Appendix C

Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:827
Trimsize:8.5 in11 in
Appendix C
PHYSICAL PROPERTIES OF LIQUIDS AND GASES
TABLES OF PHYSICAL PROPERTIES OF LIQUIDS AND

GASES
C-1
C-2
C-3
C-4
C-5
C-6
C-7
C-8
C-9
C-10
C-11
C-12
C-13
C-14
C-15
C-16
C-17
C-18
C-19
C-20
Density of Liquids
Viscosity of Gas
Viscosity of Liquids
Heat Capacity of Gas
Heat Capacity of Liquid
Thermal Conductivity of Gas
Thermal Conductivity of Liquids and Solids
Surface Tension of Organic Liquids
Vapor Pressure
Enthalpy of Vaporization
Enthalpy of Formation
Gibbs Energy of Formation
Solubility in Salt Water
Solubility of Organic Compounds in Water as a
Function of Temperature
Henrys Law Constant for Gases in Water as a Function
of Temperature
Solubility of Selected Gases in Water as a Function of
Temperature
Solubility of Sulfur Compounds in Water as a Function
of Boiling Point for Mercaptans and Aromatics
C-21
C-22
Solubility of Naphthenes in Water

Solubility of Nitrogen Compounds in Water
Henrys Law Constant for Nitrogen Compounds in
Water
Coefcient of Thermal Expansion of Liquids
Adsorption Capacity of Activated Carbon
FURTHER READING
1. Yaws, C.L., Chemical Properties Handbook: Physical, Thermodynamic, Environmental, Transport, Safety, and Health Related
Properties for Organic and Inorganic Chemicals, McGraw-Hill,
1995.
2. Yaws, C.L., J.R. Hopper, and R.W. Pike, Calculating Solubility and
Henrys Law Constants for Gases in Water, Chem. Eng., Jun 1999,
p. 102.
3. Yaws, C.L., J.R. Hopper, Sunil R. Mishra, and R.W. Pike, Solubility
and Henrys Law Constants for Amines in Water, Chem. Eng., Aug
2001, p. 84.
4. Yaws, C.L., P. Bajaj, H. Singh, and R.W. Pike, Solubility and Henrys
Law Constants for Sulfur Compounds in Water, Chem. Eng., Aug 2003,
p. 60.
827
Fonts used:Times & Universal 55 family
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:828
828 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

TABLE C-1
Density of Liquids
( L g/ml, T K)
L = A B(1 T/Tc)n
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
NH3
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CC14
Cl2
CHC13
C6H12
C6H12O
C3H6
CH2C12
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
CH4O
Substance
1,1,1-Trichloroethane
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butanol (n-Butanol)
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
1-Propanol (n-Propanol)
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Ammonia
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Carbon tetrachloride
Chlorine
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Fluorine
Glycerol
Hydrogen
Hydrogen chloride
Hydrogen cyanide
Hydrogen peroxide
i-Butane (iso-Butane)
Methane
Methanol
Margins:Top:3p6
A
0.47476
0.47455
0.41231
0.46501
0.24597
0.37018
0.26891
0.23224
0.23981
0.23364
0.23682
0.27684
0.28207
0.35182
0.33578
0.27728
0.34645
0.23689
0.31190
0.30090
0.31132
0.47589
0.46382
0.29818
0.56607
0.56600
0.49807
0.27376
0.29681
0.25880
0.45965
0.27267
0.25635
0.24110
0.20087
0.26570
0.30654
0.32259
0.28889
0.21428
0.32503
0.31402
0.57092
0.34908
0.03125
0.44134
0.19501
0.43776
0.22281
0.15998
0.27197
Gutter:4p6
B
0.27258
0.25475
0.26533
0.28742
0.27227
0.28130
0.26674
0.26630
0.25776
0.25556
0.25649
0.27200
0.26004
0.26954
0.24080
0.25760
0.25822
0.25471
0.25000
0.26770
0.26192
0.28749
0.26160
0.27655
0.27663
0.27315
0.25274
0.27408
0.24340
0.27400
0.25678
0.27608
0.24291
0.26785
0.27330
0.26395
0.25856
0.27464
0.26438
0.28061
0.25499
0.26089
0.28518
0.24902
0.34730
0.26957
0.18589
0.24982
0.27294
0.28810
0.27192
n
0.29333
0.31000
0.28700
0.31041
0.29074
0.30470
0.24570
0.28530
0.28562
0.28571
0.28571
0.24940
0.27760
0.26843
0.26990
0.29903
0.30701
0.28870
0.28571
0.28180
0.27997
0.32260
0.29030
0.29053
0.29000
0.28830
0.28766
0.28511
0.28570
0.28571
0.29020
0.29358
0.27364
0.24800
0.28330
0.23670
0.27800
0.23140
0.29210
0.28571
0.17200
0.28253
0.29000
0.15410
0.27560
0.31870
0.28206
0.28770
0.27301
0.27700
0.23310
Tc
545.00
602.00
523.00
561.00
425.37
587.00
562.93
419.59
617.05
595.65
566.60
536.71
461.00
592.71
569.15
508.20
615.00
405.65
699.00
562.16
628.00
552.00
304.19
132.92
556.35
417.15
536.40
553.54
625.15
397.91
510.00
466.70
560.95
437.65
305.42
516.25
523.30
460.35
617.17
282.36
645.00
469.15
144.31
723.00
33.18
324.65
456.65
730.15
408.14
190.58
512.58
Font Size:9/10 pt
Tmin
242.75
236.50
176.19
237.49
164.25
284.95
183.85
87.80
206.89
219.63
171.45
146.95
150.15
289.81
200.15
178.45
286.65
195.41
267.13
278.68
267.95
161.58
216.58
68.15
250.33
172.12
209.63
279.69
296.60
145.73
178.01
156.85
234.18
180.96
90.35
159.05
189.60
136.75
178.20
104.01
260.15
161.45
53.48
291.33
13.95
159.97
259.91
272.74
113.54
90.67
175.47
Tmax
545.00
602.00
523.00
561.00
425.37
587.00
562.93
419.59
617.05
595.65
566.60
536.71
461.00
592.71
569.15
508.20
615.00
405.65
699.00
562.16
628.00
552.00
304.19
132.92
556.35
417.15
536.40
553.54
625.15
397.91
510.00
466.70
560.95
437.65
305.42
516.25
523.30
460.35
617.17
282.36
645.00
469.15
144.31
723.00
33.18
324.65
465.65
730.15
408.14
190.58
512.58
Text Width:41p6
L at 25 C
1.330
1.435
1.168
1.246
0.615
1.029
0.806
0.588
0.737
0.715
0.711
0.802
0.774
1.043
1.077
0.786
1.046
0.602
1.018
0.873
0.953
1.256
0.713
1.583
1.398
1.480
0.773
0.960
0.619
1.318
0.708
0.810
0.650
0.315
0.787
0.894
0.890
0.865
1.110
0.862
1.257
0.796
0.680
1.443
0.552
0.787
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:829
APPENDIX C
829
TABLE C-1(continued)
L = A B(1 T/ Tc)n
( L g/ml, T K)
A
No.
Formula
Substance
52 CH3Br
Methyl bromide
0.60859
53 CH3Cl
Methyl chloride
0.35821
Methyl isobutyl ketone
0.26654
54 C6H12O
Methylamine
0.20168
55 CH5N
m-Xylene
0.27866
56 C8H10
57 C10H8
Naphthalene
0.30619
58 C4H10
n-Butane
0.22827
59 C10H22
n-Decane
0.23276
60 C7H16
n-Heptane
0.23237
61 C6H14
n-Hexane
0.23242
62 C6H5NO2
Nitrobenzene
0.36140
63 N2
Nitrogen
0.31205
64 C9H20
n-Nonane
0.23364
65 C8H18
n-Octane
0.22807
66 C5H12
n-Pentane
0.23143
67 O2
Oxygen
0.43533
68 C8H10
o-Xylene
0.28381
69 C6H6O
Phenol
0.41476
70 C8H10
p-Xylene
0.27984
71 C5H5N
Pyridine
0.30752
Styrene
0.29383
72 C8H8
73 C7H8
Toluene
0.29999
74 C4H6O2
Vinyl acetate
0.31843
75 H2O
Water
0.34710
L density of liquid, g/ml
A, B, n, and Tc regression coefficients of chemical compound
T temperature, K
Tmin minimum temperature, K
Tmax maximum temperature, K
Margins:Top:3p6
B
0.26292
0.26109
0.25887
0.21405
0.25925
0.25037
0.27240
0.25240
0.26020
0.26500
0.24731
0.28479
0.25556
0.25476
0.26923
0.28772
0.26083
0.32162
0.26003
0.24333
0.26315
0.27108
0.25803
0.27400
Gutter:4p6
n
0.28030
0.28690
0.28571
0.22750
0.27243
0.28300
0.28630
0.28570
0.27910
0.27810
0.28570
0.29250
0.28571
0.26940
0.28215
0.29240
0.27410
0.32120
0.27900
0.30450
0.28570
0.29889
0.28270
0.28571
Tc
467.00
416.25
571.40
430.05
617.05
748.35
425.18
618.45
540.26
507.43
719.00
126.10
595.65
568.83
469.65
154.58
630.37
694.25
616.26
619.95
648.00
591.79
524.00
647.13
Font Size:9/10 pt
Tmin
179.55
175.45
189.15
179.69
225.30
353.43
134.86
243.49
182.57
177.84
278.91
63.15
219.63
216.38
143.42
54.35
247.98
314.06
286.41
231.53
242.54
178.18
180.35
273.16
Tmax
467.00
416.25
571.40
430.05
617.05
748.35
425.18
618.45
540.26
507.43
719.00
126.10
595.65
568.83
469.65
154.58
630.37
694.25
616.26
619.95
648.00
591.79
524.00
647.13
L at 25 C
1.662
0.913
0.796
0.655
0.861
0.573
0.728
0.682
0.656
1.199
0.715
0.699
0.621
0.876
0.858
0.979
0.900
0.865
0.926
1.027
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:830

TABLE C-2 Viscosity of Gas
G = A + BT + CT 2
No.
Formula
Substance
Tmin
Tmax
G at 25 C
G at Tmin
G at Tmax
4.0308E01
6.8618E05
347
997
112.39
314.45
8.293 3.3989E01
5.3678E05
387
987
115.21
274.89
4.0085E01
1.1779E04
320
472
103.22
149.97
1.025 3.1792E01
4.1853E05
322
561
99.06
166.21
250
650
86.60
74.77
167.28
374
994
106.64
277.99
391
1000
92.82
220.48
175
800
77.48
43.51
189.49
146.63
C2H3Cl3
C2H3Cl3
C2H4Cl2
1,1-Dichloroethane
C2H4Cl2
1,2-Dichloroethane
C4H6
1,3-Butadiene
10.256 2.6833E01
4.1148E05
C4H8O2
1,4-Dioxane
16701 3.4988E01
5.3736E05
C4H10O
11.144
2.8790E01
5.6275E05
C4H8
1-Butene
9.143 3.1562E01
8.4164E05
C10H20
1-Decene
10
C9H20
1-Nonane (n-Nonane)
11
C8H16
1-Octene
12
C3H8O
13
C2H4O
Acetaldehyde
14
C2H4O2
Acetic acid
19.216
12.991
4.015 1.8083E01
3.8216E05
444
1000
76.77
6.802 1.8688E01
3.4929E07
273
773
48.95
44.24
137.86
2.722 2.0327E01
4.3879E05
394
994
76.00
161.42
3.2171E01
5.8021E05
200
1000
75.87
47.13
248.80
0.069 3.0246E01
4.2372E05
294
1000
86.48
85.33
260.16
2.2087E04
366
523
86.97
154.71
262.12
14.894
28.660
2.3510E01
15
C4H6O3
Acetic anhydride
1.485 2.8869E01
2.3391E05
295
993
82.51
81.64
16
C3H6O
Acetone
4.055 2.6655E01
5.6936E06
300
650
75.40
166.80
17
C3H4O2
Acrylic acid
6.532 3.0600E01
4.6620E05
287
1000
80.56
77.45
252.85
18
NH3
Ammonia
7.874 3.6700E01
4.4700E06
195
1000
101.28
63.61
355.10
19
C6H7N
Aniline
6.918 2.5935E01
3.4348E05
458
1000
104.66
218.08
20
C6H6
Benzene
0.151 2.5706E01
8.9797E06
287
628
75.69
72.89
157.74
21
C4H8O2
Butyric acid
5.781 2.6159E01
3.4903E05
268
1000
69.11
61.82
220.91
22
CS2
Carbon disulfide
7.700 3.6594E01
2.5416E05
273
583
99.15
90.31
197.00
23
CO2
Carbon dioxide
11.811 4.9838E01
1.0851E04
195
1500
150.76
104.87
515.23
24
CO
Carbon monoxide
23.811 5.3944E01
1.5411E04
68
1250
170.95
59.78
457.31
25
CCl4
7.745 3.9481E01
1.1150E04
280
800
100.06
94.06
236.74
26
CHCl3
Chloroform
4.392 3.7309E01
5.1696E05
250
700
102.25
85.65
231.44
27
Cl2
Chlorine
3.571 4.8700E01
8.5300E05
200
1000
134.03
90.41
398.09
28
C6H12
Cyclohexane
29
C6H12O
Cyclohexanol
30
C3H6
Cyclopropane
31
CH2Cl2
Dichloromethane
32
C4H10O
33
C5H10O
34
C2H7N
Dimethylamine
35
C2H6
36
C2H6O
37
C4H8O2
38
1.190 2.4542E01
3.8334E05
315
600
74.69
134.64
2.9086E01
3.9472E05
400
1000
96.49
237.85
9.521 3.7037E01
13.542
1.3138E04
240
446
89.23
71.80
129.53
4.3745E01
7.7549E05
273
993
103.16
93.27
337.55
Diethyl ether
7.932 3.0235E01
7.3858E05
200
1000
75.65
49.58
220.56
Diethyl ketone
3.593 2.4308E01
3.7613E05
234
1000
65.54
51.23
201.87
9.275 2.8958E01
1.3875E06
250
450
76.94
63.03
120.75
Ethane
0.514 3.3449E01
7.1071E05
150
1000
93.92
49.09
263.93
Ethanol
1.499 3.0741E01
4.4479E05
200
1000
89.20
61.20
264.43
Ethyl acetate
9.259 3.0725E01
7.1069E05
190
1000
76.03
46.55
226.92
C2H5Cl
Ethyl chloride
0.458 3.2827E01
1.2467E05
213
523
97.22
69.81
168.73
39
C8H10
Ethylbenzene
4.267 2.4735E01
5.4264E05
409
1000
87.82
188.82
40
C2H4
Ethylene
3.985 3.8726E01
1.1227E04
150
1000
101.50
51.58
271.00
7.178 3.1246E01
261.25
20.372
41
C2H6O2
Ethylene glycol
42
C2H4O
Ethylene oxide
43
F2
Fluorine
44
C3H8O3
Glycerol
45
H2
46
HCl
47
CHN
Hydrogen cyanide
48
H2O2
Hydrogen peroxide
49
C4H10
50
CH4
Methane
51
CH3OH
Methanol
4.4028E05
260
1000
82.07
71.09
3.7672E01
7.7599E05
250
1000
93.24
77.15
286.94
0.811 8.9800E01
3.9600E04
90
500
231.59
76.76
348.97
2.8879E01
3.4277E05
563
993
128.61
229.85
Hydrogen
27.758 2.1200E01
3.2800E05
150
1500
88.03
58.81
271.76
Hydrogen chloride
9.118 5.5500E01
1.1100E04
200
1000
146.44
97.42
434.55
8.486 9.0368E02
7.9146E05
300
425
25.75
44.22
8.039 2.7000E01
8.2900E05
373
600
120.24
199.81
12.180
23.119
4.731 2.9131E01
8.0995E05
150
1000
74.92
37.14
205.58
3.844 4.0112E01
1.4303E04
91
850
110.72
39.15
241.46
14.236 3.8935E01
6.2762E05
240
1000
96.27
75.59
312.35
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:831
APPENDIX C
831
G = A + BT + CT 2
No .
Formula
52 CH 3 Br
53 CH 3 Cl
54 C 6 H 12 O
55 CH 5 N
G at Tmin
G at Tmax
Tmin
Tmax G at 25 C
Methyl bromide
27.740 5.5901E01 7.0942E05
260
440
132.62
112.81
Methyl chloride
1.374 3.8627E01 4.8650E05
230
700
109.47
84.90
245.18
3.237 2.3310E01 3.5612E05
189
1000
63.10
39.55
194.25
267
250
353
150
287
338
300
450
150
273
374
303
150
250
455
193
286
369
243
200
275
346
280
1000
1000
1000
1200
783
700
1000
1000
1500
773
670
900
1500
1000
1000
750
1000
998
1000
1000
600
1000
1073
89.97
55.94
75.33
47.45
175.52
48.95
201.85
58.51
82.61
55.09
61.70
129.10
71.22
89.68
80.63
44.15
68.47
36.99
43.78
65.93
65.30
109.59
111.67
44.24
68.20
71.76
126.04
46.59
108.98
53.72
52.25
92.05
48.94
85.07
65.89
91.06
82.07
262.18
196.05
201.78
242.75
134.66
133.97
196.70
249.75
533.12
137.86
121.92
183.91
633.08
201.16
228.40
179.92
205.52
247.93
203.94
383.30
139.82
239.65
404.97
Substance
Methylamine
5.334 3.4181E01
56 C8H10
21.620 2.7820E01
m-Xylene
Naphthalene
16.789 2.5406E01
57 C10H8
58 C4H10
n-Butane
4.946 2.9001E01
59 C10H22
n-Decane
7.297 1.8506E01
60 C7H16
n-Heptane
10.378 2.4401E01
n-Hexane
8.222 2.6229E01
61 C6H14
Nitrobenzene
16.569 2.9184E01
62 C6H5NO2
63 N2
Nitrogen
42.606 4.7500E01
64 C9H20
6.802 1.8688E01
n-Nonane
65 C8H18
3.940 1.6640E01
n-Octane
66 C5H12
3.202 2.6746E01
n-Pentane
Oxygen
44.224 5.6200E01
67 O2
68 C8H10
19.763 2.8022E01
o-Xylene
69 C6H6O
Phenol
7.185 2.7179E01
70 C3H8
Propane
5.462 3.2722E01
17.226 2.5098E01
71 C8H10
p-Xylene
72 C5H5N
Pyridine
5.739 2.7135E01
73 C8H8
Styrene
10.035 2.5191E01
74 SO2
Sulfur dioxide
11.103 5.0200E01
Toluene
75 C7H8
1.787 2.3566E01
76 C4H6O2
Vinyl acetate
7.462 3.0466E01
77 H2O
Water
36.826 4.2900E01
G viscosity of gas, P
A, B, and C regression coefficients for chemical compound
T temperature, K
Margins:Top:3p6
7.4297E05
6.0531E05
3.5495E05
6.9665E05
4.8008E06
5.4003E05
5.7366E05
2.5523E05
9.8800E05
3.4929E07
1.4470E05
6.6178E05
1.1300E04
5.9293E05
3.6205E05
1.0672E04
2.8232E05
1.7202E05
3.7932E05
1.0800E04
9.3508E06
5.7544E05
1.6200E05
Gutter:4p6
Font Size:9/10 pt
204.49
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:832

