Mains 11 Safrdarjung

21/07/2015
QuestionRevision
Question1.
Whichofthefollowingsetsofreagentsisnecessarytocarryoutthefollowingconversion?
[A]
[B]
[C]
[D]
Question2.
Whatisthemajorproducts[X]ofthegivenreaction?
[A]
[B]
[C]
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[D]
Question3.
WhichofthefollowingCHbondswouldhavethesmallestbonddissociationenergy?
[A]
[B]
[C]
[D]
Question4.
Cyclohexanefloatsoversurfaceofwaterbecause:
[A]
[B]
[C]
[D]
Ithasboatshapestructure
Ithassixmemberedringslikestructure
Itisinsolubleinwater
Itislessdensethanwater
Question5.
Identifyfinalproduct[Y]inthegivensequenceofreactions.
[A]
[B]
[C]
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[D]
Question6.
200
ofanaqueoussolutionofaproteincontain1.26goftheprotein.Whichofthefollowingtechniqueismostusefulfor
determinationofmostaccuratemolarmassofprotein?
I.Techniqueofelevationofboilingpoint
II.Techniqueofosmoticpressuredetermination
III.Techniqueofdepressioninfreezingpoint
IV.Techniqueofrelativeloweringofvapourpressure
[A]
[B]
[C]
[D]
I,III
II,IV
onlyII
I,II,III,IV
Question7.
Thedisproportionationofhypochloriteintochlorateionandchloridetakesplacebyfollowingmechanism.
Whichofthefollowingiscorrectrateexpressionfordisproportionationof
into
and
[A]
[B]
[C]
[D]
Question8.
Ifwedissolve1molKCl(74.5g),in1kgwateranddetermineitsmolecularmassbyelevationinboilingpointmethodthenthe
experimentallydeterminedmolecularmassbyelevationinboilingpointmethodislowerthanthetruevalue.Thisabnormalityinmolecular
massisdueto
[A]
[B]
EvaporationofsomemoleculesofKClonboilingthesolution
DissociationofKClmoleculesinto
and
ions
[C]
Formationofcrystalsofhydratedsalt
[D]
Increaseinconcentrationofsolutiononboiling
Question9.
Colourlesssolutionof
onmixingwithyellowcoloured
solutionproduceredcolouredprecipitateof
.Ifthesetwosolutionsareseparatedbysemipermeablemembraneasshowninfiguretheninwhichofthefollowing
conditionredprecipitateof
willbeformed:
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[A]
[B]
[C]
[D]
QuestionRevision
Redprecipitateisformedinlefthandsidecompartment(I)when0.1M
solutionand0.01M
aretaken.
Redprecipitateisformedinrighthandsidecompartment(II)when0.01M
aretaken.
Redprecipitateisformedinbothcompartmentwhen0.2M
solutionand0.1M
solutionand0.1M
Redprecipitatewillnotformedinanycompartmentirrespectiveofconcentrationof
solutions
solution
solutionaretaken.
solutionand
solution.
Question10.
Forageneralreaction
,plotofconcentrationofAvstimeisgiveninfigure.Marktheincorrectstatementonthebasisof
thisgraph.
I.Orderofreactioniszeroorder
II.Unitofrateconstantistime1
III.Slopeofthecurveis
IV.Halflifeofreactionisconstant
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
OnlyI
II,I
III,I
II,III,IV
Question11.
HowwillthepHofbrine(aq.NaClsolution)beaffectedwhenitiselectrolyzedbyusingplatinumelectrode?
[A]
[B]
[C]
[D]
pHdecreases
pHincreases
pHremainunchanged
pHbecomeshalf
Question12.
Theconstituentsofwinecontain,amongothers,carbon,hydrogenandoxygenatoms.Abottleofwinewassealedabout6yearsago.To
confirmitsage,whichoftheisotopewouldyouchooseinaradioactivedatingstudy?Thehalflivesoftheisotopesare
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years,
I.
II.
years.Assumethattheactivitiesoftheisotopeswereknownatthetimethebottlewassealed.
III.
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
OnlyI
OnlyIII
BothIandII
I,IIandIII
Question13.
Whichofthefollowingphysicaltechniquesisusedforobtainingthepuresolvent(water)fromanaqueoussolution?
