Professional Documents
Culture Documents
OCA 5, OCA 10, OCA 15, OCA 15 plus, OCA 20, OCA 30, OCAH 200 and OCAH 230
IBM and IBM-PC are registered trademarks of International Business Machine Corporation
Microsoft and Windows are registered trademarks of Microsoft Corporation
DataPhysics Instruments GmbH
Raiffeisenstrae 34
D-70794 Filderstadt
phone ++49 (0)711-770556-0
fax ++49 (0)711-770556-99
email info@dataphysics.de
page 2
D:\Documents\Texte\Manuals\OCA\En\OCA_203_E.doc 30.11.2002
6.3.2.1.6
6.3.2.1.7
6.3.2.2
6.3.3
FG-Setup ........................................................................................19
6.3.3.1
6.3.3.2
6.3.4
6.3.5
6.3.6
6.3.7
6.3.7.1
Content
1
1.1
Preface
Compliance
1.2
Safety warnings
1.3
General description
2.1
2.2
Application
6.3.7.1.1
2.3
6.3.7.1.2
2.4
13
6.3.7.2
6.3.7.3
14
6.3.7.3.1
3.1
General
14
6.3.7.3.2
15
6.3.8
6.4
3.2
19
Installation of OCA
17
6.4.1
Toolbar ...........................................................................................19
4.1.1
6.4.2
4.1.2
6.4.2.1
4.1.3
6.4.2.2
4.1.4
6.4.3
4.1.5
6.4.4
4.1.6
Electrical connection...................................................................19
6.4.5
4.2
PC setup
6.5
Analysis
4.2.1
6.5.1
4.3
Software setup
6.5.2
6.5.3
Statistics Window........................................................................19
19
19
19
Operational instructions
19
5.1
General operations
19
19
19
7.1
19
7.1.1
General...........................................................................................19
7.1.2
7.1.2.1
Preferences............................................................................................. 19
7.1.2.2
Operation ................................................................................................ 19
7.1.3
Automation...................................................................................19
5.2
5.2.1
5.2.2
5.2.3
5.2.4
Measurement
19
7.1.3.1
Settings.................................................................................................... 19
6.1
19
7.1.3.1.1
7.1.3.1.2
7.1.3.1.3
Multimeasurement ............................................................................ 19
7.1.3.1.4
7.1.3.2
Automatic Measurement................................................................. 19
7.2
7.2.1
Installation ....................................................................................19
7.2.1.1
TBA 60M.................................................................................................. 19
7.2.1.2
TBA 60E.................................................................................................... 19
7.2.1.3
7.2.2
7.2.2.1
Preferences............................................................................................. 19
7.2.2.2
Operation ................................................................................................ 19
7.2.2.2.1
7.2.2.2.2
7.2.2.3
7.3
Wafer table
6.2
6.2.1
Tangent Method..........................................................................19
6.2.2
6.3
Preparations
6.3.1
6.3.1.1
6.3.1.2
6.3.1.3
6.3.1.4
6.3.2
Preferences ...................................................................................19
6.3.2.1
Device settings................................................................................... 19
6.3.2.1.1
6.3.2.1.2
6.3.2.1.3
Load/Store settings............................................................................. 19
6.3.2.1.4
6.3.2.1.5
OCA Manual
19
19
19
19
page 3
7.3.1
Installation....................................................................................19
7.6.3
SD-DE..............................................................................................19
7.3.1.1
7.6.4
LIA-MD............................................................................................19
7.3.1.2
WT 200E / 300E.................................................................................... 19
7.6.5
7.3.2
7.6.6
7.3.2.1
Preferences ............................................................................................. 19
7.6.6.1
SP 100........................................................................................................ 19
7.3.2.2
Operation ................................................................................................ 19
7.6.6.2
FSC-80 ...................................................................................................... 19
7.4
7.6.6.3
FSH-30 ...................................................................................................... 19
7.4.1
TFC 100...........................................................................................19
7.4.2
SHD .................................................................................................19
Maintenance
19
7.4.3
8.1
General
19
7.4.4
TEC 400..........................................................................................19
8.2
19
7.4.5
8.3
19
7.4.6
Software-control .........................................................................19
7.4.7
NHD 400........................................................................................19
Technical data
19
7.4.7.1
Software control................................................................................... 19
7.5
10
Terms of Guarantee
19
7.5.1
11
Appendix
19
7.5.2
Software Settings........................................................................19
11.1
19
7.6
Special devices
11.2
Spare parts
19
7.6.1
SD-D................................................................................................19
7.6.2
SD-DM............................................................................................19
11.3
Declaration of conformity
19
page 4
19
19
19
OCA
1 Preface
This manual is valid for all optical contact-measuring devices of the series OCA. Therefore,
you can find chapters in this manual, which are only valid for some instruments of the
OCA series. This chapters are marked with the respective name of the instrument (for
example see chapter 4.1.5 Installation of the goniometric eyepiece (OCA 5/10) page 19).
This manual contains important advises for use of the OCA. Therefore, it must always
stick with the unit, especially if you give it to a third party!
1.1 Compliance
Products tested and found to comply with the requirements defined in the EMC
standards defined by 89/336/EEC as well as Low Voltage Directive (LVD) 73/23/EEC
identified by the CE label on the side of the unit.
For any additional information refer to the Letter of Compliance that shipped with the
unit (Declaration of Conformity).
Never operate the unit for any purpose other than described in the operating manual.
Do not use any accessories other than those supplied or approved by DataPhysics.
Ensure that all operators are fully trained in the correct use of this unit and have
understood all safety precautions.
Connect the power supply of the OCA to a socket with protective plug reception only!
Use a three-wire power cord. No other way of protective grounding is permitted!
You must never open the casing of the power supply. The power supply can only be
exchanged complete.
The measuring results do not only depend upon the correct use and functioning of
the unit, but may also be influenced by other factors. It is advised therefore, that the
measuring results are plausibility tested before consequential actions are taken.
OCA Manual
page 5
In addition to the warnings listed above, warnings are posted throughout the manual.
These warnings are designated by a STOP sign and with text highlighted in bold. It points
out a hazard and calls attention to a procedure, practice, or the like, which, if not correctly
performed or adhered to, could result in damage of the unit, injury or loss of life. Do not
proceed beyond a WARNING sign until indicated conditions are fully understood and met.
The HINT sign points out a remark. It calls attention to any additional information, which
might be useful for the operator.
page 6
OCA
2 General description
2.1 About this manual
This manual describes the operating of the optical contact angle measuring device of the
DataPhysics OCA Series.
Make sure you read and understand all instructions and safety precautions listed in this
operating manual before installing or operating your unit. The installation should be
carried out in the same order as described in this manual. If you have any question concerning the operation of your unit or the information in this manual, contact your sales
partner for assistance.
2.2 Application
The optical contact angle measuring devices OCA are used in research and development,
quality control and product control.
Some important applications for measuring contact angle and interfacial tension with
the OCA are:
the development of cosmetic and pharmaceutical products, e.g. pastes and creams or
powder coatings,
OCA Manual
page 7
(max. 4) and the single or multiple (max. 4) needle support with vertical and
horizontal fine adjustment. The dosing needles are connected to the syringes over a
dosing tube
Dosing bay for installation of up to four manual syringe units and of a single dosing
system SD, a single dosing system direct SD-D or a multiple dosing system MD (max.
6) for the fastening of dosing needles with vertical and horizontal fine adjustment.
The dosing needles are connected to the syringes DS over a dosing tube DT
Measuring stage, adjustable in three axis (X, Y, Z) for accurate sample positioning
All OCA devices are available in a L-version (e.g. OCA 20L) for bigger sample sizes and can
be upgraded to an other one (e.g. upgrade from OCA 10 to OCA 20 by UpOCA 10/20).
OCA 5
Special features of the OCA 5:
Up to four manual syringe units or alternatively one direct dosing unit with one
manual syringe unit
The calculation of the surface free energy of solids and their components out of the
manual measured contact angles with up to four different test liquids
tension), Owens-Wendt (dispersion & polar force contributions), van Oss & Good
page 8
OCA
OCA 10
Special features of the OCA 10:
Up to four manual syringe units or alternatively one direct dosing unit with one
manual syringe unit
Integrated temperature measurement and display in the range from -40 to 400C
The calculation of the surface free energy of solids and their components out of the
manual measured contact angles with up to four different test liquids
tension), Owens-Wendt (dispersion & polar force contributions), van Oss & Good
(EOS)
OCA 15 plus
Special features of the OCA 15:
CCD video camera with a resolution of 752 x 582 pixel and up to 50 images per second
Up to four manual dosing units or alternatively one direct dosing unit with one
manual (MS) or electronic syringe unit (ES/2-D)
The optional electronic syringe unit ES/2 can be mounted in the socket No 1-4
Static and dynamic contact angle measurement according to the Sessile and Captive
Drop method
Calculation of the surface and interfacial tension from the contours of pendant and
sessile drops as well as of liquid lamellas on plates, rods and threads
Calculation of the surface free energy of solids and their components (e.g. dispersion,
polar and hydrogen bond force contribution, acid and base portions respectively)
according to the theories of Wu, Zisman, Owens-Wendt, Extended Fowkes, Schultz 1 +
2, Fowkes and van Oss & Good
OCA Manual
page 9
OCA 20
Special features of the OCA 20:
CCD video camera with a resolution of 768 x 576 pixel and up to 50 images per second
Integrated temperature measurement and display in the range from -40 to 400C
Up to four manual and/or electronic (motor driven and software controlled) dosing
units with a manual or electronic multiple dosing system or alternatively one direct
dosing unit with one manual or electronic syringe unit
Micro-controller module for control of the electronic syringe units (ES), the electronic
multiple dosing system (E-MD), the electrically driven sample stages (TBA 60E,
TBU 90E and WT 200/300E), as well as the temperature controller (TC 150 or TC 400)
Control of the electronic syringe modules, the tilting base assemblies, wafer stages
and temperature controlled devices
Static and dynamic contact angle measurement according to the Sessile and Captive
Drop method
Calculation of the surface and interfacial tension from the contours of pendant and
sessile drops as well as of liquid lamellas on plates, rods and threads
Calculation of the surface free energy of solids and their components (e.g. dispersion,
polar and hydrogen bond force contribution, acid and base portions respectively)
according to the theories of Wu, Zisman, Owens-Wendt, Extended Fowkes, Schultz 1 +
2, Fowkes and van Oss & Good
OCA 30
Special features of the OCA 30:
CCD video camera with a resolution of 768 x 576 pixel and up to 50 images per second
Integrated temperature measurement and display in the range from -40 to 400C
Up to four manual and/or electronic (motor driven and software controlled) dosing
units with a manual or electronic multiple dosing system or alternatively one direct
dosing unit with one manual or electronic syringe unit
Micro-controller module for control of the motorized measuring stage, the electronic
syringe units (ES), the electronic multiple dosing system (E-MD), the electrically driven
sample stages (TBA 60E, TBU 90E and WT 200/300E), as well as the temperature
Control of the motorized measuring stage, the electronic syringe modules, the tilting
base assemblies, wafer stages and temperature controlled devices
Static and dynamic contact angle measurement according to the Sessile and Captive
Drop method
page 10
OCA
Calculation of the surface and interfacial tension from the contours of pendant and
sessile drops as well as of liquid lamellas on plates, rods and threads
Calculation of the surface free energy of solids and their components (e.g. dispersion,
polar and hydrogen bond force contribution, acid and base portions respectively)
according to the theories of Wu, Zisman, Owens-Wendt, Extended Fowkes, Schultz 1 +
2, Fowkes and van Oss & Good
OCAH 200
High-speed contact angle measuring device for the determination of fast sorption and
spreading with up to 360 images per second. Particularly to measure fast adsorption and
absorption processes on paper, textiles, membranes, filter cloth and porous solids.
Special features of the OCAH 200:
High-speed video system with CCD video camera with a resolution of 752 x 484 pixel
and up to 360 images per second
Integrated temperature measurement und display in the range from -40 to 400 C
Up to four manual and/or electronic (motor driven and software controlled) dosing
units with a manual or electronic multiple dosing system or alternatively one direct
dosing unit with one manual or electronic syringe unit
Micro-controller module for control of the electronic syringe units (ES), the electronic
multiple dosing system (E-MD), the electrically driven sample stages (TBA 60E and WT
200/300E), as well as the temperature controller (TC 150 or TC 400)
Control of the electronic syringe modules, the tilting base assemblies, wafer stages
and temperature controlled devices
Static and dynamic contact angle measurement according to the Sessile and Captive
Drop method
Calculation of the surface and interfacial tension from the contours of pendant and
sessile drops as well as of liquid lamellas on plates, rods and threads
Calculation of the surface free energy of solids and their components (e.g. dispersion,
polar and hydrogen bond force contribution, acid and base portions respectively)
according to the theories of Wu, Zisman, Owens-Wendt, Extended Fowkes, Schultz 1 +
2, Fowkes and van Oss & Good
OCA Manual
page 11
OCAH 230
High-speed contact angle measuring device for the determination of fast sorption and
spreading with up to 360 images per second. Particularly to measure fast adsorption and
absorption processes on paper, textiles, membranes, filter cloth and porous solids.
