Professional Documents
Culture Documents
Class: 6AS4
1) Tan Wai Liang [Leader]
2) Tan Jin Yee
3) Tan Zi Hong
acids
bases
salts
aggressive metal
Most of the metal does not occur in nature in pure form, except
gold, platinum and silver.
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ry.org
blast furnace
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electrolysis
Protective layer
Surface corrosion will forms an oxide layer which will protects the
metal instead of being corroded.
Aluminium
Oxide
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Disadvantages!
Causing tetanus
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Research Question
How does the oxide layer on the surface of the metal affect the rate
of corrosion of metal?
Problem Statement
Objective of research
Limitation of study
The electronic balance is not sensitive enough to measure the small weight
loss of the metal.
The removing process of the corroded metal is not standard due to the
limit of chemical in lab.
Experiment
i.
ii.
iii.
Experiment I
THE EFFECT OF pH ON RATE OF
CORROSION
PROCEDURE
1.
2.
The 5 lead strips are immersed into acetone solution and dry using
a hair drier.
3.
The mass and the area of the 5 lead strips are measured using
electronic balance and meter rule.
4.
The 5 lead strips are immersed into the 5 solution respectively and
the time is recorded.
6.
The 5 lead strips are taken out from the solution on the second days
and the time was recorded
7.
8.
The 5 lead strips are then immersed in acetone solution and dry
using a hair drier.
9.
10.
TABLE
Metal pH
Initial
Weight(g)
Final
Weight(g)
Weight
loss (g)
Initial
time
Final
time
Time
taken
(min)
Rate of
corrosio
n
(mm/y)
Pb
2.0
1.33
1.25
0.08
12:12
11:35
1403
0.264
Pb
6.4
1.28
1.25
0.03
12:12
11:30
1398
0.099
Pb
7.2
1.30
1.27
0.03
12:12
11:25
1393
0.100
Pb
9.7
1.34
1.33
0.01
12:12
11:25
1402
0.033
Pb
11.6
1.33
1.34
-0.01
12:12
11:34
1400
-0.033
Graph
Deduction
Graph 1 show that the rate of corrosion decrease as pH increase. The
increase of weight of lead strips at pH 11.6 show that lead strip started
to form a protective layer on its surface.
EXPERIMENT II
THE RATE OF CORROSION ON
DIFFERENT METAL
Material: lead strip, zinc strip, tin strip, copper strip, aluminum strip
(2cm x 5cm) and 0.01 moldm-3 HNO3 solution
PROCEDURE
1.
The lead strip, zinc strip, tin strip, copper strip and aluminum
strip are cleaned using sandpaper.
2.
The 5 metal strips are immersed into acetone solution and dry
using a hair drier.
3.
The mass and the area of the 5 lead strips are measured using
electronic balance and meter rule.
4.
5.
The 5 metal strips are immersed into the 5 solution respectively and
the time is recorded.
7.
5 metals strip are immersed into different type of solution with different
time.
TYPE OF METALS
TYPE OF SOLUTION
STRIPS
CH3COOH
TIME
lead
0.17
moldm-3
solution
aluminum
2 minutes
copper
2 minutes
tin
10 minutes
5 minutes
0.25
-3
8. zinc strip
The 5 metal strips1.02
are then
immersed
in acetone solution and dry
moldm
HCl solution
minutes
using a hair drier.
9.
The mass of the 5 metal strips are measured using electronic
balance.
10.
TABLE
Metal
pH
Initial
Final
Weight
Weight(g) Weight(g) loss (g)
Initial
time
Final
time
Time
taken
(min)
Rate of
corrosio
n (mm/y)
Pb
2.0
1.55
1.40
0.15
11:50
11:33
2863
0.242
Zn
2.0
1.54
1.52
0.02
11:50
11:36
2866
0.051
Sn
2.0
3.15
3.07
0.08
11:50
11:50
2880
0.201
Cu
2.0
0.80
0.78
0.02
11:50
11:48
2878
0.041
Al
2.0
0.30
0.29
0.01
11:50
11:43
2873
0.067
Graph
Deduction
Graph 2 shows that the rate of
Metal
E value (V)
Al Al3++3e-
+1.66
Zn Zn2+ +2e
+0.76
Sn Sn2++2e
+0.13
Pb Pb2++2e
+0.13
Cu Cu2++2e
-0.34
Deduction
From the table above, it shows that the stability of the metal compare to
metal ion of Cu> Pb> Sn> Zn> Al which is differ from the rate of
corrosion of the metal which shows Cu< Zn< Al< Sn< Pb.
The abnormal behavior of the metal are most probably cause by the
oxidizing of aluminum strip before immersed in the acid and the zinc
strip is not well cleaned due to the absent of corrosion inhibit specimen.
EXPERIMENT III
THE RATE OF CORROSION ON DIFFERENT
METAL WITH OXIDE LAYER
Material: lead strip, zinc strip, tin strip, copper strip, aluminum strip
(2cm x 5cm) and 0.01 moldm-3 HNO3 solution
PROCEDURE
1.
The lead strip, zinc strip, tin strip, copper strip and aluminum
strip are prepared
2.
The 5 metal strips are immersed into acetone solution and dry
using a hair drier.
