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QuestionRevision

Question1.
Whichofthefollowingis(are)correct?
[A]

Accordingtomolecularorbitaltheorydoublebondin

consistoftwo

bonds

[B]

In

[C]

Forsquareplanarmoleculargeometryhybridizationstateofcentralatomis

[D]

Theorderoffirstionizationenthalpyvaluesofgroup13elementsisB>Al<Ga>ln<Tl

oxidationstateofnitrogenis+5anditshybridizationstateis

Question2.
Considerthereactionsoforganiccompound[X]andidentifythecorrectstatement(s).

[A]
[B]
[C]
[D]

Product[Y]existintwostereoisomericforms
Product[Z]existintwostereoisomericforms
[Y]onacidcatalyzedhydrationform[Z]
[Z]onacidcatalyzedhydrationform[Y]

Question3.
Whichofthefollowingstatement(s)is(are)correctforGlucoseandFructose?
[A]
[B]
[C]
[D]

GlucoseandFructosearefunctionalisomers
BothformsilvermirrorwithTollen'sReagent
Bothformsametypeofosazoneonreactionwithexcessofphenylhydrazine
GlucoseandFructoseareepimers

Question4.
Whichofthefollowingoxoacidsofphosphorousis(are)reducinginnature?
[A]
[B]
[C]
[D]

Question5.
ApotentialdiagramforrheniumatpH=0showsthefollowingEovalues:

ThevalueofEoforthereductionof
[A]
[B]
[C]
[D]

toRe(0)is:

+0.97V
+0.32V
+0.14V
+0.37V

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Question6.
Whichofthefollowingstatement(s)is(are)correctfordrugDopaminehavingstructureasshown?

[A]
[B]
[C]
[D]

Itisopticallyactive
Itsonemolreactswith3molesofNaOH
Itexistaszwitterioninaq.solution
Itformhydroxylderivativeonreactionwith

Question7.
ThereactionsequenceofFriedelCraftsacylationfollowedbyClemmensenreductionaccomplishes
[A]
[B]
[C]
[D]

Thetransformationofanelectronwithdrawinggroupintoanelectronreleasinggroup
Thetransformationofanelectronreleasinggroupintoanelectronwithdrawinggroup
Theformalalkylationofbenzenewithaprimaryalkylhalidewithoutrearrangement
Transformdeactivatedbenzenetoactivatedbenzene

Question8.
Inwhichofthefollowingsetsofores,allorescontainsametypeofanion?
[A]
[B]
[C]
[D]

Cinnabar,Galena,Zincblende,Argentite
Magnetite,Haematite,Cassiterite,Chromite
Dolomite,Calamine,Siderite,Calcite
Malachite,Carnallite,Cryolite,Fluorspar

Question9.
Intermolecularforcesarestrongerinliquidstatethaningaseousstate.Moleculesinliquidaresoclosethatthereisverylittleempty
spacebetweenthemandundernormalconditionsliquidsaredenserthangases.Moleculesofliquidsareheldtogetherbyattractive
intermolecularforces.Someofthephysicalpropertiesoftheliquidssuchasvapourpressure,surfacetension,viscosityandboilingpoint
arerelatedwithstrengthoftheseintermolecularforces.Theconditionoffreevapourizationthroughouttheliquidiscalledboiling.The
temperatureatwhichvapourpressureofliquidisequaltotheexternalpressureiscalledboilingtemperatureatthatpressure.

Onincreasingtemperature
[A]
[B]
[C]
[D]

vapourpressureofliquidincreases
surfacetensionofliquiddecreases
viscosityofliquiddecrease
densityofliquiddecreases

Question10.
Intermolecularforcesarestrongerinliquidstatethaningaseousstate.Moleculesinliquidaresoclosethatthereisverylittleempty
spacebetweenthemandundernormalconditionsliquidsaredenserthangases.Moleculesofliquidsareheldtogetherbyattractive
intermolecularforces.Someofthephysicalpropertiesoftheliquidssuchasvapourpressure,surfacetension,viscosityandboilingpoint
arerelatedwithstrengthoftheseintermolecularforces.Theconditionoffreevapourizationthroughouttheliquidiscalledboiling.The
temperatureatwhichvapourpressureofliquidisequaltotheexternalpressureiscalledboilingtemperatureatthatpressure.

