United States Patent 1»
Conway et al.
USOOSSS8745A
(s4] TREATMENT OF ABSORBENT SANITARY
PAPER PRODUCTS
(75) Inventors: Marlene E. Conway, Brampton;
Francois Jooste, Beamsville; Michael
(73) Assignee:
D.
smith, Brampton, all of Canada
Knowaste Technologies Inc,
Mississauga, Canada
[21] Appl. No.
(22) PCT Filed
(86) PCT No.
$371 Daw:
4 3026) Dat:
[87] PCT Pub. No: WO9207995
PCT Pub, Date: May 14, 1992
(nder 37 CFR 1.47)
(30) Foreign Application Priority Data
(oe. 29, 1990 163)
Jon. 17,1991
cx}
{1} Int. cL
[52] US. Ch
[58] Field of Search
(56)
1.798.459
2ossass
3.89516
(200486
4219381
4485308
400,640
4338767
460.117
490244
81,369
Oct. 29, 1991
PCTICAS1/00393
Jun. 29, 1993
Tan. 29, 1993
United Kingdom ou23ce
United Kingdom ccc 9113004
pain 1732
vn WOUGO, 162/5; 16214;
13406
241/99.3, DIG.38
1462/4, 60, 5, 55; 32140; 2087, 4,7, 9,
"AF; 13426, 27, 28, 29,30
References Cited
US. PATENT DOCUMENTS
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ut) Patent Number 5,558,745
(45) Date of Patent: Sep. 24, 1996
522504571993 Watson reas
FOREIGN PATENT DOCUMENTS
3199677 W991 Japa se veut
2100861 2/1983 United Kingdom
5008789 1990 WIPO
(OTHER PUBLICATIONS.
Report on Disposable Diaper Recyeling Programs, Final
Report to Procter & Gamble Co. Apr 29,1991, by Arthur D.
Litle, Aco Park, Cambridge, Mass.
P & G invests $400,000 in diaper recycling project Non:
woven World, Vol. 5, No. 6, Aug. 1990.
Pulp recovery unit with separation of fu, Abstract Bulletin
ofthe Insite of Paper Chemisty, Vol. 36, No. 2, p. 211,
Aug. 1985. An provided by applicant but not cited on
PTOL-1449,
James E, Alexander, Chemical Pulp Recovery Plant with
Separation ofthe Floceulent Pulp,Clovis, Inc. Ape 4, 1992.
NonWovens Markets, Miller Freeman Publications Inc.,
Max. 16, 1990,
Primary ExaminerBrenda A Lam’
tn ABSTRACT
‘A process for the treatment of absorbent sanitary paper
products 1 separate such products ino components thereot
in a form suitable for recycling or re-use is disclose
absorbent sanitary paper products include disposable dia
pers, incontinence products, feminine hygiene products,
bedpads and other related absorbent and adsorbent products,
‘The process comprises the step of treating said products in
atleast one bath of an agueous solution to remove particulate
and/or soluble matter from the products. The bath is oper-
fated under conditions that are conducive to non-destructive
separation of said products into components thereof. In
preferred embodimens, the treated product ths obtained is
‘treated with atleast one aqueous washing solution and with
at least one aqueous solution of at least one of bleaching
agent and antimicrobial agent, and separate streams of
plastic and celulosic materials are recovered, The process
results in the recovery of usable products from absorbent
sanitary paper products.