Special features of the OCAH 230:
High-speed video system with CCD video camera with a resolution of 752 x 484 pixel
and up to 360 images per second
Integrated temperature measurement und display in the range from -40 to 400 C
Up to four manual and/or electronic (motor driven and software controlled) dosing
units with a manual or electronic multiple dosing system or alternatively one direct
Micro-controller module for control of the electronic syringe units (ES), the electronic
multiple dosing system (E-MD), the electrically driven sample stages (TBA 60E and WT
200/300E), as well as the temperature controller (TC 150 or TC 400)
Control of the motorized measuring stage, the electronic syringe modules, the tilting
base assemblies, wafer stages and temperature controlled devices
Static and dynamic contact angle measurement according to the Sessile and Captive
Drop method
Calculation of the surface and interfacial tension from the contours of pendant and
sessile drops as well as of liquid lamellas on plates, rods and threads
Calculation of the surface free energy of solids and their components (e.g. dispersion,
polar and hydrogen bond force contribution, acid and base portions respectively)
according to the theories of Wu, Zisman, Owens-Wendt, Extended Fowkes, Schultz 1 +
2, Fowkes and van Oss & Good
page 12
OCA
OCA Manual
page 13
3.1 General
Please open all packages on the desired openings. Avoid all damages to the packing
material.
Keep the packing material for a later sending. The OCA is best protected in the original
packing!
Find yourself a comfortable working place where you want to set up your OCA system
with its peripheral equipment. There should be sufficient room to set up the base unit,
the substances to be measured and the peripheral equipment (e.g. printer, computer and
refrigerated and heating circulator).
For the connection of the OCA power supply to the mains, you need an grounded mains
socket with corresponding fuse protection (see technical data). You do require some
additional sockets for the connection of the peripheral equipment.
Your working environment and the place where you store your OCA should not be
extremely hot, extremely cold (see chapter 9 Technical data page 19), extremely damp or
extremely bright.
Also, avoid places in which the temperature and the atmospheric moisture greatly
fluctuate.
Because the OCA measures the shape of small droplets by a high magnifying zoom lens
avoid places with vibrations (watch out for vibrations because of steps, close of doors ).
Furthermore, make sure that the OCA electronics is not exposed to
objects which emit great heat (e.g. radiators), except the DataPhysics Temperature
controlled chambers
The instrument must be warm before you install and operate it (if it comes out of a cold
room watch out for condensed water).
page 14
OCA
the basic module with linear stage, the high-performance 6x par focal zoom lens with
integrated continuous fine focus, the goniometric eyepiece (OCA 5/10) or the CCD
video camera (OCA 15+/20/30 and OCAH 200/230)
the dosing bay for installation of syringe units and needle support or the electronic
multiple dosing system (E-MD)
an high performance video digitizing board for the PC (not OCA 5/10)
a bubble level
this manual
optical standards for contact angle, drop shape and lamella method
temperature controlled chambers from -10 400 C (liquid, peltier or electrically controlled)
OCA Manual
page 15
To run the software SCA 10 (for OCA 5/10) your PC must be able to run Windows NT 4.0,
Windows 2000 or Windows XP without failure. The following specifications are our
recommendation for comfortable work with the SCA 10 (minimum requirements in
brackets):
To run the software SCA 20 your PC must be able to run Windows NT 4.0, Windows 2000
or Windows XP without failure. The following specifications are our recommendation for
comfortable work with the SCA 20 (minimum requirements in brackets):
MS-WINDOWS NT 4.0 with Service Pack 5/6, Windows 2000 with Service Pack 2/3 or
Windows XP; for OCAH systems: Windows NT 4.0 with Service Pack 5/6 or Windows
2000 with Service Pack 2/3
ATI Graphic Adapter XPERT/XPERT 128/XPERT 2000 with a 3D Rage Pro/ Rage 128/
Rage 128 Pro (GL) chip-set (without TV-Out) and on-board memory of 4 Mbyte or
more (not necessary OCAH systems)
page 16
OCA
4 Installation of OCA
17 color monitor with 1280 x 1024 Pixel resolution or higher (18" or above
recommended)
A
D
about two turns. Level the base unit along the optical axis by use of the right back foot.
Now level it diagonally to the optical axis by use of the left front foot. Finally turn down
the right front foot until it touches the base.
guidance (C). Adjust the position of the dosing bay so that the hinges are congruent with
the base. Only if you use the wafer stage WT you adjust the hinges congruent with the
guiding mark. With the lever (E) you can loosen the complete dosing bay (useful when
Single dosing unit (11) To install the SD onto the dosing bay open the upper setscrew in
the dosing bay (A). Push the axis of the single dosing unit into the dosing bay. Put on the
washer and tighten it by means of the knurled thumbscrew.
Multiple dosing unit (12) The multiple dosing unit will be delivered mounted with the
dosing bay. It should never be dismounted from the dosing bay.
Direct dosing unit (SD-D or SD-DM) (9) To install onto the dosing bay push it over the
dosing bay. Put on the washer and tighten it by means of the knurled thumbscrew. (see
Figure 12).
OCA Manual
page 17
Electronic multiple dosing unit (E-MD/4-6) (13) The E-MD is dismounted in delivery
state. To install the E-MD open the two hinges, loosen the two sliding blocks on each
side by means of the hex screws (wrench size 3) and place it over the guidance. Adjust
the position of the dosing bay so that the hinges are congruent with the base. With
the lever, you can loosen the complete E-MD to tilt it over 90 (useful when changing
large samples to protect the installed needles).
The E-MD is controlled and supplied with power over the 15-pin Sub-D connector.
Connect the Sub-D connector to socket 6 on the bottom of the illumination unit.
Direct dosing unit for E-MD (SD-DE) (10) The SD-DE is dismounted in delivery state. It is
Figure 13: Installation of the electronic multiple
designed to be mounted on top of the E-MD. To get the needle on the SD-DE in focus
Adjusting the E-MD: Tilt the E-MD about 90 and loosen the hex screws (wrench
size 3) of the sliding blocks just about one turn. Take care, not to take the screws out
of the sliding blocks, or the E-MD can fall down. Move the E-MD to the mark on the
base plate (about 30 mm). Align the E-MD in this position and tight the hex screws.
Re-tilt the E-MD back to position 0.
Installation of the SD-DE: Guide the mounting-bush of the SDDE over the holding cup
of the E-MD and tight the knurled screw (A).
Tilting base assembly TBA 60M and TBA 60E (23, 24)
Some of these have knurled nuts to fix, in this case please remove the two knurled
screws.
page 18
OCA
Screw it onto the dosing bay with the both hex screws (wrench size 2.5)
The manual syringe unit is designed to be used with the standard (not gas tight) 1000 l
dosing syringe DS 1000 or with the precision, gas tight 500 or 1000 l dosing syringe DS
500GT or DS 1000GT and with the 300 mm long dosing tube DT 300/xx.
Electronic Syringe unit (ES) (15) On both sides of the OCA (not OCA 5) you can mount
two syringe units. The software SCA 20 controls the electronic syringe units by their
number, defined by their position on the OCA (the positions are labeled with their
numbers 1 - 4). The electronic syringe units were controlled and supplied with power over
the 15-pin Sub-D connector.
Position the electronic syringe unit onto the two (A, B) bolts (the upper one is
installed on the OCA, the lower one on the syringe unit) and press carefully on it (the
15-pin Sub-D connector on the OCA is a little bit adjustable)
Fix the two bolts by means of two set screws (wrench size 2.0)
The electronic syringe unit is designed to be used with the precision, gas tight 500 or
1000 l dosing syringe DS 500GT or DS 1000GT and with the 300 mm long dosing tube
DT 300/xx for the ones in position 1 and 4, and the 400 mm long DT 400/xx for position
2 and 3.
With the OCA 15 the electronic syringe unit can only be used with the single direct dosing
system (SD-D) with the delivered cable to the socket F on the bottom of the illumination
unit. With the OCA 15 plus it can be used additionally with the socket 1-4 and without the
SD-D.
install onto the lens mount open the upper knurled thumbscrew (A), guide it into the
hole in the lens mount and fix it with the screw.
OCA Manual
page 19
S-Video
Composite Video 1
Composite Video 0
Plug the video cable from the frame grabber board in the computer to the Video OUT
Socket on the OCA (BNC-Connector). With the standard frame grabber use the delivered
adapter (BNC to Cinch) and connect the video cable to the Composite Video 0.
The serial cable leads from the Serial PC socket on the OCA to any free serial port on the
computer.
If you have a (optional) Pt 100 connect the plug to the T1 or T2 socket.
The standard electronic syringe units ES do not need an extra cabling, because they plug
directly onto the OCA. Only the ES mounted on the direct dosing unit (SD-D or SD-DE)
cable.
4.2 PC setup
Information for the setup of your computer system and Windows you can take out of the
enclosed documentation.
The PC must be compliant to the EN60950.
To install the high-speed frame grabber board in your PC you need a empty, full-length
32-bit PCI slot, for the standard frame grabber board a half-long slot is enough.
page 20
OCA
Your PCI system BIOS must be compatible with the PCI 2.1 specification and be able to
ISA
recognize a PCI-to-PCI bridge configuration and initialize the VGA display controller
PCI
residing on the other side of the PCI bridge. For example, BIOS software based on the
Phoenix reference BIOS software (v4.05 or later), or based on the AMI BIOS software
(v10.10.94 or later), should support PCI-to-PCI bridge. The high-speed frame grabber board
AGP
includes a SVGA graphic board, so if you have any graphic board installed in your PC you
must remove it, or if it is onboard you must deactivate it (to do this see the manual of
your PC). With the standard frame grabber, you need an additional graphic board. Which
boards or VGA chips are tested is described in the inlay of the CD-ROM, as well as in the
README.TXT.
The parallel operation of a graphic board and the high-speed frame grabber
board is not possible.
Ensure that the relative humidity of your work area is at least 50%
Remove the power cable and other connection cables from the computer
Before you install the high-speed frame grabber board, ensure that the DIP switches
are set to default (single screen configuration SW1=OFF and SW2=OFF) as shown
beside
Insert the frame grabber board into an empty, full-length PCI slot and screw the
bracket tight.
DIP switch
Some computers have a large, black-ridged heat sink that prevents long
boards from using most PCI board slots. High-speed frame grabber must not
touch this heat sink.
OCA Manual
page 21
Now the connection cables and the power cable can be re-plugged into the computer
Plug the 15-pin connector of the monitor to the high-speed frame grabber board
page 22
OCA
5 Operational instructions
In the following chapters, you learn how to prepare and how to perform a standard test.
The result of a test is always a function of the history of the sample, the condition of the
measuring unit and the way you measure. In surface chemistry, it is also a function of
cleanliness and liquid handling.
Most contact angle measurements are not a single test but a complex series of tests.
The first point seams to be obvious but a precise definition of the problem or the terms
relieves the single-mindedly actions by the practical realization of an experiment.
Preparation of the sample The preparation of the sample (solid surface or liquid) is
decisively important for the measuring results. Therefore, be sure to treat the samples
always the same way, unless you want to measure the difference of different sample
treatments.
If the results of the test should be comparable, it is necessary to prepare the
sample (solid) always the same way.
Preparation of the test liquids The selection of the test liquids arise from the measuring
job (e.g. detection of the parts of the surface free energy according to OWRK) as well as
according to the tolerability to the sample. It must be noticed (or be tested) that the used
solvents neither react with the solid nor etch it or are absorbed.
Toxic and inflammable liquids must only be used in a fume cupboard! Be sure
to watch always the maximum working place concentration (MAK) of the
used chemical as well as the attached security datasheets! On questions
about the handling of chemicals turn to the manufacturer or supplier.
Great care and cleanliness must be taken in filling the syringes with the liquids, especially
if surface-active substances (e.g. surfactants) will be used. Smallest pollution can reduce
the surface tension of liquids, especially of water.
Note, that there exist substances, which can hardly be removed from a solid
surface (e.g. silicone oil), and smallest contamination with surfactants will
reduce the surface tension of the liquid (esp. Water).
OCA Manual
page 23
Setup of the measuring device The setup of the measuring device is also important for
good and reproducible results. Have a look to the following points:
Do you use the right sample stage adapter (tilting stage, wafer stage or temperature
control)
Is the inner diameter of the dosing tube and dosing needle adapted to the viscosity of
the liquid (see chapter 11.2 Spare parts page 19).