Whichofthefollowingstatement(s)is(are)correctformostofthepureliquids?
[A]
[B]
[C]

Boilingdoesnotoccurwhenliquidisheatedinaclosedvessel
Atcriticaltemperature,densityofliquidanddensityofvapourissame
Liquidsathighaltitudesboilatlowertemperaturesincomparisontothatatsealevel

[D]

Entropychangeofvapourization

isalmostsameformostoftheliquidexceptHbondedliquid

Question11.
Potassiumpermanganateisastrongoxidizingagent,oxidizesquantitativelymostofthecommonreducingagent.Theintensepurple
colourofpermanganateionserveasaselfindicator,onedropinexcesswillimpartadistinctcolourtoalargevolumeofsolution.
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Certainamountofapureironcontainingcompoundwasdissolvedinsulphuricacidsolutionandthentitratedwithstandardpermanganate
solution.Thetitrationrequired34.5mLof0.108Mstandardpermanganatesolution.Whichofthefollowingisironcontainingcompound?
[A]

1.356g

[B]

1.356g

[C]

2.161g

[D]

1.356g

Question12.
Potassiumpermanganateisastrongoxidizingagent,oxidizesquantitativelymostofthecommonreducingagent.Theintensepurple
colourofpermanganateionserveasaselfindicator,onedropinexcesswillimpartadistinctcolourtoalargevolumeofsolution.

Indiluteaqueous

isoxidizedby

.Forthisreactionwhichofthefollowing

statement(s)is(are)correct?
[A]

Onemoleofcomplexiononoxidationgives5moleofelectrons

[B]

Onemoleof

[C]

Onemoleofcomplexiononoxidationgives3moleofelectron

[D]

Theratiooftherateofchangeof

iononreductiongain5moleofelectrons
totherateofchangeof

is8:1

Question13.
Thesumofnumberof

particle(s),generatedinthefollowingradioactivedecayprocess,are_________.

Question14.
Howmanyisomers(excludingstereoisomers)ofthealkanehavingmolecularmass100canbepreparedbycatalytichydrogenationof
alkene?

Question15.
HowmanyofthefollowingdisproportionatewhentreatedwithNaOH?

Question16.
Findthenumberoflonepairofelectronsinmainorganicproductofthereactiongivenbelow:

Question17.
Thekineticsofthereaction
concentrationsof

inliquidbrominemediumwasmeasuredindependentlyforthreedifferent
,0.11,0.07and0.05molL1.Thehalflifeofthereactionwasfoundtobe4.5hoursforallthese

concentrations.Theorderofthereactionis________.
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Question18.
ThesumofcoordinationnumberandoxidationnumberofthemetalMinthecomplex

is_______.

Question19.
HowmanymonoadductsofHClandpenta1,3diene

arepossible?

Question20.
Findthenumberofhydroxylgroupinproduct[A]formedinfollowingconversion.

Question21.
Inthediagramshown,alightrayisincidentonthelowermediumboundaryatanangleif
statementsis(are)true?

[A]

If

,thenangleofdeviationis

[B]

If

,thenangleofdeviationis

[C]

If

,thenangleofdeviationis

[D]

If

,thenangleofdeviationis

withthenormal.Whichofthefollowing

Question22.
Atransparentslabofthicknesstandrefractiveindex
isinsertedinfrontofupperslitofYDSEapparatus.Thewavelengthoflight
usedis
.Assumethatthereisnoabsorptionoflightbytheslab.Markthecorrectstatement(s).
[A]
[B]

Theintensityofdarkfringeswillbe0,ifslitsareidentical.
Thechangeinopticalpathduetoinsertionofplateis

[C]

Thechangeinopticalpathduetoinsertionofplateis

[D]

Formakingintensityzeroatcentreofscreen,thethicknesscanbe

Question23.
Adriverinastationarycarblowsahornwhichproducesmonochromaticsoundwavesoffrequency1000Hznormallytowardsa
reflectingwall.Thewallapproachesthecarwithspeedof3.3m/s.Speedofsoundis340m/s.
[A]
[B]
[C]

Thefrequencyofsoundreflectedfromwallandheardbythedriveris1020Hz
Thefrequencyofsoundreflectedfromwallandheardbythedriveris980Hz
Thepercentageincreaseinfrequencyofsoundafterreflectionfromwallis
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[D]

QuestionRevision

Thepercentagedecreaseinfrequencyofsoundafterreflectionfromwallis

Question24.
Aspringofspringconstantkstores5Jofenergywhenstretchedby25cm.Itiskeptverticalwithoneendfixed.Amassmisattached
totheotherend.Itmakes5oscillationspersecond.Then:
[A]
[B]
[C]
[D]

m=0.16kg
m=0.32kg
k=160N/m
k=320N/m

Question25.
Aball'A'collideselasticallywithanidenticalballBwithvelocity10m/satanangleof

fromthelinejoiningtheircentresC1andC2.