3.
The mass and the area of the 5 lead strips are measured using
electronic balance and meter rule.
4.
5.
The 5 metal strips are immersed into the 5 solution respectively and
the time is recorded.
7.
5 metals strip are immersed into different type of solution with different
time.
TYPE OF METALS
TYPE OF SOLUTION
STRIPS
CH3COOH
TIME
lead
0.17
moldm-3
solution
aluminum
2 minutes
copper
2 minutes
tin
10 minutes
5 minutes
0.25
-3
zinc
strip
1.02
moldm
HCl
solution
8.
The 5 metal strips are then immersed in acetone solution
minutesand dry
using a hair drier.
9.
The mass of the 5 metal strips are measured using electronic
balance.
10.
Snapchat-2292876068090922376.mp4
TABLE
Metal
pH
Initial
Final
Weight
Initial
Final
Time
Rate of
Weight(g
Weight(g
loss
time
time
taken
corrosi
(g)
(min)
on
(mm/y)
Pb
2.0
1.83
1.77
0.06
12:25
10:42
2777
0.100
Zn
2.0
1.62
1.60
0.02
12:25
10:47
2782
0.052
Sn
2.0
3.00
2.96
0.04
12:25
10:49
2784
0.103
Cu
2.0
0.96
0.94
0.02
12:25
10:38
2773
0.042
Al
2.0
0.30
0.30
12:25
10:50
2785
Graph
Deduction
By referring to the Eh-pH graph, it shows
that the Pb2+ is the predominant species to
occur when Pb is immersed with H2O
solution at pH 2. Thus we can predict that
the lead metal have react with nitric
acid ,HNO3 to form lead(II) nitrate,
Pb(NO3)2 ,nitrogen dioxide, NO2 and
water. The lead(II) nitrate, Pb(NO3)2 will
then dissolve in water to form Pb2+ and
NO3- which is colourless.
3Pb + 8HNO3 3Pb(NO3)2 + 4H2O +
2NO
Pb(NO3)2 Pb2+ + 2NO3Pourbaix Diagram: Eh-pH graph for Lead
Deduction
PbO is not form in this experiment is due to distilled water was used
in this experiment and the diffusion rate of oxygen into water is low.
The low concentration of oxygen causes the formation of PbO
does not happen or not significant to be detected by naked eyes.
Figure
1: Lead
metal
immers
ed in
pH 2
solution
Figure
2:
Corrod
ed
Lead
Deduction
The lead metal strips sample which is immersed
Figure 3:
Lead
metal
immerse
d in pH
6.4
solution
Figure 4:
Lead
metal
immerse
d in pH
7.2
solution
Deduction
While at pH 9.7, due to the higher
Figure
5: Lead
metal
immers
ed in
pH 9.7
solution
or sometime written as
Deduction
Met
al
pH
Initial
Final
Weight Weight
(g)
(g)
Pb
11.
6
1.33
Weight
loss (g)
Initi
al
time
Final
time
Time
take
n
(min
)
Rate of
corrosio
n
(mm/y)
1.34 EFFECT
-0.01
12:12
11:34
1400 -0.033
THE
OF pH ON
RATE
OF
CORROSION
But at pH 11.6 the lead metal does
Figure 6:
Lead metal
immersed
in pH 11.6
solution
Deduction
Figure 7:
Copper
metal
immerse
d in pH 2
solution
Figure 8:
Aluminu Cu + 4HNO3 Cu(NO3)2+2NO+2H2O
blue
yellow
m metal
immerse
d in pH 2 2Al + 6HNO3 2Al(NO3)3 + 3H2
colourless
solution
Deduction
When zinc is immersed in cold and diluted nitric acid, zinc will liberate
nitrogen monoxide, NO, zinc nitrate, Zn(NO3)2 and water. The zinc
nitrate will then dissolve in water to form a colourless solution.
3Zn + 8HNO3 3Zn(NO3)2 + 2NO + 4H2O
Zn(NO3)2 Zn2+ + 2NO3The thin layer of black solid detect in the experiment may due to the
impurities in the zinc metal strips
Figure 9:
Zinc metal
(with
scrubbing)
immersed
in pH 2
solution
Figure 10:
Zinc metal
(without
scrubbing)
immersed
in pH 2
solution
Deduction
When tin (stannum) is immersed in nitric acid, tin will liberate
nitrogen dioxide, NO2, tin nitrate, Sn(NO3)2 and water. The tin
nitrate will then dissolve in water to form a colourless solution. But due
to the yellow nitrogen dioxide, NO2 that form in this reaction, the
nitrogen dioxide that remain dissolved in the solution forming a yellow
solution instead of colourless solution.
Sn + 4HNO3 Sn(NO3)2 + 2NO2 + 2H2O
Sn(NO3)2 Sn2+ + 2NO3Figure 11:
Tin metal
(with
scrubbing)
immersed in
pH 2
solution
Figure 12:
Tin metal
(without
scrubbing)
immersed in
pH 2
solution
Conclusion
The rate of corrosion of the metal under acidic condition of Pb> Sn>
Al> Zn> Cu
The protective layer of aluminum, lead and tin are able to decrease
the rate of corrosion under acidic condition but not zinc and copper.