Cinetica Reactor

Se desea determinar los parametros cineticos de la reaccin de descomposicin CH 3CHO a
En un reactor tubular (PFR) cuya dimensiones son: diametro= 3,3 cm; longitud= 80 cm.
flujos a la entrada y esperando que se alcancen las condiciones estacionarias, se obtuvieron
datos.
F(g/h)
XA
130
0.05
50
0.13
21
0.24
10.8
0.35
(Edo estacionario)
Determine el orden de reaccin y la constante de velocidad

FA0
XA
PFR
CH3CHO(g)
h
D
h
P
T
Solucin
Ecuacin de diseo para un PFR
/0=
24_0^(_)
_/ _
A.h
====>
V
V
=
=
Datos
=
=
=
=
FA0 =
Di2
CH
3.3
cm
80
cm
1
atm
518
C =
791.15
Flujo molar del reactivo limitante
4
684.24
cm3
( 3,3cm )
4
=
0.68424
Se asume que el CH3CHO es puro, sin contaminantes; por lo tanto

PM
FnA
Fm
====>
Fn
F(mol/h)
=
130 g/h
44
g/mol
Fn
Fm
PM
PM
44
====>
FnA =
2.9545
mol/h
FnA
50 g/h
44
g/mol
====>
FnA =
1.1364
mol/h
FnA
21 g/h
44
g/mol
====>
FnA =
0.4773
mol/h
FnA
10.8 g/h
44
g/mol
====>
FnA =
0.2455
mol/h
F(g/h)
2.9545
1.1364
g/mol
0.4773
Tabla de resultados
XA
0.05
0.13
0.24
posicin CH3CHO a 518C y 1 atn. F

A
ongitud= 80 cm. Cambiando los
rias, se obtuvieron los siguientes
-rA
-rA
Determinacin de K
FAo FAo XA
=
=
=
=
CH4 (g)
n
CA
FA =
FAo
k
VAo
V
YA
====>
k
n
a
-rA
791.15 K
eactivo limitante
80 cm
0.68424
CO(g)
CA
====> FA
1
1
1 ====>
=
=
( 1
orden de la reaccin
FA
V
( 1
XA )
( 1
XA )
n =
moles producto
n =
1
+
1
YA =
1 es puro
a
=
1
=
1
Por lo tanto la ecu
( 1
XA )
( 1
XA )
Asumimos comportamiento de gas ideal y as nos queda
PT
YA0 =
CAo =
1 atm
1
RT
0.081
atm.L
791.15
mol.K
/0= _0^(_) _/ _
Reordenamos
=
CAo
= _0^(_) _/(_0
((1_)/(1+_ )) )
(_(0 ))/0=1/
_0^(_)(1+_ )_/
((1_ ) ) 1 - X
g/mol
FAo
Es un pro
====> XA
dXA
=
=
1-u
-du
====>
_0^(_) (1+_ )_/((1_ ) ) = 24_1^( 1 _)(1+1)/

()=_1^( 1 _)(2)/ =24_1^(1 _) 2/ +
24_1^(1_)/
2 ()+ 8(1_@1)=2 (1_ )+(1_ )+2
(11)1
=2 (1_ )+1 _+2(0)1=2 ( 1_ ) _
(_(0 ))/0=1/
((1_ ) _ )
y
0.4773
0.2455
CA0
FA0
1
k
0.24
0.35
XA
CA0
FA0
en de la reaccin
es producto
Por lo tanto la ecuacin nos queda:
queda
=
0.684239 L
y
x
0.003614 0.009396 0.02237

0.0526
0.1485
0.3089
moles reactantes
=
1
====> CAo
0.015605 mol/L
0.05
0.045
0.04
0.035
0.03
0.025
0.02
0.015
0.01
0.005
0
0.0526
0.1485
No es una reaccin de primer orde
ordenamos
(_(0 ))/0=1/
_0^(_) _/
(((1_)/(1+_ )) )
Asumimos que la reaccin es de 2doorde

-rA =
CA 2
k
====>
Es un proceso isotrmico
====> XA
XA
=
=
1 -XA
0
u
u
=
=
_)(1+1)/
2/ +
1 -XA
1
/0= _0^(_) _/ _ = _0^(_)