TABLE C-3 Viscosity of Liquids
log10 liq = A + B/T + CT + CT 2
No.
Formula
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
NH3
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CCl4
Cl2
CHCl3
C6H12
C6H12O
C3H6
CH2Cl2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Ammonia
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chlorine
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Fluorine
Glycerol
Hydrogen
Hydrogen chloride
Hydrogen cyanide
Hydrogen peroxide
Methane
3.9096 7.0709E+02
3.2716 6.8810E+02
3.8388 5.9046E+02
0.1656 2.7576E+02
0.3772 7.9658E+01
7.5724 1.3813E+03
5.3970 1.3256E+03
4.9218 4.9503E+02
6.8845 1.1003E+03
6.0742 9.6861E+02
5.6209 8.1305E+02
3.7702 9.9151E+02
6.6171 6.8123E+02
3.8937 7.8482E+02
17.3580 2.3611E+03
7.2126 9.0305E+02
15.9215 2.4408E+03
8.5910 8.7640E+02
13.8625 2.5109E+03
7.4005 1.1815E+03
7.9846 1.3636E+03
9.1108 1.1216E+03
19.4921 1.5948E+03
1.1224 5.7858E+01
6.4564 1.0379E+03
0.7681 1.5140E+02
47831
6.9902E+02
4.7423 2.5322E+02
5.3792 1.8793E+03
3.2541 3.2192E+02
5.1043 6.8653E+02
8.5060 1.0020E+03
9.2905 1.2716E+03
11.5558 1.2126E+03
4.2694 2.8954E+02
6.4406 1.1176E+03
3.6861 5.5228E+02
4.4279 5.1891E+02
5.2585 8.3065E+02
4.5611 3.0811E+02
16.9728 3.1886E+03
5.7794 6.7020E+02
1.5760 8.5630E+01
18.2152 4.2305E+03
7.0154 4.0791E+01
1.5150 1.9460E+02
12.0812 1.3183E+03
1.6150 5.0380E+02
13.4207 1.3131E+03
7.3801 3.1925E+02
Margins:Top:3p6
Gutter:4p6
Tmin
Tmax
7.5847E03
4.8932E03
8.0953E03
3.3493E03
5.8889E03
1.3556E02
6.2223E03
1.4390E02
1.4341E02
1.2677E02
1.2523E02
4.0836E03
1.9979E02
6.6650E03
4.2734E02
1.8385E02
3.4383E02
2.6810E02
2.5681E02
1.4888E02
1.6315E02
2.3216E02
7.9274E02
4.9174E03
1.4021E02
8.0650E04
1.0929E02
1.6927E02
1.7011E03
9.9766E03
1.2459E02
2.2753E02
2.1925E02
3.4999E02
1.7111E02
1.3721E02
8.0018E03
1.2035E02
1.0784E02
1.8030E02
3.2537E02
1.5686E02
4.0730E04
2.8705E02
2.3714E01
3.0670E03
3.5234E02
3.5010E04
4.4329E02
4.7934E02
9.1662E06
5.4671E06
9.9210E06
1.4093E06
2.9221E06
1.1464E05
5.5062E06
2.0853E05
1.3520E05
1.2675E05
1.3384E05
5.4586E06
2.5563E05
7.5606E06
3.8202E05
2.0353E05
2.7677E05
3.6120E05
1.8281E05
1.3713E05
1.4511E05
2.2648E05
1.2025E04
8.2233E06
1.4107E05
4.0750E07
1.2244E05
1.2472E05
1.0187E07
1.8191E05
1.4540E05
2.5780E05
2.1036E05
4.1253E05
3.6092E05
1.5465E05
1.0439E05
1.6620E05
1.0618E05
3.8145E05
2.4480E05
1.9462E05
2.7250E06
1.8648E05
4.0830E03
1.3760E05
4.0185E05
1.1680E06
5.5793E05
1.4120E04
243
237
176
245
250
288
250
160
273
220
250
220
260
290
265
223
293
195
268
285
268
235
219
69
265
172
210
285
303
146
208
233
274
240
98
240
220
150
210
105
261
190
54
293
14
159
260
273
190
91
545
602
523
561
425
587
563
420
617
596
567
537
461
593
569
508
615
406
699
562
628
552
304
133
556
417
536
554
625
398
510
467
561
438
305
516
523
460
617
282
645
469
145
723
33
325
457
728
408
191
Font Size:9/10 pt
liq
liq
at 25 C
at Tmax
0.810
1.021
0.471
0.769
0.141
1.211
2.599
0.150
0.758
0.672
0.447
1.939
0.225
1.132
0.806
0.308
1.138
0.135
3.898
0.606
1.457
0.363
0.064
0.893
0.343
0.539
0.901
0.152
0.417
0.222
0.438
0.190
0.039
1.057
0.421
0.265
0.629
17.645
0.260
749.338
0.067
0.188
1.189
0.174
0.063
0.069
0.065
0.078
0.039
0.061
0.052
0.042
0.040
0.040
0.041
0.05
0.043
0.053
0.055
0.045
0.053
0.032
0.056
0.055
0.051
0.068
0.055
0.064
0.070
0.214
0.073
0.054
0.054
0.044
0.065
0.044
0.045
0.042
0.035
0.049
0.050
0.052
0.050
0.038
0.059
0.053
0.079
0.044
0.004
0.042
0.033
0.052
0.039
0.020
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:833
APPENDIX C
833
log10 liq = A + B/T + CT + CT 2
T min
T max
Methyl bromide
51 CH3Br
9.5533 1.0306E+03 2.8322E02 3.1920E05 193
Methyl chloride
52 CH3Cl
7.3473 8.5395E+02 1.9485E02 2.3484E05 249
Methyl isobutyl ketone 3.0570 5.0050E+02 6.5038E03 8.8243E06 246
53 C6H12O
Methylamine
54 CH5N
9.4670 9.8286E+02 2.8918E02 3.5672E05 180
m-Xylene
55 C8H10
6.0517 9.2460E+02 1.2583E02 1.1850E05 225
Naphthalene
56 C10H8
10.3716 1.8572E+03 1.9320E02 1.4012E05 353
n-Butane
57 C4H10
6.8590 6.7393E+02 2.1973E02 3.0686E05 180
n-Decane
58 C10H22
6.0716 1.0177E+03 1.2247E02 1.1892E05 243
n-Heptane
59 C7H16
5.7782 8.0587E+02 1.3355E02 1.4794E05 183
n-Hexane
60 C6H14
5.0715 6.5536E+02 1.2349E02 1.5042E05 178
61 C6H5NO2 Nitrobenzene
7.7710 1.4019E+03 1.4653E02 1.1512E05 273
Nitrogen
62 N2
15.6104 4.6505E+02 1.6259E01 6.3353E04 63
n-Nonane
63 C9H20
6.0742 9.6861E+02 1.2677E02 1.2675E05 220
n-Octane
64 C8H18
5.9245 8.8809E+02 1.2955E02 1.3596E05 216
n-Pentane
65 C5H12
7.1711 7.4736E+02 2.1697E02 2.7176E05 143
Oxygen
66 O2
5.0957 1.7983E+02 3.9779E02 1.4664E04 54
o-Xylene
67 C8H10
7.8805 1.2500E+03 1.6116E02 1.3993E05 268
Phenol
68 C6H6O
1.5349 4.2620E+02 9.1577E03 6.2322E06 318
p-Xylene
69 C8H10
9.4655 1.4400E+03 1.9910E02 1.6994E05 288
Pyridine
70 C5H5N
6.8100 1.1496E+03 1.3229E02 1.1661E05 232
Styrene
71 C8H8
8.0291 1.2666E+03 1.6127E02 1.3475E05 243
Sulfur dioxide
72 SO2
2.6700 4.0670E+02 6.1440E03 1.2540E05 200
Toluene
73 C7H8
5.1649 8.1068E+02 1.0454E02 1.0488E05 200
Vinyl acetate
74 C4H6O2
9.0671 1.1863E+03 2.2663E02 2.3208E05 250
Water
75 H2O
10.2158 1.7925E+03 1.7730E02 1.2631E05 273
liq viscosity of gas, P
T temperature, K
467
416
571
430
617
748
425
618
540
507
719
125
596
569
470
150
630
694
616
620
648
431
592
524
643
No.
Formula
Substance
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
liq
at 25 C
0.324
0.173
0.598
0.191
0.559
0.168
0.863
0.390
0.296
1.890
0.672
0.511
0.245
0.747
0.616
0.898
0.675
0.257
0.548
0.403
0.911
liq
at Tmax
0.083
0.056
0.045
0.045
0.050
0.053
0.033
0.040
0.041
0.041
0.058
0.034
0.040
0.040
0.041
0.059
0.050
0.062
0.049
0.058
0.052
0.039
0.052
0.050
0.056
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:834

TABLE C-4 Heat Capacity of Gas
Cp = A + BT + CT 2 + DT 3 + ET 4
No. Formula
Substance
A
1 C2H3C13 1,1,1-Trichloroethane
18.674
2 C2H3C13 1,1,2-Trichloroethane
28.881
15.730
3 C2H4C12 1,1-Dichloroethane
4 C2H4C12 1,2-Dichloroethane
37.275
5 C4H6
1,3-Butadiene
18.835
46.223
6 C4H8O2 1,4-Dioxane
7 C4H10O 1-Butanol (n-Butanol)
8.157
1-Butene
24.915
8 C4H8
1-Decene
121.553
9 C10H20
1-Nonane (n-Nonane)
29.687
10 C9H10
11 C8H16
1-Octene
56.266
31.507
12 C3H8O
Acetaldehyde
34.140
13 C2H4O
14 C2H4O2 Acetic acid
34.850
9.500
15 C4H6O3 Acetic anhydride
16 C3H6O
Acetone
35.918
7.755
17 C3H4O2 Acrylic acid
18 NH3
Ammonia
33.573
Aniline
22.062
19 C6H7N
20 C6H6
Benzene
31.368
21 C4H8O2 Butyric acid
14.368
Carbon disulfide
20.461
22 CS2
Carbon dioxide
27.437
23 CO2
24 CO
Carbon monoxide
29.556
25 CCl4
19.816
26 Cl2
Chlorine
27.213
27 CHCl3
Chloroform
22.487
28 C6H12
Cyclohexane
13.783
29 C6H12O Cyclohexanol
17.124
Cyclopropane
21.172
30 C3H6
31 CH2Cl2 Dichloromethane
26.694
35.979
32 C4H10O Diethyl ether
33 C5H10O Diethyl ketone
49.800
Dimethylamine
30.638
34 C2H7N
Ethane
28.146
35 C2H6
Ethanol
27.091
36 C2H6O
69.848
37 C4H8O2 Ethyl acetate
38 C2H5Cl Ethyl chloride
35.946
39 C8H10
Ethylbenzene
20.527
40 C2H4
Ethylene
32.083
41 C2H6O2 Ethylene glycol
48.218
Ethylene oxide
30.827
42 C2H4O
43 F2
Fluorine
27.408
9.656
44 C3H8O3 Glycerol
45 H2
Hydrogen
25.399
46 HCl
Hydrogen chloride
29.244
47 CHN
Hydrogen cyanide
25.766
48 H2O2
Hydrogen peroxide
36.181
6.772
49 C4H10
Methane
34.942
50 CH4
51 CH4O
Methanol
40.046
Margins:Top:3p6
B
3.3443E01
2.4893E01
2.6124E01
1.4362E01
2.0473E01
5.7263E01
4.1032E01
2.0648E01
2.0974E01
6.6821E01
4.0665E01
2.3082E01
4.0020E02
3.7626E02
3.4425E01
9.3896E02
2.9386E01
1.2581E02
5.7313E01
4.7460E01
3.9591E01
1.2299E01
4.2315E02
6.5807E03
3.3311E01
3.0426E02
1.9823E01
2.0742E01
3.3700E01
6.3106E02
8.3984E02
2.8444E01
2.6897E01
1.0737E01
4.3447E02
1.1055E01
8.2338E02
5.2294E02
5.9578E01
1.4831E02
1.9073E01
7.6041E03
1.2928E02
4.2826E01
2.0178E02
1.2615E03
3.7969E02
8.2657E03
3.1447E01
3.9957E02
3.8287E02
Gutter:4p6
C
3.4963E04
1.7639E04
2.1489E04
1.0378E05
6.2485E05
3.8800E04
2.2645E04
5.9828E05
7.8760E04
9.6492E05
1.5805E04
7.8983E05
1.5634E04
2.8311E04
8.6736E05
1.8730E04
2.0878E04
8.8906E05
4.5651E04
3.1137E04
1.8906E04
1.6184E04
1.9555E05
2.0130E05
5.0511E04
3.3353E05
2.1676E04
5.3682E04
2.8176E04
2.9197E04
8.9712E06
1.2673E06
5.0669E05
1.5824E04
1.8946E04
1.0957E04
3.7159E04
2.0321E04
3.0849E04
2.4774E04
6.6117E08
3.2347E04
7.0701E06
2.6797E04
3.8549E05
1.1210E06
1.2416E05
6.6420E05
1.0271E04
1.9184E04
2.4529E04
(Cpjoule/(mol K), TK)

Tmin
D
E
1.8764E07 4.0744E11 100
5.2632E08 3.5668E12 200
9.5761E08 1.8004E11 200
7.8305E08 2.8872E11 200
1.7148E07 6.0858E11 100
1.1392E07 9.0669E12 298
6.0372E08 6.2802E12 200
1.4166E07 4.7053E11 200
8.6982E07 2.6033E10 150
2.0014E07 8.2200E11 200
3.2277E07 1.0600E10 200
6.3696E09 8.6908E13 100
1.6445E07 4.7248E11 100
3.0767E07 9.2646E11 50
7.6769E08 3.6721E11 200
2.1643E07 6.3174E11 100
7.1591E08 9.0960E12 250
7.1783E08 1.8569E11 100
1.8410E07 2.9867E11 200
8.5237E08 5.0524E12 200
7.6462E09 2.0812E11 298
1.0199E07 2.4444E11 100
3.9968E09 2.9872E13 50
60
1.2227E08 2.2617E12
3.4057E07 8.4249E11 100
1.5961E08 2.7021E12 50
1.1636E07 2.4555E11 100
6.3012E07 1.8988E10 100
4.2713E07 1.3215E10 200
3.2708E07 9.9730E11 100
5.0924E08 1.8726E11 100
1.0128E07 3.4529E11 200
1.5227E07 4.9510E11 200
1.9418E07 5.8509E11 200
1.9082E07 5.3349E11 100
1.5046E07 4.6601E11 100
4.1129E07 1.2369E10 200
2.2795E07 6.9123E11 100
3.5621E08 1.2409E11 200
2.3766E07 6.8274E11 60
1.8834E08 1.2555E11 200
3.2747E07 9.7271E11 50
1.6302E08 5.9789E12 100
3.1794E08 2.7745E11 298
3.1880E08 8.7585E12 250
4.9676E09 2.4963E12 50
3.2240E09 2.2610E12 100
6.9944E08 2.0951E11 100
3.6849E08 2.0429E11 200
1.5303E07 3.9321E11 50
2.1679E07 5.9909E11 100
Font Size:9/10 pt
Tmax
1500
1500
1500
1500
1500
1500
2980
1500
1500
1500
1500
2980
1500
1500
1500
1500
1500
1500
1500
1500
1200
1500
5000
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1200
1500
1500
1500
1500
1500
1500
1500
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:835
APPENDIX C
835
Cp = A + BT + CT 2 + DT 3 + ET 4
No. Formula
Substance
A
B
Methyl bromide
2.4374E02
52 CH3Br
29.146
2.404
5.8495E01
53 C6H12O
54 CH5N
Methylamine
40.039
1.5108E02
55 C8H10
m-Xylene
16.725
5.6424E01
56 C10H8
Naphthalene
67.099
4.3239E02
n-Butane
20.056
2.8153E01
57 C4H10
n-Decane
31.780
7.4489E01
58 C10H22
n-Heptane
26.984
5.0387E01
59 C7H16
n-Hexane
25.924
4.1927E01
60 C6H14
-16.202
5.6182E01
62 N2
Nitrogen
29.342
3.5395E03
n-Nonane
29.687
6.6821E01
63 C9H20
64 C8H18
n-Octane
29.053
5.8016E01
n-Pentane
26.671
3.2324E01
65 C5H12
Oxygen
29.526
8.8999E03
66 O2
o-Xylene
0.182
5.1344E01
67 C8H10
68 C6H6O
Phenol
4.408
3.6338E01
p-Xylene
17.360
5.6470E01
69 C8H10
Pyridine
23.262
1.1251E01
70 C5H5N
71 C8H8
Styrene
71.201
5.4767E02
72 SO2
Sulfur dioxide
29.637
3.4735E02
73 C7H8
Toluene
24.097
5.2187E01
Vinyl acetate
27.664
2.3366E01
74 C4H6O2
75 H2O
Water
33.933
8.4186E03
Cp heat capacity of ideal gas, joule/(mol K)
A, B, C, D, and E regression coefficients for chemical compound
T temperature, K
Margins:Top:3p6
Gutter:4p6
(Cpjoule/(mol K), T K)
Tmin
C
D
E
1.0655E04 1.1324E07 3.3241E11 100
3.7647E04
1.2418E07 1.7051E11 298
2.5012E04 2.3336E07 6.5582E11 100
2.6465E04
1.3381E08 1.5869E11 200
9.1740E04 1.0019E06 3.0896E10 50
1.3143E05 9.4571E08 3.4149E11 200
1.0945E04 2.2668E07 9.3458E11 200
4.4748E05 1.6835E07 6.5183E11 200
1.2491E05 1.55916E07 5.8784E11 200
3.9302E04
1.0043E07 1.2252E12 200
1.0076E05 4.3116E09 2.5935E13 50
9.6492E05 2.0014E07 8.2200E11 200
5.7103E05 1.9548E07 7.6614E11 200
4.2820E05 1.6639E07 5.6036E11 200
3.8083E05 3.2629E08 8.8607E12 50
2.0212E04 2.1615E08 2.3212E11 200
6.0417E05 1.2794E07 5.5287E11 100
2.6293E04
1.1217E08 1.6544E11 200
3.7351E04 4.5402E07 1.4286E10 50
6.4793E04 6.9875E07 2.1232E10 100
9.2903E06 2.9885E08 1.0937E11 100
2.9827E04
6.1220E08 1.2576E12 200
6.2106E05 1.6972E07 5.7917E11 100
2.9906E05 1.7825E08 3.6934E12 100
Font Size:9/10 pt
Tmax
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:836

