Order of Experiments

Color Solubility Experiment Result Salt

Brown       FeCl3+MgSO4
Yes CuSO4+NH4Cl
Yes K2HgI4
No Cu(NO3)2+ZnSO4
Blue
Chromyl Yes CuCl2+CaCO3
No
chloride No CuCO3+Al2(SO4)3
Yes     NH4Cl+Al2(SO4)3
KMnO4 Yes BaCl2+ZnS
White K2Cr2O7 Yes (NH4)2CO3+BaCl2
No
Yes NH4CO3+Pb(NO3)2
K2HgI4
No CaCO3+Pb(NO3)2
 Anion Procedure
Slno. Experiment Reagents Observation Inference
White no Cu
1 Color Nil Green/Blue Cu
Brown FeCl3+MgSO4
Amorphous CO3 / S
2 Appearance Nil
Crystalline SO4/NO3/Cl
Soluble SO4/NO3/Cl
3 Solublity Water
Insoluble CO3 / S
4 Action of Heat Lime water milky CO3
Blue Cu
5 Flame test HCl Red Ca
Green Ba
HCl Pink Mg
6 Ash test Co(NO3)2 Green Zn
Blue Al
Dil. HCl Effervescence CO3
7 HCl test Pass thro Ca(OH)2 Milky
KMnO4
8 KMnO4 test Pink S
dil. H2SO4
Con H2SO4
9 Con,H2SO4 White fumes Cl
Rod in NH4OH
MnO2 Yellow gas
10 MnO2 test Starch iodide Cl
Con. H2SO4
blue
Cu Brown fumes
11 Cu turnings test NO3
Con.H2SO4
NaOH Punjent smell
12 NaOH test NH4
Rod in con. HCl White fumes
K2Cr2O7 Red vapour
Con.H2SO4
13 Cromyl chloride Cl
thro H2O yellow sol.
Add (CH3COO)2Pb Yellow ppte,
Na2CO3
14 Extract
Boil,cool,filter
Extract White ppte.
AgNO3
15 AgNO3 test Cl
HNO3
NH4Cl Soluble
CH3COOH White ppte.
Extract
16 (CH3COO)2Pb test (CH3COO)2Pb SO4
NH4Cl
Soluble
CH3COONH4
Extract
17
BaCl2 test Dil. HCl White ppte. SO4
BaCl2
Extract
Dil. H2SO4
18 Brown ring test Brown ring NO3
Fresh FeCl2
Con. H2SO4
 Cation Procedure

Slno. Cation Reagents Observation

K2HgI4 Brown ppte.
1 NH4 NaOH punjent smell
rod in HCl white fumes
Sol.
2 Pb White ppte,
Dil. HCl
above Sol.
3 Cu Black ppte.
H2 S
Al Sol. Gelatinous white ppte
4 Fe NH4Cl Brown ppte.
NH4OH
above Sol.
5 Zn dull white ppte.
H2 S
Ca Sol.
Ba NH4Cl
6 White ppte.
NH4OH
(NH4)2CO3
NH4Cl
7 Mg NH4OH White ppte.
Na2HPO4

Conformation of cation
Group Cation Reagents Observation
K2HgI4 Brown ppte.
0 NH4 NaOH Punjent smell
rod in HCl White fumes
K2CrO4 Yellow ppte.
1 Pb KI
Yellow ppte.
H2 O
NH4OH Blue ppte.
2 Cu
K4[Fe(CN)6] Brown ppte.
NaOH White ppte.
3 Al NH4OH
Red lake
Aluminon
K4[Fe(CN)6] Prussian Blue ppte.
4 Fe
NH4CNS Blood Red ppte.
NH4OH
Ca White ppte.
(COONH4)2
5
KCrO4 Yellow ppte.
Ba
dil. H2SO4 White ppte.
NaOH White ppte.
Magneson Blue ppte.
6 Mg
Crystalline white
Na2HPO4
ppte.