((1_)/(1+_ ))^2 )= ( _0 ^2)/_0 =1
_0^(_) ((1+_ )^2 _)/( (1_ )^2 )=
U
si
=
XA
XA
1
=
=
XA
XA
====>
0 ====> U
====> U
_0^(_) ((1+_ )^2 _)/( (1_ )^2 )

=_1^(1_) ((1+1)^2 ())/( ()^2 )=
_1^( 1 _) ((2)^2 )/( ()^2 )= "
-2Ln ( 1 -XA ) - XA
_1^( 1 _) (44+^2 )/( ()^2 )=

_1^( 1 _) ( 4)/()^2 _1^( 1
( ()^2 )+ _1^(1_) (^2 )/( ()^2 )=
4_1^( 1 _) ^(2) 4_1^( 1 _
( 1 _) = (4^(1))/(1)4

(4)/(1_ ) 4(1 _ )1+ _+4+1=
(1_ ) +4
(4)/(1_ ) 4(1 _ )1+ _+4+1=

(1_ ) +4
4(1 _ )+ _ (4+4 _)/(1_ )=4(1
)
1
k
CA0
x
=
-2Ln ( 1 -XA ) - XA
( _0 ^2)/_0 = 1/ (4
__/(1_ ))
0.015605
0.043492
0.5116
CA02
= V
FA0
x
Ln (1 - X
-4
V =
CA0 =
0.6842
0.01560
0.0008
0.0007
0.0006
85
0.3089
0.0005
0.5116
0.0004
n de primer orden
0.0003
0.0002
in es de 2doorden
-rA =
CAo2
( 1
( 1
XA
XA
)
)2
0.0001
0
0.2025415986
= _0^(_) _/( _0 ^2
_0 ^2)/_0 =1/
)/( (1_ )^2 )=
XA
=
=
1
1
1
====>
dXA
dU
y2
x2
0.445629
XA
_)/( (1_ )^2 )

))/( ()^2 )=
)/( ()^2 )= " "
2 )/( ()^2 )=
^2 _1^( 1 _) 4/
^2 )/( ()^2 )= " "
4_1^( 1 _) /+ _1^
)/(1)4 | 8(1_@1)
)1+ _+4+1= 4(1 _ )+ _ 4/
1
m
)1+ _+4+1= 4(1 _ )+ _ 4/
)/(1_ )=4(1_ )+_ _/(1_
)/_0 = 1/ (4 (1_ )+
_ ))
Ln (1 - XA)
XA
1
k
x
0.2025416
0.537623
1.0219579
1.5346701
XA
1 XA
L
mol/L
y
5.6394E-005
0.00014662
0.00034908
0.00067869
986
0.537622982
0.445629
=
y1
x1
1.0219579091
0.000146619
0.000349083
====>
1
=
0.445629
m
2.244017
5.639441E-005
0.0001466185
1
k
1.5346701259
F(mol/h)
XA
2.9545
0.05
1.1364
0.13
0.4773
0.24
0.2455
0.35
3.5
3
2.5
2
F (mol/h)
1.5
1
0.5
0
0.05
0.13
0.24
XA
0.13
0.24
XA
0.35

datos.
F(g/h)
XA
130
0.05
50
0.13
21
0.24
10.8
0.35
(Edo estacionario)

FA0
XA
PFR
CH3CHO(g)
h
D
h
P
T
Solucin
/0=
_0^(_)_
/ _
A.h
====>
V
V
=
=
Datos
=
=
=
=
FA0 =
Di2
CH
3.3
cm
80
cm
1.5
atm
315
C =
588.15
4
684.24
cm3
( 3,3cm )
4
=
0.68424

PM
FnA
Fm
====>
Fn
F(mol/h)
=
130 g/h
44
g/mol
Fn
Fm
PM
PM
44
====>
FnA =
2.9545
mol/h
FnA
50 g/h
44
g/mol
====>
FnA =
1.1364
mol/h
FnA
21 g/h
44
g/mol
====>
FnA =
0.4773
mol/h
FnA
10.8 g/h
44
g/mol
====>
FnA =
0.2455
mol/h
F(g/h)
2.9545
1.1364
g/mol
0.4773
Tabla de resultados
XA
0.05
0.13
0.24