TABLE C-5 Heat Capacity of Liquids
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
NH3
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CCl4
Cl2
CHCl3
C6H12
C6H12O
C3H6
CH2Cl2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
CH3OH
Cp = A + BT + CT 2 + DT 3
Substance
A
11.142
34.934
1,1-Dichloroethane
57.325
1,2-Dichloroethane
26.310
1,3-Butadiene
34.680
1,4-Dioxane
20.729
83.877
1-Butene
74.597
1-Decene
137.962
1-Nonane (n-Nonane)
98.040
1-Octene
119.984
88.080
Acetaldehyde
45.056
Acetic acid
18.944
Acetic anhydride
71.831
Acetone
46.878
Acrylic acid
18.242
Ammonia
182.157
Aniline
63.288
Benzene
31.663
Butyric acid
28.210
Carbon disulfide
39.938
Carbon dioxide
338.956
Carbon monoxide
19.312
9.671
Chlorine
127.601
Chloroform
28.296
Cyclohexane
44.417
Cyclohexanol
47.321
Cyclopropane
30.543
Dichloromethane
38.941
Diethyl ether
75.939
Diethyl ketone
26.231
Dimethylamine
36.962
Ethane
38.332
Ethanol
59.342
Ethyl acetate
62.832
Ethyl chloride
60.180
Ethylbenzene
102.11
Ethylene
25.597
Ethylene glycol
75.878
Ethylene oxide
35.720
Fluorine
83.829
Glycerol
132.145
Hydrogen
50.607
Hydrogen chloride
73.993
Hydrogen cyanide
123.155
Hydrogen peroxide
15.248
71.791
Methane
0.018
Methanol
40.152
Margins:Top:3p6
B
1.0501E+00
8.5054E01
5.6014E01
7.7555E01
7.3205E01
1.2913E+00
5.6628E01
3.3434E04
1.1934E+00
1.3538E+00
8.3332E01
4.0224E01
4.4853E01
1.0971E+00
8.8879E01
6.2652E01
1.2106E+00
3.3618E+00
9.8960E01
1.3043E+00
1.1040E+00
2.3565E01
5.2796E+00
2.5072E+00
9.3363E01
6.0215E01
6.5897E01
1.6016E+00
1.9131E+00
5.0198E01
4.9008E01
7.7335E01
1.2822E+00
9.5817E01
4.1006E01
3.6358E01
8.4097E01
3.4553E01
5.5959E01
5.7078E01
6.4182E01
4.2908E01
7.8518E01
8.6007E01
6.1136E+00
1.2946E01
1.7769E+00
6.7693E01
4.8472E01
1.1982E+00
3.1046E01
Gutter:4p6
C
3.0826E03
2.3306E03
1.8136E03
2.2271E03
2.8426E03
3.5408E03
1.7208E03
1.3914E03
3.2863E03
3.8058E03
2.5321E03
1.3032E03
1.6607E03
2.8921E03
2.6534E03
2.0761E03
3.1160E03
1.4398E02
2.3583E03
3.6078E03
2.8523E03
7.2098E04
2.3279E02
2.8970E02
2.6768E03
1.5776E03
2.0353E03
4.4676E03
4.8388E03
2.1040E03
1.6224E03
2.7936E03
3.7449E03
3.5846E03
2.3024E03
1.2164E03
2.6998E03
1.2983E03
1.5609E03
3.3620E03
1.6493E03
1.5473E03
5.2305E03
1.9745E03
3.0930E01
7.8980E05
5.8083E03
1.4948E03
2.0519E03
9.8722E03
1.0291E03
D
T min
3.5983E06 244
2.6455E06 238
2.5617E06 177
2.6107E06 238
4.6035E06 165
3.5408E06 286
2.2780E06 185
3.0241E06
89
3.9390E06 208
4.4991E06 221
3.4745E06 172
1.9677E06 148
2.7000E06 151
2.9275E06 291
3.3501E06 201
2.9583E06 179
3.1409E06 241
2.0371E05 195
2.3296E06 268
3.8243E06 280
2.9528E06 269
1.0443E06 163
3.5980E05 218
1.2745E04
69
3.0425E06 251
5.3099E07 172
2.5901E06 211
4.7582E06 281
4.7281E06 298
3.7444E06 147
2.3069E06 179
4.4383E06 158
4.3816E06 235
5.3990E06 182
5.9347E06
91
1.8030E06 160
3.6631E06 191
2.1963E06 138
2.0149E06 179
8.4120E06 105
1.6937E06 261
2.4070E06 162
4.6617E06
53
1.8068E06 292
4.1480E03 14
2.6409E06 165
6.9129E06 261
1.2018E06 273
4.0634E06 115
3.1670E05
92
1.4598E06 176
Font Size:9/10 pt
T max
491
542
471
505
383
528
507
378
555
536
510
483
415
533
512
457
617
385
629
506
565
497
274
120
501
396
483
498
563
358
459
420
505
394
275
465
471
414
555
254
581
422
137
651
32
308
411
694
367
172
461
Cp at 25 C
145.56
151.46
131.00
128.77
122.26
153.23
160.12
130.74
306.05
282.60
235.43
144.32
102.72
128.66
189.75
127.53
123.05
80.16
210.44
137.87
182.09
73.79
130.72
74.23
112.49
162.07
218.25
92.42
101.98
175.81
191.76
147.08
107.40
170.66
106.00
183.60
165.52
89.90
260.94
98.37
73.52
85.55
141.61
79.93
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:837
APPENDIX C
837
Cp = A + BT + CT 2 + DT 3
No. Formula
Substance
A
B
52 CH3Br
Methyl bromide
25.042 4.9312E01
Methyl chloride
11.381 6.2328E01
53 CH3Cl
54 C6H12O
96.184 8.5227E01
55 CH5N
Methylamine
13.565 9.0836E01
m-Xylene
70.916 8.0450E01
56 C8H10
57 C10H8
Naphthalene
30.842 1.5362E+00
n-Butane
62.873 5.8913E01
58 C4H10
59 C10H22
n-Decane
79.741 1.6926E+00
n-Heptane
101.121 9.7739E01
60 C7H16
61 C6H14
n-Hexane
78.848 8.8729E01
51.773 9.1277E01
63 N2
Nitrogen
76.452 3.5226E01
64 C9H20
n-Nonane
98.040 1.3538E+00
65 C8H18
n-Octane
82.736 1.3043E+00
66 C5H12
n-Pentane
80.641 6.2195E01
67 O2
Oxygen
46.432 3.9506E01
68 C8H10
o-Xylene
56.460 9.4926E01
Phenol
38.622 1.0983E+00
69 C6H6O
70 C8H10
p-Xylene
11.035 1.5158E+00
Pyridine
37.150 6.9497E01
71 C5H5N
72 C8H8
Styrene
66.737 8.4051E01
73 SO2
Sulfur dioxide
203.445 1.0537E+00
74 C7H8
Toluene
83.703 5.1666E01
75 C4H6O2
Vinyl acetate
63.910 7.0656E01
Water
76 H2O
92.053 3.9953E02
C p heat capacity of liquid, J/(mol K)
A, B, C, and D regression coefficients for chemical compound
T temperature, K
T min minimum temperature, K
T max maximum temperature, K
Margins:Top:3p6
Gutter:4p6
C
1.7627E03
2.4353E03
2.5379E03
3.4881E03
2.1885E03
3.2492E03
2.3588E03
4.5287E03
3.0712E03
2.9482E03
2.1098E03
2.6690E03
3.8058E03
3.8254E03
2.2682E03
7.0522E03
2.4902E03
2.4897E03
3.9039E03
1.8749E03
2.1615E03
2.6113E03
1.4910E03
2.2832E03
2.1103E04
D
T min
2.5993E06 181
3.8333E06 176
3.3066E06 190
5.2770E06 181
2.5061E06 226
2.6568E06 354
4.2257E06 136
4.9769E06 244
4.1844E06 184
4.1999E06 179
2.0093E06 280
5.0057E05
64
4.4991E06 221
4.6459E06 217
3.7423E06 144
3.9897E05
54
2.6838E06 249
2.2802E06 315
3.9193E06 287
2.1188E06 233
2.3324E06 244
1.0697E06 198
1.9725E06 179
3.1788E06 181
5.3469E07 273
Font Size:9/10 pt
T max
420
375
514
3887
555
674
383
557
486
457
647
120
536
512
423
147
567
625
555
558
583
409
533
472
615
C p at 25 C
85.16
82.33
212.42
114.19
182.66
140.84
313.73
230.42
192.63
189.62
282.60
254.71
163.64
189.25
197.75
133.85
187.00
93.06
157.49
155.86
75.55
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:838

TABLE C-6 Thermal Conductivity of Gas
Kgas = A + BT + CT 2
No. Formula
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
NH3
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CC14
C12
CHC13
C6H12
C6H12O
C3H6
CH2Cl2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Ammonia
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chlorine
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Fluorine
Glycerol
Hydrogen
Hydrogen chloride
Hydrogen cyanide
Hydrogen peroxide
Methane
Tmin
0.00070
0.00609
0.00739
0.00682
0.00085
0.01642
0.01783
0.00293
0.01118
0.00655
0.00463
0.00333
0.00181
0.00234
0.00846
0.00084
0.00889
0.00457
0.01796
0.00565
0.12421
0.00239
0.01200
0.00158
0.00070
0.00194
0.00019
0.00159
0.02696
0.00430
0.00122
0.00032
0.00004
0.01559
0.01936
0.00556
0.00207
0.00291
0.00797
0.00123
0.01076
0.01612
0.00076
0.00842
0.03951
0.00119
0.00136
0.00858
0.00115
0.00935
3.9347E06
3.2555E05
4.4752E05
4.0081E05
7.1537E06
8.0095E05
4.8291E05
3.0205E05
6.2751E05
3.2637E05
2.8829E05
2.8691E05
2.1187E05
6.5956E06
5.2818E05
8.7475E06
6.0453E05
2.3239E05
8.3464E05
3.4493E05
3.6238E04
3.2574E05
1.0208E04
8.2511E05
2.2065E05
3.8300E05
2.2269E05
1.7494E07
1.1162E04
3.7668E05
1.8440E05
1.6530E05
2.7408E07
8.3374E05
1.2547E04
4.3620E05
4.8558E06
3.1284E05
4.0572E05
3.6219E05
7.9631E05
7.3460E05
9.5961E05
4.4977E05
4.5918E04
4.4775E05
3.7886E05
8.6933E05
1.4943E05
1.4028E04
3.3468E09
3.0529E08
3.3174E08
3.1925E08
1.6202E07
1.7582E08
1.6334E07
1.0192E07
2.8360E08
7.7150E08
8.4175E08
1.0222E07
8.0192E08
1.1569E07
1.7355E08
1.0678E07
1.2049E08
1.4810E07
1.5022E09
6.9298E08
3.7750E07
2.1193E10
2.2403E08
1.9081E08
6.7913E09
6.3523E09
1.2257E09
1.4588E07
1.2497E08
1.0953E07
3.5385E08
1.1709E07
1.2105E07
6.3822E08
3.8298E08
8.5033E08
1.1222E07
5.5316E08
6.7289E08
1.2459E07
5.7243E09
2.1215E07
2.1800E08
2.4839E08
6.4933E08
2.0997E10
2.6807E08
6.2970E09
1.4921E07
3.3180E08
347
387
330
357
250
285
371
225
444
449
394
372
200
295
413
273
414
200
458
325
523
273
195
70
255
200
273
325
434
240
250
200
273
273
225
351
273
273
400
150
470
273
70
563
150
159
260
275
261
97
Margins:Top:3p6
Gutter:4p6
(Kgas W/(m K), T K)

Kgas
Kgas
Tmax
at Tmin
at 25 C
997
0.00107
997
0.01108
990
0.01099
997
0.01156
850 0.01569
0.01106
1000 0.00902
0.00784
713
0.02240
800 0.01514
0.00903
1000
0.02227
678
0.02366
500
0.01980
720
0.02149
700 0.01164
0.00564
687 0.01066
0.01046
993
0.01631
572 0.01126
0.00951
1000
0.01820
700 0.02466
0.01514
1000
0.02058
700
0.01288
707
0.03794
999 0.00734
0.00652
1500 0.01644
0.00705
1250 0.02448
0.00726
556 0.00648
0.00537
1000 0.00891
0.00547
573 0.00656
0.00598
650
0.01376
1000
0.02384
1000 0.01667
0.01105
500 0.00742
0.00560
600 0.01502
0.00767
1000 0.01072
0.00899
990 0.01494
0.01193
825 0.02145
0.01081
991
0.02023
1000 0.01060
0.00911
773 0.01133
0.00975
825
0.01903
750 0.02064
0.00701
990
0.02793
673 0.01308
0.01188
700 0.02591
0.00585
993
0.02478
1500 0.17064
0.10693
1000 0.01456
0.00831
360 0.01232
0.01030
1200 0.01678
0.01485
673 0.01657
0.01291
1400 0.03542
0.00457
Font Size:9/10 pt
Kgas
at Tmax
0.00655
0.05674
0.06943
0.06487
0.12229
0.08126
0.06644
0.08646
0.07993
0.05104
0.03083
0.07032
0.05231
0.05241
0.06110
0.03910
0.06361
0.09341
0.06701
0.05246
0.05670
0.03036
0.09071
0.07490
0.01367
0.03001
0.01297
0.05993
0.09716
0.14290
0.01685
0.05175
0.12082
0.12950
0.11022
0.12118
0.10943
0.05433
0.07130
0.09602
0.07369
0.06277
0.05573
0.06073
0.58218
0.04617
0.01575
0.08667
0.07649
0.25207
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:839
APPENDIX C
839
Kgas = A + BT + CT 2
No. Formula
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
Substance
CH3Br
Methyl bromide
CH3Cl
Methyl chloride
C6H12O
CH5N
Methylamine
C8H10
m-Xylene
C10H8
Naphthalene
C4H10
n-Butane
C10H22
n-Decane
C7H16
n-Heptane
C6H14
n-Hexane
C6H5NO2 Nitrobenzene
N2
Nitrogen
C9H20
n-Nonane
C8H18
n-Octane
C5H12
n-Pentane
O2
Oxygen
C8H10
o-Xylene
C6H6O
Phenol
C8H10
p-Xylene
C3H8
Propane
C5H5N
Pyridine
C8H8
Styrene
SO2
Sulfur dioxide
C7H8
Toluene
C4H6O2
Vinyl acetate
H2O
Water
(Kgas W/(m K), T K)
0.00421
0.00185
0.00209
0.01136
0.00375
0.02306
0.00182
0.00113
0.00172
0.00200
0.00309
0.00655
0.00213
0.00137
0.00121
0.00979
0.00552
0.00870
0.00869
0.00469
0.00712
0.00394
0.00776
0.00846
0.00053
2.7182E05
2.0296E05
7.7952E06
8.0400E05
2.9995E05
9.2610E05
1.9396E05
8.1090E06
1.6565E05
7.7788E06
7.5930E05
3.2637E05
1.8456E05
1.8081E05
8.6157E05
7.4087E05
4.4952E05
4.7349E05
6.6409E05
1.6151E05
4.5538E05
4.4847E05
4.4905E05
5.8704E08
4.7093E05
Margins:Top:3p6
Gutter:4p6
C
3.9758E08
7.3234E08
1.2993E07
5.8607E08
7.4603E08
4.4577E10
1.3818E07
9.6092E08
1.0525E07
1.3824E07
1.1014E08
7.7150E08
9.4775E08
1.2136E07
1.3346E08
1.8418E08
3.9900E08
5.8829E08
7.8760E08
9.4006E08
3.9529E08
2.1066E09
6.4514E08
1.7678E08
4.9551E08
Tmin
Tmax
273
213
390
267
400
353
225
470
250
290
78
449
300
225
80
400
455
400
233
388
273
198
350
346
275
825
750
1000
800
825
1259
675
700
750
480
1500
678
800
480
1500
825
995
825
773
998
973
1000
800
996
1073
Font Size:9/10 pt
Kgas
at 25 C
0.00743
0.01071
0.01782
0.01625
0.01257
0.01261
0.02475
0.01481
0.02571
0.01811
0.00997
0.00962
0.01898
Kgas
at Tmin
0.00617
0.00580
0.01881
0.01428
0.02018
0.00969
0.00954
0.02391
0.00900
0.01188
0.00895
0.02366
0.01194
0.00884
0.00802
0.02279
0.02319
0.01965
0.01106
0.01573
0.00826
0.00502
0.01586
0.01397
0.01723
Kgas
at Tmax
0.04528
0.05457
0.12422
0.09047
0.07177
0.09424
0.07423
0.05163
0.06991
0.03358
0.09220
0.05104
0.07329
0.03527
0.10042
0.06387
0.07871
0.07040
0.08971
0.10506
0.07461
0.04301
0.06945
0.06755
0.10811
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:840

