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Antoine : ln P sat =A
B
T+C
Linear with
Ideal
sat
P
K
Rel . Votality : 12 = 1sat = 1 ( weak fucntion of T )
K2
P2
5.Given T PFind x i y i
sat
sat
P ( x 1P 1 + x 2P2 )1
=
P2sat
Psat
2
o
o
PPsat
x 1= sat 2 sat
P1 P2
P
P
> P =
=
(1)
sat
x
x 1P1
1
12 + x 2
+ x2
Psat
2
sat
2
6.Given x yFind T P
o
o
y iP
1
Z 1 1Z1
+ sat
sat
P1
P2
P1
1
1
> P=
=
(2)
y1
y2
yi
+
sat
P2
Psat
Pi
1
x i=1x i=
( )
sat
1
= 1=
sat
sat
Z 1=x 1(1V ) + y 1V =V =
Z 1x 1
(4)
y 1x 1
Case I:
is independent of xi ( H . C)
y 1 1Psat
1
=
x1
P
y1
=K 1 . If K >1=alcohol ,<1=H 2 O
x1
Pdew=
y1
y2
+
sat
1P 1 2P2
sat
sat
Pbubble =x1 Psat
1 1 + ( 1x1 ) P 2 2
Pbubble =x1
Find Psat using Antoine
Find K1 using:
sat
1
y 1=
o
y i=1
y i=1=x 1K 1+ ( 1x 1 )K 2
12.Given x 1 , y 1Z 1Find P , T
o
Choose
sat
Psat
2 < P I< P 1
that satisfies
these Psat
At this P,T read Ks or use Raoults to
find out either x or y. Compare the
calculated to the given.
y 1P= x1H
Find y 1 by Substitute x 1=
P=x 1 H 1 + x 2P2sat
sat
1
y1
into ( 3 ) ,
K1
Z 1K 1
(6)
1+ V( K 1 1 )
* Azeotrope
9. GivenT , y 1Find P , x1
x 1= y 1 /K 1= 1= y 1 / K 1 + ( 1 y 1 )K 2 (8)
Law*
o
8. GivenT , x 1Find P , y 1
o
o
7.Given T , P , Z Calculate x , y , V
Let
o
o
depends on T , Px i
Case II:
Solve (5)
If i depends on xi
exist
az
az
az
az
x 1 = y 1 x 2 = y 2
1 P1
y2
sat
y1
2 P2
P
=
=
x1
x2
P
sat
y1
sat
x1 1P1
> 12 = =
y 2 2P2sat
x2
x1 Psat
1
y 1=
P
x2 Psat
2
y 2=
P
x1 1
1
o
x 2 1
compare to
o
o
P = 1 P1
az
az
sat
az
sat
1 P1
P
= 1az = 2sat
sat
2P2
2 P1
az
12=1=
y 3=
( 1x 1x 2 ) P sat
3
P
4 equations, 4 unknowns.
Non Raoults
sat
Z 1K 1
1+V ( K 11 )
sat
P=x 1 P1sat + x2 Psat
2 + ( 1x 1x 2 ) P 3
Calculate x using K.