Is the outer diameter of the dosing needle adapted to the liquid on pendant drop
method
Positioning of the sample and of the dosing needle according to the field of view
Adjusting of zoom and inner fine focus according to magnification and working distance
Take great care to avoid air bubbles in the complete dosing system (syringe tube
needle).
page 24
OCA
Z-Position
Y-Position
X-Position
Adjustment in x-direction The x-direction corresponds with the optical axis (the look
through the lens). You can adjust the x-position of the sample stage by turning the hand
wheel at the front edge of the base unit.
Adjustment in y-direction The y-direction is horizontally right-angled to the optical axis
(x-direction). You adjust the y-position of the sample stage by turning the hand wheel at
the side of the base unit.
Adjustment in z-direction The z-direction is vertically right-angled to the optical axis (xdirection). You adjust the z-position of the sample stage by turning the hand wheel above
the wheel for the y-direction. Opposite of the hand wheel is a fixing screw, with which
you can fix the z-position of the stage. This avoids self-movement caused by heavy
weight of the sample.
OCA Manual
page 25
the optical axis by means of two fine adjustment screws. A movement of the needle
holder in x-direction (optical axis) is not possible.
The needle holder has a quick movement knob for a very quick adjustment in vertical (C)
direction (the direct dosing unit has no quick movement knob). It is used e.g. together
with a temperature control to adjust the measuring position exactly with the fine adjustment screws and then to allow a quick move out of the temperature control and quick
back in.
The positioning of the needles with the electronic multiple dosing unit E-MD is software
Tilting of lens To determine the contact angle on a solid surface you need to see the reflection of the drop on the surface. A visible reflection is necessary for the software
SCA 20 to detect the base line and then to calculate the contact angle. To obtain a reflection, you tilt the zoom lens with the horizontal wheel (C) so you see the drop on the surface under an angle.
The observation angle should be as small as possible, but as big as necessary.
C
Figure 25: Controls of the zoom lens
The visible contact angle will be distorted, if you use a too big observation
angle.
Adjust of magnification The magnification of the image could be adjusted directly at
the zoom lens (A). The magnification should be adjusted so that the drop fills up to 2/3 of
the field of view.
Adjust the focus With the built-in fine focus (B) it is very easily to adjust the working
distance. Turn the fine focus until the image is sharp
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OCA
6 Measurement
Before you start to measure, some preparations should be done. You have to
place the sample to the stage (or TBA or WT) or into the temperature controlled
chamber (only for sessile drop method)
fill all necessary syringes with test liquids and insert them into the syringe unit
All the procedures that are independent from the measuring methods are described in
this chapter. The method dependent procedures are described in particular chapters.
Fill syringe If you use the manual syringe units MS for dosing you can put the delivered
spring over the piston (to suck liquid back to measure receding contact angles) before you
fill the syringe. Fill the syringe with the test liquid and connect the dosing tube and the
required dosing needle. The dosing tube and needle must be also filled with the liquid.
E
D
B
A
Take great care to avoid air bubbles in the complete dosing system
(syringetubeneedle).
Insert syringe Insert the syringe into the syringe unit.
Using the manual syringe unit MS you open the micrometer screw and push the syringe
carefully into the holder. Turn the micrometer screw of the dosing unit until the piston of
the syringe gets into contact with it and a liquid drop issues from the dosing needle.
OCA Manual
page 27
Using the electronic syringe units proceed as follows (only possible if software is not yet
started or is in manual control mode):
If software is started enter the manual control mode with a click on the icon
. The
push the syringe carefully into the holder (D)and fix it with the knurled screw (E)
move the piston up by means of the up switch (B) until the piston of the syringe gets
into contact with it and a liquid drop issues from the dosing needle.
Position the sample and the dosing needle Adjust the magnification to the lowest value
to see a bigger part of the image (easier to find the needle). Lift the stage up until the
surface of the sample (substrate line) is visible in the lower quarter of the image on the
screen or in the eyepiece. Bring the needle into the middle of the image. Lower the syringe
holder and adjust the desired distance between needle and surface (depending on the
drop size and if you measure equilibrium or dynamic contact angles). Now adjust the
magnification to see a good and big enough image. The needle should be visible as a
Figure 28: Piston Holder of ES
reference size). If necessary, adjust the needle and the stage again.
Take care to avoid contact between the solid surface and the dosing needle.
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OCA
Place sample on stage Before placing a sample onto the stage lower the stage and lift
up the needle holder (by means of the quick movement) or tilt the dosing unit 90. If you
want to measure, contact angles under air place the sample (solid surface) directly onto
the sample stage. If you use the tilting table, you must fix the sample (for example with a
tape).
Liquid dispensing If you use a manually syringe unit dispense a drop by turning the
micrometer screw. Place the drop onto the sample by moving up the sample stage. Then
lower the sample stage again until the substrate line is congruent with the base line in
the goniometric eyepiece.
Base line adjustment If the substrate line is not parallel to the base line of the eyepiece,
you must adjust the base line:
Drop image adjustment To get good results it is important to adjust the image of the
drop in the eyepiece:
Adjust the zoom lens to lowest magnification to get the maximum field of view
Lower the dosing needle and move their end into the center of the field of view (see
chapter 5.2.2 Positioning of the dosing needle page 19), move it up so you can just see the
end of the needle in the upper field of view
Adjust the focus of the zoom lens until you see the needle and the drop shape sharp
Adjust the tilting of the zoom lens, the X-position of the sample stage and the illumination until you see a substrate line and the reflection of the drop on the solid
surface
Focus the base and the cursor line in the eyepiece with the diopter control ring (C) so
that you see both lines and the drop with its substrate line sharp
Adjust the magnification of the zoom lens so that the drop fills about 2/3 of the field
of view
OCA Manual
page 29
angle = 45.8
60
70
80
90
100
110
50
cursor line
40
13
0
goniometric eyepiece.
30
0
15
drop
170
180
substrate line
10
20
160
base line
reflection
170
160
20
10
15
0
30
14
0
40
0
13
0
12
50
110
100
90
80
70
60
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OCA
To measure reproducible static contact angles you must work very conscientious. Influence parameters are
time
dosing rate
temperature
drop size
volume
drop environment
density
evaporation
gravitation
Method
Information
Min. No. of
Application
Examples
non-polar solids
Fluids
Zisman
Fowkes
non-polar systems
OWRK (Owens-
universal
polymers, aluminum,
Wendt-Rabel and
coatings, varnishes
Kaelble)
Extended Fowkes
Mean)
Acid-Base Theory
specific questions of
surface properties
polymers
organic solutions,
systems
polymers, organic
specific questions of
biological system
pigments
3
surface properties
1
universal
theory
coatings, varnishes
Schultz 1 (Polar
Drop Phase)
Schultz 2 (Polar
Bulk Phase)
OCA Manual
polymers, aluminum,
high energetic
metal, glass
system
2
high energetic
polymers, aluminum,
system
coatings, varnishes
page 31
With the Browse... button you can select the liquid database.
Select the liquid you measured the contact angle in the combo-box Liquid or type in the
parameters of the surface tension and their components (if not found in the liquid database). Now you must enter the measured contact angle manually.
The choice of liquids depends on the selected analysis method. Only if all the
necessary parameters for the analysis method are available the liquid is
available in the combo-box Liquid. Also only these liquids can be transferred
with all necessary parameters from the result-window.
With the + button you add the liquid with his SFT (and its components) and the contact angle to the liquid list. If you have entered enough (but not more than 4) liquids
(see table above) you can calculate the surface free energy (and its components) by a
click on the Calculate-button. After the calculation is ready, you get the surface free
energy and a corresponding graph.
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OCA
6.3 Preparations
This chapter describes how to perform a measurement with the software SCA for all the
video-based contact angle measuring devices (not OCA 5/10).
Before you can work with the SCA software, the following setups must be already done:
DAO Setup
All necessary programs and drivers are on the delivered CD-ROM. For a complete setup,
please see the README-file on the CD-ROM.
The SCA20 software recognizes all electronic components and modules like ES, TBA 60E,
WT 200E, stage control and TEC/TPC. For this manual, we assume a standard OCA 20
with three ES, an E-MD and a temperature sensor PT 100 on T1. The other components
will be explained in separate chapters. The specific features for high-speed measurement
with the OCAH 150/200/230 will be explained in chapter 9.3.
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In the following, all the menu items, which are activated when the Drop Window is active,
will be explained.
The File menu subdivide into the following items (see Figure 33):
Open... To open a stored file in a new window depending one the file extension you
selected
Save As... Stores the data in active window under a new name
Save As... - Stores the active movie file under a new name (besides
the standard format *.flm you can select the *.avi format)
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Cut Cuts the marked data and copies them into the clipboard
TC-Program... Open the edit control for the TC control program (s page 19)
ARCA settings Open the edit control for automatic dosing to measure Advancing
and Receding Contact Angle
For the following controllable modules, a reference run can be executed in the menu
OCA/PCA Maintenance (see Figure 37):
Sub-menu Preferences:
Device settings - Device settings and parameters (see chapter 6.3.2.1 Device
Zoom Zoom of the drop window up to 1:4; depending on the used frame grabber
not all active
Clear Overlay Erases all overlays and contour lines in the drop window
Drop Window Always On Top The drop window will stay on top of all windows, so
it is always visible
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Get Image Dimension Determines the size of the droplet (not yet implemented)
Kill Fitting Stops and deletes the calculated contour i.e. after Y-L.
Ellipse Fitting Calculation of the contact angle using the ellipse fitting
Circle Fitting - Calculation of the contact angle using the circle fitting (also known
as Height/Width method)
Tangent Searching - Calculation of the contact angle using by fitting the tangent
line in the three phase point on both sides of the drop image
LogFiles Displays the error.log, which is usefully in any irregular behavior of the
SCA (only available if started as SCA 20 Service)
Reset Drop Timer To set the drop age of the actual image to zero
E-MD dosing position - Opens the dialog with the E-MD controls
YZTable - Opens the dialog YZ-Table with the controls for the motorized sample stage
(only with OCA 30/OCAH 230)
Tilting Base Device - Opens the dialog with the tilting base controls device (TBA 60E or
TBU 90E)
Wafer Table - Opens the dialog with the controls of the wafer table
Temp. Controller I-IV - Opens the dialog with the controls for the temperature
controlled units 1-4 (i.e. TEC 400)
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Arrange Icons - Arrange all minimized icon bars and windows on the
lower left side
1-10 To select one of the open windows (the actual active is marked)
Context menu of the Drop Window (click on the right mouse button):
Open... To open a stored file in a new window depending one the file extension you
selected
Save As... Stores the data in active window under a new name
Show Result On Image Shows the result of the calculation in the drop image
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In the following, all the menu items of the Result Collection Window, which are
additional or different to the ones of the Drop Window, will be explained:
Transfer Result to Active SE-Window Transfers the marked result into the active
SE-Window
Delete Deletes all the marked data (note that there is no Undo function available)
Define as Active Result Window Defines the actual result window as active. (the
results of the active drop window will be transferred to this result window)
Result Drop Window Always On Top The Result Window will stay on top of all
windows, so it is always visible
Cursors Displays cursor lines in the active drop window (base line, line for select the
calibration range)
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Context menu of the Result Window (click on the right mouse button):
Transfer Result to Active SFT-Window - Calculates the geometric mean of the marked
result data and transfer it to the active SFT-window
Define as Active Result Window - Defines the actual result window as active. (the
results of the active drop window will be transferred to this result window)
In the following the menu Method of the SE Calculation Window, which is the only
additional to the ones of the Drop Window will be explained.:
In this menu you can select the calculation method of the surface free energy:
Fowkes
Owens-Wendt-Rabel-Kaelble
Extended Fowkes
Wu (Harmonic Mean)
Acid-Base theory
Wu (Geometric Mean)
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page 39
6.3.2 Preferences
Before you start the first measurement check the preferences described in this chapter.
Which options are available in the preferences depends from which window you click to
it. All options are only available from the Drop Window.
The Preferences are divided into two main blocks (see Figure 54):
general Preferences...
device settings... Settings for the devices and modules of the OCA
In the tree OCA 20 you can set all parameters and presetting for the control of electronic
syringe modules ES, temperature sensors, temperature controlled unit (like TEC 400, TPC
150 ), electronic multiple dosing unit E-MD/4, YZ-stage (only OCA 30 and OCAH 230),
electronic tilting base units (TBA 60E and TBU 90E) and electronic wafer table.
In the tree General settings, all other settings for the software can be defined (see Figure
55).
Figure 55: Device settings
Allow use of unknown liquids In a series of measurements, it is often necessary to use liquids without defined or
known surface tension. The surface tension of defined liquids is mostly also unknown
outside the temperature range of 20-25C. Therefore, it is recommended to allow the use
of unknown liquids. The parameters of the substitute liquid were used during the
measurement.
