Professional Documents
Culture Documents
Chapter 1
Topic 1A
P1A.1
233N
P1A.3
-272.95oC
P1A.5
P1A.7
2.8 x 108 dm3 = 2.8 x 105 m3, 4.1 x 108 dm3 = 4.1 x 105 m3
P1A.9
P1A.13
(b) 0.72
Topic 1B
12
P1B.3
2RT
P1B.5
0.47 vx
P1B.7
n 2 e3(1 n
P1B.9
P1C.1
P1C.3
initial
)/ 2
Topic 1C
inversion temperature
P1C.5
P1C.7
P1C.9
B= b
P1C.11
2
B3
3C
1
, B ,
,
2
3
RC
B
3
27C
(b) 0.6957
(c) 0.7158
a
, C = b 2 , 34.6 cm3 mol1, 1.26 dm 6 atm mol2
RT
P1C.17
0.011
P1C.21
b {1 (bRT / a )1/ 2 }
1 bRT / a
Chapter 2
Topic 2A
P2A.1
P2A.3
P2A.5
V nb 2 1 1
nRT ln 2
n a
V1 nb
V2 V1
(a) 1.7 kJ
(b) 1.8 kJ
(a) 1.5kJ
(b) 1.6kJ
1
2
(c) 1.5 kJ
kF xf 2
Topic 2B
P2B.1
62.2 kJ mol1
P2B.3
w = 0, U =
+2.35 kJ , +3.03 kJ
Topic 2C
P2C.1
1270 kJ mol1
P2C.3
P2C.5
994.30 kJ mol1
P2C.7
802.31 kJ mol1
P2C.9
+37 K , 4.09 kg
Topic 2D
P2D.1
P2D.3
nR
P2D.5
p
na
T=
(V nb) +
2
nR
RV
P2D.7
p
cs =
P2D.11
( )
1/ 2
T
V nb
=
(V nb) ,
nR
p V
, 322 m s-1
(b) 14.0 K MPa -1
Topic 2E
P2E.1
41.40 J K 1 mol1
Chapter 3
Topic 3A
P3A.5
P3A.7
10.7 J K 1 mol1
P3A.9
P3A.11
nC p , m ln
P3A.13
477 J K 1 mol1
Topic 3B
(b) 232.0 J K 1 mol1
P3B.1
P3B.3
P3B.5
Topic 3C
P3C.1
P3C.3
(c) 0.46
mol ATP
mol glutamine
Topic 3D
P3D.1
501 kJ mol1
P3D.3
21kJ mol1
P3D.5
( VS )
P3D.7
( )
= T , S
p
p
S V
p
=
T V
C p dT TV dp , TV p , 0.50 kJ
Chapter 4
Topic 4B
P4B.1
196.0 K , 11.1Torr
P4B.3
P4B.5
P4B.7
22C
P4B.9
(a) 227.5C
P4B.13
9.8Torr
P4B.15
363 K
P4B.17
1
dp
dp C p , m2 C p , m1
= 2
,
=
dT T , 2 T ,1 dT TVm ( 2 1 )
Chapter 5
Topic 5A
P5A.1
18.079 0.11482x 3/ 2
P5A.3
P5A.5
4.6 cm3
Topic 5B
P5B.3
P5B.5
P5B.7
P5B.9
fus H
fus H 1 1
, ln =
xA
2
R
RT
T T
P5B.11
P5B.13
xA = xB = 0.5
P5B.15
(b) (ii) 0.19, 0.82, 0.24 (c) xPb = 0.19, xCu = 0.18
Topic 5C
(c) 0.532
P5C.1
(b) 391.0 K
P5C.7
P5C.9
xA pA* / pB*
1 + ( pA* / pB* 1) xA
Topic 5E
P5E.3
= [B]RT
Chapter 6
Topic 6A
P6A.1
P6A.3
P6A.5
= 1
1
O
1
ap
p
+
/
1/ 2
Topic 6B
P6B.3
300. kJ mol1
P6B.5
P6B.7
P6B.9
T
K c (T ) K c (Tref ) ref e
=
T
r H O
R
1 1
Tref T