Selectthecorrectalternative(s):

[A]
[B]

velocityofballAaftercollisionis5m/s
velocityofballBaftercollisionis

[C]
[D]

boththeballsmoveatrightanglesaftercollision
kineticenergywillnotbeconservedhere,becausecollisionisnotheadon

m/s

Question26.
A100Hzsinusoidalwaveistravellinginthepositivexdirectionalongastringwithalinearmassdensityof
tensionof35N.Attimet=0,thepointx=0haszerodisplacementandtheslopeofthestringis

anda

.Thenselectthewrong

alternative(s):
[A]

Velocityofwaveis100m/s

[B]

Angularvelocityis

[C]
[D]

Amplitudeofwaveis0.025m
Noneofthese

rad/s

Question27.
ApositivelychargedthinmetalringofradiusRisfixedinthexyplanewithitscentreattheoriginO.AnegativelychargedparticlePis
releasedfromrestatthepoint(0,0,z 0)wherez 0>0.ThenthemotionofPis:
[A]

Periodicforallvaluesofz 0satisfying

[B]

Simpleharmonicforallvaluesofz 0satisfying

[C]
[D]

Approximatelysimpleharmonicprovidez 0<<R
SuchthatPcrossesOandcontinuoustomovealongthenegativezaxistowards

Question28.
Achargedparticleofspecificcharge

moveswithavelocity

inamagneticfield

.Then

(specificcharge=chargeperunitmass)
[A]
[B]

pathoftheparticleishelix
pathoftheparticleisacircle
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[C]

[D]

QuestionRevision

distancemovedbyparticleintime

velocityofparticleaftertime

Question29.
Intheadjacentfigure,thetwocapacitorseachofequalcapacitanceChavechargesCE/2andCEasshowninitially

Assoonastheswitchisclosed,thecurrentinresistanceRis.
[A]
[B]
[C]
[D]

Question30.
Intheadjacentfigure,thetwocapacitorseachofequalcapacitanceChavechargesCE/2andCEasshowninitially

Heatdissipatedinthecircuitafterclosingtheswitchis:
[A]

[B]

[C]

[D]

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Question31.
Thecurrentthrough

resistanceiszeroandthrough

is2A.

resistanceiszeroandthrough

is2A.

ThevalueofRis:
[A]
[B]
[C]
[D]

Question32.
Thecurrentthrough

TheemfEoftheidealcellis:
[A]
[B]
[C]
[D]

14V
8V
10V
12V

Question33.
Acylindricaltubeoflength6.93cmandinnerandouterradiiof2.5cmand5cmrespectivelyarecoveredwithtwoidenticalhemispherical
lidsofsameinnerandouterradii.Thematerialsoflidsandthetubeissameofthermalconductivityof0.5cal/smK.Anenergysource
radiating1256cal/sisplacedinside.Thesteadystateinsidetemperatureis
Findthevalue

andsurroundingtemperatureis

,given

Question34.
AsshowninfigurestringPQRisstretchedbyforceF=(310Kt)N,wherekisaconstantandtistimeinsecond.Attimet=0,apulse
isgeneratedattheendPofthestring.ForthevalueofK(inN/s)ifthevalueofforcebecomezeroasthepulsereachespointQ.
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Question35.
Therearetwoliquidsofdifferentdensities.Asolidbodycanbecompletelysubmergedinliquid1,byapplying1.36Ndownwardforcesand
thesamebodycanbecompletingsubmergedinliquid2byapplying0.82Ninotherliquid.Theseliquidaremixedinvolumeproportion
Vliqui1:Vliquid2=4:x.Forwhatvalueofx,thesolidcanbecompletelysubmergedinmixtureliquidbyapplyingdownwardforceof1N.

Question36.
Waterisflowinginvaryingcrosssectionpipe.Areaofcrosssection1,2and3are1cm2,2cm2andAcm2respectively.Waterlevels
areshownindifferentverticaltubes.Speedofwateratcrosssection3is

.Thevalueofxis__________.

Question37.
PotentiometerwireABhaslength=100cm.Totalresistances
,whenthejockyisconnectedatD(AD=xcm),ammeterreading
is0.5amp.Thevalueofxis__________.(Resistanceofammeteris
).

Question38.
AglasssphericalshellofradiusRhasapointsourceofmonochromaticlightofwavelength
.Thicknessofglasswallist(<<R).The
innersurfacesofthesphereispaintedblacksothatitabsorbsalltheradiationincidentonitThemaximumpowerofthesourcesuchthat
thespheredoesnotruptureduetoradianpressureis

.Where

=tensilestrengthofglass,c=speedof

light.Thevalueof(x+a+b+d+e)is__________.

Question39.
Twocoils,1and2haveamutualinductanceM=5HandresistanceR=
as:

each.Acurrentflowsincoil1,whichvarieswithtime

,wheretistime.Findthetotalcharge(inC)thathasflownthroughcoil2betweent=0andt=2s

Question40.
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AsolidsphereofradiusRhasachargeQdistributedinitsvolumewithachargedensity

,wherekandaarepositive

constantsandristhedistancefromitscentre.Iftheelectricfieldatr=R/2is1/8timesthatatr=R,findthevalueofa.