A
-rA
-rA
Determinacin de K
FAo FAo XA
=
=
=
=
CH4 (g)
n
CA
FA =
FAo
k
VAo
V
YA
====>
k
n
a
-rA
588.15 K
eactivo limitante
80 cm
0.68424
CO(g)
CA
====> FA
1
1
1 ====>
=
=
( 1
orden de la reaccin
FA
V
( 1
XA )
( 1
XA )
n =
moles producto
n =
1
+
1
YA =
1 es puro
a
=
1
=
1
Por lo tanto la ecu
( 1
XA )
( 1
XA )
PT
YA0 =
CAo =
1.5
atm
1
RT
0.081
atm.L
588.15
mol.K
/0= _0^(_) _/ _
Reordenamos
=
CAo
= _0^(_) _/(_0
((1_)/(1+_ )) )
(_(0 ))/0=1/
_0^(_)(1+_ )_/
((1_ ) ) 1 - X
g/mol
FAo
Es un pro
====> XA
dXA
=
=
1-u
-du
====>
_0^(_) (1+_ )_/((1_ ) ) = _1^( 1 _)(1+1)/

()=_1^( 1 _)(2)/ =_1^(1 _) 2/ +
_1^(1_)/
2 ()+ 8(1_@1)=2 (1_ )+(1_ )+2
(11)1
=2 (1_ )+1 _+2(0)1=2 ( 1_ ) _
(_(0 ))/0=1/
((1_ ) _ )
y
0.4773
0.2455
CA0
FA0
1
k
0.24
0.35
XA
CA0
FA0
en de la reaccin
es producto
queda
=
0.684239 L
y
x
0.007292 0.018958 0.045137

0.0526
0.1485
0.3089
moles reactantes
=
1
====> CAo
0.031486 mol/L
0.1
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0
0.0526
0.1485
ordenamos
(_(0 ))/0=1/
_0^(_) _/
(((1_)/(1+_ )) )

-rA =
CA 2
k
====>
====> XA
XA
=
=
1 -XA
0
u
u
=
=
_)(1+1)/
2/ +
1 -XA
1
/0= _0^(_) _/ _ = _0^(_)

((1_)/(1+_ ))^2 )= ( _0 ^2)/_0 =1
_0^(_) ((1+_ )^2 _)/( (1_ )^2 )=
U
si
=
XA
XA
1
=
=
XA
XA
====>
0 ====> U
====> U
_0^(_) ((1+_ )^2 _)/( (1_ )^2 )

=_1^(1_) ((1+1)^2 ())/( ()^2 )=
_) ((2)^2 )/( ()^2 )= " "
-2Ln ( 1 -XA ) - XA
_1^( 1 _) (44+^2 )/( ()^2 )=

_1^( 1 _) ( 4)/()^2 _1^( 1 _
( ()^2 )+ _1^(1_) (^2 )/( ()^2 )=
4_1^( 1 _) ^(2) 4_1^( 1 _
_1^( 1 _) = (4^(1))/(1)4

(4)/(1_ ) 4(1 _ )1+ _+4+1=
(1_ ) +4
(4)/(1_ ) 4(1 _ )1+ _+4+1=

(1_ ) +4
4(1 _ )+ _ (4+4 _)/(1_ )=4(1
)
1
k
CA0
-2Ln ( 1 -XA ) - XA
( _0 ^2)/_0 = 1/ (4
__/(1_ ))
0.031486
0.087756
0.5116
CA02
= V
FA0
x
Ln (1 - X
-4
V =
CA0 =
0.6842
0.03149
0.003
0.0025
0.3089
0.002
0.5116
0.0015
n de primer orden
0.001
in es de 2 orden
-rA =
do
CAo2
( 1
( 1
XA
XA
0.0005
)2
)2
0
0.2025415986
= _0^(_) _/( _0 ^2
_0 ^2)/_0 =1/
)/( (1_ )^2 )=
XA
=
=
1
1
1
====>
dXA
dU
y2
x2
0.445629
XA
_)/( (1_ )^2 )