Topic 6C
P6C.1
(a) +1.23V
(b) +1.09 V
P6C.3
Topic 6D
P6D.1
+0.26843 V
Chapter 7
Topic 7A
(b) 2.5 104 J m 3
P7A.1
P7A.3
max T
P7A.5
255 K or 18 C , 11 m ,
P7A.7
(a) 8hc , hc
P7A.9
hc / k
cE
4
(b) WienT 4
c
(b) 343 K , E = 0.897
Topic 7B
1/ 2
P7B.1
(a) N =
L
P7B.3
0.0183
(b) N =
1
c(2 L)1/ 2
(c) N =
1
(a 3 )1/ 2
(d) N =
1
(32a 5 )1/ 2
P7B.7
xmax = a
Topic 7C
2 d 2
2 d 2
e2
E (b)
=
2
2
4 0 x
2 m dx
2me dx
2 d 2
E (c)
E
cx =
=
2
2
m
d
x
P7C.1
(a)
P7C.3
(a) Yes
(b) Yes
(c) No
(d) No
P7C.5
(a) Yes, k 2
(b) Yes
(c) Yes
(d) No
(ii) (c)
P7C.7
(a) + k
(b) 0
P7C.9
1
a
P7C.11
12
(c) 0
(ii) N = ( 32a05 )
12
30a02
P7C.15
[ x, p x ] = i
Chapter 8
Topic 8A
P8A.1
P8A.3
(a)
P8A.5
1.2 106
P8A.7
4k12 k22
T =| A3 |2 =A3 A3* = 2
2
(a + b ) sinh 2 (k2 L) + b 2
(a)
L
, L
2 31/ 2
1
(b) L , L
2 3 4(n / L) 2
1/ 2
Topic 8B
(ii) 5a0 ,
P8B.5
1
1
v +
2
2
Topic 8C
P8C.1
P8C.3
(a) +
(b) 2
(c) 0
(d) cos 2
2
(a)
2
(b) 2
2
(c)
2
(d)
2I
2I
2I
P8C.5
P8C.7
P8C.9
y z , z x , x y , lz.
y i x
x
i z
i
z i y
Chapter 9
Topic 9A
P9A.1
106 pm
P9A.3
(b) node =
3 + 3 and node =
3 3 , node 0=
=
and node 4 , node = 0
27 a
r 3s = 0
2
Z
a0
Z
4a0
Z
4a0
P9A.7
(a)
P9A.11
(b)
Topic 9B
P9B.1
0.420 pm
Topic 9C
P9C.1
n2 6
(c)
(d)
Z
a0
(c)
P9C.3
Li 2 +
P9C.5
P9C.7
P9C.9
(a) 0.9 cm 1
(b) small
P9C.11
(a) 2kT
(b) 23.8 T m 1
Chapter 10
Topic 10A
P10A.1
Z 3/ 2 e / 2 2 sin
Topic 10B
P10B.1
P10B.3
EH1s
P10B.5
(b) 2.5a0 = 1.31010 m, 0.555j0/a0 = 15.1 eV, 0.565j0/a0 = 15.4 eV, 0.055j0/a0 =
1.5 eV, 0.065j0/a0 = 1.8 eV
j + k j0
j k j0
+ , EH1s
+
1+ S R
1 S R
Topic 10C
P10C.1
2.1a0
P10C.3
(c) /4 or 3/4
Topic 10D
P10D.1
A + B 2 S
2(1 S )
2
B S
1 S 2
P10D.3
A B
1 +
2(1 S 2 )
1/ 2
4( + A S )( + B S )
( A B ) 2
A S
1 S
( + A S )( + B S )
,
( A B )(1 S 2 )
( + A S )( + B S )
( A B )(1 S 2 )
Topic 10E
P10E.1
E = O,
1
12 2
O + C ( O C ) 1 +
2
( O C ) 2
12 2
4 2
1+
( O C ) 1 +
2
( O C )
( O C ) 2
4 2
,
O C
P10E.7
P10E.13
Chapter 11
Topic 11A
P11A.1
(a) D3d
P11A.3
S4 , C2 , S4
(c) D2h