I.DistillationII.Freezing
IIIReverseOsmosisIVCrystallization
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
OnlyIII
IandIII
IIIandIV
I,IIandIII
Question14.
Theratioofvalueofanycolligativepropertyfor
solutiontothatof
solutionisnearly(assumecomplete
ionization)
[A]
[B]
[C]
[D]
0.57
0.29
0.30
0.08
Question15.
Intheadjacentdiagramtheelectrolyticcellcontains1Lofanaqueous1Mcopper(II)sulphatesolution.If0.4moleofelectronspasses
throughthecell,theconcentrationofcopperionsafterpassageofthechargewillbe(assumenochangeinvolumeofelectrolytesolution)
[A]
[B]
[C]
[D]
0.4M
0.8M
1.0M
1.2M
Question16.
Thereaction:
occursinthegalvaniccell:
[A]
[B]
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[C]
[D]
Question17.
Thereactionofperoxydisulphateion
withiodideion
is:
Fromthefollowingdatacollectedatacertaintemperature,determinetheratelawofthereaction.
[A]
[B]
[C]
[D]
Question18.
Considerthegeneralreaction:
andthefollowingaverageratedataoveraspecifictimeperiod
Determineasetofpossiblecoefficienttobalancethisgeneralreaction
[A]
[B]
[C]
[D]
abc
324
234
432
342
Question19.
TheequivalencepointoftitrationofHIsolutionwithKOHsolutionisdeterminedconductometricallybymeasuringtheconductanceofthe
solutionatvariousstagesofthetitrationandplottingagraph.Whichofthefollowinggraphiscorrect?
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[A]
[B]
[C]
[D]
Question20.
Themagnitude(butnotthesigns)ofthestandardreductionpotentialsoftwometalsxandyare
Whenthehalfcellsxandyareconnected,electronsflowfromxtoy.Whenxis
connectedtoaSHE,electronsflowfromxtoSHE.
Whichofthefollowingstatementsis(are)INCORRECT?
I.EoforxisnegativeandEoforyispositive
II.Thestandardemfofacellmadeupofxandyhalfcellsis0.09V.
III.EoforxispositiveandEoforyisnegative
IV.Inelectrochemicalcellmadeupofhalfcellsxandy,anodeisyhalfcellandcathodeisxhalfcell.
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
OnlyIII
OnlyI
I,IIandIII
II,IIIandIV
Question21.
Leadstoragebatteriesareratedbyamperehours,thatis,thenumberofamperestheycandeliverinanhour.Theleadanodesofa
certainleadstoragebatteryhaveatotalmassof406g.Calculatethemaximumtheoreticalcapacityofthebatteryinamperehours.
[Atomicmass:Pb=207]
[A]
[B]
[C]
[D]
52.5A.h
105A.h
150A.h
160A.h
Question22.
Whichofthefollowinghasnonzerovalueforidealliquidsolution?
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I.
II.
III.
IV.
Thecorrectchoiceis
[A]
[B]
[C]
[D]
OnlyIII
III,IV
I,II
I,II,IV
Question23.
Whichofthefollowingisusefulasanantifreeze,butitshouldberemovedfromthecarradiatorduringthesummerseason?
[A]
[B]
[C]
[D]
Ethyleneglycol
Methanol
Both(A)and(B)
Noneofthese
Question24.
Thespecificrateconstantofdecompositionofacompoundisrepresentedby
Theactivationenergyofdecompositionforthiscompoundat300Kis:
[A]
[B]
[C]
[D]
24kcal/mole
12kcal/mole
24cal/mole
12cal/mole
Question25.
Thefreezingpointdepressionconstantforwateris1.86Kkgmol1.Thefreezingpointofsolutionwhen0.01molglucoseisaddedto1kg
wateris:
[A]
[B]
[C]
[D]
Question26.
Fortheconcentrationcell
theEMF(E)ofthecellatatemperature(T)
equals:
[A]
[B]
[C]
[D]
Question27.
Whenanaqueoussolutionfreezes,
[A]
[B]
[C]
[D]
usuallyitisthesolutethatsolidifiesfirst
thesolventandthesolutesolidifyatthesametime
itisthewaterthatsolidifiesfirst
thevapourpressureofthesolventbecomesabnormallyhigh
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Question28.
is150ohm1cm2andtheionicconductancesof
Theequivalentconductanceofaninfinitelydilutesolutionof
ionsare198
and
solutionis9.6
[A]
[B]
[C]
[D]
and
respectively.Iftheequivalentconductanceofa0.01N
,whatwillbeitsdegreeofdissociation?