TABLE C-7a Thermal Conductivity of Liquids
log10 kliq = A + B [1 T/C]27
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
NH3
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CCl4
Cl2
CHCl3
C6H12
C6H12O
C3H6
CH2Cl2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Ammonia
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chlorine
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Fluorine
Glycerol
Hydrogen
Hydrogen chloride
Hydrogen cyanide
Hydrogen peroxide
Methane
A
1.7352
2.6567
1.7265
1.6509
1.6512
2.1607
1.3120
1.6539
1.7491
1.7865
1.6274
1.2131
1.4826
1.2836
1.3593
1.3857
1.6101
1.1606
1.3485
1.6846
1.3420
1.2917
1.3679
1.7115
1.8791
0.2246
1.5271
1.6817
1.3475
1.5958
1.8069
1.5629
1.5868
1.2557
1.3474
1.3172
1.6938
2.0001
1.7498
1.3314
0.5918
1.4656
0.2758
0.3550
0.1433
0.8045
1.4117
0.4425
1.6862
1.0976
Margins:Top:3p6
B
0.9286
2.1686
0.9930
0.9701
0.9899
1.6668
0.6190
0.9786
1.0443
1.1033
0.9136
0.5097
0.9821
0.5893
0.7106
0.7643
0.9742
2.2840E03
0.6888
1.0520
0.6161
0.5809
0.8092
1.1359
1.0875
6.4000E05
0.7577
0.9649
0.5719
0.9876
1.2216
0.9357
0.9252
0.6069
0.7003
0.6987
1.0862
1.4496
1.0437
0.8527
0.8777
1.6297E03
0.2097
2.3627E02
2.1020E03
10.0351
1.8406E04
0.9802
0.5387
Gutter:4p6
Tmin
Tmax
kliq
at 25 C
545.00
602.00
523.00
561.00
425.37
587.00
562.93
419.59
617.05
595.65
566.60
536.71
461.00
592.71
569.15
508.20
615.00
3.1245E18
699.00
562.16
628.00
552.00
304.19
132.59
556.35
7.8800E07
536.40
553.54
625.15
397.91
510.00
466.70
560.95
437.65
305.42
516.25
523.30
460.35
617.17
282.36
645.00
469.15
3.7475E18
723.00
5.1480E04
2.3238E16
456.65
3.8824E07
408.14
190.58
243
237
176
237
164
285
184
88
207
220
171
147
150
290
200
178
287
220
267
279
268
162
217
68
250
172
210
280
297
146
178
157
234
181
90
159
190
137
178
104
260
161
53
293
14
273
260
273
114
91
518
572
497
533
404
558
535
399
586
566
538
510
438
563
541
483
584
400
664
534
597
524
289
126
529
410
510
526
594
378
485
443
533
416
290
490
497
437
586
268
613
446
130
550
33
323
434
657
388
181
0.1012
0.1340
0.1132
0.1350
0.1122
0.1586
0.1538
0.1078
0.1305
0.1313
0.1290
0.1553
0.1766
0.1581
0.1643
0.1615
0.1570
0.480
0.1734
0.1456
0.1481
0.1491
0.0987
0.135
0.1185
0.1236
0.1342
0.1173
0.1392
0.1369
0.1439
0.1521
0.1694
0.1445
0.1191
0.1302
0.2560
0.1557
0.2916
0.178
0.2256
0.353
0.0972
Font Size:9/10 pt
kliq
kliq
at Tmin
0.1096
0.1601
0.1412
0.1476
0.1592
0.1578
0.1725
0.1809
0.1489
0.1486
0.1555
0.1776
0.2447
0.1569
0.1834
0.1925
0.1559
0.658
0.1763
0.1469
0.1505
0.1702
0.1500
0.1580
0.1063
0.190
0.1330
0.1244
0.1323
0.1833
0.1841
0.1832
0.1576
0.1819
0.1916
0.2030
0.1789
0.2003
0.1554
0.2568
0.2560
0.2026
0.189
0.2994
0.0866
0.231
0.2429
0.363
0.1589
0.2206
at Tmax
0.0184
0.0022
0.0188
0.0223
0.0223
0.0069
0.0488
0.0222
0.0293
0.0163
0.0236
0.0612
0.0329
0.0520
0.0437
0.0411
0.0245
0.247
0.0448
0.0207
0.0455
0.0511
0.0429
0.0194
0.0132
0.066
0.0297
0.0208
0.0449
0.0254
0.0156
0.0274
0.0259
0.0555
0.0449
0.0482
0.0202
0.0100
0.0178
0.0466
0.2560
0.0342
0.064
0.4416
0.0737
0.126
0.0388
0.154
0.0206
0.0799
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:841
APPENDIX C
841
TABLE C-7a(continued)
log10 kliq = A + B [1 T/C]27
No.
Formula
Substance
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
CH3Br
Methyl bromide
Methyl chloride
CH3Cl
C6H12O
Methylamine
CH5N
C8H10
m-Xylene
Naphthalene
C10H8
C4H10
n-Butane
C10H22
n-Decane
n-Heptane
C7H16
n-Hexane
C6H14
C6H5NO2
Nitrobenzene
N2
Nitrogen
C9H20
n-Nonane
C8H18
n-Octane
C5H12
n-Pentane
O2
Oxygen
C8H10
o-Xylene
Phenol
C6H6O
C8H10
p-Xylene
Pyridine
C5H5N
C8H8
Styrene
SO2
Sulfur dioxide
Toluene
C7H8
C4H6O2
Vinyl acetate
Water
H2O
kliq thermal conductivity of liquid, W/(m K)
A
1.7379
1.7528
1.6520
1.0947
1.7286
1.0304
1.8929
1.7768
1.8482
1.8389
1.3942
0.2130
1.7865
1.8388
1.2287
0.2320
1.7372
1.1489
1.7354
1.2083
1.7023
0.3822
1.6735
1.7519
0.2758
Tmin
Tmax
kliq
at 25 C
1.0082
1.3666
0.9961
0.5539
1.0193
0.1860
1.2885
1.0839
1.1843
1.1860
0.6571
4.2050E04
1.1033
1.1699
0.5822
5.6357E04
1.0282
0.4091
1.0254
0.5146
1.0002
6.2540E04
0.9773
1.1895
4.6120E03
467.00
416.25
571.40
430.05
617.05
748.35
425.18
618.45
540.26
507.43
719.00
7.2951E06
595.65
568.83
469.65
3.8093E06
630.37
694.25
616.26
619.95
648.00
5.6891E19
591.79
524.00
5.5391E06
180
175
189
180
225
353
135
243
183
178
279
70
220
216
143
60
248
314
286
232
243
200
178
180
273
444
395
543
409
586
711
404
588
513
482
683
126
566
540
446
155
599
660
585
589
616
400
562
498
633
0.1038
0.1593
0.1428
0.1997
0.1305
0.1046
0.1322
0.1240
0.1208
0.1478
0.1313
0.1281
0.1480
0.1315
0.1299
0.1653
0.1369
0.196
0.1338
0.1525
0.607
kliq
kliq
at Tmin
0.1352
0.2541
0.1696
0.2369
0.1442
0.1326
0.1796
0.1425
0.1570
0.1588
0.1484
0.148
0.1486
0.1487
0.1769
0.184
0.1398
0.1553
0.1291
0.1729
0.1460
0.257
0.1596
0.1970
0.570
at Tmax
0.0183
0.0177
0.0223
0.0804
0.0187
0.0932
0.0128
0.0167
0.0142
0.0145
0.0403
0.044
0.0163
0.0145
0.0591
0.053
0.0183
0.0710
0.0184
0.0619
0.0198
0.132
0.0212
0.0177
0.424

T temperature, K
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:842

TABLE C-7b Thermal Conductivity of Liquids and Solids (Inorganic)
k = A + BT + CT 2
No. Formula
Substance
1 Ag
Silver
438.2178 2.2947E02
2 Al
Aluminum
228.2103 5.7999E02
3 As
Arsenic
122.7520 3.4038E01
4 Au
Gold
335.4544 5.8253E02
5 Ba
Barium
26.5122 5.3067E02
Bromine
0.1325 1.0331E04
6 Br2
7 Cd
Cadmium
101.2521 5.5398E03
8 Co
Cobalt
150.4892 1.9030E01
9 Cu
Copper
426.2970 8.3932E02
10 HCl
Hydrogen chloride
0.8045 2.1020E03
Water
0.2758 4.6120E03
11 H2O
12 Hg
Mercury
0.9230 2.8887E02
13 I2
Iodine
0.0965 1.7970E04
14 K
Potassium
69.3316 4.7493E02
15 KBr
Potassium bromide
13.8899 5.4091E02
16 KCl
Potassium chloride
39.3670 1.9735E01
17 Li
Lithium
28.9331 3.5692E02
18 Mg
Magnesium
165.8119 3.7721E02
19 NH3
Ammonia
1.1606 2.2840E03
20 NH5S
Ammonium hydrogen sulfide
0.1661 6.3855E04
21 NO
Nitric oxide
0.1878 1.0293E03
22 Na
Sodium
98.8908 4.3158E02
23 NaBr
Sodium bromide
0.3616 3.3985E05
24 NaCl
Sodium chloride
51.6119 2.9610E01
25 NaOH
Sodium hydroxide
3.2252 4.0045E03
26 Ni
Nickel
144.4370 2.2793E01
27 Pb
Lead
39.3335 1.3469E02
28 S
Sulfur
0.0262 4.1738E04
29 Sb
Antimony
39.6013 6.0319E02
Silicon oxide
2.1744 3.7847E03
30 SiO2
31 Sn
Tin
92.3073 1.1537E01
32 SnCl2
Stannous chloride
0.1616 1.1786E04
Stannic chloride
0.1482 6.7765E05
33 SnCl4
34 Zn
Zinc
125.5025 3.0320E02
35 ZnCl2
Zinc chloride
2.2616 6.2681E03
36 ZnO
Zinc oxide
71.4550 1.8504E01
k thermal conductivity, W/(m K)
T temperature, K
Margins:Top:3p6
Gutter:4p6
Tmin
Tmax
Phase
3.5429E05
8.6806E05
3.3153E04
7.4773E06
8.6615E05
4.5514E07
2.7578E05
8.9428E05
9.3782E06
2.3238E16
5.5391E06
1.5499E05
3.4020E07
9.4295E06
8.0015E05
2.8892E04
1.0087E05
1.6112E05
3.1245E18
1.6809E06
9.4300E06
5.2876E06
7.3045E09
4.7053E04
5.0633E06
1.6434E04
5.1500E07
3.2471E07
3.9401E05
4.6353E06
1.0000E04
1.7857E07
1.8857E07
1.1471E05
4.9822E06
1.6306E04
200
200
200
200
150
266
200
200
200
273
273
234
387
350
241
120
454
200
220
391
110
371
1020
80
592
250
200
388
200
273
200
260
243
200
563
319
1200
934
500
1300
300
584
594
1200
1300
323
633
1562
785
1600
372
360
3677
900
400
449
176
2316
3858
380
592
800
600
1182
900
1400
500
340
558
693
641
418
solid
solid
solid
solid
solid
liquid
solid
solid
solid
liquid
liquid
liquid
liquid
liquid
solid
solid
liquid
solid
liquid
liquid
liquid
liquid
liquid
solid
solid
solid
solid
liquid
solid
solid
solid
liquid
liquid
solid
solid
solid
Font Size:9/10 pt
k at
25 C
428.227
237.786
50.739
317.422
18.390
0.123
97.149
101.701
402.106
0.178
0.607
8.158
4.875
6.210
155.998
0.480
5.157
91.088
35.363
25.120
1.458
66.799
0.111
0.111
115.443
k at
Tmin
432.211
236.338
67.937
323.505
20.501
0.128
99.041
116.006
409.886
0.231
0.570
6.834
0.115
53.864
5.501
19.845
43.058
158.912
0.658
0.159
0.187
83.607
0.319
30.935
0.920
97.726
36.660
0.139
29.114
1.487
73.233
0.119
0.121
118.980
0.312
29.020
Text Width:41p6
k at
Tmax
359.664
206.658
35.445
247.089
18.387
0.038
88.231
50.906
333.035
0.126
0.424
8.229
0.028
17.482
4.841
5.765
23.793
144.914
0.247
0.114
0.077
27.299
0.122
7.038
0.920
67.271
31.438
0.066
17.229
5.961
59.622
0.101
0.052
98.982
0.291
22.599
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:843
APPENDIX C
843
TABLE C-8 Surface Tension of Organic Liquids
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
C6H7N
C 6H 6
C4H8O2
CS2
CO2
CO
CCl4
Cl2
CHCl3
C6H12
C6H12O
C3H6
CH2Cl 2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
CH4O
CH3Br
= A (1 T/Tc)n
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chlorine
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Fluorine
Glycerol
Hydrogen
Hydrogen chloride
Hydrogen cyanide
Hydrogen peroxide
Methane
Methanol
Methyl bromide
Margins:Top:3p6
A
65.600
77.200
72.110
80.140
47.682
82.160
64.526
56.000
54.880
55.400
54.040
66.660
67.660
57.050
80.370
62.200
65.495
77.260
71.950
56.230
79.590
79.970
27.959
66.750
67.560
69.284
66.097
65.400
74.254
88.570
57.356
54.700
56.215
48.984
67.036
59.870
57.652
65.700
52.940
106.491
74.730
40.040
124.793
5.336
85.200
52.256
141.031
52.165
35.684
68.329
83.795
Gutter:4p6
Tc
545.00
602.00
523.00
561.00
425.37
587.00
562.93
419.59
617.05
595.65
566.60
536.71
476.00
592.71
569.15
508.20
615.00
699.00
562.16
628.00
552.00
304.19
132.92
556.35
417.15
536.40
553.54
625.15
397.91
510.00
466.70
560.95
437.65
305.42
516.25
523.30
460.35
617.05
282.36
645.00
469.15
144.31
723.00
33.18
324.65
456.65
730.15
408.14
190.58
512.58
467.00
n
1.2170
1.2100
1.2530
1.2000
1.0507
1.2899
1.2222
1.2341
1.2818
1.3027
1.2468
1.2222
1.1940
1.0703
1.2420
1.1240
1.2549
1.0800
1.2389
1.1930
1.1909
1.2617
1.1330
1.2140
1.0850
1.1761
1.2553
1.0360
1.2599
1.2800
1.2280
1.0560
1.0807
1.2065
1.2222
1.1220
1.0880
1.2780
1.2784
1.2222
1.1410
1.2266
1.2222
1.0622
1.2970
1.0198
1.2222
1.2723
1.0920
1.2222
1.2222
Tmin
242.75
236.50
176.19
237.49
164.25
284.95
283.15
87.80
206.89
219.63
171.45
283.15
150.15
289.81
200.15
178.45
286.65
267.13
278.68
267.95
161.11
216.58
68.15
250.33
172.12
209.63
279.69
296.60
145.59
178.01
156.85
234.18
180.96
90.35
273.15
189.60
134.80
225.30
103.97
260.15
160.71
53.53
291.33
13.95
158.97
259.83
272.72
113.54
90.67
273.10
179.47
Font Size:9/10 pt
T max
545.00
602.00
523.00
561.00
425.37
587.00
562.93
419.59
617.05
595.65
566.60
536.71
461.00
592.71
569.15
508.20
615.00
699.00
562.16
628.00
552.00
304.19
132.92
556.35
417.15
536.40
553.54
625.15
397.91
510.00
466.70
560.95
437.65
305.42
516.25
523.30
460.35
617.05
282.36
645.00
469.15
144.31
723.00
33.18
324.65
456.65
730.15
408.14
190.58
512.58
467.00
at 25 C
25.02
33.75
25.04
32.27
13.41
32.92
25.67
12.12
23.55
22.43
21.29
24.74
19.53
26.99
31.98
23.04
28.50
42.38
28.21
26.08
19.72
0.57
26.29
17.32
26.68
24.65
3.42
12.99
28.77
16.42
24.56
16.34
0.54
23.39
23.24
18.53
28.26
49.89
23.63
22.68
65.16
2.99
3.30
17.76
74.26
9.84
23.55
24.17
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:844

= A (1 T /Tc)n
A
No.
Formula
Substance
52 CH3Cl
Methyl chloride
68.594
57.130
53 C6Hl2O
Methylamine
85.600
54 CH5N
55 C8H10
m-Xylene
65.700
Naphthalene
83.190
56 C10H8
n-Butane
52.660
57 C4H10
n-Decane
55.777
58 C10H22
n-Heptane
53.640
59 C7H16
60 C6H14
n-Hexane
56.081
61 C6H5NO2
Nitrobenzene
79.440
62 C9H20
n-Nonane
55.400
n-Octane
52.036
63 C8H18
64 C5H12
n-Pentane
52.090
65 C8H10
o-Xylene
66.100
66 C6H6O
Phenol
74.500
p-Xylene
64.850
67 C8H10
68 C5H5N
Pyridine
81.500
69 C8H8
Styrene
68.178
70 C7H8
Toluene
66.850
Vinyl acetate
68.685
71 C4H6O2
Water
72 H2O
132.674
surface tension, dyn /cm surface tension, dyn /cm
A , Tc , and n regression coefficients for chemical compound
T temperature, K
Tmax minimum temperature, K
Margins:Top:3p6
Gutter:4p6
Tc
416.25
571.40
430.05
617.05
748.35
425.18
618.45
540.26
507.43
719.00
595.65
568.83
469.65
630.37
694.25
616.26
619.95
648.00
591.79
524.00
647.13
n
1.1966
1.2040
1.2556
1.2780
1.3896
1.2330
1.3198
1.2431
1.2843
1.1362
1.3027
1.2168
1.2054
1.2544
1.0767
1.2743
1.2160
1.2222
1.2456
1.2500
0.9550
Font Size:9/10 pt
Tmin
175.43
189.15
179.69
225.30
353.43
134.86
243.49
182.56
177.84
278.91
219.63
216.38
143.42
247.98
314.06
286.41
231.51
273.15
178.18
180.35
273.15
Tmax
416.25
571.40
430.05
617.05
748.35
425.18
618.45
540.26
507.43
719.00
595.65
568.83
469.65
630.37
694.25
616.26
619.95
648.00
591.79
524.00
647.13
at 25 C
15.19
23.50
19.41
28.26
11.87
23.41
19.78
17.98
43.23
22.43
21.08
15.47
29.60
27.92
36.72
32.10
27.93
23.99
73.56
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:845
APPENDIX C
845
TABLE C-9 Vapor Pressure

log10 Pv = A + B/T + C log10T + DT + ET 2
No .
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
NH3
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CCl 4
Cl2
CHCl3
C6H12
C6H12O
C3H6
CH2Cl 2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
CH4O
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Ammonia
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chlorine
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Fluorine
Glycerol
Hydrogen
Hydrogen chloride
Hydrogen cyanide
Hydrogen peroxide
Methane
Methanol
36.5468
25.0845
33.3800
48.4226
30.0572
20.5761
39.6673
27.3116
2.2678
8.8817
56.1183
31.5155
87.3702
28.3756
43.5021
28.5884
23.0607
37.1575
124.3764
31.7718
8.0847
25.1475
35.0169
51.8145
31.9407
28.8659
56.6178
48.5529
49.9123
37.8180
32.5609
41.7519
32.2560
36.9182
20.6973
23.8442
0.6955
28.3448
36.1998
18.7964
82.4062
39.9235
27.1409
62.7929
3.4132
43.5455
57.5717
33.3222
31.2541
14.6667
45.6171
2.8421E+03
2.7368E+03
2.6102E+03
3.1803E+03
1.9891E+03
2.4658E+03
4.0017E+03
1.9235E+03
3.1244E+03
2.8042E+03
3.7657E+03
3.4570E+03
3.6822E+03
2.9734E+03
3.8643E+03
2.4690E+03
3.1347E+03
2.0277E+03
7.1676E+03
2.7254E+03
3.3219E+03
2.0439E+03
1.5119E+03
7.8824E+02
2.6614E+03
1.6745E+03
3.2462E+03
3.0874E+03
4.8446E+03
1.8661E+03
2.5166E+03
2.7410E+03
2.9431E+03
2.4965E+03
1.341E+03
2.8642E+03
2.2498E+03
2.0788E+03
3.3402E+03
9.9962E+02
6.3472E+03
2.3595E+03
5.7201E+02
3.6585E+03
4.1316E+01
1.6279E+03
3.5182E+02
3.7350E+03
1.9532E+03
5.7097E+02
3.2447E+03
1.0205E+01
5.9182E+00
9.1336E+00
1.5370E+01
8.2922E+00
4.3645E+00
1.0295E+01
7.2064E+00
5.4320E+00
1.5262E+00
1.8006E+01
7.5235E+00
3.1548E+01
7.0320E+00
1.2162E+01
7.3510E+00
4.8813E+00
1.1601E+01
4.2763E+01
8.4443E+00
2.4312E+00
6.7794E+00
1.1334E+01
2.2734E+01
8.5763E+00
8.5216E+00
1.8700E+01
1.5521E+01
1.3711E+01
1.2278E+01
8.8015E+00
1.2270E+01
8.5068E+00
1.0417E+01
5.2514E+00
5.0474E+00
5.4643E+00
7.5387E+00
9.7970E+00
4.5788E+00
2.5433E+01
1.2517E+01
1.0015E+01
3.4249E+01
1.0947E+00
1.5214E+01
2.9640E+01
8.3458E+00
8.8060E+00
3.3373E+00
1.3988E+01
2.6369E09
2.5155E01
2.8388E11
7.2935E03
2.5664E10
2.7053E10
3.2572E10
7.4852E12
2.0137E02
1.0464E02
7.7387E03
4.2870E11
2.0114E02
1.5051E09
2.1843E09
2.8025E10
4.3690E04
7.4625E03
1.7336E02
5.3534E09
1.1734E02
3.4828E03
9.3368E03
5.1225E02
6.7136E10
5.3792E03
9.5150E03
7.3830E03
3.5451E09
8.5721E03
1.2934E10
3.1948E10
4.5720E10
1.6287E09
9.8774E11
3.7448E11
1.9451E02
1.6384E11
1.1467E11
9.9746E11
2.3732E09
6.9835E03
2.1078E02
5.1940E02
6.6896E10
1.3783E02
4.7820E02
1.2351E10
8.9246E11
2.1999E09
6.6365E03
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
E
3.7075E06
1.1831E06
3.7323E06
2.6844E14
5.1334E06
8.5235E07
8.6672E07
3.6481E06
1.1221E05
5.7972E06
1.3036E13
1.3029E07
5.5341E13
2.1806E06
3.3250E06
2.7361E06
4.9161E13
9.5811E12
5.7138E15
2.7187E06
5.7992E06
1.0105E14
1.7136E09
6.1896E11
2.9732E06
7.7867E13
1.553E12
6.3563E12
1.5932E06
2.9652E13
3.194E06
5.9802E06
2.6177E06
4.6496E06
6.7329E06
2.7361E07
1.2362E05
4.0550E06
2.5758E06
6.7880E06
8.7467E06
1.1101E13
8.9567E13
2.2830E05
1.4589E04
1.4984E11
2.8550E05
1.6917E06
5.7501E06
1.3096E05
1.0507E13
T min
T max
242.75
236.50
176.19
237.49
164.25
284.95
183.85
87.80
206.89
219.63
171.45
146.95
150.15
289.81
200.15
178.45
286.65
195.41
267.13
276.68
267.95
161.58
216.58
68.15
250.33
172.12
209.63
279.69
296.60
145.59
178.01
156.85
234.18
180.96
90.35
159.05
189.60
136.75
178.15
104.01
260.15
160.71
53.48
291.33
13.95
158.97
259.91
272.74
113.54
90.67
175.47
545.00
602.00
523.00
561.00
425.37
587.00
562.93
419.59
617.05
595.65
566.60
536.71
461.00
592.71
448.15
508.20
615.00
405.65
699.00
562.16
628.00
552.00
304.19
132.92
556.35
417.15
536.40
553.54
625.15
397.91
510.00
466.70
560.95
437.65
305.42
516.25
523.30
460.35
617.17
282.36
645.00
469.15
144.31
723.00
33.18
324.65
456.65
730.15
408.14
190.58
512.58
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:846