))/( ()^2 )= _1^( 1
""
2 )/( ()^2 )=
2 _1^( 1 _) 4/
^2 )/( ()^2 )= " "
4_1^( 1 _) /+
(1))/(1)4 | 8(1_@1)
)1+ _+4+1= 4(1 _ )+ _ 4/
1
m
)1+ _+4+1= 4(1 _ )+ _ 4/
)/(1_ )=4(1_ )+_ _/(1_
2)/_0 = 1/ (4 (1_ )+
_ ))
Ln (1 - XA)
XA
1
k
x
0.2025416
0.537623
1.0219579
1.5346701
XA
1 XA
L
mol/L
y
0.00022959
0.00059692
0.00142119
0.00276307
986
0.537622982
0.445629
=
y1
x1
1.0219579091
0.000596915
0.001421191
====>
1
=
0.445629
m
2.244017
0.0002295937
0.0005969154
1
k
1.5346701259
F(mol/h)
XA
2.9545
0.05
1.1364
0.13
0.4773
0.24
0.2455
0.35
3.5
3
2.5
2
F (mol/h)
1.5
1
0.5
0
0.05
0.13
0.24
XA
0.13
0.24
XA
0.35

datos.
F(g/h)
XA
130
0.05
50
0.13
21
0.24
10.8
0.35
(Edo estacionario)

FA0
XA
PFR
CH3CHO(g)
h
D
h
P
T
Solucin
/0=
_0^(_)_
/ _
A.h
====>
V
V
=
=
Datos
=
=
=
=
FA0 =
Di2
CH
3.3
cm
80
cm
3
atm
700
C =
973.15
4
684.24
cm3
( 3,3cm )
4
=
0.68424

PM
FnA
Fm
====>
Fn
F(mol/h)
=
130 g/h
44
g/mol
Fn
Fm
PM
PM
44
====>
FnA =
2.9545
mol/h
FnA
50 g/h
44
g/mol
====>
FnA =
1.1364
mol/h
FnA
21 g/h
44
g/mol
====>
FnA =
0.4773
mol/h
FnA
10.8 g/h
44
g/mol
====>
FnA =
0.2455
mol/h
F(g/h)
2.9545
1.1364
g/mol
0.4773
Tabla de resultados
XA
0.05
0.13
0.24

A
-rA
-rA
Determinacin de K
FAo FAo XA
=
=
=
=
CH4 (g)
n
CA
FA =
FAo
k
VAo
V
YA
====>
k
n
a
-rA
973.15 K
eactivo limitante
80 cm
0.68424
CO(g)
CA
====> FA
1
1
1 ====>
=
=
( 1
orden de la reaccin
FA
V
( 1
XA )
( 1
XA )
n =
moles producto
n =
1
+
1
YA =
1 es puro
a
=
1
=
1
Por lo tanto la ecu
( 1
XA )
( 1
XA )
PT
YA0 =
CAo =
3
atm
1
RT
0.081
atm.L
973.15
mol.K
/0= _0^(_) _/ _
Reordenamos
=
CAo
= _0^(_) _/(_0
((1_)/(1+_ )) )
(_(0 ))/0=1/
_0^(_)(1+_ )_/
((1_ ) ) 1 - X
g/mol
FAo
Es un pro
====> XA
dXA
=
=
1-u
-du
====>
_0^(_) (1+_ )_/((1_ ) ) = _1^( 1 _)(1+1)/

()=_1^( 1 _)(2)/ =_1^(1 _) 2/ +
_1^(1_)/
2 ()+ 8(1_@1)=2 (1_ )+(1_ )+2
(11)1
=2 (1_ )+1 _+2(0)1=2 ( 1_ ) _
(_(0 ))/0=1/
((1_ ) _ )
y
0.4773
0.2455
CA0
FA0
1
k
0.24
0.35
XA
CA0
FA0
en de la reaccin
es producto
=
V
0.684239 L
y
x
0.008814 0.022916 0.05456

0.0526
0.1485
0.3089
moles reactantes
=
1
0.12
0.1
0.08
0.06
0.04
0.02
queda
====> CAo
0
0.0526
0.038059 mol/L
0.1485
ordenamos
(_(0 ))/0=1/
_0^(_) _/
(((1_)/(1+_ )) )

-rA =
CA 2
k
====>
====> XA
XA
=
=
1 -XA
0
u
u
=
=
_)(1+1)/
2/ +
1 -XA
1
/0= _0^(_) _/ _ = _0^(_)

((1_)/(1+_ ))^2 )= ( _0 ^2)/_0 =1
_0^(_) ((1+_ )^2 _)/( (1_ )^2 )=
U
si
=
XA
XA
1
=
=
XA
XA
====>
0 ====> U
====> U
_0^(_) ((1+_ )^2 _)/( (1_ )^2 )