31 Claims, 3 Drawing SheetsUSS. Patent
FIG.1
19
Sep. 24, 1996
Sheet 1 of 3
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20U.S. Patent Sep. 24, 1996 Sheet 2 of 3 5,558,7455,558,745
Sheet 3 of 3
Sep. 24, 1996
US. Patent
FIG.35,558,745
1
‘TREATMENT OF ABSORBENT SANITARY
PAPER PRODUCTS
The present application relates to the treatment of absor
bent sanitary paper products in a manner that provides
‘materials that may be recycled for further use. AS used
herein, absorbent sanitary paper products include disposable
Aiapets, incontinence products, feminine hygiene products,
bedpads and othr related absorbent and adsorbent products
‘Absorbent sanitary paper products typically consist of ()
‘non-woven shee formed from a liquid permeable material,
for example a liguid permeable membrane formed from
Polypropylene, polyethylene, or woven products formed
from cotion oF rayon, (il) a liquid impermeable back sheet
formed from for example polyethylene, polypropylene,
starch based degradable plastic films, wovea cloth or rubber,
and it) an adsorbent or absorbent core of air laid wood pulp
Aull, commonly referred to as ar felt, andor synthetic pulp
including polypropylene or polyethylene filaments that may
be bonded or unbonded, hemp or other adsorbent fibrous
material. The core is typically wrapped or encased in a
creped envelope of wet strength tissue paper or a material
with similar characterises. The wrapping on the core may
cor may not be breathable, biodegradable, odour degradable
or degradable or dissolvable by other means. The core
usually also contains a super absorbent polymer (SAP)
‘material, which is typically a polyacrylae, polyacrylamide,
crosslinked starch or other hydrophilic component, whic
ray be synthetic, and may be in granular, flbrous or lami-
nate form, possesting the ability to bond with water, urine or
other body Muids or retain them without substantial release
for discharge from the absorbent pation. Diapers and incon
tinence products typically wtlize pressure sensitive adbe-
sives for refastenable tape tabs or similar closure mechs
nisms. Feminine hygiene pads and incontinence products
often use pressure sensitive adhesives for glue ines o attach
the pad or linr to the user's undergarments. Diaper and
‘Incontinence products typically utilize elastic, polyurethane,
puckering and welding or adhesives to create close fitting
fulfs around the leg and waist openings to provide e more
leakproof fit,
‘Absorbent sanitary paper products are normaly disposed
of along with garbage generated by households, institutions,
hotels and the like, by incineration or in landfill disposal
sites Incineration tends to sesult in air or other pollation
being generated. Landfill disposal results in an accumulation
of such products,
‘Thu, the consequences ofthe convenience or necessity
‘fuse of absorbent sanitary paper products include problems
relating to disposal of such products. In addition, use of
either incineration or landill disposal results in Toss or
estruction of the components of the absorbent sanitary
paper products, rather than reeycling some or all of those
components to the same or other end-uses, The disposal
problems are becoming of ever increasing concer to envi-
ronmental and governmental authorities, and means aze
required for ellective disposal and uiliation of used absor-
ben sanitary paper products
Continuous batch type washing machines for the wash
ing of cloth goods are described by NL. Pellerin etal in US.
Pat, No. 4,485,508, issued 1984 Dec, 4, and by .M. Katzfoy
{in Canadian Patent 1,115,075, issued 1981 Dec.29.U.S, Pat
No, 4,162,019 of C.’G. Joa, issued 1979 Ju, 24, describes
cutting of sanitary anicles to expose the filler and then
recovery ofthe filler using suction means; the plastic back-
‘ng film is discarded. U.S. Pat. No, 4,500,040 of B, Steffens,
Which issued 1985 Feb, 19, describes shredding of sanitary
0
ey
s
2
anicles followed by recovery of the filler using suction
‘means. In U.S. Pat. No. 4,303,501, issued 1981 Dec. 1,
Steffens describes the use of sioves to recover Mock and cut
slbsorbent materials from discarded sanitary articles. In U.S,
Pat. No, 4,592,115, which issued 1986 Jun 3, 8. Holmstrom
discloses apparatus and a process for separating cellulose
fff fbres from waste fous material using an apertured
cylindrical separator. The aforementioned processes are
‘understood to be directed to dry separation and recovery of
‘components of reject producs, and not recovery of compo-
‘ents from products that have been used by consumers.
R. Albers discloses a drum for a continuously operaiing
laundry processing machine in US. Pat. No. 4,391,108,
which issued 1983 Jul. 5.
Tt has now been found that absorbent sanitary paper
products may be tresce! in a manner that permits recovery
‘of some or all ofthe components of such prodets in form
that facilitates recycling or other use of those components.
‘Accordingly, the present invention provides a process for
‘he ueatment of absorbent sanitary paper products to sepa
rate such producs into components thereof that are in @ form
Suitable for reeycling or reuse, said products being com-
prised of plastic, cellulosic and super absorbent polymer
fractions, characterized in thal said process comprises the
steps of:
(j) eating sad products in atleast one bath of an aqueous
‘solution under conditions that are conducive 10 non