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OCA
To store the new defined syringe type in the actual selected database click on Save. If you
want to add the new syringe type also in another database, you must first select the
other database and insert it again.
The following standard syringes are available (see Figure 58):
Hamilton 200 l,
Hamilton 300 l
For ordering information, see chapter 11.2 Spare parts page 19.
For use with the portable contact angle system PCA select the
syringe PCA100 Type-1.
OCA Manual
page 41
Transmit shutdown
checked permanently, so the software can detect if the OCA is switched off. A dialog
appears which tell that the instrument is switched off and the software stores all settings
and will end.
icon of the
from the actual syringe database. If you cannot find the desired
syringe type you must enter it into the actual used database (see
chapter Define syringe type page 19) or select a database which
contains it.
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OCA
In the tabbed dialog Test Liquid, (see Figure 62) you can select a
test liquid from the actual liquids database. All physical
parameters of the selected liquid, which are stored in the
database where used automatically for measurement and
calculation when you select this syringe unit for measuring. If
you cannot find the desired liquid, you must enter it into the
actual used database (see chapter Selection of data base page 19, or
chapter Liquid data base page 19) or select a database, which
contains it. In the dialog box Properties, you can verify the
parameters of the selected liquid.
Figure 62: Device settings Unit 1, Test liquid
If you decided to allow unknown liquids (see page 19) select the
name of your substitute liquid. The parameters of the substitute liquid were used during
the measurement
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page 43
You can reach the general Preferences in the menu Edit under Preferences, or with a click
on the icon
.
Drop Window-Appearance Image Window Setting In this tabbed
dialog you can select which of the calculated lines where shown as an
overlay on the drop image.
Extracted Drop Profile show the line of the extracted profile in red
color.
Filtered Drop Profile show the line of the filtered profile in green
color.
Result Values show the result of the calculation (e.g. the contact
angle) in yellow on a blue background.
Tangent lines (only for Sessile Drops) show the line of the extracted
profile in the three-phase point in a red color.
The function
selected.
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OCA
Drop Type Set Measuring Drop Type In this tabbed dialog you can
select one of the eight drop types. This can also be done before the
measurement by a right mouse click (context menu) in the drop
window (see page 19). If you use the dynamic tracking function, you
must pre-set the drop type in this dialog. The default setting is
Normal SD (Sessile Drop).
Calculation Options In this tabbed dialog you can choose the default
calculation steps.
Calibrate before Performing Calculation (for PDs only) will only be
used on pendant drop measurements. This means that the calibration
of the image size will be done automatically. The diameter of the
needle will be taken out of the active Result window (Ref.-Size [mm]: ).
If no Result window can be found the default reference size of the
diameter (1 mm) will be taken.
Detect substrate line automatically (for SDs only) will only be used
on sessile drop measurements. Should only be deactivated if the
software is unable to detect the base line automatically (at contact
angle around 90 or bad lighting situations). The button in the icon
line has a higher priority.
Extract Profile if not yet done
Add Result to the active Result window will copy the results of the
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page 45
Correct Tilt will correct the tilt caused by a distorted installed camera. It will not correct
the tilt caused by a crooked needle.
Average Profile will calculate a mean profile between the profiles of the two sides of
the drop.
AR-optimization will adjust the Aspect Ratio of the image. Should only be selected
Figure 71: Extracted and smoothed profile
when necessary, because the AR-optimization will take up to a second per frame.
Fast-optimization if unchecked the calculation takes longer, but also unusable drop
shapes can be determined.
Image Processing Setting In this tabbed dialog you can set, among others, the cursor
positions for calculation of sessile drops.
Upper limit line at:
50
between the upper border of the drop window and the upper limit
cursor. The part of the image above this cursor line will not be taken
into calculation of the sessile drop. This is helpfully in use of
temperature controlled chambers.
Base line at:
100
difference in brightness two neighboring pixels must have to detect an edge (white=255
and black=0). The standard value is 50 and should only be changed when the image is not
sharp enough.
Image Processing Tilt base parameters In this dialog the parameters must only be set
if you have activated the Alternative method in the dialog Image Processing Image
Processing Setting.
Use non-standard parameter As non-standard parameter you can
set the upper and left margin of the image area where the calculation
of the contact angle will be carried out.
Use Command tilt angle When activated the calculation method
for the contact angle will be adapted to the tilting angle of the TBA
60E.
Tilting direction anticlockwise Must be activated if the tilting
direction is anticlockwise (depending on the mounting direction of
Figure 73: general Preferences Image Processing; Tilt base parameters
page 46
the device).
OCA
OCA Manual
page 47
Dynamic Tracking Setting Advanced Timing In this dialog you can set the parameter
for processes with variable frame rate. The frame rate is calculated as an exponential
sloping function.
times per To set the unit of the time to second, minute or hour.
With the vertical slider you set the maximum frame rate of the
measurement. If you selected minutes or hours frame rates will be
converted into seconds
With the horizontal slider you set the maximum frame rate of the
measurement.
Process Speed To set the gradient of the function (Fast result in a
steep drop). In all the multiplication of the frame rate with the
process speed results in the number of frames over the period of
observation. This function is useful for very long dynamic processes.
Figure 75: general Preferences Dynamic Tracking; Advanced Timing
WX The arrow keys below the diagram are used to zoom-in (or zoomout) the time interval of the diagram.
Dynamic Tracking Setting Extra In this tabbed dialog you can set the stop criteria for the
dynamic tracking function. This function can only be used with the interfacial or surface
tension measurement.
Measurement Stop Criteria:
Least measuring duration: The least measuring duration is
independent from the changes in the IFT. The shortest possible
duration is dependent from the performance of the PC-System.
Within the least measuring duration no check for stop criteria is
performed.
Measuring value alteration falling under: The measurement stops
if the difference between the actual measured IFT and the one before
is smaller than the maximum permissible alteration of the IFT in
[mN/m per Minute (d/dt)]. This is normally the case if a balance of
forces turns up.
Figure 76: general Preferences Dynamic Tracking; Extra
announcement dialog.
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OCA
Movie Control Camera Parameters In this tabbed dialog you can set the camera
format.
With the OCA 15, OCA 20 and OCA 30 you select CCIR-Standard, the
Vertically Scanning Frequency (Frame Rate): will be set automatically.
With the OCAH 200 and OCAH 230 you select Other/No-Standard
Format and set the Vertically Scanning Frequency (Frame Rate):
according to the selected camera mode (See chapter 7.5 OCAH 200/230
page 19).
Movie Control Recording In this tabbed dialog you can set the recording parameters.
defines how many frames
were recorded per second. Because the maximum frame rate is fix,
this will be defined by how many times an image will be taken (i.e.
every second one). With the STbuttons, you can change the value
between 1 and 25; greater intervals must be directly typed in.
Recording Duration: Can be set to
predefine the duration by setting
(RAM) and the available virtual memory. In the line below, you see the estimated
reachable number of recordable frames.
Limit the maximum frame number to
of frames ( X ) in the movie. With very fast PCs it is possible to record more frames than
displayed in the estimated number of frames.
Compress Image during Recording ? To compress every stored frame will increase the
maximum reachable number of frames, but you need a fast computer. The compression
rate is dependent on the quality of the image. A very sharp and clear image with a good
black/white contrast can be compressed very high, this means you can record a lot more
frames with the same amount of memory. An image with grey shading can be nearly not
compressed. In addition, the detection of the contour is dependent on the quality of the
image. The default setting is
OCA Manual
page 49
Movie Control Trigger Control In this tabbed dialog you can set
how the start of the recording will be triggered.
Using none To start the recording manually without a software
trigger.
Using software trigger To start the recording when the gray
value at the defined line:
-
At y (or x)
window)
is changing.
Figure 79: general Preferences Movie Control; Trigger Control
Trigger barrier
Movie Control Playing In this tabbed dialog you can set the
playing parameters.
Full images Use full images, if deactivated frames (interlaced
images) were displayed).
Cycle Playing the movie will be played continuously.
Perform Default Calculation You can pre-select that the images
where automatically calculated during playing, using the default
calculation method (see Preferences Calculation Options at page 19).
Waiting for Interactions from Operator Plays only one image
and then opens a dialog were you can decide to continue the
Figure 80: general Preferences Movie Control; Playing
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OCA
Result Window General Option In this tabbed dialog you can set some general
options for the result window.
Store autosnapshots in .ref file, stores the bitmap to every
measuring result in an own file. Please note that this option make
only sense in single measurements or in slow dynamic tracking
functions.
Result Window Display Items In this tabbed dialog you can select the items which
will be displayed in the result window.
Only the items in the To be displayed items box will be shown in the
result window.
Copy the marked item to the To be displayed items box.
Deletes the marked item from the To be displayed items box.
Result Window Export Items In this tabbed dialog you can select the items which will
be exported from the result window.
Only the items in the To be exported items box will be exported from
the result window. The data will be stored in ASCII format in columns
separated with tabs. The selection of the data can be done in the
same way like in the tabbed dialog Display Items.
Link the to be exported items to the displayed items The
exported data will be the same as the displayed.
Link export to file save The exported data will be saved
automatically to a file in ASCII format in the same directory and the
same name but with the extension .txt
Figure 83: general Preferences Result Window; Export Items
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6.3.3 FG-Setup
6.3.3.1 Standard frame grabber
References This tabbed dialog is used to define the Contrast between 0 and max. 512 as
well as the Brightness between 0 and max. 255. Good values for the Contrast
and Brightness reference depend on various factors like the brightness of the
environment, the reflection, shape and size of the sample. Therefore, you have to
adjust these values. Standard start values are:
Input Channel In this tabbed dialog you select the input channel of your frame
Figure 84: Dialog Frame Grabber-Setup with standard frame
grabber
grabber on which the OCA video camera is connected. Standard- input channel
is the connector Composite Video 1.
Camera Format In this tabbed dialog you select the used video camera format. The
default setting is CCIR, 768 x 576 pixels, 8 bits, 14.8 MHz, analog.
Brightness Reference = 50
Input Gain In this tabbed dialog you select the input signal gain of the frame
grabber on which the OCA video camera is connected. The standard value is
0.98.
Input Channel In this tabbed dialog you select the input channel of your frame
Figure 85: Dialog Frame grabber-Setup Setup for High-speed
grabber on which the OCA video camera is connected. The default value is
frame grabber
channel 0.
Camera Format In this tabbed dialog you select the used video camera format.
With the OCA 15 or OCA 20 select
For the settings of the OCAH 200 and OCAH 230 see chapter 7.5 22 OCAH 200/230
page 19.
The frame grabber settings must only be always done or done again if the camera is
changed or if the camera mode is changed (only OCAH 200/230). After changes of the
frame grabber settings, you should end the software immediately. Only at software start,
the frame grabber settings were taken over.
Restart the software immediately after every change in the frame grabber
setting before you produce a live image!
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OCA Manual
page 53
To use the movie functions of the SCA 20 software follow these instructions:
On the right side or at the top of the software window you will now find several icons
will stop during the recording time (with high-speed frame grabber), or will show
every second the actual image (with standard frame grabber). If you have selected a
trigger in the General Preferences, the recording will start immediately but when the
trigger event occurs.
To stop the recording of a movie sequence click on the icon marked with a black
.
square
If you like to play the movie backwards click on the icon with the yellow triangle
To look at singular pictures of the movie click on the forward / backward icon
.
.
.
or
To perform an automatic evaluation of the whole movie opens a result collection window and chooses the option default calculation in the movie playing preferences. You
reach this menu by choosing General Preferences in the edit menu of the SCA
software or by clicking on the options icon of the movie control task bar
To start and stop the calculation during playing press the icon
If you are doing this default calculation, be sure that the preferences for the default
calculation are chosen correct (drop type, calculation method).
If you like to pause the calculation and playing of the movie sequence use the pause
icon
If you like to set the actual image time to zero use the button
To change the default values for playing or recording a movie sequence click on the
icon with the three dots
You can save the movie under File->Movie Document->Save As or with a right mouse
click in the Drop Window.
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OCA
surface free energy or surface tension). If more than one line is marked, the mean value
will be transferred.
Export Result Data Stores the complete table in a file in ASCII-format.
Options Activates the menu General Preferences (see page 19). The possible variables to
display and export are:
Calculation Error
Calculation Method
Comment
OCA Manual
page 55
page 56
Coord Type
Coord1
Coord2
OCA
area
page 57
Coord3
Density Difference
Drop Age
Drop Curv. Radius at Apex Radius of the drop contour at the apex
Drop Height
Drop Phase
Drop Shape Parameter
Run Number
Solid Phase
Surface Tension
Surrounding Phase
Temperature
Tilt Base Angle
Define as Active Result Window Sets the actual selected result window to active. The
results from the drop window will be transferred only to the active result window.