=_1^(1_) ((1+1)^2 ())/( ()^2 )=
_) ((2)^2 )/( ()^2 )= " "
-2Ln ( 1 -XA ) - XA
_1^( 1 _) (44+^2 )/( ()^2 )=

_1^( 1 _) ( 4)/()^2 _1^( 1 _
( ()^2 )+ _1^(1_) (^2 )/( ()^2 )=
4_1^( 1 _) ^(2) 4_1^( 1 _
_1^( 1 _) = (4^(1))/(1)4

(4)/(1_ ) 4(1 _ )1+ _+4+1=
(1_ ) +4
(4)/(1_ ) 4(1 _ )1+ _+4+1=

(1_ ) +4
4(1 _ )+ _ (4+4 _)/(1_ )=4(1
)
1
k
CA0
-2Ln ( 1 -XA ) - XA
( _0 ^2)/_0 = 1/ (4
__/(1_ ))
0.038059
0.106075
0.5116
CA02
= V
FA0
x
Ln (1 - X
-4
V =
CA0 =
0.6842
0.03806
0.0045
0.004
0.0035
0.3089
0.003
0.5116
0.0025
n de primer orden
0.002
0.0015
in es de 2 orden
-rA =
do
0.001
2
Ao
( 1
( 1
XA
XA
)
)2
0.0005
0
0.2025415986
= _0^(_) _/( _0 ^2
_0 ^2)/_0 =1/
)/( (1_ )^2 )=
XA
=
=
1
1
1
====>
dXA
dU
y2
x2
0.445629
XA
_)/( (1_ )^2 )

))/( ()^2 )= _1^( 1
""
2 )/( ()^2 )=
2 _1^( 1 _) 4/
^2 )/( ()^2 )= " "
4_1^( 1 _) /+
(1))/(1)4 | 8(1_@1)
)1+ _+4+1= 4(1 _ )+ _ 4/
1
m
)1+ _+4+1= 4(1 _ )+ _ 4/
)/(1_ )=4(1_ )+_ _/(1_
2)/_0 = 1/ (4 (1_ )+
_ ))
Ln (1 - XA)
XA
1
k
x
0.2025416
0.537623
1.0219579
1.5346701
XA
1 XA
L
mol/L
y
0.00033546
0.00087215
0.00207649
0.0040371
986
0.537622982
0.445629
=
y1
x1
1.0219579091
0.000872146
0.002076487
====>
1
=
0.445629
m
2.244017
0.0003354568
0.0008721465
1
k
1.5346701259
F(mol/h)
XA
2.9545
0.05
1.1364
0.13
0.4773
0.24
0.2455
0.35
3.5
3
2.5
2
F (mol/h)
1.5
1
0.5
0
0.05
0.13
0.24
XA
0.13
0.24
XA
0.35

datos.
F(g/h)
XA
130
0.05
50
0.13
21
0.24
10.8
0.35
(Edo estacionario)

FA0
XA
PFR
CH3CHO(g)
h
D
h
P
T
Solucin
/0=
_0^(_)_
/ _
A.h
====>
V
V
=
=
Datos
=
=
=
=
FA0 =
Di2
CH
3.3
cm
80
cm
0.5
atm
300
C =
573.15
4
684.24
cm3
( 3,3cm )
4
=
0.68424

PM
FnA
Fm
====>
Fn
F(mol/h)
=
130 g/h
44
g/mol
Fn
Fm
PM
PM
44
====>
FnA =
2.9545
mol/h
FnA
50 g/h
44
g/mol
====>
FnA =
1.1364
mol/h
FnA
21 g/h
44
g/mol
====>
FnA =
0.4773
mol/h
FnA
10.8 g/h
44
g/mol
====>
FnA =
0.2455
mol/h
F(g/h)
2.9545
1.1364
g/mol
0.4773
Tabla de resultados
XA
0.05
0.13
0.24
posicin CH 3CHO a 518C y 1 atn. F