(d) D3
(b) A1 + 3E
(c) A1 + T1 + T2
(e) D4d
Topic 11B
P11B.1
trans -CHCl=CHCl
P11B.3
= 3A1 + B1 + 2B2
P11B.7
+1 or 1 , +1 , 1
P11B.9
A 2u + T1u + T2u
Topic 11C
P11C.1
A1 + T2 , s and p, (d xy , d yz , d zx )
Chapter 12
Topic 12A
P12A.1
4.4 103
(d)
P12A.3
=
A [ J ]0 (1 e L / ) , A = '[J]0
P12A.7
1
4
3
1
2
P12A.9
P12A.11
2 ( kT / mc 2 )
1/ 2
1/ 2
Topic 12B
P12B.1
meff R 2
Topic 12C
P12C.1
P12C.3
P12C.5
116.28 pm , 155.97 pm
P12C.7
14.35 m 1 , 26 , 15
P12C.9
kT
2hcB
12
12
1
kT
, 30 ,
2
hcB
1
, 6
2
Topic 12D
P12D.1
kf = 2 Da 2 .
P12D.3
P12D.7
e / 1
2D
2
P12D.9
112.83 pm , 123.52 pm
P12D.11
0 = 10.433 cm-1
B
P12D.13
x2
=
1 = 10.126 cm-1
, B
1
(v + ). , rotational constant B decreases, B decreases with increased
kf
anharmonicity
1.91cm 1
(d)
(e) 113 pm
Topic 12E
P12E.1
P12E.3
(a) C3v
(b) nine
(c) 3A1 + 3E
Chapter 13
Topic 13A
g+ 2 u+ is allowed
P13A.1
P13A.3
Topic 13C
P13C.1
4 1010 s or 0.4 ns
Chapter 14
Topic 14A
P14A.1
Topic 14B
P14B.1
29 T m -1
P14B.3
P14B.5
cos = B/4C
Topic 14C
P14C.1
(e)
P14C.5
a
1
2 2
2 1 + (0 )
P14C.7
158 pm
P14C.9
0.58 mT
Topic 14D
P14D.1
2.8 1013 Hz
P14D.3
6.9 mT , 2.1mT
Chapter 15
Topic 15A
P15A.1
P15A.7
Topic 15B
(ii) 6.26
P15B.3
P15B.5
1.209 , 3.004
P15B.7
(a) 1.049
P15B.9
(a) 660.6
(a) 104 K
(b) 1 + a
Topic 15C
P15C.3
Topic 15E
P15E.1
P15E.3
4.2 J K 1 mol1
P15E.5
P15E.7
eq
q
q
q q
(a) nRT , nR , nR + ln
q
N
q q
P15E.11
191 J K 1 mol1
P15E.17
V
Ti
P15E.19
e (
1 e
2Ti )
V
Ti
9.57 1015 J K 1
Topic 15F
P15F.3
100 T
P15F.5
45.76 kJ mol1
Chapter 16
Topic 16A
P16A.1
(a) 0
P16A.5
1.00 D
P16A.7
P16A.9
P16A.11
68.8 cm3 mol1 , 4.40 , 2.10 , 8.14 cm3 mol1 , 1.76 , 1.33
P16A.13
(b) 0.7 D
(c) 0.4 D
Topic 16B
P16B.1
1.9 nm
P16B.3
P16B.5
6C
r7
P16B.7
kTi H2i
e ( D RTi )
p O qiV qiR ( Hi )
Chapter 17
Topic 17A
P17A.1
(a)
(b)
P17A.3
Nl 2
P17A.5
(a)
a,
a, a/2
1
12
(b)
a,
1 RT 2
, 6.3 GHz
2l M
Topic 17D
P17D.1
2
M +
P17D.3
(a)
1/ 2
, 1.96 nm
l , 0.35 nm , 46 nm
Topic 17B
P17B.1
1/3
20
45
90
3500 r.p.m.