log10 Pv = A + B/T + C log10T + DT + ET 2
No. Formula
Substance
A
B
C
D
52 CH3Br
Methyl bromide
29.3988 2.0406E+03 7.9966E+00 4.1899E10
53 CH3Cl
Methyl chloride
25.7264 1.7503E+03 6.7151E+00 1.2956E09
54 C6H12O
64.1919 4.3577E+03 1.9766E+01 3.9997E10
55 CH5N
Methylamine
30.5366 2.2074E+03 8.0919E+00 2.7828E11
56 C8H10
m-Xylene
34.6803 3.2981E+03 9.2570E+00 4.3563E10
Naphthalene
34.9161 3.9357E+03 9.0648E+00 2.0672E09
57 C10H 8
n-Butane
27.0441 1.9049E+03 7.1805E+05 6.6845E11
58 C4H10
59 C10H22
n-Decane
26.5125 3.3584E+03 6.1174E+00 3.3225E10
n-Heptane
65.0257 3.8188E+03 2.1684E+01 1.0387E02
60 C7H16
61 C6H14
n-Hexane
69.7378 3.6278E+03 2.3927E+01 1.2810E02
54.4937 2.1123E+03 2.9321E+01 4.4839E02
63 N2
Nitrogen
23.8572 4.7668E+02 8.6689E+00 2.0128E02
64 C9H20
n-Nonane
8.8817 2.8042E+03 1.5262E+00 1.0464E02
65 C8H18
n-Octane
29.0948 3.0114E+03 7.2653E+00 2.2696E11
66 C5H12
n-Pentane
33.3239 2.4227E+03 9.2354E+00 9.0199E11
67 O2
Oxygen
20.6695 5.2697E+02 6.7062E+00 1.2926E02
68 C8H10
o-Xylene
37.2413 3.4573E+03 1.0126E+01 9.0676E11
69 C6H6O
Phenol
23.5332 3.4961E+03 4.8990E+00 1.2160E04
70 C8H10
p-Xylene
60.0531 4.0159E+03 1.9441E+01 8.2881E03
71 C5H5N
Pyridine
33.5541 3.1318E+03 8.8646E+00 7.1293E12
Styrene
55.8621 4.0240E+03 1.7609E+01 6.6842E03
72 C8H8
73 SO2
Sulfur dioxide
19.7418 1.8132E+03 4.1458E+00 4.4284E09
74 C7H 8
Toluene
34.0775 3.0379E+03 9.1635E+00 1.0289E11
75 C4H6O 2
Vinyl acetate
12.7220 2.1770E+03 9.1458E01 4.5688E03
Water
76 H2O
29.8605 3.1522E+03 7.3037E+00 2.4247E09
P v vapor pressure, mmHg
A, B, C, D, and E regression coefficients for chemical compound
T temperature, K
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
E
5.0174E06
4.4341E06
7.1020E06
3.5234E06
2.4103E06
1.5550E06
4.2190E06
4.8554E07
1.0206E14
1.6844E13
2.0162E05
2.4139E11
5.7972E06
1.4680E06
4.1050E06
9.8832E13
2.6123E06
9.6537E13
2.3647E12
2.2813E06
1.9438E13
8.4918E07
2.7035E06
2.9673E06
1.8090E06
T min
179.47
175.43
189.15
179.69
225.30
353.43
134.86
243.49
182.56
177.84
278.91
63.15
219.63
216.38
143.42
54.35
247.98
314.06
286.41
231.51
242.54
197.67
178.18
180.35
273.16
T max
467.00
416.25
571.40
430.05
617.05
748.35
425.18
618.45
540.26
507.43
719.00
126.10
595.65
568.83
469.65
154.58
630.37
694.25
616.26
619.95
648.00
430.75
591.79
524.00
647.13
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:847
APPENDIX C
847
TABLE C-10 Enthalpy of Vaporization
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2 H4 O
C2 H4 O2
C4 H6 O3
C3 H6 O
C3 H4 O2
NH3
C6 H7 N
C6 H6
C4H8O2
CS2
CO2
CO
CCl4
Cl2
CHCl3
C6 H12
C6 H12O
C3 H6
CH2Cl2
C4 H10O
C5 H10O
C2H7N
C2 H6
C2 H6 O
C4 H8 O2
C2 H5 Cl
C8 H10
C2 H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2 O2
C4 H10
CH4
CH4O
Hv = A (1 T/Tc)n
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Ammonia
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chlorine
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Fluorine
Glycerol
Hydrogen
Hydrogen chloride
Hydrogen cyanide
Hydrogen peroxide
Methane
Methanol
Margins:Top:3p6
A
44.083
46.865
42.180
45.426
35.170
36.047
63.024
33.390
65.577
59.378
55.443
70.179
44.950
11.575
58.520
49.244
62.977
31.523
72.038
49.888
18.437
34.997
15.326
8.003
37.890
28.560
42.953
49.060
85.741
28.060
41.910
41.972
49.640
41.070
21.342
43.122
49.346
35.233
54.788
19.986
88.200
36.474
10.549
104.153
0.659
30.540
42.384
61.900
31.954
10.312
52.723
Tc
545.00
602.00
523.00
561.00
425.37
587.00
562.93
419.59
617.05
595.65
566.60
536.71
461.00
592.71
569.15
508.20
615.00
405.65
699.00
562.16
628.00
552.00
304.19
132.92
556.35
417.15
536.40
553.54
625.15
397.91
510.00
466.70
560.95
437.65
305.42
516.25
523.30
460.35
617.17
282.36
645.00
469.15
144.31
723.00
33.18
324.65
456.65
730.15
408.14
190.58
512.58
Gutter:4p6
n
0.385
0.294
0.367
0.342
0.448
0.049
0.318
0.393
0.402
0.377
0.401
0.451
0.594
0.650
0.280
0.481
0.351
0.364
0.459
0.489
0.757
0.299
0.227
0.318
0.241
0.401
0.375
0.486
0.527
0.361
0.410
0.407
0.354
0.424
0.403
0.079
0.385
0.365
0.388
0.431
0.397
0.377
0.546
0.301
0.380
0.647
0.428
0.325
0.392
0.265
0.377
T min
242.75
236.50
176.19
237.49
200.00
340.00
220.00
87.80
206.89
219.63
171.45
146.95
150.15
289.81
200.15
260.00
286.65
195.41
267.13
278.68
320.00
161.11
216.58
68.15
250.33
172.12
209.63
279.69
296.60
145.59
178.01
156.85
234.18
180.96
90.35
300.00
189.60
134.80
178.15
103.97
260.15
160.71
53.48
291.33
13.95
158.97
259.83
272.74
113.54
90.67
175.47
Font Size:9/10 pt
T max
545.00
602.00
523.00
561.00
425.37
587.00
562.93
419.59
617.05
595.65
566.60
536.71
461.00
391.05
569.15
508.20
615.00
405.65
699.00
562.16
436.42
552.00
304.19
132.92
556.35
417.15
536.40
553.54
625.15
397.91
510.00
466.70
560.95
437.65
305.42
516.25
523.30
460.35
617.17
282.36
645.00
469.15
144.31
723.00
33.18
324.65
456.65
730.15
408.14
190.58
512.58
TB
347.23
387.00
330.45
356.59
266.74
374.47
390.81
266.90
443.75
423.97
394.44
370.35
293.55
391.05
411.78
392.44
414.15
239.72
457.60
353.24
436.42
270.65
194.67
81.70
349.79
239.12
334.33
353.87
434.00
240.37
312.90
307.58
375.14
280.03
184.55
351.44
350.21
285.42
409.35
169.47
470.45
283.85
84.95
563.15
20.39
188.15
298.85
423.35
261.43
111.66
337.85
Hv at TB
29.84
34.62
29.23
32.16
22.48
34.30
43.24
22.44
39.36
37.15
34.39
41.38
24.63
23.33
40.83
29.79
42.52
22.77
44.22
30.75
45.29
28.61
5.91
29.84
20.29
29.79
29.89
45.92
20.08
28.38
27.09
33.57
26.64
14.69
39.40
32.23
24.75
35.91
13.46
52.49
25.70
6.50
66.13
0.46
17.43
26.90
46.72
21.40
8.16
35.14
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:848

n
No.
Formula Substance
A
52 CH3Br
Methyl bromide
32.009
Methyl chloride
32.534
53 CH3Cl
54 C6H12O
57.680
55 CH5N
38.656
Methylamine
56 C8H10
m-Xylene
60.216
57 C10H8
Naphthalene
76.150
n-Butane
33.020
58 C4H10
59 C10H22
n-Decane
71.428
n-Heptane
49.730
60 C7H16
61 C6H14
n-Hexane
45.610
62 C6H5NO2
Nitrobenzene
67.414
63 N2
Nitrogen
9.430
64 C9H20
n-Nonane
59.378
n-Octane
59.077
65 C8H18
66 C5H12
n-Pentane
39.854
67 O2
Oxygen
8.040
68 C8H10
o-Xylene
55.606
69 C6H6O
Phenol
77.397
70 C8H10
p-Xylene
52.910
71 C5H5N
Pyridine
53.461
72 C8H8
Styrene
65.327
73 SO2
Sulfur dioxide
46.900
Toluene
50.139
74 C7H8
75 C4H6O2
Vinyl acetate
45.805
Water
76 H2O
52.053
v enthalpy of vaporization, kJ/mol
A, Tc , and n regression coefficients of chemical compound
T temperature, K
TB boiling temperature, K
Margins:Top:3p6
Gutter:4p6
Tc
467.00
416.25
571.40
430.05
617.05
748.35
425.18
618.45
540.26
507.43
719.00
126.10
595.65
568.83
469.65
154.58
630.37
694.25
616.26
619.95
648.00
430.75
591.79
524.00
647.13
n
0.308
0.452
0.416
0.405
0.458
0.526
0.377
0.451
0.386
0.401
0.380
0.533
0.377
0.439
0.398
0.201
0.375
0.462
0.354
0.408
0.558
0.636
0.383
0.353
0.321
Tmin
179.47
175.43
189.15
179.69
225.30
353.46
134.86
243.49
182.56
177.84
278.91
63.15
219.63
216.38
143.42
54.35
247.98
314.06
286.41
231.51
350.00
197.67
178.18
180.35
273.16
Font Size:9/10 pt
T max
467.00
416.25
571.40
430.05
617.05
748.35
425.18
618.45
540.26
507.43
719.00
126.10
595.65
568.83
469.65
154.58
630.37
694.25
616.26
619.95
648.00
430.75
591.79
524.00
647.13
TB
276.71
248.93
389.65
266.82
412.27
491.14
272.65
447.30
371.58
341.88
483.95
77.35
423.97
398.83
309.22
90.17
417.58
454.99
411.51
388.41
418.31
263.13
383.78
345.65
373.15
H v at T B
24.28
21.55
35.82
26.11
36.33
43.42
22.44
40.02
31.73
29.11
44.08
5.68
37.15
34.77
25.99
6.74
37.00
47.31
35.82
35.77
36.62
25.72
33.59
31.31
39.50
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:849
APPENDIX C
849
TABLE C-11 Enthalpy of Formation

(Hf kjoule/mol, T K)
Hf = A + BT + CT 2
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CCl4
CHCl3
C6H12
C6H12O
C3H6
CH2Cl2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
C3H8O3
CHN
C4H10
CH4
CH4O
CH3Br
CH3Cl
C6H12O
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Glycerol
Hydrogen cyanide
Methane
Methanol
Methyl bromide
Methyl chloride
136.019
131.466
119.156
119.407
123.286
286.843
245.806
21.822
72.195
175.883
41.002
233.653
154.122
422.584
554.715
199.175
325.038
105.261
101.403
448.775
137.658
393.422
112.190
103.244
98.906
81.822
255.672
71.797
88.943
223.739
230.936
2.793
66.735
216.961
420.199
96.985
58.099
63.053
377.811
38.880
559.438
135.847
106.746
63.425
188.188
44.104
76.576
256.000
Margins:Top:3p6
2.6621E02 1.7816E05
2.9213E02 1.7876E05
4.3078E02 2.2469E05
4.0489E02 1.9654E05
5.1225E02 2.3192E05
1.1418E01 6.2626E05
1.1235E01 5.3505E05
8.5458E02 3.8902E05
2.0530E01 1.0175E04
2.1036E01 1.0501E04
1.6529E01 8.0839E05
9.2123E02 4.2848E05
4.7166E02 2.0279E05
4.8354E02 2.3337E05
8.4124E02 4.3618E05
7.1484E02 3.2534E05
4.4058E02 2.0926E05
7.3513E02 3.7553E05
7.2136E02 3.2877E05
8.5107E02 4.2361E05
8.1634E02 4.2246E05
1.5913E04 1.3945E06
8.1182E03 8.0425E06
9.0605E03 9.5332E07
1.0149E02 7.1513E06
1.6705E01 9.2830E05
1.5846E01 9.1123E05
7.2889E02 3.4947E05
2.5399E02 1.2304E05
1.1173E01 5.3459E05
1.1046E01 5.2823E05
8.5680E02 4.2790E05
6.9337E02 3.0379E05
6.9572E02 3.1744E05
8.9885E02 4.4497E05
5.7861E02 2.7636E05
1.1129E01 5.3183E05
4.1076E02 1.6598E05
4.5844E02 2.3144E05
5.4041E02 2.5601E05
9.2185E02 4.5003E05
2.1831E03 4.3739E07
1.0929E01 5.2693E05
4.3355E02 1.7220E05
4.9823E02 2.0791E05
3.5166E02 1.5043E05
3.7541E02 1.6128E05
1.2779E01 6.2353E05
Gutter:4p6
Tmin
Tmax
H f
at 298 K
H f
at 500 K
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
389
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
333
298
298
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
717
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
142.30
138.49
129.91
129.70
110.16
315.06
274.43
0.13
124.14
229.03
82.93
257.53
166.36
434.84
575.72
217.57
336.23
86.86
82.93
470.28
117.07
393.51
110.54
100.42
101.25
123.14
294.55
53.30
95.40
252.21
259.20
18.83
84.68
234.81
442.92
111.71
29.79
52.30
389.32
52.63
582.80
135.14
134.52
74.85
201.17
37.66
86.32
288.49
144.88
141.60
135.08
134.74
103.47
328.28
288.61
11.18
149.40
254.91
103.44
269.30
172.64
440.93
585.87
226.78
341.84
77.89
73.55
480.74
107.40
393.69
110.14
98.48
102.19
142.14
312.12
44.09
98.57
266.24
272.96
29.35
93.81
243.81
454.02
119.01
15.75
46.66
394.95
59.50
594.28
134.65
148.22
80.80
207.90
57.93
91.31
304.30
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:850

Hf = A + BT + CT 2
No.
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
Formula
CH5N
C8H10
C10H8
C4H10
C10H22
C7H16
C6H14
C6H5NO2
C9H20
C8H18
C5H12
C8H10
C6H6O
C8H10
C5H5N
C8H8
C7H8
C4H6O2
T min
T max
H f
at 298 K
7.489
46.618
173.657
98.186
191.468
144.670
129.114
175.883
160.339
113.399
46.756
80.956
47.806
156.938
167.879
74.320
296.867
6.0538E02
1.1480E01
8.9278E02
1.0974E01
2.3050E01
1.7028E01
1.5013E01
2.1036E01
1.9025E01
1.3001E01
1.0824E01
6.1053E02
1.1644E01
6.7082E02
8.0354E02
9.5998E02
7.5158E02
2.7800E05
5.3371E05
4.2685E05
5.2254E05
1.1559E04
8.4057E05
7.3458E05
1.0501E04
9.4491E05
6.2902E05
4.9928E05
3.0058E05
5.3672E05
3.4853E05
3.7418E05
4.7011E05
3.9850E05
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
23.01
17.24
150.96
126.15
249.66
187.78
167.19
67.60
229.03
208.45
146.44
19.00
96.36
17.95
140.16
147.36
50.00
315.70
Substance
Methylamine
m-Xylene
Naphthalene
n-Butane
n-Decane
n-Heptane
n-Hexane
Nitrobenzene
n-Nonane
n-Octane
n-Pentane
o-Xylene
Phenol
p-Xylene
Pyridine
Styrene
Toluene
Vinyl acetate
(H f kjoule/mol, T K)
H f
at 500 K
30.81
2.56
139.69
139.99
277.82
208.79
185.82
254.81
231.84
162.68
5.12
103.97
3.01
132.11
137.06
38.07
324.48
Hf enthalpy of formation of ideal gas, kjoule/mol

