INDIAN NATIONAL JUNIOR SCIENCE OLYMPAID

January 30, 2016

ANSWER KEY & SOLUTIONS

Section A

Section B

Sol.31 A) (I)
2ZnS + 3O2 2ZnO + 2SO2
(II) ZnCO3 ZnO + CO2
(III) ZnO + C Zn + CO
B) (I)
(II)
C)

i)

It is an exothermic reaction between iron oxide and aluminium where aluminium acts as
reducing agent and iron acts as oxidizing agent.
Fe2O3 + 2Al Al2O3 + 2 Fe.
The question is based on Gay-Lussacs law.

P1
P2
=
T1
T2

1 06
250 10 3
=
T2
300

T2 = 1200 K.
The melting point of cylinder is 1800 K. Thus, the cylinder will blow up before melting.
Sol.32 A)

(i) 64 N
(ii) 93.2 N

(I)

For const. speed Fres. = 0

N = 48
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F=N+f
F = 48 + 16 = 64 N
(II & III)

R=

N' 2 f 2

tan =

f
48
=
N'
80

6
3
=
10
5
R = 93.2 N
B) (I) 66.67 W
(II) 1367.64 J
tan =

(III) *

105

Sol.33

Sol.34 (I), (ii) ~ 425 (vi) ~ 680

(II) Violet Indigo Blue Orange and red.
(III) Chlorophyll
(IV) Absorb and Transmit respectively.
(V) Yes
Light
C6H12O6 + 6O2 + 6H2O
(VI) 6 CIO2 + 12 H2O Chlorophyl
l

(VII) Spectrometer
Sol.35 (I)
(II)

(III)
(IV)

3NaOH (aq.) + H3PO4(aq.) Na3PO4(aq.) + 3H2O()

Miliequivalents of H3PO4 = Miliequivalents of NaOH
w 1000
N v(ml) =
E
w 1000
3 0.9 23 =
40
0.9 23 40 3
w=
= 2.484 g
1000
no. of moles of solute
10
M=
=
= 2.6167
vol. of solution (L)
36.5 0.1047
NaHCO3 + HCl NaCl + H2O + CO2
1.2 g
40 mL
1.14 g/mL
Applying POAC on C-atoms

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n NaHCO3 = n CO2

1 .2
= n CO2
84
1.2
mass of CO2 =
44 g
84
= 0.62857 g
Density of CO2 = 1.98 g/L
Volume of CO2 = 0.317 L
r = 2.Gx . cy . mz

Sol.36 (A)
i)

G=

Fr 2
M1L1T 2 L2
=
= M1 L3T2
m2
M2

r M0L1T0

c M0L1T1

ii)

m M1L0T0
M0L1T0 = [M1L3T2]x [L1T1]y [M]z
M0L1T0 = Mx+z L3x+y T2xy
x+z=0
3x + y = 1
2x y = 0
x=z
3x 2x = 1
2x = y
x=1
z=1
y=2
r = 2Gc2 m
2Gm
r=
c2
r=2

1
20
1011 6 1024
3
9 1016

2 20 6
103 m
3 9
r = 8.9 103 m
r=

(B) i)
For meeting.
1
5t +
2 t2 = 6
2
t2 = 5t 6 = 0
t 1sec
x6

meeting time and position.

ii)

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for meeting
5t = t2 + 6
t2 5t + 6 = 0
t = 2, 3
meeting twise.

Sol.37 I) 6CO2 + 6H2O sunlight

C6H12O6 + 6O2
6
II) 1 Ton = 10 g
Wt. of carbon from 1 Ton coal containing
70
70% weight of carbon =
106 g
100
C + O2 CO2
7 105 g C will produce 25.67 105 g CO2
6 CO2 + 6 H2O sunlight
C6H12O6 + 6O2
According to the above equation.
6 44 g CO2 produce 180 g sugar

25.67 105 g CO2 will produce

25.67 10 5 180
=
= 17.5 105 g = 1750 kg
6 44
30 21 10 6 m
III)
= 500 106 8000 3600
100
500 8000 3600 100
5 8 36
m=
=
108 = 22.85 108 kg
30 21
63
IV) 1 kg 21 106 J
50 1000 21 106 50 1000
21 10 6 50 1000 A
= 500 106
365 3600 24

500 10 365 3600 24

21 10 6 50 1000
365 36 24
A=
hectare
21
A = 15017.14 hectare
V) *
A=

Sol.38

H2O is produced only from KHCO3.

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Applying POAC on H-atoms.

n KHCO3 = n H 2 O 2
n KHCO3 = 2
Mass of KHCO3 = 200 g.
CO2 is produced from KHCO3 and K2CO3. Applying POAC on C-atoms

n KHCO3 + n K 2CO 3 = n CO 2
2 + n K 2CO 3 =

290
44

n K 2 CO 3 = 4.59
mass of K2CO3 = 633.42 g
mass of KClO3 in 1000 g mixture = 166.58 g.
Sol.39 R = 160 m
u 2 sin 2
= 160
g

1
T1 =

2 90

2u sin
2u cos
T2 =
g
g

T1 T2 = 6 sec
2u sin
2u cos

= 6.
g
g

usin u cos = 30
u2 2u2 sin cos = 900
u2 u2 sin 2 = 900
u2 1600 = 900
u2 = 1600 + 900 = 2500
u = 50 m/s
Sol.40 (I) P1 Nucleus
(II) P1 Hematoxylin
(III) Mitochondria
(IV) SER

P2 Mitochondria
P2 Redox dyes

P3 Membrane Fraction
P3 Lipophilic Stains

P4 Ribosome

Sol.41 (I) (i) P

(II) (i) P
(III) (iii) R
(IV) (iii) O2, H2O and temperature
(V) (i) No change in germination frequency
Sol.42 (I) (ii) Water
(II) (ii) Active transport of salts from ascending tubule to interstitial fluid.
(III) (iii) It will excrete large amount of dilute urine.
(IV) (i) Aquatic
(V) (iv) Semipermeable, hypotonic, active.
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