A
-rA
-rA
Determinacin de K
FAo FAo XA
=
=
=
=
CH4 (g)
n
CA
FA =
FAo
k
VAo
V
YA
====>
k
n
a
-rA
573.15 K
eactivo limitante
80 cm
0.68424
CO(g)
CA
====> FA
1
1
1 ====>
=
=
( 1
orden de la reaccin
FA
V
( 1
XA )
( 1
XA )
n =
moles producto
n =
1
+
1
YA =
1 es puro
a
=
1
=
1
Por lo tanto la ecu
( 1
XA )
( 1
XA )
PT
YA0 =
CAo =
0.5
atm
1
RT
0.081
atm.L
573.15
mol.K
/0= _0^(_) _/ _
Reordenamos
=
CAo
= _0^(_) _/(_0
((1_)/(1+_ )) )
(_(0 ))/0=1/
_0^(_)(1+_ )_/
((1_ ) ) 1 - X
g/mol
FAo
Es un pro
====> XA
dXA
=
=
1-u
-du
====>
_0^(_) (1+_ )_/((1_ ) ) = _1^( 1 _)(1+1)/

()=_1^( 1 _)(2)/ =_1^(1 _) 2/ +
_1^(1_)/
2 ()+ 8(1_@1)=2 (1_ )+(1_ )+2
(11)1
=2 (1_ )+1 _+2(0)1=2 ( 1_ ) _
(_(0 ))/0=1/
((1_ ) _ )
y
0.4773
0.2455
CA0
FA0
1
k
0.24
0.35
XA
CA0
FA0
en de la reaccin
es producto
=
V
0.684239 L
y
x
0.002494 0.006485 0.015439

0.0526
0.1485
0.3089
moles reactantes
=
1
0.035
0.03
0.025
0.02
0.015
0.01
0.005
queda
====> CAo
0
0.0526
0.01077 mol/L
0.1485
ordenamos
(_(0 ))/0=1/
_0^(_) _/
(((1_)/(1+_ )) )

-rA =
CA 2
k
====>
====> XA
XA
=
=
1 -XA
0
u
u
=
=
_)(1+1)/
2/ +
1 -XA
1
/0= _0^(_) _/ _ = _0^(_)

((1_)/(1+_ ))^2 )= ( _0 ^2)/_0 =1
_0^(_) ((1+_ )^2 _)/( (1_ )^2 )=
U
si
=
XA
XA
1
=
=
XA
XA
====>
0 ====> U
====> U
_0^(_) ((1+_ )^2 _)/( (1_ )^2 )

=_1^(1_) ((1+1)^2 ())/( ()^2 )=
_) ((2)^2 )/( ()^2 )= " "
-2Ln ( 1 -XA ) - XA
_1^( 1 _) (44+^2 )/( ()^2 )=

_1^( 1 _) ( 4)/()^2 _1^( 1 _
( ()^2 )+ _1^(1_) (^2 )/( ()^2 )=
4_1^( 1 _) ^(2) 4_1^( 1 _
_1^( 1 _) = (4^(1))/(1)4

(4)/(1_ ) 4(1 _ )1+ _+4+1=
(1_ ) +4
(4)/(1_ ) 4(1 _ )1+ _+4+1=

(1_ ) +4
4(1 _ )+ _ (4+4 _)/(1_ )=4(1
)
1
k
CA0
x
=
-2Ln ( 1 -XA ) - XA
( _0 ^2)/_0 = 1/ (4
__/(1_ ))
0.01077
0.030017
0.5116
CA02
= V
FA0
x
Ln (1 - X
-4
V =
CA0 =
0.6842
0.01077
0.00035
0.0003
0.00025
85
0.3089
0.5116
0.0002
n de primer orden
0.00015
0.0001
in es de 2doorden
-rA =
CAo2
( 1
( 1
XA
XA
0.00005
)2
)2
0
0.2025415986
= _0^(_) _/( _0 ^2
_0 ^2)/_0 =1/
)/( (1_ )^2 )=
XA
=
=
1
1
1
====>
dXA
dU
y2
x2
0.445629
XA
_)/( (1_ )^2 )

))/( ()^2 )= _1^( 1
""
2 )/( ()^2 )=
2 _1^( 1 _) 4/
^2 )/( ()^2 )= " "
4_1^( 1 _) /+
(1))/(1)4 | 8(1_@1)
)1+ _+4+1= 4(1 _ )+ _ 4/
1
m
)1+ _+4+1= 4(1 _ )+ _ 4/
)/(1_ )=4(1_ )+_ _/(1_
2)/_0 = 1/ (4 (1_ )+
_ ))
Ln (1 - XA)
XA
1
k
x
0.2025416
0.537623
1.0219579
1.5346701
XA
1 XA
L
mol/L
y
2.6863E-005
6.9841E-005
0.00016628
0.00032329
5986
0.537622982
0.445629
=
y1
x1
1.0219579091
6.9841E-005
0.000166284
====>
1
=
0.445629
m
2.244017
2.686316E-005
6.984091E-005
1
k
1.5346701259
F(mol/h)
XA
2.9545
0.05
1.1364
0.13
0.4773
0.24
0.2455
0.35
3.5
3
2.5
2
F (mol/h)
1.5
1
0.5
0
0.05
0.13
0.24
XA
0.13
0.24
XA
0.35