Graphic Display Switches the graphic on/off.
Always Update Switches the automatic update of table and graphic on/off.
Update Now Updates the content of the result window if the automatic update is
switched off.
Maximize Size Enlarges the window to full screen size.
Restore Size Restores the previous window size.
With the tabbed dialog in the parameter area, you can define the following:
General Data for the whole measuring row like Measurement, Device, Customer,
Sample, Operator and Remarks.
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OCA
System Data for a single measurement like Drop Phase, Surrounding Phase, Solid Phase
and the Phase Densities [g/cm3] of drop and surrounding. To calculate the density
dependent on the actual temperature during measurement you can enter the
necessary parameters in Setup Parameters... for both phases. In this dialog you can
enter the density coefficients up to the third order (A to D). The coefficient A is the
density at 0C. The coefficients B to D (first to third order) define the linear and
polynomial density difference per Kelvin.
Drop Phase, activates the calculation of the drop density during the measuring.
Ambient Phase, activates the calculation of ambient density during the measuring
M-Info Data for a single measurement like Dosing Vol. [l] and Dosing Rate [l/s],
Temperature, Drop Age [ms], Reference Size [mm], Magnification [pixel/mm] and the
Measuring Date.
C-Info Data for a single measurement like Analysis Method, Aspect Ratio and
Acceleration of Gravity. To calculate absolute contact angles and surface/interfacial
tensions you have to input the aspect ratio of the cameraframe grabber-system and
the acceleration of gravity. Directly onto the camera you can read the aspect ratio. The
aspect ratio lays into the range of 1.002-1.005, normally 1.0037. For the OCAH 200/230
please see chapter 7.5 page 19. The value of the acceleration of gravity can be calculated
with the button Look up after the input of the Latitude []) and the Location above Sea
Level [m]).
Result Display of the data for a single measurement like surface/interfacial tension (IFT),
Fitting Error, Contact Angle, Drop Volume, Drop Area, Shape Parameter, Curvature Radius,
All data available in the table area can be displayed in the graphic area. With the context
menu (right mouse button) the following settings can be done:
X as You can choose the variable for the X-axis out of 4 often used variables (Run
Number, Drop Age, Temperature or Volume).
Y as You can choose the variable for the Y-axis out of 4 often used variables (Contact
Angle, Surface Tension, Drop Volume or Base Diameter).
Auto Range Automatic scaling for X- and/or Y-axis
Set Axis-Variables Selection of the Y-axis variables. With the button Parameter and
switched off automatic scaling you can set the parameters for the Y-axis.
FileSave As Metafile Stores the graphic to disk in the enhanced metafile - format.
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FilePrint Prints the graphic according to the pre-defined options to the actual
standard printer.
FilePrinting Options Setting of the printing options
FilePrinter Setup Printer setup
EditCopy Graph Copy the graphic to the clipboard
EditGraph Parameters Parameter of the graphic like Position and Size of the
graphic and plot area as well as the background color.
Figure 93: Context menu FilePrinting Options
EditPlot Parameters Plot parameter like the kind of the graphic, line attributes etc.
Maximize Size Displays the graphic area in full size window.
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Control Bar.
The STOP button aborts the actual action (movement) of every software-controlled
device immediately. It is only active while any process is running (the STOP sign is red and
the toothed wheel is turning)
position (minimum filling volume) and resets the internal position control. It is recommended to remove the syringe before resetting the syringe position.
Position You can set the position of the selected dispense unit by moving the slider up
and down, by entering the relative position value (0 100), or by clicking one of the icons
T or S.
Velocity You can set the velocity of the selected dispense unit by moving the slider up
and down, by entering the relative velocity value (0 100), or by clicking one of the icons
T or S.
If necessary set the preferences for the syringe type and/or the test liquids
if you change the syringe (see chapter 6.3.2.1.2 Define syringe type page 19)
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icon in the Device Control Bar opens the dialog Wafer table
maintenance.
In the dialog Wafer table maintenance, you must select the right diameter of the
mounted wafer table.
The following wafer tables are available:
Figure 98: Wafer table maintenance
Select the correct diameter of the wafer table before you use it or before you
Tilting base devices TBA 60E and TBU 90E (see chapter 7.2 page 19)
Please ensure that the device can move without any risk of contusion or
collision before you start a reference run!
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of the syringe. If the shown filling volume seems not to correspond with the real filling
volume please carry out a reset of the respective dispense unit (see chapter 6.3.7.1.1 page 19).
Volume To set the dosing volume. The minimum dosing volume is 0.007 l, the
maximum the complete content of the used syringe. You can set the dosing volume by
moving the slider left and right, by entering the value, or by clicking to one of the
buttons
Continuous Dos. If set the dosing will last until the syringe is empty or the STOP
button (see page 19) is pressed.
Rate To set the dosing rate. The minimum dosing rate is 0.06 l/s, the maximum
dosing rate is 26.4 l/s. You can set the dosing rate by moving the slider left and right, by
entering the value or by selecting one of the pre-defined dosing rates:
Needles up Moves the actual selected needle to the uppermost position (only with
connected E-MD).
Reverse dosing of the defined volume with the defined rate.
Dosing of the defined volume at the defined rate.
Syringe Shows the selected syringe type (see chapter 6.3.2.1.5 page 19)
Liquid Shows the selected test liquid (see chapter 6.3.2.1.5 page 19).
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before you start the ARCA-program, otherwise the complete content of the syringe will be
dosed and reverse dosed.
ARCA-measurement Edit/Load Opens the dialog Advancing/Receding Angle settings in
which you can set the parameters for automated measurement.
new ARCA settings creates a new ARCA-procedure.
save new ARCA stores the actual defined parameters
load new ARCA loads a stored procedure.
OK Takes the actual defined procedure as measuring procedure, and the
button Unload in the dialog Dispense Parameter will be activated. If you
close the dialog without the OK button (but with the ) no measuring
keyboard. The needle moves as long as you hold the cursor key pressed. It is not possible
to move in more than one direction, so pressing more than one cursor key has no
function.
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You open the liquid database with the menu File New/Open Window. In the left part of
window, you select the liquid and in the right part you get the parameters depending
what method you have selected with the tab ruler.
There are not all parameters for all methods available.
To avoid an unintentionally destroy of the liquid database it is not possible to edit the
standard database liquids.mdb. Edit and add is only possible in the database
liquids_editable.mdb (see chapter 6.3.2.1.1 page 19).
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8 9 10 11 12
13 14
15 16
17
18 19
20 21 22
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Tangent leaning; leans a tangent to the curve at the three phase point
The most accurate results you get with the Young-Laplace fitting, so if you have time
enough use this method.
Figure 107: Context menu Drop
Type
Do all the preparations described in chapter 6.1 Method independent procedures page
19 and the additional ones described in here.
Requirements First you must choose the basic drop form. With a right mouse click
youll get a context menu where you can choose one of the possible drop forms by click
with the left mouse key.
In the System register of the result-window, you can select the Drop Phase and the
Ambient Phase from the liquid database, the Solid Phase must be entered manually.
The knowledge of the density and the force of gravity are not necessary for the
determination of the contact angle. Under certain marginal conditions (great drops with
big contact angles), the surface tension can be calculated by means of the Young-Laplacemethod, if the density and gravity values are known.
Place sample on the stage Before placing a sample onto the stage lower the stage and
lift up the needle holder (with the MD by means of the quick movement knob), or tilt the
dosing bay or the E-MD. If you want to measure contact angles under air, place the
sample (solid surface) directly onto the sample stage. If you use the tilting base device,
you must fix the sample (for example with a tape).
Liquid dispensing If you use a manually syringe unit dispense a drop by turning the
micrometer screw. If you use the -recommended- electronic syringe units the liquid
dispensing can be adjust in the dialog Device control Dispense parameter (see chapter
6.3.7.3.1 page 19). First select the dispense unit with the dosing needle you want to use (No 1 -
4). Dose a drop with the desired size (volume). A small droplet will hang on the needle tip
a big drop will fall down to the sample due to his weight.
If the drop did not fall down to the sample move the sample stage carefully up (without
touching the needle) until the drop will set down to the sample. Now move the sample
stage down again until the substrate line is in the lower third of the drop window.
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Adjust the drop image The first step you have to do is to focus the
dosing needle. Move the dosing needle into the center of the visible
area by means of the fine adjustment screws of the MD or SD-D or by
means of the controls (i.e. cursor keys with activated dialog NeedlePosition) of the E-MD (see page 19). Zoom in the dosing needle by
turning the zoom of the lens). Focus the dosing needle by means of
the inner fine focus. Dose a liquid drop and place it onto the surface.
Adjust the magnification (turn the zoom of the lens) until the drop
has a minimum of 2/3 of the visible area.
If the reflection of the drop on the surface is not clear enough to
detect the base line you have to do additional adjustments:
shape the software cannot detect the contact angle. The look of the
drop is less important than the bright-dark difference in the so-called three phase
point!
Snap the image If you get a good drop then snap the image by means of the
camera icon. To reduce errors out of vibrations and wind effects all calculations should be
done with this still frame.
Determination of the base line The base line will be detected automatically in
most cases. If not readjust the tilt of the lens, adjust the brightness and re-focus the drop
with the fine focus. With contact angles about 90 or non-reflecting materials, you must
adjust the base line manually. For that deactivate the Detect substrate line automatically
function in the tabbed dialog Calculation Options in General Preferences (see page 19) or
click on the icon
the SCA 20 detects the base line by the gradient of the contour line of the drop.
To adjust the base line manually you must select it with left mouse click. Now you can
adjust the base line with four arrow keys on the keyboard. The keys
base line vertically up and down and the keys
and
and
move the
click sets the base horizontal. The base line must not be absolute horizontal.
Determination of the drop shape The drop shape will be detected by the
contrast (bright-dark difference) of the drop to his surrounding.
Calculation of the contact angle The contact angle will be calculated
according to the pre-set fitting (see Calculation Options page 19). The contact
angle can be calculated according to a not pre-set fitting with the menu
ProfileCompute Contact Angle using X.
With the icon
Figure 110: Compute Contact Angle using X
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and
) were
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Calculation of contact angle or surface tension The contact angle (of sessile
drops) or the surface tension (of pendant drops) will be calculated according to the
Young-Laplace equation.
To measure reproducible static contact angles you must work very conscientious. Influence parameters are
time
dosing rate
temperature
drop size
volume
drop environment
density
evaporation
gravitation
(see chapter
6.3.4 page19). For using this function, you must have an active result window to which the
results will be transferred automatically.
All data of a dynamic tracking measurement will be lost without an active
result window.
The sample preparation can be done in the same way like for static contact angles.
Choose the drop size so that the drop will just hanging on the needle tip. Move the
sample stage with the sample carefully up so the sample is not yet touching the hanging
drop. On reflecting samples, you will see the reflection of the drop. In the middle between
the reflection and the drop, you set the base line manually. With contact angles smaller
than 80 you can use the automatic base line detection
than 80, the automatic base line detection should be switched off. The automatic base
line detection takes some extra time during the calculation of the contact angle so if you
want to detect the contact angle as fast as possible switch it off and set the base line
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manually. Also, please note that every taken image where the software cannot detect the
base line automatically is lost as a result. If you use a slow dynamic tracking (1 frame per
10 second) and have activated the option Store autosnapshots in .ref file every taken
image will be stored, so you cannot loose a measuring point.
To save time during calculation and to reduce the risk of loosing measuring
points switch the automatic base line detection off when using the dynamic
tracking function.
Now you can add on (dispense) a small amount of liquid, so the drop get in contact with
the sample (normally it settle down then) or fall down. Immediately after or before you
click the icon to start the dynamic tracking function. If there is no more change in the
contact angle the dynamic process is ended. Similar you can test high viscose liquids to
their stable (equilibrium) contact angle.
Also the ARCA (Advancing and Receding Contact Angle)-function can be used to measure
dynamic contact angles (see chapter 6.3.7.3.1 page 19). If the drop volume is increased by
adding liquid to it, the interface will advance on the sample and you can measure the
advancing contact angle. If the drop volume is decreased by sucking off liquid, the
Figure 111: Menu
ARCA
interface will recede on the sample and you can measure the receding contact angle.
Set all necessary parameters for the ARCA function (see chapter 6.3.7.3.1 page 19).
Prepare the needle so that she has a contact angle of 90 to the test liquid. If this is
not the case, the drop shape will deform because the liquid will rise up or pushed off
the needle.
Dose a droplet small that it just moistens the sample. Adjust the needle again, if she is
not in the middle of the drop.
Now you can start the ARCA- function and the dynamic tracking (or movie) to
measure the advancing and receding contact angle.