T temperature, K
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:851
APPENDIX C
851
TABLE C-12 Gibbs Energy of Formation

Gf = A + BT + CT 2
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CCl4
CHCl3
C6H12
C6H12O
C3H6
CH2Cl2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
C3H8O3
CHN
CH4
CH4O
CH3Br
CH3Cl
C6H12O
CH5N
C8H10
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Glycerol
Hydrogen cyanide
Methane
Methanol
Methyl bromide
Methyl chloride
Methylamine
m-Xylene
A
143.436
139.616
131.060
130.549
109.172
318.550
276.720
1.692
128.709
233.826
86.500
259.317
167.052
435.963
578.076
218.77
337.271
84.822
81.512
472.274
121.242
393.360
109.885
100.838
101.846
127.917
299.464
51.643
95.965
254.382
261.163
20.837
85.787
236.103
444.940
112.949
27.421
51.752
390.502
53.838
584.906
135.278
75.262
201.860
55.241
86.903
291.134
24.115
15.063
Margins:Top:3p6
2.2407E01 3.9301E06
2.0630E01 5.9155E06
1.9006E01 1.2939E05
1.8562E01 1.3775E05
1.3296E01 1.9003E05
4.5161E01 3.0870E05
4.0989E01 3.9100E05
2.3442E01 3.1582E05
8.1530E01 6.7574E05
8.4477E01 6.8451E05
6.2135E01 5.5457E05
3.1232E01 3.3063E05
1.0714E01 1.8665E05
1.9346E01 1.6362E05
3.3162E01 2.5188E05
2.1177E01 2.6619E05
1.6672E01 1.5209E05
2.6707E01 2.2598E05
1.5282E01 2.6522E05
3.8416E01 2.7623E05
1.9750E01 5.0587E05
3.8212E03 1.3322E06
9.2218E02 1.4547E06
1.4561E01 8.6766E06
1.1137E01 8.6302E07
5.2032E01 4.4706E05
5.9552E01 3.9211E05
1.6873E01 2.4956E05
8.8080E02 8.5438E06
4.3005E01 3.8907E05
4.1025E01 3.8997E05
2.8875E01 2.7736E05
1.6858E01 2.6853E05
2.1904E01 2.5659E05
3.8444E01 2.9614E05
1.7104E01 1.9992E05
3.3327E01 3.8542E05
4.9338E02 1.7284E05
2.8378E01 1.4492E05
1.3048E01 1.8741E05
4.4735E01 3.0773E05
3.6253E02 2.3053E06
7.5925E02 1.8700E05
1.2542E01 2.0345E05
8.0199E02 1.1207E05
7.5722E02 1.4823E05
5.0824E01 4.3056E05
1.8179E01 2.2182E05
3.3452E01 4.1387E05
Gutter:4p6
Tmin
Tmax
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
389
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
298
333
298
298
298
298
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
717
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Font Size:9/10 pt
Gf
Gf
at 298 K
at 500 K
76.19
77.49
73.09
73.85
150.67
180.79
150.67
71.30
121.04
24.81
104.22
162.97
133.30
376.69
476.68
153.05
286.06
166.69
129.66
355.00
66.90
394.38
137.28
58.24
68.53
31.76
117.91
104.39
68.87
122.34
135.06
67.99
32.93
168.28
327.40
60.00
130.58
68.12
304.47
13.10
448.49
124.68
50.84
162.51
28.16
62.89
135.36
32.26
118.87
30.42
34.99
32.79
34.29
180.40
85.03
62.00
123.42
295.84
205.67
238.04
94.89
108.82
335.14
405.97
106.24
250.11
224.01
164.55
273.29
35.14
394.94
155.63
30.20
45.95
143.42
8.10
142.25
49.79
29.63
46.39
130.47
5.21
120.17
245.32
22.43
203.69
80.74
244.99
16.09
353.54
117.73
32.63
134.06
12.34
45.34
26.25
72.32
192.67
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:852
Gf = A + BT + CT 2
No.
Formula
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
C10H8
C4H10
C10H22
C7H16
C6H14
C6H5NO2
C9H20
C8H18
C5H12
C8H10
C6H6O
C8H10
C5H5N
C8H8
C7H8
Substance
Naphthalene
n-Butane
n-Decane
n-Heptane
n-Hexane
Nitrobenzene
n-Nonane
n-Octane
n-Pentane
o-Xylene
Phenol
p-Xylene
Pyridine
Styrene
Toluene
A
148.988
128.375
255.000
191.520
170.447
233.826
212.692
149.141
17.048
97.896
15.763
138.330
145.657
47.813
Tmin
Tmax
2.4014E01
3.6047E01
9.4201E01
6.5052E01
5.5417E01
8.4477E01
7.4774E01
4.5748E01
3.3940E01
2.1140E01
3.3952E01
1.6730E01
2.1917E01
2.3831E01
3.0705E05
3.8256E05
7.4254E05
5.6444E05
5.0303E05
6.8451E05
6.2361E05
4.4417E05
3.9428E05
1.9980E05
4.2301E05
2.0124E05
2.8490E05
3.1916E05
298
298
298
298
298
298
298
298
298
298
298
298
298
298
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Gf
Gf
at 298 K
at 500 K
223.59
17.15
33.22
7.99
0.25
158.00
24.81
16.40
8.37
122.09
32.89
121.13
190.20
213.80
122.01
276.74
61.43
234.57
147.85
119.21
205.67
176.77
90.70
196.61
12.80
196.10
227.01
262.36
174.95
Gf Gibbs energy of formation of ideal gas, kJ/mol

T temperature, K
TABLE C-13 Solubility of Salt Water

log10 S = A + BX + CX2
No. Formula
Substance
Mw
TB
A
B
1 C9H20
1-Nonane (Nonane) 128.257
423.81 0.9136 3.8600E06
Benzene
78.113
353.31
3.2443 3.2714E06
2 C6H6
Cyclohexane
84.161
353.90
1.7490 4.5987E06
3 C6H12
4 C8H10
Ethylbenzene
106.167
409.17
2.2178 5.0916E06
m-Xylene
106.67
412.22
2.2405 6.3514E06
5 C8H10
n-Heptane (Heptane) 100.203
371.56
0.3502 3.8600E06
6 C7H16
n-Hexane (Hexane)
86.177
341.93
0.9763 3.8600E06
7 C6H14
8 C9H20
n-Nonane (Nonane) 128.257
423.81 0.9136 3.8600E06
9 C8H18
n-Octane (Octane)
114.230
398.77 0.3655 3.8600E06
10 C5H12
n-Pentane (Pentane)
72.150
309.22
1.5966 4.5956E06
o-Xylene
106.167
417.46
2.3441 6.8318E06
11 C8H10
12 C8H10
p-Xylene
106.67
411.44
2.3047 7.6669E06
13 C7H8
Toluene
92.140
383.73
2.7343 3.8393E06
S solubility in salt water at 25 C, parts per million by weight, ppm (wt)
X concentration of salt (NaCl) in water, parts per million by weight, ppm (wt)
A, B, and C correlation constants for compound
Mw molecular weight of compound, g/mol
TB boiling point of compound, K
X = 0 for water without salt
X = 34,472 for sea water
Margins:Top:3p6
Gutter:4p6
C
1.9300E12
1.6357E16
2.2993E12
2.5458E12
3.1757E12
1.9300E12
1.9300E12
1.9300E12
1.9300E12
2.2978E12
3.4159E12
3.8335E12
1.9196E12
Font Size:9/10 pt
S at X = 0 S at X = 34,472
1.2200E01 9.0290E02
1.7550E+03 1.3540E+03
5.6100E+01 3.9190E+01
1.6510E+02 1.1100E+02
1.7400E+02 1.0600E+02
2.2400E+00 1.6570E+00
9.4700E+00 7.0070E+00
1.2200E01 9.0290E02
4.3100E01 3.1900E01
3.9500E+01 2.7600E+01
2.2080E+02 1.2960E+02
2.0170E+02 1.1090E+02
5.4240E+02 4.0200E+02
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:853
APPENDIX C
853
TABLE C-14 Solubility of Organic Compounds in Water as a Function of Temperature

log10 S = A + B/T + CT2
No. Formula
Substance
Mw
TB
1 C9H20
128.257 423.81
1-Nonane (Nonane)
2 C6H6
78.113 353.31
Benzene
3 C6H12
84.161 353.90
Cyclohexane
4 C8H10
106.167 409.17
Ethylbenzene
5 C8H10
106.167 412.22
m -Xylene
6 C7H16
100.203 371.56
n - Heptane (Heptane)
7 C6H14
86.177 341.93
n - Hexane (Hexane)
8 C9H20
128.257 423.81
n -Nonane (Nonane)
9 C8H18
114.230 398.77
n-Octane (Octane)
10 C5H12
72.150 309.22
n-Pentane (Pentane)
11 C8H10
106.167 417.46
o-Xylene
12 C8H10
106.167 411.44
p-Xylene
13 C7H8
92.140 383.73
Toluene
14 C5H10
70.134 322.41
Cyclopentane
15 C5H12
72.150 301.15
2-Methylbutane (isopentane)
16 C6H12
84.161 344.97
Methylcyclopentane
17 C7H14
98.188 376.60
Ethylcyclopentane
18 C7H14
98.188 374.08
Methylcyclohexane
19 C9H12
120.194 430.17
Propylbenzene
20 C9H12
120.194 426.31
Cumene
21 C9H18
126.241 429.76
Butylcyclopentane
22 C9H18
126.241 429.90
Propylcyclohexane
23 C10H14 Butylbenzene
134.221 456.43
24 C10H14 m-Diethylbenzene
134.221 454.25
25 C10H14 o-Diethylbenzene
134.221 457.02
26 C10H14 p-Diethylbenzene
134.221 456.94
27 C10H22 Decane
142.284 446.86
28 C11H16 Pentylbenzene
148.247 478.62
29 C11H22 Pentylcyclohexane
154.295 476.87
30 C11H24 Undecane
156.311 468.70
31 C12H18 Hexylbenzene
162.274 499.26
32 C12H26 Dodecane
170.337 488.61
33 C13H28 Tridecane
184.364 507.77
34 C14H22 1-Phenyloctane
190.328 537.56
35 C14H30 Tetradecane
198.391 526.14
36 C15H32 Pentadecane
212.418 543.59
37 C16H34 Hexadecane
226.445 560.50
38 C17H36 Heptadecane
240.471 576.00
S solubility in water, parts per million by weight, ppm (wt)
T temperature, K
Margins:Top:3p6
Gutter:4p6
A
18.222
11.994
6.403
13.365
14.743
12.811
10.992
18.222
16.865
9.036
13.112
13.731
15.471
8.665
9.473
12.430
14.360
13.091
11.722
13.052
20.741
18.885
9.533
10.975
10.908
10.910
17.396
9.504
22.316
28.051
11.076
23.755
22.937
9.743
17.765
18.533
16.462
10.581
B
11404.793
5214.537
2773.806
6643.672
7451.440
7426.389
5969.484
11404.793
10269.143
4433.922
6417.607
6810.190
7591.270
3850.808
4645.254
6436.630
7974.533
7084.522
5962.906
6766.120
12579.687
11356.483
5001.869
5686.134
5686.174
5686.175
11133.010
5316.406
14034.923
18123.096
6596.944
15607.165
15279.183
6166.179
12172.057
12808.889
11626.514
8007.275
C
1.6993E+06
7.76966E+05
4.13297E+05
9.89907E+05
1.11026E+06
1.10653E+06
8.89453E+05
1.69931E+06
1.53010E+06
6.60654E+05
9.56223E+05
1.01472E+06
1.13110E+06
5.73770E+05
6.92143E+05
9.59058E+05
1.18821E+06
1.05559E+06
8.88473E+05
1.00815E+06
1.87437E+06
1.69212E+06
7.45278E+05
8.47234E+05
8.47240E+05
8.47240E+05
1.65882E+06
7.92144E+05
2.09120E+06
2.70034E+06
9.82945E+05
2.32547E+06
2.27660E+06
9.18761E+05
1.81364E+06
1.90852E+06
1.73235E+06
1.19308E+06
Font Size:9/10 pt
S at 25 C
1.2200E01
1.7550E+03
5.6100E+01
1.6510E+02
1.7400E+02
2.2400E+00
9.4700E+00
1.2200E01
4.3100E01
3.9500E+01
2.2080E+02
2.0170E+02
5.4240E+02
1.6000E+02
4.7800E+01
4.2640E+01
9.5560E+00
1.6000E+01
5.2160E+01
5.0000E+01
4.3080E01
6.7730E01
1.3820E+01
2.7230E+01
2.3320E+01
2.3420E+01
5.2000E02
3.8400E+00
5.8500E02
4.4000E03
1.0180E+00
3.7000E03
2.0000E03
2.4970E01
2.2000E03
1.1000E03
9.0000E04
1.4000E03
S at 100 C
7.2870E01
3.9780E+03
8.6640E+01
4.6780E+02
5.5930E+02
7.1780E+00
2.4120E+01
7.2870E01
2.1560E+00
7.9120E+01
6.0390E+02
5.8610E+02
1.7810E+03
2.9240E+02
9.8870E+01
1.1700E+02
3.3310E+01
4.8570E+01
1.3270E+02
1.4450E+02
3.0920E+00
4.0120E+00
3.0270E+01
6.6290E+01
5.6810E+01
5.7070E+01
2.9790E01
8.8240E+00
5.2790E01
7.5240E02
2.8590E+00
4.2720E02
2.1910E02
6.5570E01
1.4810E02
8.1890E03
5.5670E03
4.9080E03
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:854

TABLE C-15 Henrys Law Constant for Gases in Water as a Function of Temperature
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
Formula
Ar
CF4
CH4
CO
COS
CO2
C2H2
C2H3Cl
C2H4
C2H6
C3H6
C3H6
C3H8
C4H8
C4H8
C4H10
C4H10
ClO2
Cl2
H2
H2S
He
Kr
NO
N2
N2O
Ne
O2
PH3
Rn
SF6
SO2
Xe
log10 H = A + B/T + C log T + DT

A
B
Tmin Tmax H at 25 C
Mw
C
D
Substance
65.3235 3.24690E+03 2.01398E+01 0.00000E+00 273.15 348.15 39696.1
Argon
39.948
Carbon tetrafluoride 88.005 1507.2737 4.19725E+04 5.99350E+02 4.09087E01 273.15 323.15 259777.3
146.8858 5.76834E+03 5.19144E+01 1.84936E02 273.15 360.95 39240.1
Methane
16.043
74.5962 3.60330E+03 2.33376E+01 0.00000E+00 273.15 353.15 57978.5
Carbon monoxide
28.010
2607.5
96.0704 5.22240E+03 3.03658E+01 0.00000E+00 273.15 303.15
Carbonyl sulfide
60.076
1635.2
69.4237 3.79646E+03 2.16694E+01 4.78857E04 273.15 353.15
Carbon dioxide
44.010
1332.6
67.9714 3.54393E+03 2.14030E+01 0.00000E+00 274.15 343.15
Acetylene
26.038
1403.3
61.1868 3.43853E+03 1.90984E+01 2.51906E03 273.15 323.15
Vinyl chloride
62.499
107.7298 6.33990E+03 3.17169E+01 1.32533E02 283.15 360.95 10784.4
Ethylene
28.054
108.9263 5.51363E+03 3.47413E+01 0.00000E+00 275.15 323.15 29402.4
Ethane
30.070
4820.7
42.081 141.9730 5.87466E+03 5.09015E+01 0.00000E+00 298.15 361.15
Cyclopropane
8182.3
Propylene
42.081 2570.0227 6.86740E+04 1.03384E+03 7.19694E01 283.15 360.95
44.096 2874.1130 8.56732E+04 1.12809E+03 7.01580E01 283.15 360.95 35420.1
Propane
12.9563 2.78226E+03 0.00000E+00 0.00000E+00 311.15 378.15

56.107
1-Butene
9714.4
103.9814 5.54785E+03 3.28909E+01 0.00000E+00 273.15 343.15
Isobutene
56.107
n -Butane
121.8305 6.34244E+03 3.87599E+01 0.00000E+00 273.15 349.15 44563.3
58.123
161.2644 7.94950E+03 5.24651E+01 0.00000E+00 278.15 318.15 60280.3
Isobutane
58.123
54.814
24.6413 6.21813E+01 1.07454E+01 0.00000E+00 283.15 333.15
67.452
Chloride dioxide
599.8
232.4396 8.21980E+03 8.69997E+01 4.42155E02 283.15 353.15
Chlorine
70.905
54.6946 2.40098E+03 1.68893E+01 0.00000E+00 273.15 345.15 70832.1
Hydrogen
2.016
10.8191 1.51009E+03 3.99300E01 6.81842E03 273.15 353.15
34.082
541.18
Hydrogen sulfide
46.0252 1.84993E+03 1.40094E+01 0.00000E+00 273.15 348.15 142950.4
4.003
Helium
77.5359 3.95280E+03 2.42207E+01 0.00000E+00 273.15 353.15 22161.3
83.800
Krypton
30.2512 2.42215E+03 5.70490E+00 1.19149E02 273.15 353.15 28739.1
30.006
Nitric oxide
78.8622 3.74498E+03 2.47981E+01 0.00000E+00 273.15 350.15 87143.1
Nitrogen
28.013
68.8882 3.85775E+03 2.12530E+01 0.00000E+00 273.15 313.15
44.013
2291.4
Nitrous oxide
60.7869 2.65134E+03 1.89157E+01 0.00000E+00 273.15 348.15 12262.8
20.180
Neon
77.8881 3.79901E+03 2.44526E+01 0.00000E+00 273.15 348.15 43630.9
31.999
Oxygen
67.5831 3.57648E+03 2.09165E+01 0.00000E+00 298.15 323.15
33.998
Phosphine
6776.6
109.3341 5.64696E+03 3.50047E+01 0.00000E+00 273.15 323.15
222.000
Radon
5987.3
191.8514 9.19008E+03 6.29116E+01 0.00000E+00 276.15 323.15 22752.1
Sulfur hexafluoride 146.056
22.3423 1.98711E+03 5.68540E+00 0.00000E+00 283.15 323.15
64.065
Sulfur dioxide
40.674
87.3918 4.56921E+03 2.74664E+01 0.00000E+00 273.15 348.15 12669.1
131.290
Xenon
H at Tmax
64077.9
374833.0
64820.5
85034.9
3060.5
4263.7
2381.4
2719.5
18502.9
48324.7
30453.0
29043.9
90695.7
399742.0
26279.4
125372.9
94825.0
190.01
1279.3
74664.1
1311.5
126766.7
42614.9
44559.0
118634.5
3363.7
123620.2
66575.2
10656.0
10449.8
348071.1
84.355
28466.9
H Henry's Law constant (atm/mol fraction) for gas in water at pressure of 1 atm (101.325 kPa)
1. Henry's Law constant is applicable at very low concentration (x<<<1). Most compounds in the tabulation are at very low concentrations (range of
0.00010.00001).
2. A few compounds (e.g., ClO2 and SO2) are not at very low concentrations. The tabulated data for these compounds should be considered rough values.
3. For those compounds that react with water, all chemical species of the gas and its reaction products are included.
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:855
APPENDIX C
855
TABLE C-16 Solubility of Selected Gases in Water as a Function of Temperature