0.35
0.035
0.0035
0.17
Question29.
Forafirstorderhomogeneousgaseousreaction
Theinitialpressurewas
whilepressureaftertimet,wasp.Whichofthefollowingiscorrectexpressionofrateconstantk?
[A]
[B]
[C]
[D]
Question30.
Considerthefollowingconversionandidentifycorrectorderofsequenceofreactions.
[A]
[B]
[C]
[D]
A
B
C
D
Question31.
Somewhereinacircuitthereisaresistor.Aconstantcurrentisflowinginthedirectionasindicatedinfigure.IngoingfromAtoB,we
measure
.Whatdowefind?
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[A]
[B]
[C]
[D]
QuestionRevision
Apositivevalue
Anegativevalue
Zero
Wedonothaveenoughinformationtoanswer
Question32.
AsolidinsulatingsphereofradiusRhasanonuniformchargedensitythatvarieswithaccordingtotheexpression
Aisaconstantandrismeasuredfromthecentreofthesphere.(
,where
unitvectorawayfromthecentre).
Theelectricfieldoutsidethesphereis:(r>R)
[A]
[B]
[C]
[D]
Question33.
,where
Theelectricpotentialinside(r<R)thesphereis:[Theelectricpotentialatinfinityisassumedtobezero]
[A]
[B]
[C]
[D]
Question34.
,where
Theelectricpotentialoutsidethesphereis:(r>R)
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[A]
[B]
[C]
[D]
Question35.
Inthesethreecircuitsallthebatteriesareidenticalandhavenegligibleinternalresistance,andalllightbulbsareidentical.Rank5light
bulls
inorderofbrightnessfrombrightesttodimmest.
[A]
[B]
[C]
[D]
Noneofthese
Question36.
Aparallelplatecapacitorhasplatearea
andseparation
.Itischargedtopotentialdifference
Thechargingbatteryisdisconnectedandtheplatesarepulledaparttothreetimestheinitialseparation.Theworkrequiredtoseparate
theplatesis:
[A]
[B]
[C]
[D]
Question37.
AnAmmeterhasresistance
andrangeI.Whatresistanceshouldbeconnectedinparallelwithittoincreaseitsrangeto
[A]
[B]
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[C]
[D]
Question38.
Considerthesituationshowninfigure.Theswitchisclosedatt=0whenthecapacitorsareuncharged.ThechargeonthecapacitorC1
asafunctionoftimet
[A]
[B]
[C]
[D]
Question39.
Twoidenticalconductingspheresareheldatadistancedapartfromeachother.Thechargeonthefirstsphereis
onthesecondsphereis
Thecharge
Theelectrostaticforcebetweenthetwosphereis8N.Now,supposeaverythinconductingwireis
brieflyattachedtoconnectthetwospheresandthenremoved.Whatistheelectrostaticforcebetweenthetwospheres(inN)afterthis
hasbeendone?
[A]
[B]
[C]
[D]
Increases
Decreases
Remainssame
Cannotbesaid
Question40.
Aresistancecapacitornetworkisshowninthefigure.ThechargeonthecapacitorsC1andC2areQ 1andQ 2respectively.Thevalues
ofQ 1andQ 2are:
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[A]
[B]
[C]
[D]
Question41.
Aparallelplatecapacitorischargedandchargingbatteryisremoved.Iftheplatesofcapacitorarenowmovedfartherapartbyinsulating
handles.ChoosetheCORRECTalternative:
[A]
[B]
[C]
[D]
Chargeoncapacitorincreases
Potentialdifferenceacrosscapacitorremainssame
Capacitanceincreases
Energystoredincapacitorincreases
Question42.
Apointchargeqisplacedatadistance2rfromthecentreOofaconductingunchargedsphereofradiusr.Potentialofinducedcharges
atpointP(lyinginalinejoiningthepointchargeandcentreofsphere)is:
[A]
[B]
[C]
[D]
Noneofthese
Question43.
Acircularportioniscutoutofadiscofthicknesst,itsresistivityis
andradiiofdiscareaandb
Thentheequivalent
resistancebetweenthetwocylindricalsurfacesis:
[A]
[B]
[C]
[D]
Question44.