P17D.7
69 kg mol1 , 3.4 nm
P17D.9
0.0716 dm3 g 1
P17D.11
Chapter 18
Topic 18A
1
12
(c)
P18A.1
P18A.3
V = 3 3 / 2 a2c
P18A.5
P18A.7
P18A.9
1 h k l
= + +
d2 a b c
P18A.11
P18A.13
P18A.15
P18A.17
Topic 18B
P18B.1
0.340
P18B.3
7.654 g cm 3
P18B.7
(a) 0.41421
(b) 0.73205
Topic 18C
P18C.1
P18C.3
3 + 2
3
=
P( E ) 1 when E < , lim
lim
f ( E ) 0 when E > , ( 3N / 8 )
=
T 0
T 0
2/3
(h
/ 2me ) , 3.1 eV
P18C.5
0.736 eV
P18C.7
0.127 106 m3 mol1 , 0.254 106 m3 mol1 , 0.423 106 m3 mol1 , 0.254 cm mol
P18C.9
0.41
Chapter 19
Topic 19A
P19A.3
P19A.5
Topic 19B
P19B.1
10.2 kJ mol1
P19B.3
P19B.5
P19B.7
0.83 nm
P19B.9
9.3 kJ mol1
(b)
(c) 172
Topic 19C
P19C.1
/ x2
1/ 2
= 31/ 4
P19C.7
x4
P19C.9
(a) 0
P19C.11
2 n2 / 2 N
P=
e
N
(b) 0.0156
(c) 0.0537
Chapter 20
Topic 20A
P20A.1
Second order
P20A.3
(a) 1, 2, 3
Topic 20B
P20B.3
P20B.7
14 yr
6 1014 mol dm 3 s 1 , 4.4 108 s =
P20B.9
P20B.11
P20B.13
P20B.15
First-order, third-order
P20B.17
(2 x A0 ) B0
1
ln
3 A0 2 B0 A0 (3 x B0 )
P20B.19
2n 1 1
( 34 )
n 1
Topic 20C
P20C.3
([A]0 + [B]0 ) ,
[A] kr
kr + kr
P20C.5
(a) (i) 8ka ka [A]tot + (ka ) 2 (c) 1.7 107 s 1 , 2.7 109 dm3 mol1 s 1 , 1.6 102
Topic 20D
P20D.3
P20D.5
Topic 20E
P20E.1
Steady-state approximation
P20E.3
Steady-state intermediate
P20E.5
Topic 20F
P20F.3
(1 + 2k t[A] )
2 12
0
Topic 20G
P20G.1
1.11
P20G.3
(a) 6.7 ns
P20G.5
P20G.7
3.5 nm
(b) 0.105 ns 1
Topic 20H
P20H.1
max
1+
P20H.5
1
K [S]0
2.31 mol dm3 s1, 115 s1, 115 s1, 1.11 mol dm3, 104 dm3 mol1 s1
Chapter 21
Topic 21A
P21A.1
P21A.3
P21A.5
3.12 1014 dm3 mol1 s 1 , 193 kJ mol1 , 7.29 1011 dm3 mol1 s 1 , 175 kJ mol1
(b) 0.15
Topic 21C
P21C.1
P21C.5
3 107
P21C.9
P21C.11
(a) 0.06
Topic 21D
P21D.1
I = I 0 e N L
Topic 21E
P21E.1
kr (kAAkDDK)1/2
P21E.3
1.15 eV
Topic 21F
P21F.1
0.78, 0.38
P21F.3
(a) 0.618 V
P21F.5
Chapter 22
Topic 22A
P22A.1
P22A.3
P22B.3
P22B.5
P22B.7
P22B.9
Topic 22B
0.138 mg g 1 , 0.58
P22B.13
Topic 22C
P22C.1
kr pNH 3
p p0 p0
p
=
ln
, kc
, kc = 2.5103 kPa s1
K pH 2
t
t
p0