log xwt = A + B/T + ClogT + DT
No. Formula
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
Ar
CF4
CH4
CO
COS
CO2
C2H2
C2H3Cl
C2H4
C2H6
C3H6
C3H6
C3H8
C4H8
C4H8
C4H10
C4H10
ClO2
Cl2
H2
H2S
He
Kr
NO
N2
N2O
Ne
O2
PH3
Rn
SF6
SO2
Xe
Substance
MW, g/mol
39.948 106.3705
Argon
Carbon tetrafluoride 88.005 1923.2642
16.043 1388.5451
Methane
28.010 1316.0154
Carbon monoxide
60.076 310.8791
Carbonyl sulfide
44.010 1307.3028
Carbon dioxide
26.038 904.6169
Acetylene
62.499 466.7040
Vinyl chloride
28.054 2717.3688
Ethylene
30.070 546.9272
Ethane
42.081 3892.0392
Cyclopropane
39.4402
42.081
Propylene
44.096 5554.9049
Propane
56.107 2991.5526
1-Butene
56.107 919.4382
Isobutene
n -Butane
58.123 1160.1487
58.123 566.9083
Isobutane
67.452 569.1018
Chloride dioxide
70.905 1847.3759
Chlorine
2.016 938.5889
Hydrogen
34.082 1247.8348
Hydrogen sulfide
4.003 1043.1419
Helium
83.800 1318.1442
Krypton
30.006 1271.6006
Nitric oxide
28.013 1163.3807
Nitrogen
44.013 371.1999
Nitrous oxide
20.180 1057.1943
Neon
31.999 1074.0450
Oxygen
33.998 864.2313
Phosphine
222.000 514.8565
Radon
Sulfur hexafluoride 146.056 640.4119
64.065 359.9136
Sulfur dioxide
131.290 1081.4609
Xenon
2.87724E+04
5.23082E+04
3.78016E+04
3.56367E+04
1.03967E+04
3.57336E+04
2.48670E+04
1.34792E+04
7.56485E+04
1.64179E+04
1.04154E+05
6.34551E+02
1.56979E+05
8.40296E+04
2.63056E+04
3.29912E+04
1.80393E+04
1.46852E+04
5.05934E+04
2.49279E+04
3.34178E+02
2.73774E+04
3.59766E+04
3.44544E+04
3.16107E+04
1.12586E+04
2.81787E+04
2.93249E+04
2.41128E+04
1.57032E+04
2.03918E+04
9.82234E+03
3.00530E+04
4.24672E+02
7.69721E+02
5.55218E+02
5.26642E+02
1.19013E+02
5.23648E+02
3.61545E+02
1.85229E+02
1.08310E+03
2.13803E+02
1.56543E+03
1.75424E+01
2.20789E+03
1.19372E+03
3.64670E+02
4.60393E+02
2.18486E+02
2.32419E+02
7.39612E+02
3.75683E+02
5.01994E+02
4.18569E+02
5.27392E+02
5.08993E+02
4.64916E+02
1.45406E+02
4.23473E+02
4.28990E+02
3.44136E+02
2.01357E+02
2.46507E+02
1.45582E+02
4.31418E+02
3.02604E01
5.41819E01
3.91585E01
3.73092E01
7.17370E02
3.72704E01
2.56198E01
1.32359E01
7.38856E01
1.38988E01
1.12081E+00
3.24155E02
1.47267E+00
8.29111E01
2.50383E01
3.14847E01
1.29161E01
1.89385E01
5.18667E01
2.69793E01
3.65161E01
3.02623E01
3.73004E01
3.61166E01
3.28050E01
9.84292E02
3.02621E01
3.02607E01
2.40666E01
1.29996E01
1.42242E01
1.15277E01
3.02221E01
Tmin
Tmax
xwt at 25 C
xwt at Tmax
273.15
273.15
273.15
273.15
273.15
273.15
273.15
273.15
283.15
275.15
298.15
283.15
283.15
311.15
273.15
273.15
278.15
283.15
283.15
273.15
273.15
273.15
273.15
273.15
273.15
273.15
273.15
273.15
298.15
273.15
276.15
283.15
273.15
348.15
323.15
360.95
353.15
303.15
353.15
343.15
323.15
360.96
323.15
361.15
360.95
360.95
348.15
343.15
349.15
318.15
333.15
353.15
345.15
353.15
348.15
353.15
353.15
350.15
313.15
348.15
348.15
323.15
323.15
323.15
323.15
348.15
5.4131E05
1.8227E05
2.1949E05
2.5937E05
1.2373E03
1.4429E03
1.0504E03
2.3906E03
1.3646E04
5.5018E05
4.7881E04
2.6979E04
6.5123E05
3.1083E04
7.0137E05
5.1857E05
6.2050E02
6.2695E03
1.5319E06
3.3698E03
1.5063E06
2.0297E04
5.6051E05
1.7282E05
1.0319E03
8.8522E06
3.9450E05
2.6973E04
1.9910E03
3.4534E05
7.8097E02
5.5714E04
2.1760E05
1.1456E05
6.0342E06
9.9946E06
1.0429E03
3.1311E04
4.2360E04
1.1202E03
3.1695E05
3.0358E05
2.8627E05
3.0288E05
1.0153E05
2.0827E05
8.2769E05
1.5785E05
3.0814E05
1.5612E02
1.6680E03
1.0072E06
7.8792E04
1.1022E06
5.9664E05
2.0432E05
7.8317E06
6.7314E04
5.6978E06
1.6776E05
1.5551E04
1.0349E03
2.0471E05
3.5720E02
1.6095E04
xwt solubility (weight fraction) of compound in water at pressure of 1 atm (101.325 kPa)
1. Most compounds in the tabulation are at very low concentrations (range of 0.00010.000001). At very low concentrations, Henry's Law is applicable ( p = Hx
where x <<<1).
2. A few compounds (e.g., ClO2 and SO2) are not at very low concentrations. The tabulation data for these compounds should be considered rough values.
3. For those compounds that react with water, all chemical species of the gas and its reaction products are included.
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:856
TABLE C-17
No.
Solubility of Sulfur Compounds in Water as a Function of Boiling Point

for Mercaptans and Aromatics
Formula
Substance
Type
1 CH4S
mercaptan
Methyl mercaptan
2 C2H6S
mercaptan
Ethyl mercaptan
3 C3H8S
mercaptan
Propyl mercaptan
4 C3H8S
mercaptan
Isopropyl mercaptan
5 C4H10S
mercaptan
Butyl mercaptan
6 C4H10S
mercaptan
Isobutyl mercaptan
7 C4H10S
mercaptan
sec-Butyl mercaptan
8 C4H10S
mercaptan
tert-Butyl mercaptan
9 C5H12S
mercaptan
Penyl Mercaptan
10 C5H12S
mercaptan
2-Pentanethiol
11 C5H12S
mercaptan
3-Pentanethiol
12 C5H12S
mercaptan
2-Methyl-1-butanethiol
13 C5H12S
mercaptan
14 C5H12S
mercaptan
15 C5H12S
mercaptan
16 C5H12S
mercaptan
2,2-Dimethyl-1-propanethiol
17 C6H14S
mercaptan
Hexyl mercaptan
18 C6H14S
mercaptan
2-Hexanethiol
19 C8H18S
mercaptan
Octyl mercaptan
20 C8H18S
mercaptan
2-Octanethiol
21 C8H18S
mercaptan
tert-Octyl mercaptan
22 C9H20S
mercaptan
Nonyl mercaptan
23 C9H20S
mercaptan
2-Nonanethiol
24 C10H22S
mercaptan
Decyl mercaptan
25 C10H22S
mercaptan
2-Decanethiol
26 C11H24S
mercaptan
1-Undecanethiol
27 C11H24S
mercaptan
2-Undecanethiol
28 C12H26S
mercaptan
1-Dodecanethiol
29 C12H26S
mercaptan
2-Dodecanethiol
30 C13H28S
mercaptan
1-Tridecanethiol
30 C13H28S
mercaptan
2-Tridecanethiol
31 C14H30S
mercaptan
1-Tetradecanethiol
32 C14H30S
2-Tetradecanethiol
mercaptan
Code: 1 experimental data; 2 estimate
TB boiling point, K
S solubility in water, ppm (wt); ppm = parts per million
T temperature, C
Margins:Top:3p6
T B, K
279.11
308.15
340.87
325.71
371.61
361.64
358.13
337.37
399.79
385.55
387.05
392.15
391.50
372.28
382.91
376.83
425.81
412.05
472.19
459.55
429.00
492.95
481.35
512.35
501.45
530.55
520.45
547.75
538.35
563.96
555.15
579.36
571.15
Gutter:4p6
S at 25 C, ppm (wt) S at 25 C, ppm (mol)

2.3300E+04
1.5000E+04
3.6899E+03
6.1810E+03
6.0000E+02
1.6210E+03
1.8786E+03
4.1849E+03
2.7257E+02
5.4872E+02
5.1059E+02
3.9851E+02
4.1147E+02
1.0171E+03
6.2217E+02
8.2658E+02
7.0459E+01
1.4553E+02
5.6934E+00
1.1319E+01
5.9408E+01
1.8771E+00
3.4756E+00
6.9284E01
1.2056E+00
2.8701E01
4.6457E01
1.3292E01
2.0073E01
6.8950E02
9.7619E02
3.9756E02
5.2816E02
8.8548E+03
4.3962E+03
8.7535E+02
1.4691E+03
1.1992E+02
3.2425E+02
3.7586E+02
8.3883E+02
4.7132E+01
9.4907E+01
8.8310E+01
6.8919E+01
7.1161E+01
1.7599E+02
1.0762E+02
1.4300E+02
1.0737E+01
2.2177E+01
7.0119E01
1.3940E+00
7.3169E+00
2.1095E01
3.9059E01
7.1599E02
1.2459E01
2.7451E02
4.4434E02
1.1832E02
1.7868E02
5.7399E03
8.1266E03
3.1082E03
4.1293E03
Font Size:9/10 pt
Code
1
1
2
2
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:857
APPENDIX C
857
TABLE C-18 Solubility of Napthenes in Water

log10 S = A + B/T + C/T 2
Mw
TB
S at 25 C
S at 100 C
Cyclopentane
70.134
322.4
8.665
3850.808
5737.704E+02
1600E01
2924E01
C6H12
Cyclohexane
84.161
353.9
6.403
2773.806
4132.971E+02
5610E02
8664E02
C6H12
Methylcyclopentane
84.161
345.0
12.430
6436.630
9590.579E+02
4264E02
1170E01
C7H14
Ethylcyclopentane
98.188
376.6
14.360
7974.533
1188.205E+03
9556E03
3331E02
C7H14
1,1-Dimethylcyclopentane
98.188
361.0
12.634
6723.665
1001.826E+03
2253E02
6460E02
C7H14
C-1,2-Dimethylcyclopentane
98.188
372.7
7647.583
1139.49E+03
1191E02
3944E02
C7H14
T-1,2-Dimethylcyclopentane
98.188
365.0
13.907
13.057
7031.220
1047.652E+03
1816E02
5472E02
C7H14
C-1,3-Dimethylcyclopentane
98.188
363.9
12.940
6946.544
1035.035E+03
1927E02
5721E02
C7H14
T-1,3-Dimethylcylopentane
98.188
364.9
13.042
7020.299
1046.025E+03
1830E02
5505E02
10
C7H14
Methylcyclohexane
98.188
374.1
13.091
7084.522
1055.594E+03
1600E02
4857E02
11
C8H16
Propylcyclopentane
112.214
404.1
17.327
10142.370
1511.213E+03
2040E03
9996E03
12
C8H16
Ethylcyclohexane
112.214
404.9
19.501
11345.870
1690.535E+03
2916E03
1724E02
13
C8H16
1,1-Dimethylcyclohexane
112.214
392.7
14.606
8241.599
1227.998E+03
5989E03
2181E02
14
C8H16
402.9
11.610
6455.995
9619.432E+02
6000E03
1649E02
C8H16
C-1,2-Dimethycyclohexane
T-1,2-Dimethylcyclohexane
112.214
15
112.214
396.7
15.082
8586.692
1279.417E+03
4734E03
1816E02
16
C8H16
C-1,3-Dimethylcyclohexane
112.214
393.3
14.671
8288.887
1235.044E+03
5799E03
2126E02
17
C8H16
112.214
397.6
15.189
8663.467
1290.857E+03
4493E03
1748E02
18
C8H16
C-1,4-Dimethylcyclohexane
112.214
397.6
15.184
8660
1290.340E+03
4504E03
1750E02
19
C8H16
112.214
392.5
17.766
10240.17
1525.786E+03
3840E03
1911E02
429.8
429.9
411.7
413.7
453.8
454.1
476.3
476.9
497.3
497.9
516.9
518.1
535.3
536.8
552.5
554.7
20.741
18.885
16.852
17.089
22.985
21.087
24.302
22.316
24.467
22.412
23.457
21.326
21.217
19.067
17.98
15.592
12579.69
11356.48
9869.544
10041.88
1459.12
13014.7
15330.35
14034.92
15649.31
14310.59
15199.39
13817.11
13948.64
12553.52
12044.88
10498.13
1874.373E+03
1692.116E+03
1470.562E+03
1496.240E+03
2124.608E+03
1939.191E+03
2284.223E+03
2091.204E+03
2331.747E+03
2132.278E+03
2264.709E+03
2058.750E+03
2078.347E+03
1870.474E+03
1794.686E+03
1564.222E+03
4308E04
6773E04
1962E03
1740E03
1150E04
1781E04
3800E05
5850E05
1620E05
2520E05
9000E06
1390E05
6500E06
1010E05
5900E06
9500E06
3092E03
4012E03
9205E03
8387E03
1073E03
1368E03
4200E04
5279E04
1883E04
2370E04
9750E05
1211E04
5787E05
7217E05
3892E05
4922E05
No.
1
Formula
C5H10
Substance
20 C9H18
126.241
Butylcyclopentane
21 C9H18
126.241
Propylcyclopentane
22 C9H18
126.241
C-C-1,5-Trimethylcyclohexane
23 C9H18
126.241
C-T-1,3,5-Trimethylcyclohexane
24 C10H20
140.268
1-Cyclopentylpentane
25 C10H20
140.268
Butylcyclohexane
26 C11H22
154.295
1-Cyclopentylhexane
27 C11H22
154.295
Pentylcyclohexane
28 C12H24
168.322
1-Cyclopentylheptane
29 C12H24
168.322
1-Cyclohexylhexane
30 C13H26
182.348
1-Cyclopentyloctane
31 C13H26
182.348
1-Cyclohexylheptane
32 C14H28
196.375
1-Cyclopentylnonane
33 C14H28
196.375
1-Cyclohexyloctane
34 C15H30
210.402
1-Cyclopentyldecane
35 C15H30
1-Cyclohexylnonane
210.402
S solubility in salt water at 25 C, parts per million by weight, ppm (wt)
Temperature range is 298393 K (25120 C)
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:858

TABLE C-19 Solubility of Nitrogen Compounds in Water
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
Formula
CH5N
C 2 H7 N
C 2 H7 N
C3H9N
C 3 H9 N
C 3 H9 N
C 3 H9 N
C4H11N
C4H11N
C4H11N
C4H11N
C4H11N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C6H15N
C6H15N
C6H15N
C7H17N
C7H17N
C7H17N
C7H17N
C7H17N
C8H19N
C8H19N
C8H19N
C8H19N
C8H19N
C8H19N
C8H19N
C9H21N
C9H21N
C9H21N
C10H23N
C10H23N
C10H23N
C11H25N
C11H25N
Substance
Methylamine
Ethylamine
Dimethylamine
n-Propylamine
iso-Propylamine
Methylethylamine
Trimethylamine
n-Butylamine
iso-Butylamine
sec-Butylamine
tert-Butylamine
Diethylamine
n-Pentylamine
1-Methylbutylamine
1-Ethylpropylamine
2-Methylbutylamine
3-Methylbutylamine
n-Hexylamine
1-Methylpentylamine
1-Ethylbutylamine
n-Heptylamine
Methyl-n-hexylamine
Ethyl-n-pentylamine
Dimethyl-n-pentylamine
Dimethyl-2-Pentylamine
n-Octylamine
2-Ethylhexylamine
Di-n-butylamine
Methyl-n-heptylamine
Ethyl-n-hexylamine
Dimethyl-n-hexylamine
Diethyl-n-butylamine
n-Nonylamine
Methyl-n-octylamine
Ethyl-n-heptylamine
n-Decylamine
Di-n-pentylamine
Methyl-n-nonylamine
n-Undecylamine
Methyl-n-decylamine
TB
266.82
289.73
280.03
321.65
305.55
309.15
276.02
350.55
340.88
336.15
317.55
328.60
377.65
364.85
362.15
368.65
370.15
404.65
403.15
400.45
430.05
415.15
407.15
395.15
382.15
452.75
442.35
432.00
438.15
431.15
418.15
409.15
475.35
459.85
453.85
493.65
476.15
480.15
516.15
499.35
Code
1
1
2
1
1
2
2
1
1
2
2
1
1
2
2
2
2
1
2
2
2
2
2
2
2
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
T
25
20
25
100
100
25
25
100
20
20
20
38
25
25
25
25
25
25
25
25
25
25
25
25
25
25
20
25
25
25
25
25
25
25
25
25
25
25
25
25
S at T, ppm (wt)
High
High
High
1.0000E+06
1.0000E+06
High
High
1.0000E+06
1.0000E+06
High
High
1.0000E+06
High
High
High
High
High
1.2000E+04
2.6103E+04
3.0072E+04
7.1302E+03
1.0213E+04
1.5615E+04
8.6243E+03
1.7197E+04
2.0000E+02
2.5000E+03
3.5000E+03
3.3545E+03
4.8771E+03
2.8303E+03
4.5801E+03
7.7899E+02
1.1549E+03
1.5929E+03
5.5000E+02
5.3283E+02
4.2996E+02
1.0516E+02
1.6721E+02
S at T, ppm (mol)
High
High
High
1.0000E+06
1.0000E+06
High
High
1.0000E+06
1.0000E+06
High
High
1.0000E+06
High
High
High
High
High
2.1576E+03
4.7490E+03
5.4893E+03
1.1216E+03
1.6107E+03
2.4740E+03
1.3583E+03
2.7284E+03
2.7882E+01
3.4921E+02
4.8932E+02
4.6893E+02
6.8266E+02
3.9546E+02
6.4092E+02
9.8706E+01
1.4638E+02
2.0197E+02
6.3021E+01
6.1053E+01
4.9261E+01
1.1059E+01
1.7585E+01
Code: 1 experimental data; 2 estimate