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Asolidconductingspherehasacharge
andissurroundedbyaneutralconcentrichollowconductingsphericalshellofdouble
theradius.ThepotentialdifferencebetweenthesolidsphereandtheshellisV.Theshellis,nowgivenacharge
thenew
potentialdifferencebetweenthemwillbe:
[A]
[B]
[C]
[D]
Question45.
Threechargedcapacitors,
andtwoopenswitches,S1andS2areassembledintoa
networkwithinitialvoltagesandpolarities,asshown,Finalstatusofthenetworkisattainedwhenthetwoswitches,S1andS2areclosed.
ThenthefinalchargeoncapacitorC2(in
[A]
[B]
[C]
[D]
),isclosestto:
Zero
410
1200
1360
Question46.
Forthecircuitshowsinthefigure,thepowerdissipatedinthe
[A]
[B]
[C]
[D]
resisteris:
36W
18W
Zero
11W
Question47.
Figureshowsthreesimilarcapacitorsconnectedtoabatteryforalongtimeasshowninfigurewhenswitch(s)isat1.Nowswitchis
thrownfrompoint1to2foralongtimethenworkdonebythebatteryforthisprocessis:
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[A]
[B]
[C]
[D]
Question48.
Inaparallelplatecapacitor,theregionbetweentheplatesisfilledbyadielectricslab.Thecapacitorisconnectedtoacellforsufficiently
longtime.Nowtheslabistakenoutslowly.Whiletheslabisbeingtakenout,whichofthefollowingiscorrect:
[A]
[B]
[C]
[D]
Somechangeisdrawnfromthecell
Noworkisdonebyanexternalagentintakingtheslabout
Somechargeisreturnedtothecell
Thepotentialdifferenceacrossthecapacitorisreduced.
Question49.
SixidenticalplateseachhavingareaAareplacedatequalseparationsd.ThentheequivalentcapacitancebetweenAandBis:
[A]
[B]
[C]
[D]
Noneofthese
Question50.
ThechangeincurrentthroughbranchAB,ifa
resistanceisconnectedtotheexisting
resistance(inCD)is
findthevalueofx.
[A]
[B]
[C]
[D]
3
2
1
5
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Question51.
Threeidenticalcapacitorsareconnectedtogetherforthesamevoltagetoeverycombination,theonethatstoresmaximumenergyis:
[A]
[B]
[C]
[D]
Thethreeinparallel
Thethreeinseries
Twoinparallelwiththethirdinserieswithit
Twoinserieswiththethirdinparallelwithit
Question52.
AbatteryofemfEisconnectedtoasystemasshowninfigure.TowhatmaximumchargewillthecapacitorCbefinallycharged?
(Neglectthebattery'sinternalresistance)
[A]
[B]
[C]
[D]
Question53.
ConsideranRCcircuitasshownbelow:
Thecapacitanceofthecapacitorshownis:
[A]
[B]
[C]
[D]
units
units
units
units
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Question54.
Choosethecorrectstatement:
I.Beforetheswitchwasclosed,10Vbatterywasgettingdischargedand6Vwasgettingcharged
II.Justaftertheswitchisclosed,boththebatteriesaredischarging.
III.Afteralongtime,batteryof10Vwillbegettingdischargedand6Vbatterywillbegettingcharged.
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
I,II,III
IandIII
IandII
IIandIII
Question55.
Thecurrentthrough10Vbatteryjustaftertheswitchisputonis:
[A]
[B]
0A
[C]
[D]
Question56.
Twocapacitorsofcapacitances
chargesonthecapacitors,then
areconnectedinparallelacrossabattery.If
respectivelybethe
willbeequalto:
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[A]
[B]
[C]
[D]
Question57.
Forthecircuitshowninthefigurethepotentialdifferencebetweenpoints
is:
[A]
[B]
[C]
[D]
Question58.
Twocapacitorsofcapacitance
areconnectedinseriesacrossa90VDCsupply.Now,ifthesupplyvoltageis
removedandthecapacitorsareconnectedinparallelsuchthatpositiveplatesareconnectedtogether,thefinalchargeonthe
capacitoris:
[A]
[B]
[C]
[D]
Question59.
Inthegivencircuit,
Volts.Then:
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Volts
[A]
Volts
[B]
[C]
[D]
Chargeon
capacitoris
E=10Volts
Question60.