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result-window, you must define the phase densities (the drop and the ambient). If the
selected media are in the liquid database, the density will be taken out there.
Furthermore, the absolute drop volume must be known. Therefore, a scaling of the window part is necessary.
Needle selection For the measurement of pendant drops you should use needles where
the drop will not form out too spherical. It is recommended to use needles as big as
possible (use the SNP needles like the SNP 165/119 Part no: 6 000 027).
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Liquid dispensing If you use a manually syringe unit dispense a drop by turning the
micrometer screw. If you use the -recommended- electronic syringe units the liquid
dispensing can be adjust in the dialog Device control Dispense parameter (see chapter
6.3.7.3.1 page 19). First select the dispense unit with the dosing needle you want to use (No 1 -
4). Dose a drop as big as possible. The best way to do is to dose with a very slow dosing
rate and
means of the camera icon. To reduce errors out of vibrations and wind effects all
calculations should be done with this still frame.
Scaling of the image window To calibrate the absolute image size the
software needs a reference value. For this, the needle will be used. In the M-Info
register of the result-window, you type in the diameter in mm of the used dosing
needle (Ref. - Size [mm]). Set the upper (with turned camera the left or right)
boundary line near the end of the dosing needle (the needle must not be wetted
with liquid). The scaling of the image will be calculated automatically when the
calculation of the surface tension starts. By pressing the
Figure 114: M-Info dialog in the result window
and
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= 90
in contact with the material are easy to clean and the sample vessel is open so that no gas
inclusion can happen.
The lamella method is based on the balance of power between the surface tension and the
force of gravity, just as the pendant drop method. A liquid lamella will shape if we bring a
vertical test piece in contact with a liquid. Based on the Young-Laplace differential equation the
surface tension can be calculated if the contour of the lamella and the force of gravity is
known.
Figure 115: Lamella at different
At a contact angle of 90, no lamella will shape with a cylindrical test piece (see opposite figure). contact angles
Therefore, a spherical test piece is used to produce the lamella.
The measurement of the surface tension by the lamella shape will be done in the soft-
ware SCA 20/23. In the following, you will get a short introduction how to measure surSphere on test piece
Filling of sample vessel First you have to fill the sample vessel. The vessel must be
filled right up (see Figure 116). The surface of the sample should wet the complete vessel
surface and must be as flat as possible. Lower the sample stage. If you use a thermal
Sample vessel
chamber (TEC 400, TPC 150 or TFC 100) open the cover, place the vessel in the middle of
the stage and close the cover.
Fix the test piece Connect the spherical test piece to a Luer-Lock adapter and fix it in the
needle holder (SD or MD). Adjust the needle holder (see chapter 5.2.2 Positioning of the
dosing needle page 19) so that you see the sphere of the test piece in the life picture on
the software.
Adjust the image Move the test piece into the left part of the visible area. Adjust the
magnification by turning the zoom until the needle of the test piece is about 1/3 of
the visible area (see opposite figure). The left side of the test piece needle must be
minimum 30 pixels apart from the left border of the image window, and minimum
50 pixel of the needle part must be visible. Focus the test piece by means of the inner
fine focus. It is usually necessary to cover the upper right part of the illumination to
prevent too strong reflections on the flat wetted part of the lamella.
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Requirements First you must choose the basic drop form. With a right mouse click
youll get a context menu where you can select the lamella forms by click with the left
mouse key.
For the mathematical analysis of the lamella contour the force of gravity, which influence
the lamella, must be known. Likewise, the knowledge of the density of the sample and the
surrounding medium is necessary. In the System register of the result-window, you define
the phase density of the drop and the surrounding. If the selected media are in the liquid
database, the density will be taken out there.
Furthermore, the absolute size of the image must be known. Therefore, a scaling of the
Figure 118: Context menu Drop Form
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Icon 1 to 3 is to define the type of base line, 4 to 6 to define the shape of the drop. Icon 7
starts the contact angle calculation.
Straight base line (Button 1):
To set a straight base line, defined by two points in the drop image window.
Points are defined with a mouse click in the drop image window. If more than two points
are defined, a linear regression line is calculated.
To remove a single point press the SHIFT-KEY ( ) and click on the point, to remove all
points press the STRG-KEY and click on one point
Circular shaped base line (Button 2):
To set a circular shaped base line, defined by three points at least.
Points are defined with a mouse click in the drop image window. If more than three
points are defined, a best fit is calculated.
To remove a point press the SHIFT KEY ( ) and click on the point, to remove all points
press the STRG KEY and click on one point.
Ellipse shaped base line (Button 3):
To set an ellipse shaped base line, defined by five points at least.
Points are defined with a mouse click in the drop image window. If more than five points
are defined, a best fit is calculated.
To remove a point press the SHIFT-KEY ( ) and click on the point, to remove all points
press the STRG-KEY and click on one point
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6.5 Analysis
6.5.1 Calculation of surface free energy
The calculation of the surface free energy of solids
will be done in the SE Calculation Window. You open
a new one with the menu File New/Open
Window. The look of the Window depends on the
selected calculation method. You can select one of
the following methods in the menu Method. The
given applications and examples are meant as a
rule. A more detailed investigation of the
applicability for the analyzed system might be
necessary.
Method
Information
Min. No. of
Application
Examples
Fluids
Zisman
non-polar solids
Fowkes
non-polar systems
OWRK (Owens-
universal
polymers, aluminum,
Wendt-Rabel and
coatings, varnishes
Kaelble)
Extended Fowkes
Mean)
specific questions of
surface properties
polymers
systems
organic solutions,
polymers, organic
pigments
Acid-Base Theory
specific questions of
biological system
surface properties
universal
polymers, aluminum,
Schultz 1 (Polar
high energetic
metal, glass
Drop Phase)
Schultz 2 (Polar
Bulk Phase)
theory
coatings, varnishes
system
2
high energetic
polymers, aluminum,
system
coatings, varnishes
With the Browse... button you can select the liquid database.
Select the liquid you measured the contact angle in the combo-box Liquid or type in the
parameters of the surface tension and their components (if not found in the liquid database). Now you must enter the measured contact angle manually or transfer it form the
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result window (a right-mouse-click opens the context menu where you click on Transfer
Result to Active SE-Window). If more than one result is marked, the geometric mean is
calculated and transferred to the SE-Window. By manual input, it can happen that a
message box appears Please enter more than 5 characters. This message has no
influence to the calculation it came from missing values in the liquid database. Confirm
the message with OK and check if the entered value is ok.
The choice of liquids depends on the selected analysis method. Only if all the
necessary parameters for the analysis method are available the liquid is
available in the combo-box Liquid. In addition, these liquids only can be
transferred with all necessary parameters from the result-window.
With the + button you add the liquid with his SFT (and its components) and the contact angle to the liquid list. If you have entered enough liquids (see table above) you
can calculate the surface free energy (and its components) by a click on the Calculatebutton. The calculate button is set inactive if any of the necessary data is missing.
After the calculation is ready, you get the surface free energy and a corresponding
graph.
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mounted. For upgrade an OCA 20 or OCAH 200 with a motorized and software
controllable YZ-stage please turns to the service departments of our representations or to
us directly at DataPhysics Instruments GmbH.
7.1.1 General
The motorized YZ-stage has two movable axes. The Y-axis is horizontally right-angled to
the optical axis (X-axis). The Z-axis is vertically right-angled to the optical axis.
The Y-axis exists in two designs, the standard one with a maximum travel of 100 mm and
the Long-Version with a maximum travel of 150 mm.
The Z-axis has a maximum travel of 50 mm.
The following vertical positions were defined in the software preferences:
Y
Figure 123: motorized YZ-stage
Ground Level Normally the vertical position of the stage after the reference run.
Working Level Vertical position to pick-up the drop from the needle.
7.1.2.1 Preferences
Before you start the first measurement, you should enter the
preferences. In the menu Edit> Preferences>device settings...
you will find the tree YZ-table with the register YZ-Table
Settings, DIP-Mode and Coordinate System.
In the register
With
position (Ground level) before it moves to the new horizontal position and then to the
vertical position it had before.
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With
horizontal position.
The Moving Mode is only active in the Y-Step- mode (see page 19).
Never use the L-movement mode if the risk of collision of the needle with
the sample exists!
Y Key-Velocity Here you can set how fast the motorized YZ-stage will move horizontally
(Y-direction). You can change the velocity with the slider or by entering a value.
Z Key-Velocity Here you can set how fast the motorized YZ-stage will move vertically
(Y-direction). You can change the velocity with the slider or by entering a value.
If you use the cursor keys to control the position, the stage always move with
its maximum velocity!
In the register DIP-mode you can set the parameters to pick-up the drop from the needle
automatically by moving the stage up and down again.
Enable DIP-Mode, Activates the DIP-Mode.
Z-velocity To set the speed [mm/sec] for the stage movement
in vertical direction while it picks-up the drop. You can change
the velocity with the slider or by entering a value.
Dip-time Time, which the stage will pause at the Working
level to give the drop enough time to settle down on the
sample.
E-MD needle up Moves the needle completely up after the
drop is picked up (Note: Only with a connected E-MD).
Figure 125: General settings DIP-mode
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7.1.2.2 Operation
Before you control the position of the motorized YZ-stage the first time, it is
recommended to start the Reference Run. Open the Device Control window and select
the register
Please ensure that the device can move without any risk of contusion or
collision before you start a reference run!
move one step to the left wit a click to the button X one step to the right.
Depending on the Moving mode you had pre-defined in Preferences the stage
moves directly to the new Y-position (L-movement mode), or the stage first
move vertically to the ground position (Ground level) before it moves to the
new horizontal position and then back to the vertical position it had before
(U-movement mode).
Z-Position The actual Z-position of the motorized YZ-stage. You can change
the value of the Z-position with the slider or by entering a value. The stage does not move
immediately, but only when you click to the button Apply.
Z-Level You can define the following vertical positions:
Ground Normally the vertical position of the stage after the reference run (i.e. used
by the U-movement mode).
You can enter the values for the three Z-Levels or you can move the stage to the desired
vertical position and click the button accept Z-pos. to store this position as one of the new
Z-Level.
Normally you should not set the Focus and /or GroundLevel higher than the Working-Level!
If the dialog YZ-table is active (blue headline) you can also move the stage directly with
the cursor keys on the keyboard. The stage moves as long as you hold a cursor key
pressed. It is not possible to move in more than one direction, so pressing more than one
cursor key has no function.
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7.1.3 Automation
With the motorized YZ-stage, the electronic syringe units ES and the (optional)
electronic multiple dosing system E-MD you can automate series measurements.
You can create a new automation program in the menu File New/Open Window
new DCP file (Device Control Program). Then depending on the connected devices, you
can select one of the four measuring methods.
The following measuring methods are available (depending on the used devices):
standard measurement (YZ) Usable with a motorized YZ-stage and electronic syringe
units ES
7.1.3.1 Settings
Before you can measure automatically, you must create an automation program. In this
automation program, you must pre-define all parameter like the selection of syringe
modules, the dosing, the needle positioning and the travel of the motorized YZ-stage. You
can select one of the four automation methods:
standard measurement (YZ) Single measurement to measure the contact
angle at exactly one position of the sample with one test liquid.
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set title string, you can enter a title for this automation program.
In the register
In the register
set Z-Level, you can set the control parameter for the vertical axis.
copy current device settings A click on this button copies the values defined in the
device control dialog (see dialog YZ-table page 19).
Use host device parameter Uses the actual Z-Level values, defined in the dialog device
control of the YZ-stage, when starting the automation program. If you change the values
for the Z-Level in the dialog device control of the YZ-stage the new values where used for
the next automation program. If activated ( ) the other controls in this dialog will be
deactivated (grey).
Figure 132: Register tab Set Z-Level
working, focus and ground You can set the three Z-Level of the vertical axis (Change the
values of the Z-Level position with the slider or by entering a value). A click to one of the
copies the value of the actual position of the Z-axis to
three buttons
corresponding Z-Level.
Working level is upper boundary Defines the value of the Working Level as the upper
limit of the travel. With that, the travel range is limited (i.e. to avoid damaging the
needles)
In the register
disp. unit param you can set the control parameter for the dispense
unit.
copy current device settings A click on this button copies the values defined in the
dialog device control Dispense parameter (see chapter 6.3.7.3.1 Dispense parameter page 19).
Use host device parameter Uses the actual control parameter of the active dispense
unit in the dialog device control Dispense parameter. If activated ( ) the other controls in
this dialog will be deactivated (grey).
Click on one of this syringe-icons to select the dispense unit you want to use.
Figure 133: Register tab dispense unit
parameter
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You will find as much syringe icons as you had electronic syringe units ES installed, all
signed with their number (1 6).