TB boiling point temperature, K
S solubility in water, ppm
ppm parts per million
T temperature, C
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:859
APPENDIX C
859
TABLE C-20 Henrys Law Constant for Nitrogen Compounds in Water
No. Formula
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
CH5N
C 2 H7 N
C 2 H7 N
C 3 H9 N
C 3 H9 N
C 3 H9 N
C 3 H9 N
C4H11N
C4H11N
C4H11N
C4H11N
C4H11N
C4H11N
C4H11N
C4H11N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C5H13N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
H at T
(atm/mol frac)
0.49
0.66
0.88
1.08
0.85
1.44
2.62
1.51
1.37
1.35
1.04
1.87
2.20
1.90
4.90
2.12
1.60
1.51
1.73
1.79
1.21
1.38
1.21
4.34
3.14
3.03
2.75
3.28
2.96
6.87
6.87
6.87
2.70
2.68
2.51
2.48
2.40
2.31
1.50
1.56
Henrys Law Constant, H, at 25 C

H at T
No.
Formula
(atm/mol/m3)
8.8019E06
1.1897E05
1.5886E05
1.9362E05
1.5374E05
2.5904E05
4.7117E05
2.7141E05
2.4672E05
2.4361E05
1.8769E05
3.3586E05
3.9552E05
3.4228E05
8.8180E05
3.8121E05
2.8776E05
2.7255E05
3.1144E05
3.2159E05
2.1851E05
2.4756E05
2.1851E05
7.8193E05
5.6540E05
5.4504E05
4.9531E05
5.9117E05
5.3200E05
1.2367E04
1.2368E04
1.2368E04
4.8577E05
4.8233E05
4.5156E05
4.4721E05
4.3140E05
4.1631E05
2.7003E05
2.8105E05
Margins:Top:3p6
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
Gutter:4p6
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C6H15N
C7H17N
C7H17N
C7H17N
C7H17N
C7H17N
C7H17N
C7H17N
C7H17N
C7H17N
H at T
(atm/mol frac)
H at T
(atm/mol/m3)
1.64
2.26
2.39
1.83
1.53
1.66
1.50
1.44
2.37
5.62
2.87
7.23
6.34
5.81
5.48
5.33
5.18
5.03
4.89
5.48
4.14
4.14
2.50
4.17
11.16
12.64
12.64
9.33
11.47
11.89
11.89
3.21
5.51
4.50
26.88
18.64
22.63
21.39
21.09
23.95
2.9579E05
4.0759E05
4.3037E05
3.2888E05
2.7546E05
2.9888E05
2.7003E05
2.5967E05
4.2731E05
1.0111E04
5.1655E05
1.3021E04
1.1417E04
1.0455E04
9.8659E05
9.5861E05
9.3157E05
9.0544E05
8.8017E05
9.8659E05
7.4531E05
7.4531E05
4.5008E05
7.5143E05
2.0095E04
2.2744E04
2.2744E04
1.6793E04
2.0645E04
2.1401E04
2.1401E04
5.7839E05
9.9229E05
8.1079E05
4.8377E04
3.3546E04
4.0727E04
3.8501E04
3.7968E04
4.3107E04
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:860

TABLE C-21 Coefcient of Thermal Expansion of Liquids
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
NH3
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CCl4
Cl2
CHCl3
C6H12
C6H12O
C3H6
CH2Cl2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
CH4O
Substance
1,1-Dichloroethane
1,2-Dichloroethane
1,3-Butadiene
1,4-Dioxane
1-Butene
1-Decene
1-Nonane (n-Nonane)
1-Octene
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acrylic acid
Ammonia
Aniline
Benzene
Butyric acid
Carbon disulfide
Carbon dioxide
Carbon monoxide
Chlorine
Chloroform
Cyclohexane
Cyclohexanol
Cyclopropane
Dichloromethane
Diethyl ether
Diethyl ketone
Dimethylamine
Ethane
Ethanol
Ethyl acetate
Ethyl chloride
Ethylbenzene
Ethylene
Ethylene glycol
Ethylene oxide
Fluorine
Glycerol
Hydrogen
Hydrogen chloride
Hydrogen cyanide
Hydrogen peroxide
Methane
Methanol
Bliq = a (1 T/Tc )m
m
a
Tc
6.9960E04 545.00 0.7067
7.0420E04 602.00 0.6900
7.2810E04 523.00 0.7130
6.8990E04 561.00 0.6896
8.8920E04 425.37 0.7093
6.5840E04 587.00 0.6953
5.7680E04 562.93 0.7543
8.9970E04 419.59 0.7147
6.2750E04 617.05 0.7144
6.5440E04 595.65 0.7143
6.8610E04 566.60 0.7143
6.0500E04 536.71 0.7506
8.1110E04 461.00 0.7224
5.9380E04 592.71 0.7316
6.7520E04 569.15 0.7301
7.9810E04 508.20 0.7010
6.7590E04 615.00 0.6930
9.7330E04 405.65 0.7113
5.6660E04 699.00 0.7143
6.6060E04 562.16 0.7182
5.9730E04 628.00 0.7200
7.2850E04 552.00 0.6774
1.2800E03 304.19 0.7097
2.8090E03 132.92 0.7095
6.6990E04 556.35 0.7100
8.9690E04 417.15 0.7117
7.3760E04 536.40 0.7123
6.6670E04 553.54 0.7149
6.4580E04 625.15 0.7143
9.2960E04 397.91 0.7143
7.7360E04 510.00 0.7098
8.0960E04 466.70 0.7064
6.9030E04 560.95 0.7264
7.4650E04 437.65 0.7520
1.2030E03 305.42 0.7167
6.1070E04 516.25 0.7633
7.1860E04 523.30 0.7220
6.4960E04 460.35 0.7686
6.2960E04 617.17 0.7079
1.2860E03 282.36 0.7143
3.6440E04 645.00 0.8280
8.0920E04 469.15 0.7175
2.5210E03 144.31 0.7100
2.9630E04 723.00 0.8459
8.7840E03 33.18 0.7244
1.2870E03 324.65 0.6813
1.0390E03 456.65 0.7179
5.4650E04 730.15 0.7123
8.6860E04 408.14 0.7270
1.8090E03 190.58 0.7230
5.9220E04 512.58 0.7669
Margins:Top:3p6
Gutter:4p6
T min
242.75
236.50
176.19
237.49
164.25
284.95
183.85
87.80
206.89
219.63
171.45
146.95
150.15
289.81
200.15
178.45
286.65
195.41
267.13
278.68
267.95
161.58
216.58
68.15
250.33
172.12
209.63
279.69
296.60
145.73
178.01
156.85
234.18
180.96
90.35
159.05
189.60
136.75
178.20
104.01
260.15
161.45
53.48
291.33
13.95
158.97
259.91
272.74
113.54
90.67
175.47
T max
517.75
571.90
496.85
532.95
404.10
557.65
534.78
398.61
586.20
565.87
538.27
509.87
437.95
563.07
540.69
482.79
584.25
385.37
664.05
534.05
596.60
524.40
288.98
126.27
528.53
396.29
509.58
525.86
593.89
378.01
484.50
443.37
532.90
415.77
290.15
490.44
497.14
437.33
586.31
268.24
612.75
445.69
137.00
686.85
31.52
308.42
433.82
693.64
387.73
181.05
486.95
Font Size:9/10 pt
Bliq at 25 C
densityliq at 25 C
1.2240E03
1.290E03
1.3290E03
1.1640E03
2.0930E03
1.0780E03
1.0190E03
2.1820E03
1.0060E03
1.0740E03
1.1700E03
1.1120E03
1.7200E03
9.9030E04
1.1610E03
1.4830E03
1.0700E03
2.5030E03
8.4290E04
1.1370E03
9.4950E04
1.2330E03
1.1550E03
2.1900E03
1.3150E03
1.1590E03
1.0260E03
2.4970E03
1.4430E03
1.6620E03
1.1970E03
1.7640E03
1.1790E03
1.3210E03
1.4480E05
1.0050E03
6.0910E04
1.6690E03
4.6460E04
7.0940E03
2.2220E03
7.9430E04
2.2530E03
1.1550E03
1.330
1.435
1.168
1.246
0.615
1.029
0.806
0.588
0.737
0.715
0.711
0.802
0.774
1.043
1.077
0.786
1.046
0.602
1.018
0.873
0.953
1.256
0.713
1.583
1.398
1.480
0.773
0.774
0.619
1.318
0.708
0.810
0.650
0.315
0.787
0.894
0.890
0.865
1.110
0.862
1.257
0.796
0.680
1.443
0.552
0.787
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:861
APPENDIX C
861
Bliq = a (1 T/Tc )m
No. Formula
Substance
a
Tc
m
52 CH3Br
8.0180E04 467.00 0.7197
Methyl bromide
53 CH3Cl
9.2560E04 416.25 0.7131
Methyl chloride
54 C6H12O
6.7570E04 571.40 0.7143
55 CH5N
8.1550E04 430.05 0.7725
Methylamine
56 C8H10
5.9600E04 617.05 0.7276
m-Xylene
57 C10H8
5.0520E04 748.35 0.7270
Naphthalene
58 C4H10
8.7570E04 425.18 0.7137
n-Butane
59 C10H22
6.3600E04 618.45 0.7143
n-Decane
60 C7H16
6.9550E04 540.26 0.7209
n-Heptane
61 C6H14
7.2780E04 507.43 0.7219
n-Hexane
5.5520E04 719.00 0.7143
63 N2
2.9130E03 126.10 0.7075
Nitrogen
64 C9H20
6.5440E04 595.65 0.7143
n-Nonane
65 C8H18
6.4760E04 568.83 0.7306
n-Octane
66 C5H12
7.8830E04 469.65 0.7179
n-Pentane
67 O2
2.3560E03 154.58 0.7076
Oxygen
68 C8H10
5.8440E04 630.37 0.7259
o-Xylene
69 C6H6O
5.2480E04 694.25 0.6788
Phenol
70 C8H10
6.0980E04 616.26 0.7210
p-Xylene
71 C5H5N
6.9420E04 619.95 0.6955
Pyridine
72 C8H8
5.8860E04 648.00 0.7143
Styrene
73 SO2
9.1740E04 430.75 0.7107
Sulfur dioxide
74 C7H8
6.5930E04 591.79 0.7011
Toluene
75 C4H6O2
7.3090E04 524.00 0.7173
Vinyl acetate
76 H2O
Water
5.7160E04 647.13 0.7143
B liq coefficient of thermal expansion of liquid, 1/C
densityliq density of liquid, g/cm3
T min minimum tempearature, K
T max maximum temperature, K
Margins:Top:3p6
Gutter:4p6
T min
179.55
175.45
189.15
179.69
225.30
353.43
134.86
243.49
182.57
177.84
278.91
63.15
219.63
216.38
143.42
54.35
247.98
314.06
286.41
231.53
242.54
197.67
178.18
180.35
273.16
T max
443.65
395.44
542.83
408.55
586.20
710.93
403.92
587.53
513.25
482.06
683.05
119.80
565.87
540.39
446.17
146.85
598.85
659.54
585.45
588.95
615.60
409.21
562.20
497.80
614.77
Font Size:9/10 pt
B liq at 25 C
1.6670E03
2.2730E03
1.1450E03
2.0320E03
9.6340E04
2.0740E03
1.0180E03
1.2410E03
1.3790E03
8.1390E04
1.0740E03
1.1140E03
1.6250E03
9.3020E04
9.8230E04
1.0950E03
9.1420E04
2.1190E03
1.0780E03
1.3370E03
8.8850E04
densityliq at 25 C
1.662
0.913
0.796
0.655
0.861
0.573
0.728
0.682
0.656
1.199
0.715
0.699
0.621
0.876
0.858
0.979
0.900
1.366
0.865
0.926
1.027
Text Width:41p6
Depth:65 Lines
Elsevier US
Job Code:CAPA
Chapter:0capaappC
22-12-2006
5:31 p.m.
Page:862

TABLE C-22 Adsorption Capacity of Activated Carbon
log10 Q = A + B [log10y] + C [log10y]2
Formula
C2H3Cl3
ymin
ymax
0.9733
2.8737E01
2.2770E02
10
10000
17.29
28.64
42.70
C2H3Cl3
1,1,2-trichloroethane
1.1716
2.7791E01
2.7460E02
10
10000
26.43
41.46
57.31
C2H4Cl2
1,1-Dichloroethane
0.5449
3.6091E01
2.1920E02
10
10000
7.65
15.10
26.93
C2H4Cl2
1,2-Dichloroethane
0.5534
3.7072E01
2.1610E02
10
10000
7.99
16.16
29.59
C3H8O
0.3864
4.8033E01
4.5050E02
10
10000
6.63
14.69
26.42
C2H4O
Acetaldehyde
1.1705
6.2766E01
2.4750E02
10
10000
0.27
0.97
3.09
C2H4O2
Acetic acid
0.0555
6.8410E01
6.0710E02
10
10000
3.70
11.74
28.21
C3H6O
Acetone
0.1455
4.7497E01
2.2860E02
10
10000
2.03
5.16
11.85
C3H4O2
Acrylic acid
0.7555
4.7108E01
5.6150E02
10
5221
14.81
29.72
46.06
10
CS2
Carbon disulfide
0.1890
4.7093E01
1.4810E02
10
10000
1.85
4.94
12.32
11
CO2
Carbon dioxide
3.6522
8.0180E01
3.2800E03
10
10000
1.4E03
8.7E03
12
CO
Carbon monoxide
5.1878
9.0121E01
1.3580E02
10
10000
5.0E05
3.6E04
13
CCl4
1.0748
2.8186E01
2.2730E02
10
10000
21.57
35.29
51.98
14
CHCl3
Chloroform
0.6710
3.1648E01
2.2880E02
10
10000
10.22
20.07
35.45
15
CH2Cl2
Dichloromethane
0.0704
4.9210E01
2.2760E02
10
10000
2.51
6.65
15.89
16
C2H6
Ethane
2.4039
6.8107E01
1.9250E02
10
10000
1.8E02
7.6E02
17
C2H6O
Ethanol
0.5115
6.7525E01
4.4730E02
10
10000
1.32
4.57
12.93
18
C2H5Cl
Ethyl chloride
0.5083
5.0364E01
2.1790E02
10
10000
0.94
2.58
6.40
19
C2H4
Ethylene
2.2710
6.1731E01
1.4670E02
10
10000
2.1E02
8.0E02
0.28
20
C2H6O2
Ethylene glycol
1.4047
1.8738E01
2.6630E02
10
121
36.77
47.09
21
C2H4O
Ethylene oxide
2.4238
9.4878E01
4.0620E02
10
10000
0.03
0.20
1.14
22
CH2O
Formaldehyde
2.4852
6.9123E01
3.7500E03
10
10000
1.6E02
7.6E02
0.36
23
CH2O2
Formic acid
1.7773
1.0950E+00
6.3540E02
10
10000
0.18
1.44
8.63
24
CHN
Hydrogen cyanide
4.3925
1.0895E+00
7.4000E03
10
10000
4.9E04
5.7E03
6.4E02
25
CH4
Methane
4.3101
7.7883E01
6.2800E03
10
10000
2.9E04
1.7E03
9.3E03
26
CH4O
Methanol
1.9674
8.2107E01
1.3930E02
10
10000
0.07
0.42
2.35
27
C3H6O2
Methyl acetate
0.1331
4.2849E01
2.1880E02
10
10000
3.47
7.99
16.66
28
CH3Br
Methyl bromide
1.2384
7.8564E01
5.5210E02
10
10000
0.31
1.29
4.19
29
CH3Cl
Methyl chloride
1.9187
6.2053E03
5.4900E03
10
10000
0.05
0.20
0.78
30
CH5N
Methylamine
1.9355
6.4710E01
1.0570E02
10
10000
0.05
0.21
0.81
31
C3H7NO
N,N-Dimethylformamide
0.9025
3.7875E01
4.5230E02
10
5220
17.22
30.14
42.83
32
CH3NO2
Nitromethane
0.3285
7.0602E01
5.1110E02
10
10000
2.12
7.57
21.36
33
C3H8O
Propane
0.7946
4.9029E01
2.3980E02
10
10000
0.47
1.23
2.89
34
C3H6O2
Propionic acid
0.7785
4.4570E01
5.2090E02
10
4872
14.86
28.94
44.34
35
C2HCl3
Trichloroethylene
1.0241
2.9929E01
2.5390E02
10
10000
19.86
33.20
49.38
No.
Substance
Q at 10 ppmv
Q at 100 ppmv
Q at 1000 ppmv
5.3E02
2.5E03
0.29
Q adsorption capacity at equilibrium, g of compound/100 g of carbon

y concentration of compound in gas at 25 C and 1 atm, parts per million by volume, ppmv
ymin minimum concentration, ppmv
ymax maximum concentration, ppmv
Margins:Top:3p6
Gutter:4p6
Font Size:9/10 pt
Text Width:41p6
Depth:65 Lines

Appendix C

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Appendix C

Uploaded by

Copyright:

Available Formats

Elsevier US

PHYSICAL PROPERTIES OF LIQUIDS AND GASES

TABLES OF PHYSICAL PROPERTIES OF LIQUIDS AND

Solubility of Naphthenes in Water

Fonts used:Times & Universal 55 family

828 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

Fonts used:Times & Universal 55 family

830 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

27.740 5.5901E01 7.0942E05

1.374 3.8627E01 4.8650E05

Methyl isobutyl ketone

3.237 2.3310E01 3.5612E05

Fonts used:Times & Universal 55 family

832 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

Fonts used:Times & Universal 55 family

834 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

(Cpjoule/(mol K), TK)

Fonts used:Times & Universal 55 family

836 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

Fonts used:Times & Universal 55 family

838 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

(Kgas W/(m K), T K)

Fonts used:Times & Universal 55 family

(Kgas W/(m K), T K)

840 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

A, B, and C regression coefficients for chemical compound

Fonts used:Times & Universal 55 family

842 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

TABLE C-8 Surface Tension of Organic Liquids

Fonts used:Times & Universal 55 family

844 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

TABLE C-9 Vapor Pressure

Fonts used:Times & Universal 55 family

846 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

TABLE C-10 Enthalpy of Vaporization

Fonts used:Times & Universal 55 family

848 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Fonts used:Times & Universal 55 family

TABLE C-11 Enthalpy of Formation

Fonts used:Times & Universal 55 family

850 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Hf enthalpy of formation of ideal gas, kjoule/mol

A, B, and C regression coefficients for chemical compound

Fonts used:Times & Universal 55 family

TABLE C-12 Gibbs Energy of Formation

Fonts used:Times & Universal 55 family

852 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

Gf Gibbs energy of formation of ideal gas, kJ/mol

TABLE C-13 Solubility of Salt Water

Fonts used:Times & Universal 55 family

TABLE C-14 Solubility of Organic Compounds in Water as a Function of Temperature

Fonts used:Times & Universal 55 family

854 PHYSICAL PROPERTIES OF LIQUIDS AND GASES

log10 H = A + B/T + C log T + DT