasinthecyclicprocessshowningraphisW.Then:
[A]
[B]
[C]
[D]
Question56.
Aheatedbodyemitsradiationwhichhasmaximumradiationnearawavelength
.Theemissivityofthematerialis0.75.The
absolutetemperatureofthebodyisdoubled:
I.Themaximumintensityofradiationwillbenearwavelength
II.Themaximumintensityofradiationwillbenearwavelength
III.Thetotalenergyemittedwillincrease16times
IV.Thetotalenergyemittedwillincrease12times
Whichoftheabovestatementsis/aretrue:
[A]
[B]
[C]
[D]
IandIII
IIandIII
IIandIV
IandIV
Question57.
Apendulumclockkeepscorrecttimeat20oC.Thecorrectiontobemadeduringsummerperdaywheretheaveragetemperatureis
40oC,
[A]
[B]
[C]
[D]
willbe:
5.64s
6.64s
7.64s
8.64s
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Question58.
Acalorimeter(ofwaterequivalent50g)contains250gofwaterand50goficeat0oC.30gofwaterat80oCisaddedtoit.Thefinal
conditionofthesystemwillbe:
[A]
[B]
[C]
[D]
Thetemperatureofthesystemwillbe4.2oC
Thetemperatureofthesystemwillstillbe0oCandtheentireicewillmelt
Thetemperaturewillbe0oCandhalfoftheicewillmelt
Thetemperaturewillbe0oCand30goficewillmelt
Question59.
AwallhastwolayersAandB,eachmadeofdifferentmaterials.Thethicknessofboththelayersisthesame.Thethermalconductivity
ofAis
.Thetemperatureacrossthewallis20oC.Inthermalequilibrium:
[A]
[B]
[C]
[D]
ThetemperaturedifferenceacrossA=150oC
RateofheattransferacrossAismorethanacrossB
Rateofheattransferacrossbothissame
TemperaturedifferenceacrossAis15oC
Question60.
Inthegivenfigure,twoconductingsheetswiththermalresistanceRand3Rareshown.Thetemperatureoftheinterface
[A]
[B]
[C]
[D]
is:
20oC
60oC
75oC
80oC
Question61.
Thenumberofwaysinwhichthelettersoftheword'PERSON'canbeplacedinthesquaresofthegivenfiguresothatnorowremains
emptyis:
[A]
[B]
[C]
[D]
Question62.
Thenumberofevendivisorsofthenumber
[A]
[B]
[C]
[D]
is:
72
54
18
36
Question63.
Thenumberofwaysofchoosingacommitteeoftwowomenandthreemenfromfivewomenandsixmen,Mr.Arefusetoserveonthe
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QuestionRevision
committeeifMr.BisamemberandMr.Bcanonlyserve,ifMissCisthememberofthecommitteeis:
[A]
[B]
[C]
[D]
60
84
124
120
Question64.
ABCDisaconvexquadrilateraland3,4,5and6pointsaremarkedonthesidesAB,BC,CDandDA,respectively.Thenumberof
triangleswithverticesondifferentsidesis:
[A]
[B]
[C]
[D]
270
220
282
342
Question65.
ApersonbuyseightpacketsofTIDEdetergent.Eachpacketcontainsonecoupon,whichbearsoneofthelettersofthewordTIDE.Ifhe
showsallthelettersofthewordTIDE,hegetsonefreepacket.Ifhegetsexactlyonefreepacket,thenthenumberofdifferentpossible
combinationsofthecouponsis:
[A]
[B]
[C]
[D]
Question66.
Let
then
bethedivisorsofpositiveinteger'n'(including1andn).If
isequalto:
[A]
[B]
[C]
[D]
Question67.
Thetotalnumberofwaysinwhich
numberofidenticalballscanbeputinnnumberedboxes
suchthat
boxcontainsatleastinumberofballsis:
[A]
[B]
[C]
[D]
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Question68.
Let
denotethenumberofwaysinwhichkidenticalballscanbecolouredwithncolourssothatthereisatleastoneballof
eachcolour.Then
mustbeequalto:
[A]
[B]
[C]
[D]
Question69.
ThetotalnumberofwaysinwhichthreedistinctnumbersinA.P.canbeselectedfromtheset
[A]
[B]
[C]
[D]
isequalto:
66
132
198
99
Question70.
Thetotalnumberofwaysofselectingtwodistinctnumbersfromtheset
sothattheirsumisdivisibleby3is
equalto:
[A]
[B]
[C]
[D]
Question71.
Twopacksof52cardsareshuffledtogether.Thenumberofwaysinwhichamancanbedealt26cardssothathedoesnotgettwo
cardsofthesamesuitandsamedenominationis:
[A]
[B]
[C]
[D]
Question72.
nisselectedfromtheset
andthenumber
isformed.Totalnumberofwaysofselectingnso
thattheformednumberisdivisibleby4isequalto:
[A]
[B]
[C]
[D]
50
49
48
51
Question73.
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If
[A]
[B]
[C]
[D]
QuestionRevision
denotesthesumoffirst'n'termsofanA.P.and
,thenthevalueisnis:
21
15
16
19
Question74.
If
[A]
formtwoarithmeticprogressionsofthesamecommondifference,then
p,b,rareinA.P.
areinA.P.
[B]
[C]
areinA.P.if:
p,b,rareinG.P.
areinH.P.
[D]
Question75.
ConsideranA.P.
[A]
[B]
[C]
[D]
suchthat
and
,thenthevalueof
is:
5
7
9
Question76.
If
[A]
[B]
[C]
[D]
,thennisequalto:
256
255
254
257
Question77.
Concentriccirclesofradii1,2,3,...........,100cmaredrawn.Theinteriorofthesmallestcircleiscolouredredandtheangularregionsare
colouredalternatelygreenandred,sothatnotwoadjacentregionsareofthesamecolour.Then,thetotalareaofthegreenregionsin
sq.cmisequalto:
[A]
[B]
[C]
[D]
Question78.
If
denotesthesumoftheseries
,
and
,then
thesumoftheseries
intermsof
is:
[A]
[B]
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[C]
[D]
Question79.
Thevalueof
isequalto:
[A]
[B]
[C]
[D]
Question80.
If
[A]
[B]
[C]
[D]
for
and
,then
isequalto:
2001
0
1
Question81.
If
,then
isequalto:
[A]
[B]
2n
[C]
[D]
Question82.
Let
bethe
termandsumupto
,then
termofaseriesrespectively.Ifforanoddnaturalnumber
(mbeingevenis)is:
[A]
[B]
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[C]
[D]
Question83.
Thecoefficientof
intheexpressionof
is:
[A]
[B]
[C]
[D]
Question84.
Ifintheexpansionof
arethreeconsecutivecoefficients,thennequals:
[A]
[B]
[C]
[D]
Question85.
Thecoefficientof
intheexpansionof
are:
[A]
[B]
[C]
[D]
Noneofthese
Question86.
If
[A]
[B]
[C]
[D]
,then
equals:
10
20
210
Noneofthese
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Question87.
Thevalueof
is:[where
[A]
[B]
[C]
[D]
Question88.
Thevalueof
is:
[A]
[B]
[C]
[D]
Question89.
Thevalueof
is:
[A]
[B]
[C]
[D]
2
1
Question90.
Thevalueof
isequalto:
[A]
[B]
[C]
[D]
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