DataPhysics Instruments GmbH, Filderstadt
OCA
Volume [l] To set the dosing volume. The minimum dosing volume is 0.007 l, the
maximum the complete content of the used syringe. You can set the dosing volume by
moving the slider left and right, by entering the value, or by clicking to one of the buttons
.
Rate [l/s] To set the dosing rate. The minimum dosing rate is 0.06 l/s, the maximum
dosing rate is 26.4 l/s. You can set the dosing rate by moving the slider left and right, by
entering the value, or by clicking to one of the buttons
Forward
or reverse
In the register
working delay Time which the stage will pause at the Working level to give the drop
enough time to settle down on the sample. You can set the working delay by moving the
slider left and right, by entering the value, or by clicking to one of the buttons
focus delay Time which the program will pause when reached the Focus level before the
measurement starts. You can set the focus delay by moving the slider left and right, by
entering the value, or by clicking to one of the buttons
no working delay and
In the register
E-MD param. you can set the control parameter for the E-MD.
copy current device settings A click on this button copies the values defined in the
dialog device control Needle-Position (see chapter 6.3.7.3.2 Electric Multiple Dosing unit (E-MD) page
19).
Use host device parameter Uses the actual control parameter of the active needle in
the dialog device control Needle-Position device. If activated ( ) the other controls in this
dialog will be deactivated (grey).
dosing pos. To set the horizontal and vertical position of the needle during dosing the
liquid. You can set the horizontal and vertical position by moving the slider, by entering
the value, or by clicking to one of the buttons
post dosing pos. To set the horizontal and vertical position of the needle after dosing
the liquid. You can set the horizontal and vertical position by moving the slider, by
entering the value, or by clicking to one of the buttons
link horizontal positions To set the horizontal position after the dosing equal the
position during the dosing. If activated ( ) the control for the horizontal position after
the dosing in this dialog will be deactivated (grey).
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In the register
Load configure File you can load a stored configuration file which
To edit a stored automation program open the file in the menu File open, change the
Figure 136: Register tab Load configure file
measuring points by defining the number of points and the start and end position. The
measuring points will be set in equal distances between the start and end position.
Start position Horizontal position of the first measuring point. You can set the Start
position by entering the value, or by clicking to one of the buttons
End position Horizontal position of the last measuring point. You can set the End
position by entering the value, or by clicking to one of the buttons
use current Y-Pos. A click on this button sets the value of the actual horizontal of the
Figure 137: Register tab Y-Series
Parameter
7.1.3.1.3 Multimeasurement
The automation program multimeasurement is for measure a
single measuring point with multiple test liquids. This is a helpful
method to measure the surface free energy of a sample. This
automation program has one additional register tab, the multi.
parameter tab. Depending on the number of drops defined you will
see additional trees run01, run02 in the left part of the tabbed
dialog. In this trees, the dispense, timing and E-MD parameters will
be defined.
In the register
additional tree run## will appear in the left part of the tabbed
dialog (i.e. for three measurements three trees will be added, run01, run02 and run03).
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OCA
drop distance Defines the horizontal distance between two neighboring drops. You can
set the distance by moving the slider, by entering the value, or by clicking to one of the
buttons
Center Set the drops so that they are centered around the actual Y-position of the
stage (zero position). With an uneven number of points, for example 3 drops the second
drop will be set to the zero position the first drop will be set to the left, the third drop to
the right. With an even number of points, for example 4 drops the zero position lays
between drop 2 and 3.
Left Set the first drop to the zero position and every additional one to the right,
Right Set the first drop to the zero position and every additional one to the left,
OCA Manual
page 87
Weight: 0.9 kg
holes of the sample stage. Fix the TBA 60M with the two knurled nuts.
Operation Move up the dosing needle by means of the quick movement knob on the
needle holder of the MD or SD-D or by means of the controls (e.g. cursor keys with
activated dialog Needle-Position) of the E-MD (see page 19). Move down the stage.
Place the sample onto the tilting plate and fix it (e.g. with an adhesive tape). Move up
the stage by means of the height adjustment knob B and down the needle. Adjust the
tilting angle according to the desired application with front wheel A. Now you can perform the measurement.
weight: 1..3 kg
Installation If any other sample stage adapter is already installed, take it apart from the
sample stage. Position the TBA 60E over the sample stage with the motor to the backside
of the OCA. Guide the two pins on the bottom of the TBA 60E into the two corresponding
holes of the sample stage. Fix the TBA 60E with the two knurled nuts. Connect the control
cable to the TBA 60E and to the socket No. 5 or 6 on the bottom of the illumination
housing.
Operation The TBA 60E is motor driven and software controlled. Move up the dosing
needle by means of the quick movement knob on the needle holder of the MD or SD-D or
by means of the controls (e.g. cursor keys with activated dialog Needle-Position) of the EMD (see page 19). Move down the stage. Place the sample onto the tilting plate and fix it
(e.g. with an adhesive tape). Move up the stage by means of the height adjustment knob
B and down the needle. Adjust the tilting angle according to the desired application with
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OCA
front wheel A. Adjust the tilting angle according to the desired application. Now you can
perform the measurement.
Tilt angle and advancing & receding contact angle recording (CA = 0...180)
The TBU 90E is fixed with two safety plates to prevent damage by transport
shocks.
The safety plates must not taken off until the OCA is mounted onto the
TBU 90E and is standing on the place where it should stay.
If the TBU 90E is not delivered together with the OCA you must carry out the following
preparations:
Preparations on the OCA (if not already prepared!)
Take off all electronic syringe modules ES and the multiple dosing unit MD or E-MD/4
from the OCA.
Lay the OCA carefully to the backside (not onto the hand wheel of the Y-axis) onto a
soft base! The OCA 30/230 must be laid to his front side, because the motor housing
juts out to the backside.
35
67
110
160
11
M5 threads
tenon block
67
110
M5 threads
tenon block
270
112
35
11
593
Loosen the hexagon screws (Size 6) in the 4 feet of the OCA and move them to the
positions shown in the drawing beside.
Insert the four tenon blocks into the outer channels and move to the described
positions. Fix the four tenon blocks with the setscrews (Size 2). See to it that the M5
threads in the tenon blocks are positioned in the middle of the channels.
OCA Manual
page 89
Installation
Mount all electronic syringe modules ES and the multiple dosing unit MD or E-MD/4
to the OCA.
Put the complete OCA over the TBU 90E and lower it carefully.
Risk of contusion
Never bring any body parts between the movable parts of the unit!
Especially when inserting the OCA into the TBU 90E.
Guide in the four feet of the OCA, as shown in the figure above. Fix the OCA on the
TBU 90E by means of the four knurled screws.
DC-IN 12V
Electrical connection
Lead the cable for connection to the socket DC-IN 12V on the OCA as shown in the
figure beside. The cable for connection to address 5 or 6 on the bottom of the
illumination housing will be connected later.
m
Fro
u
er s
pow
pp
To adress 5 or 6
The cable from the power supply leads into the only free socket on the bottom of
the TBU 90E motor housing.
ly
Connect the serial and video (BNC) cable from the PC to the OCA.
Switch on the OCA and start the software SCA 20 (must be Version 2.0 or higher).
Carry out a reference run at first (see chapter 7.2.2.2 page 19).
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OCA
7.2.2.1 Preferences
Before you start the first measurement, you should enter the preferences.
In the menu Edit> Preferences>device settings... you will find the tree
TBA60E or TBU 90E.
Perform reference run at program start Carry out a Reference Run
every time the software starts.
Use slow mode Only available for the TBU 90E (not for TBA 60E). The
movement of the TBU 90E will be carried out in a so called Micro step
7.2.2.2 Operation
Before you control the angle of the motorized tilting base devices TBA 60E and TBU 90E
the first time it is recommended to start the Reference Run. Open the Device Control
. Click on the icon
to start the
reference run.
Please ensure that the device can move without any risk of contusion or
collision before you start a reference run!
Figure 148: Reference Run
Tilting base device TBA60e/TBU90e for the control of the motorized tilting base devices.
OCA Manual
page 91
In the register
rolling CA you can set the control parameter for the tilting base
device.
working angle [] To set the angle where the drop is dispensed
and set down to the sample. You can set the working angle by
moving the slider left and right, by entering the value, or by clicking
to one of the buttons
start angle [] To set the angle when measurement shall start. You
can set the start angle by moving the slider left and right, by
entering the value, or by clicking to one of the buttons
end angle [] To set the angle when measurement shall stop. You
can set the end angle by moving the slider left and right, by entering
the value, or by clicking to one of the buttons
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OCA
slow mode The slow mode can be activated fro both the working velocity and the
measuring velocity. If activated the movement of the TBU 90E will be carried out in a so
called Micro step mode, in which very slow movement is possible.
Stop if drop not visible or dropgauge fails Stops the Automation if the drop rolls out
of the field of view or is no longer measurable.
No start delay The measurement will start immediately after reaching the working
position. If activated ( ) the control start delay will be deactivated (grey).
start delay Time the automation program waits after the drop was dispensed. Usefully
to let the drop settle down.
Installation If any other sample stage adapter is already installed, take it apart from the
sample stage. Position the WT over the sample stage with the hand wheel to the front.
Guide the two holes on the bottom of the WT over the two corresponding holes of the
sample stage. Fix the WT by means of the two fixing screws.
Install the attachment lens WTL onto the zoom lens (it adjusts the working distance).
Loosen the two hinges on each side of the dosing bay by means of the hex screws (see
chapter 4.1.2 Installation of the dosing bay and dosing units page 17) and adjust the position of the
dosing bay so that the hinges are congruent with the guiding mark.
Operation The WT is easy to use. Move up the dosing needle by means of quick movement knob on the needle holder. Move down the stage. Place the wafer onto the wafer
stage. Move up the stage and down the needle. Adjust the position on the wafer where
you want to measure. Now you can perform the measurement.
OCA Manual
page 93
Electronic wafer stage Used to measure on wafers with a diameter from 100 mm to
300 mm. The WT is motor driven and software controlled.
Features of the WT 200E / 300E:
Installation If any other sample stage adapter is already installed take it apart from the
sample stage. Position the WT over the sample stage with the motor to the back. Guide
the two holes on the bottom of the WT over the two corresponding holes of the sample
stage. Fix the WT by means of the two knurled nuts.
To change the wafer top plate opens the hex screw in the middle of the top plate. Take
the top plate apart, center the new top plate over the motor axis, and fix it with the hex
screw.
Install the attachment lens WTL onto the zoom lens (it adjusts the working distance).
Loosen the two hinges on each side of the dosing bay by means of the hex screws (see
chapter Installation of the dosing bay and dosing units page 17) and adjust the position
of the dosing bay so that the hinges are congruent with the guiding mark.
Connect the control cable to the socket No. 5 or 6 on the bottom of the illumination
housing.
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OCA
With an OCA 30 or 230 (with a motorized YZ-stage) the preferences for the YZ-stage are
included into the controls of the wafer table and are named wafer table.
wafer table YZ-Settings you can set the parameters for the
In the register
motorized YZ-stage.
radial key-Velocity Here you can set how fast the motorized YZ-stage will move
horizontally (Y-, or radial-direction). You can change the velocity with the slider.
Z key-Velocity Here you can set how fast the motorized YZ-stage will move vertically
(Y-direction). You can change the velocity with the slider.
Enable DIP-Mode Activates the DIP-Mode (pick-up the drop from the needle
automatically by moving the stage up and down again).
dip-time Time which the stage will pause at the Working level to give the drop enough
time to settle down on the sample.
dip velocity To set the speed [mm/sec] for the stage movement in vertical direction
while it picks-up the drop. You can change the velocity with the slider or by entering a
value.
E-MD needle up Moves the needle completely up after the drop is picked up (Note:
Only with a connected E-MD).
In the register
wafer metrics, you can set the wafer centre position. You can set the
radius of the wafer centre position by moving the slider left and right, by entering the
value, or by clicking to one of the buttons
will take over the value for the centre position from the actual position of the wafer stage.
Additionally the area, which is not accessible by the needle, is displayed.
Before you use a wafer table the first time it is necessary to set the correct table size in
the software.
A click on the
icon in the Device Control Bar opens the dialog Wafer table
maintenance.
In the dialog Wafer table maintenance, you must select the real diameter of the
mounted wafer top plate.
Select the correct diameter of the wafer table before you use it or before you
carry out a reference run.
A wrong size can damage the wafer table and/or the OCA.
OCA Manual
page 95
7.3.2.2 Operation
The electronic wafer table is very easy revolving when you touch it while the OCA is
switched off. When changing the top plate it is also possible to de-adjust the position
control of the wafer table. So before you control the angle of the electronic wafer table
the first time, it is recommended to start the Reference Run. Open the Device Control
window and select the register
to start the
reference run.
