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Date of analysis:
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Reference:

14-000
Iron in Water Samples by Flame AAS
Signature: ________

'file:///var/www/apps/conversion/tmp/scratch_4/309367084.xls'#$14-000

Flame Atomic Absorption Spectrophotometry

Standard Methods for the Examination of Water and Wastewater, 20th CD-Rom Ed., American Public
Health Association, et al., APHA Washington, DC 20005 USA, 1999.
Instrumentation:
Shimadzu AA-6800
Instrumental Analytical Conditions:
Fe 248.3 nm 12 mA SW 0.2 Aspiration rate 6.40 mL/min
BGC-D2 C2H2-air pressure 0.25-0.05 MPa C2H2 flow rate 2.0 L/min
Burner Hgt 7 Lateral position 0 Angle 0

Analysis Report
1. Instrument Calibration
a. Calibration Data and Calibration Curve
STDS
Fe
Concn

0.000

0.0019

0.0023

0.050

0.0071

0.0074

0.100
0.200
0.500
1.000
2.00

AAS Rdg
II

AVE
RDG

CALIB
PTS

0.0021
0.0029
0.0073
0.0073
0.0108
0.0115
0.0112
0.0117
0.0208
0.0217
0.0213
0.0204
0.0469
0.0481
0.0475
0.0468
0.0897
0.0912
0.0905
0.0906
0.1777
0.1787
0.1782
0.1784
% RSD 2 rdgs (2.00 mg/L) = 0.397

Regression Output:
Constant
0.00290
Std Err of Y Est
0.00066
R Squared
0.99991
No. of Observations
8
Degrees of Freedom
5
X Coefficient(s)
0.08774
Std Err of Coef.
0.00037

Absorbance

Iron Calibration Curve (14-000)

0.200
0.180
0.160
Colum
nN

0.140
0.120

Colum
nO

0.100
0.080
0.060
0.040
0.020
0.000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000 1.4000 1.6000 1.8000 2.0000

Fe Concentration, mg/L

b. Slope
Acceptance Criteria of Slope: R2 > = 0.99
0.0877 Accumulating data for slope
0.9999 (Conforming)
c. Analysis of Instrument Control Standard

ERA Lot No. P166-500 (Expiration Date: Mar 2011)

0.262

Certified Value, mg/L

0.256

% Recovery
102
mg/L (Conforming)

2. Analysis of Quality Control Standard

Average 14-000-SSII, mg/L
1.00

Spike Value, mg/L

1.00

Average 14-000-SSII, mg/L

1.00

% Recovery
100.0

SSII Conc.(undigested), mg/L % Recovery

#REF!
#REF!

3. Analysis of Sample
SAMPLE

ERA S161-697 BLK

ERA S161-697 BLK
ERA S161-697 STDS
ERA S161-697 STDS

Instrumental Analysis Results

AAS Rdg
AVE
CALCD
NET DILUTION ORIG
AVE
%RSD
STD
RDG
CONCN CONCN FACTOR CONCN CONCN 2 trials
DEV
(mg/L)
(mg/L)
(mg/L) (mg/L)
Reduced to
2 Sig Fig
(1/1)
0.0032
0.0031 0.00225 0.00000
(1/1)
0.0029
0.0264 0.26782 0.26557
(1/1)
0.2656
0.0264
0.0257 0.25984 0.25759
(1/1)
0.2576
0.2616
2.2
0.006
0.0257

14-000-BLKA
14-000-BLKB
14-000-SSIA
14-000-SSIB

0.0057

14-000-BLKA
14-000-BLKB
14-000-SSIIA
14-000-SSIIB

0.0057
0.0069

14-000-BLKA
14-000-BLKB
14-000-1A
13-000-1B
14-000-2A
13-000-2B
14-000-3A
13-000-3B
14-000-4A
13-000-4B
14-000-5A
13-000-5B
14-000-6A
13-000-6B
14-000-7A
13-000-7B

4. Supporting Documents

REPTD
VALUE
(mg/L)

0.26

0.0063
0.0144
0.0163

0.03873
0.13105
0.15271

0.00000
0.09232
0.11398

(1/1)
(1/1)
(1/1)

0.0923
0.1140

0.1032

15

0.015

0.103
(Expected value=0.1 mg/L)

0.0944

0.0063
0.0931
0.0944

0.03873
1.02806
1.04287

0.00000
0.98933
1.00415

(1/1)
(1/1)
(1/1)
(1/1)

0.9893
1.0041

0.9967

1.1

0.010

1.00
(Expected value=1.0 mg/L)

0.0057
0.0069
0.0185
0.0176
0.0050
0.0058
0.0176
0.0177
0.0468
0.0470
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.0063
0.0185
0.0176
0.0050
0.0058
0.0176
0.0177
0.0468
0.0470
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.03873
0.17778
0.16752
0.02391
0.03303
0.16752
0.16866
0.50034
0.50262
-0.03308
-0.03308
-0.03308
-0.03308
-0.03308
-0.03308

0.00000
0.13905
0.12880
-0.01482
-0.00570
0.12880
0.12993
0.46161
0.46389
-0.07181
-0.07181
-0.07181
-0.07181
-0.07181
-0.07181

(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)
(1/1)

0.1391
0.1288
-0.0148
-0.0057
0.1288
0.1299
0.4616
0.4639
-0.0718
-0.0718
-0.0718
-0.0718
-0.0718
-0.0718

0.1339

0.0073

-0.0103

-63

0.0064

0.1294

0.0008

0.4628

0.0016

-0.0718

0.0000

-0.0718

0.0000

-0.0718

0.0000

0.0069
0.0144
0.0163

0.0931

Data sheets for iron.

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Certified Correct: (Signature of Supervisor and Date of checking)
Submitted:
0