Cinetica Reactor

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Cinetica Reactor

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Se desea determinar los parametros cineticos de la reaccin de descomposicin CH 3CHO a

Determine el orden de reaccin y la constante de velocidad

Se asume que el CH3CHO es puro, sin contaminantes; por lo tanto

posicin CH3CHO a 518C y 1 atn. F

_0^(_) (1+_ )_/((1_ ) ) = 24_1^( 1 _)(1+1)/

Por lo tanto la ecuacin nos queda:

0.003614 0.009396 0.02237

No es una reaccin de primer orde

Asumimos que la reaccin es de 2doorde

/0= _0^(_) _/ _ = _0^(_)

_0^(_) ((1+_ )^2 _)/( (1_ )^2 )

_1^( 1 _) (44+^2 )/( ()^2 )=

(4)/(1_ ) 4(1 _ )1+ _+4+1=

_)/( (1_ )^2 )

)1+ _+4+1= 4(1 _ )+ _ 4/

)1+ _+4+1= 4(1 _ )+ _ 4/

)/(1_ )=4(1_ )+_ _/(1_

Se desea determinar los parametros cineticos de la reaccin de descomposicin CH 3CHO a

Determine el orden de reaccin y la constante de velocidad

Se asume que el CH3CHO es puro, sin contaminantes; por lo tanto

posicin CH3CHO a 518C y 1 atn. F

_0^(_) (1+_ )_/((1_ ) ) = _1^( 1 _)(1+1)/

Por lo tanto la ecuacin nos queda:

0.007292 0.018958 0.045137

No es una reaccin de primer orde

Asumimos que la reaccin es de 2doorde

/0= _0^(_) _/ _ = _0^(_)

_0^(_) ((1+_ )^2 _)/( (1_ )^2 )

_1^( 1 _) (44+^2 )/( ()^2 )=

(4)/(1_ ) 4(1 _ )1+ _+4+1=

_)/( (1_ )^2 )

)1+ _+4+1= 4(1 _ )+ _ 4/

)1+ _+4+1= 4(1 _ )+ _ 4/

)/(1_ )=4(1_ )+_ _/(1_

Se desea determinar los parametros cineticos de la reaccin de descomposicin CH 3CHO a

Determine el orden de reaccin y la constante de velocidad

Se asume que el CH3CHO es puro, sin contaminantes; por lo tanto

posicin CH3CHO a 518C y 1 atn. F

_0^(_) (1+_ )_/((1_ ) ) = _1^( 1 _)(1+1)/

0.008814 0.022916 0.05456

Por lo tanto la ecuacin nos queda:

No es una reaccin de primer orde

Asumimos que la reaccin es de 2doorde

/0= _0^(_) _/ _ = _0^(_)

_0^(_) ((1+_ )^2 _)/( (1_ )^2 )

_1^( 1 _) (44+^2 )/( ()^2 )=

(4)/(1_ ) 4(1 _ )1+ _+4+1=

_)/( (1_ )^2 )

)1+ _+4+1= 4(1 _ )+ _ 4/

)1+ _+4+1= 4(1 _ )+ _ 4/

)/(1_ )=4(1_ )+_ _/(1_

Se desea determinar los parametros cineticos de la reaccin de descomposicin CH 3CHO a

Determine el orden de reaccin y la constante de velocidad

Se asume que el CH3CHO es puro, sin contaminantes; por lo tanto

posicin CH 3CHO a 518C y 1 atn. F

_0^(_) (1+_ )_/((1_ ) ) = _1^( 1 _)(1+1)/

0.002494 0.006485 0.015439

Por lo tanto la ecuacin nos queda:

No es una reaccin de primer orde

Asumimos que la reaccin es de 2doorde

/0= _0^(_) _/ _ = _0^(_)

_0^(_) ((1+_ )^2 _)/( (1_ )^2 )

_1^( 1 _) (44+^2 )/( ()^2 )=