Figureshowsameterbridge,wireAChasuniformcrosssection.ThelengthofwireACis
andYisacoil.WhenYisimmersedinmeltingicethenullpoint
isat
.Xisastandardresistorof
frompointA.WhenthecoilYisheatedto100oCa
resistorhastobeconnectedinparallelwithYinordertokeepthebridgebalancedatthesamepoint.Temperaturecoefficientof
resistanceofthecoilis:
[A]
[B]
[C]
[D]
Question61.
If
,thentherangef(x)is:
[A]
[B]
[C]
{0,1}
[D]
Question62.
Rangeofthefunctionfdefinedby
(where[.]and{.}respectivelydenotethegreatestintegerandthefractional
partfunction)is:
[A]
I,thesetofintegers
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[B]
[C]
[D]
QuestionRevision
N,thesetofnaturalnumbers
W,thesetofwholenumbers
Noneofthese
Question63.
Iff:
,isdefinedby
,where[x]denotestheintegerpartofx,thentherangeoff(x)is:
[A]
[B]
[C]
[D]
Noneofthese
Question64.
Let
[A]
[B]
[C]
[D]
,thentheequation
invariabley,has:
norealroot
onerealroot
tworealroots
morethantworealroots
Question65.
Ifxandysatisfytheequations
and
simultaneously,then
is:
(where[]representsintegralpartfunction)
[A]
[B]
[C]
[D]
21
9
30
12
Question66.
If
[A]
[B]
[C]
[D]
where
,thenthenumberofpointsofdiscontinuitiesof
is:
1
2
3
Infinite
Question67.
Letf(x)bedefinedasfollows:
Iff(x)iscontinuousatx=0,then(a,b)=
[A]
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[B]
[C]
(e,e)
[D]
Question68.
Let
and
Thefunction
[A]
[B]
[C]
[D]
isdiscontinuousat:
Infinitelymanypoints
Exactlyonepoint
Exactlythreepoints
Nopoint
Question69.
If
andfisinverseofg,then
isequalto:
[A]
[B]
[C]
[D]
Noneofthese
Question70.
If
[A]
[B]
and[x]isthegreatestintegerlessthanorequaltox,then
isequalto:
0
1
[C]
[D]
Question71.
Ifthefunction
hasexactlythreepointsofnonderivability,then:
[A]
[B]
[C]
[D]
Noneofthese
Question72.
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Ifforallx,yadifferentiablefunctionfisdefinedby
[A]
[B]
and
then
0
x
[C]
[D]
Question73.
Thetangentatanypointonthecurve
meetstheaxesinPandQ.ThelocusofthemidpointofPQis:
[A]
[B]
[C]
[D]
Question74.
Theslopeofthetangenttothecurve
[A]
at
is:
[B]
[C]
[D]
Question75.
Ifthenormaltothecurve
atx=0begivenbytheequation
,thenthevalueof
[A]
[B]
[C]
[D]
Question76.
Antiderivativeofthefunction
is:
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QuestionRevision
[A]
[B]
[C]
[D]
Question77.
If
then
isequalto:
[A]
[B]
[C]
[D]
Question78.
isapolynomialfunctionand
and
,then:
[A]
[B]
[C]
[D]
Noneofthese
Question79.
Theexhaustivesetofcriticalpointsofthefunction
is:
[A]
[B]
[C]
[D]
Noneofthese
Question80.
Theglobalminimumvalueoffunction
[A]
[B]
in
is:
[C]
[D]
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Question81.
Iftheintegral
[A]
[B]
[C]
[D]
thenaisequalto:
1
2
Question82.
for
then
[A]
[B]
[C]
[D]
Question83.
[A]
[B]
[C]
[D]
Question84.
[A]
[B]
[C]
[D]
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Question85.
thenA=
[A]
[B]
[C]
[D]
Question86.
Theantiderivativeof
isg(x)andthecurve
passesthrough
,thenthecurve
meetstheyaxisis:
[A]
(0,2)
[B]
[C]
(0,1)
[D]
Question87.
[A]
[B]
[C]
[D]
Question88.
[A]
[B]
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[C]
[D]
Noneofthese
Question89.
[A]
[B]
[C]
[D]
Noneofthese
Question90.
[A]
[B]
[C]
[D]
Noneofthese
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