Question41.
If
[A]

,wherea,b,c,darerealand

nonrealcuberootofunity,then:

abc+acd+abd+bcd=2

[B]
[C]

a+b+c+d=2abcd

[D]

Question42.
LetAandBbetwoindependenteventssuchthat

and

,then:

[A]
[B]
[C]
[D]

Question43.
Ifboth

satisfy

and

,then:

[A]

[B]

alsosatisfy

[C]

isaneveninteger

[D]

Question44.
IfAbea
[A]

nonsingularmatrix,then:

adj(adjA)=

[B]
[C]

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[D]

Question45.
Acurvepassesthroughoriginissuchthatslopeofthetangentatanypointisreciprocalofsumofabscissaandordinateofpointof
tangencythen:
[A]

Slopeoftangentatordinate

is

[B]

Areaboundedbycurve,y=0,y=1andyaxisis

([.]denotegreatestintegerfunction)

[C]

[D]

Question46.
Iftwodistinctcircles
astraightlinewhoseslopeis

and

cutequalinterceptson

,thenthelineistangentto:

[A]
[B]
[C]
[D]

Question47.
If
then:
[A]

rangeof

[B]

domainof

[C]

domainof

[D]

rangeof

(Iissetofintegers)
is[1,2]

Question48.
Let

and

then:

[A]
[B]

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[C]

[D]

f(x)hasmorepointsofdiscontinuitiestheng(x)in

Question49.
Pisarbitrarypointlyingontheellipse

isoneoffocusoftheellipsewhoseabscissaispositive,Risthe

midpointofPS(edenotestheeccentricityofellipse)

LocusofRisanellipse,
[A]

whosedirectricesare

[B]

whoseFociareat(ae,0)and(0,0)

[C]

whosedirectricesare

[D]

whoseFociareat

and

Question50.
Pisarbitrarypointlyingontheellipse

isoneoffocusoftheellipsewhoseabscissaispositive,Risthe

midpointofPS(edenotestheeccentricityofellipse)

Whichofthefollowingis(are)trueaboutlocusofR
[A]

Secondfocusofgivenellipse(otherthanS)liesoutsideofRif

[B]

Secondfocusofgivenellipse(otherthenS)liesonlocusofRif

[C]

probabilityanypointselectedinsidegivenellipseliesinsidelocusofRis

[D]

eccentricityoflocusofRis

Question51.
Letadicebethrown3timeswegetvaluesa,b,candpolynomialisformed

.LetSbesetofallsuch

possiblepolynomials.AbesubsetofSconsistingofallpolynomialshavingexactlytwodistinctpointsofextrema.BbesubsetofS
containingpolynomialshavingnopointofextrema.

Whichofthefollowingis/aretrue?
[A]
[B]
[C]
[D]

Aconsistsofallpolynomialshavingnegativepointoflocalminima
AllpolynomialsinShaveonenegativeroot
NumberofpolynomialsinAhavingrationalpointsofextremais5

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Question52.
Letadicebethrown3timeswegetvaluesa,b,candpolynomialisformed

.LetSbesetofallsuch

possiblepolynomials.AbesubsetofSconsistingofallpolynomialshavingexactlytwodistinctpointsofextrema.BbesubsetofS
containingpolynomialshavingnopointofextrema.

ProbabilitythatarandomlyselectedpolynomialfromS
[A]

isstrictlyincreasingis

[B]

isstrictlyincreasingis

[C]

hasintegralpointofinflectionis

[D]

hasnopointofinflectionis

Question53.
If

rootsofunity.Thenvalueof

is____________.

Question54.
Let

.Ifpbethesumofallpossibleintegersinthedomainoffunction

f(x)andqbesumofallpossibleintegersintherangeoffunctionf(x),then

is___________.({.]denotesgreatest

integerfunction,{.}denotesfractionalpart).

Question55.
LetA={1,2,3,4,5}andB={0,1,2,3,4,5,6},ifnumberofoneonefunctionfromAtoBwhicharenotstrictlyincreasingis
numberoffactorsof

,then

oftheform3kis________.

Question56.
Iftherangeofthefunction

(where{.}denotesfractionalpart),then

is

__________.

Question57.
If

arenoncoplanarvectorssuchthat

thenvalueof

is

____________.

Question58.

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is__________.([.]denotesgreatestintegerfunction)

Question59.

then

is_________.

Question60.
Letfunctionf(x)besuchthat

and

,then

is________.([.]denotes

greatestintegerfunction)

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