If the wafer table is mounted on an OCA 30 or OCA 230 the reference run will
automatically also carry out a reference run for the Y-axis and the Z-axis.
Please ensure that the wafer table can move without any risk of contusion
or collision before you start a reference run (especially when mounted on
the motorized YZ-stage)!
The STOP button aborts the actual action (movement) of every software-controlled
device immediately. It is only active while any process is running (the STOP sign is red and
the toothed wheel is turning).
With an OCA 30 or 230 (with a motorized YZ-stage) the dialog for the wafer table is
included into the dialog of the YZ-stage and is named wafer table.
Angle To define the angle of the wafer table. You can change
the angle of the wafer with the dot on the circumference of the
circle or by entering a value. The wafer table does not turn
immediately but only when you click to the button Apply.
Y-Position Shows the actual Y-position of the motorized YZstage. You can change the value of the Y-position with the slider
or by entering a value. The stage does not move immediately, but
Figure 159: Wafer Table Positioning with an OCA 30/230
Y-Step You can define a step size for the Y-movement of the
stage by entering a value or with the buttons
move one step to the left wit a click to the button X one step to the right.
Z-Position The actual Z-position of the motorized YZ-stage. You can change the value of
the Z-position with the slider or by entering a value. The stage does not move
immediately but, only when you click to the button Apply.
OCA
Ground Normally the vertical position of the stage after the reference run.
You can enter the values for the three Z-Levels or you can move the stage to the desired
vertical position and click the button accept Z-pos. to store this position as one of the new
Z-Level.
A click to
wafer).
The green dot
to). You set the target position with a click on the virtual wafer, or by
entering the coordinate values. The target position cannot lay in the
inaccessible area (see register wafer metrics, page 19).
OCA Manual
page 97
Cover plates for the optimization of the needle entry gap for varying problems
Weight: 0.6 kg
Installation If any other sample stage adapter is already installed, take it apart from the
sample stage. Tilt the dosing unit to prevent the needles from damaging. Put the distance
plate onto the sample stage and then the TFC 100 over the distance plate, so that the
Figure 161: Liquid temperature controlled
device TFC 100
liquid connectors show to the illumination. Guide the two pins on the bottom of the TFC
100 into the two corresponding holes of the distance plate. Plug the Pt 100 cable to the
corresponding sockets on the OCA. Connect the quick fitting couplings to a liquid
thermostat.
Operation Before you start with the measuring be sure that the desired temperature is
balanced. Tilt the dosing unit to prevent the needles from damaging. Move down the
stage. Now you can open the housing of the TFC 100. Place the sample into the housing.
Move up the stage and re-tilt back the dosing unit. Wait, until sample and needle has
reached the desired temperature. Now you can perform the measurement in the usual
Figure 162: TFC 100 Diffuser
way. If you measure below room temperature, the glasses could show condensation. To
prevent the glasses from condensation you can use a diffuser, connected to a nitrogen
source, instead of the distance plate.
Some accessible surfaces can become very hot. Therefore, please wait until
the system has cooled down sufficiently and the temperature allows you
to touch the system without danger, or use specific hand protectors.
page 98
OCA
7.4.2 SHD
Syringe heating device For measurements below or above room temperature, e.g. for
measuring of temperature coefficients, as well as under protective atmosphere. For use
with a liquid circulator, e.g. the liquid cryostat F25 MV. The temperature setting can be
done only manually at the circulator.
The SHD is designed to be used with the TFC 100 and one of the single direct dosing units
SD-D, SD-DM or SD-DE.
If you use it with a TEC 400 the PT 100 sensor must be taken out.
Features of the SHD:
Installation Tilt the dosing unit and guide the pin on the back of the ES-D into the corresponding hole of the single direct dosing unit. Plug the Pt 100 cable to the corresponding
sockets on the OCA. Connect the quick fitting couplings to a liquid thermostat (if
necessary in a row with the TFC 100).
Operation Fill the syringe with the test liquid and mount the needle. Open the lid of the
SHD by means of the knurled screw and put in the syringe. Before you start with the
measuring be sure that the desired temperature is balanced. Tilt the dosing unit to
prevent the needles from damaging. Move down the stage. Now you can open the
housing of the TFC 100. Place the sample into the housing. Move up the stage and re-tilt
back the dosing unit. Wait until sample, syringe and needle have reached the desired
temperature. Now you can perform the measurement in the usual way.
Some accessible surfaces can become very hot. Therefore, please wait until
the system has cooled down sufficiently and the temperature allows you
to touch the system without danger, or use specific hand protectors.
OCA Manual
page 99
Pt 100 to OCA
Pt 100 to TC 150
Power connector to TC 150
Alarm LED
the connection cable to the corresponding socket on the TC 150 and the
Pt 100 Connector
cooling water to the plate. If you need, you can connect the inert gas
and
or decrease
press it longer the change of the value becomes faster and faster. Before
you start with the measuring be sure, that the desired temperature is
balanced. Move up the dosing needle by means of quick movement
knob on the needle holder. Move down the stage. Now you can open the
Power connector
housing of the TPC 150. Place the sample into the housing. Move up the
with fuse
stage and down the needle into the housing. Wait until sample and
needle have reached the desired temperature. Now you can perform the
measurement in the usual way.
page 100
OCA
If the red alarm LED gets on it indicates that the controller states an irregular condition
OUT1
OUT2
OUT3
OUT4
and is switching of the heating power. If you have eliminated the fault, you need to reset
the controller by switching off and on.
PV
MAN
AUX
REM
SV
the system has cooled down sufficiently and the temperature allows you
to touch the system without danger, or use specific hand protectors.
A Peltier element works to the principle of a heat pump. The possible temperature
difference lay in the range of 40K to 80K. To reach the desired temperature it could be
necessary to adjust the temperature of the cooling liquid (see table below).
Table 3: Relation between temperature of cooling liquid and measuring temperature
Minimum temperature
Maximum temperature
20 C
- 20 C
110 C
70 C
15 C
150 C
OCA Manual
page 101
Pt 100 to OCA
Pt 100 to TC 150
Cover plates for the optimization of the needle entry gap for
varying problems
Installation If any other sample stage adapter is already installed, take it apart from the
sample stage. Tilt the dosing unit to prevent the needles from damaging. Position the TEC
400 over the sample stage. Guide the two holes in the bottom of the TEC 400 over the
two corresponding holes of the sample stage. Plug the control-Pt 100 cable to the corresponding sockets on the TC 400. If you want to measure the temperature in the chamber,
you need an additional Pt 100 connected to the OCA. Connect the connection cable to the
corresponding socket on the TC 400. Connect the cooling air (reduces the time needed to
cool down) to the plate and/or cover and the inert gas onto the back of the TEC 400.
Power LED
Alarm LED
Pt 100 connector
Operation The manual temperature setting will be done directly on the temperature
temperature controller
controller TC 400. Below the display with the actual value and the setting value, there are
is for selecting the operation mode and
and
you press and release quickly you select the digit of the setting value, if you press it longer
Power-connector,
or decrease
Connector from
the set temperature (if you press it longer the change of the set value becomes faster and
will decrease
faster).
Before you start with the measuring be sure that the desired temperature is balanced. Tilt
the dosing unit to prevent the needles from damaging. Move down the stage. Now you
can open the housing of the TEC 400. Place the sample into the housing. Move up the
stage and down the needle into the housing. Wait until sample and needle has reached
the desired temperature. Now you can perform the measurement in the usual way.
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OCA
If the red alarm LED gets on it indicates that the controller states an irregular condition
A1
A2
PV
C F
and is switching of the heating power. If you have eliminated the fault, you need to reset
the controller by switching off and on.
SV
OUT
the system has cooled down sufficiently and the temperature allows you
controller KS 20 or KS 20i
7.4.6 Software-control
The software control of the temperature control devices TEC 400, NHD 400 an HTFQ 1200
is nearly identical. Therefore, in this manual only the control of the TC 400 is described.
Before you start the first measurement, you
should enter the preferences. In the menu Edit>
Figure 171: Preferences for Temperature controller TC 400 and NHD 400 (KS20)
Disp. Unit To select the unit (C = degree Celsius or F = degree Fahrenheit) for the
controller display.
OCA Manual
page 103
Fahrenheit or K = Kelvin).
Figure 173: Dialog Edit TC-Program
A click to new Program enlarges the dialog and shows a graph for the TC program (in the
middle) and (on the right side) the controls.
per minute. It will be calculated out of ramp time and the temperature difference. If you
enter a value the ramp time remain the same, and the temperature will be calculated out
of the gradient and the ramp time.
Ramp time To show or edit the time or a condition for the actual segment.
means that the new segment (ramp) will not start until the actual temperature
is inside the range of the start temperature. The range for this condition is entered in the
edit box below
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OCA
After creation of a TC Program you can open the dialog for the temperature controller in
Device Control.
In the upper control you can select a stored TC Program with a click to the button
Single step mode If selected the program stops at the end of every segment. To
continue the program you must click to Run again.
const. Temperature To define a constant temperature. You can set the constant
temperature by moving the slider left and right, by entering the value, or by clicking to
one of the buttons
OCA Manual
page 105
on a solid sample. Initial pick-up of the liquid amount from an aluminum sample
vessel with a liquid/melt reservoir.
Manually or software controlled temperature setting with PID controller
TC 400/NHD
Consisting of:
Temperature measuring and controlling sensor for the electrically heated cover
3 dosing cannulas made from stainless steel (outer diameter = 1.65 mm)
Heating carrier with fine adjustment screws for the axial and horizontal cannula
positioning
Serial connection cable in Y-form for two controllers (NHD 400 and TEC 400).
Installation If any other dosing unit is already installed, take it apart from the OCA. To
install the NHD 400 dosing bay loosen the two nuts on each side by means of the hex
screws (wrench size 3) and place it over the guidance. Adjust the position of the dosing
bay so that the hinges are congruent with the base. Plug the sensor cable to the
corresponding socket on front of the TC 400/NHD. Connect the power connection cable
to the corresponding socket on the back of the TC 400/NHD. Connect the cooling air to
the NHD 400 cooling air connectors (C).
Power LED
Alarm LED
Pt 100 connector
Never use the NHD 400 without the air-cooling. Without cooling some
bearings and seals can be damaged.
Some accessible surfaces can become very hot. Therefore, please wait until
the system has cooled down sufficiently and the temperature allows you
Serial connector
Fuse for controller
Power-connector,
-selector and -fuse
Connect the serial connection cable to the OCA, to the TC 400/NHD and if available to the
TC 400. Move the heating device up using the fast adjusting screw (E). Put the cannula
Connector from
adapter (made of three parts) and the cannula into the heating device. Mount the piston
NHD 400
of the cannula into the movable dosing holder and fix it with the knurled screw (F).
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OCA
Exchange of piston and cannula Open the fast adjustment screw (F) and move the
piston holder (pull and turn on knob A) in his highest position. Open the knurled screw (E)
of the piston holder and take the piston out.
If you want to take out the cannula, you must open the knurled nut (H). Take out the
cannula by pressing a tool (i.e. a small screwdriver) to the cannula from the bottom of the
heating carrier (D).
Manual operation The manual temperature setting will be done directly on the
temperature controller TC 400/NHD. Below the display with the actual value and the
setting value, there are three silicone rubber buttons. The left button
the operation mode and to program and is normally out of function.
If a KS20 controller is build in the other both buttons (
and
is for selecting
you press and release quickly you select the digit of the setting value, if you press it longer
the selected digit will increase
or decrease
A1
A2
PV
C F
will decrease
the set temperature (if you press it longer the change of the set value becomes faster and
faster).
SV
OUT
If the red alarm LED gets on it indicates that the controller states an irregular condition
and is switching of the heating power. If you have eliminated the fault, you need to reset
the controller by switching off and on.
Before you start with the measuring be sure that the desired temperature is balanced
in the TEC 400 and in the NHD 400.
Fill the aluminum sample vessel. The vessel must be filled right up. The surface of the
Cannula
Piston
sample should wet the complete vessel surface and must be as flat as possible. Put
the aluminum sample vessel with the sample into the TEC 400 chamber. Give the
Sample
sample enough time to melt. Bring the piston in the cannula down to its lowest
position using the dosing screw (A). Lower the NHD 400 by means of the fine
Aluminium
adjustment screw (B) down to the surface of your sample. Soak up the sample
sample vessel
moving the piston up by turning the dosing screw (A). Now you can dose a droplet
out the cannula for a pendant or a sessile drop measuring.
OCA Manual
page 107
Dip switches
Switch the OCA always off before you change the dipswitch setting of the
high-speed camera!
Table 4: Switch settings, resolution, speed and used DCF file for the high-speed cameras
Aspect ratio
1.167
1.167
1.167
1.167
all OFF
H2S752x484 60i.DCF
H2S750x484 30i.DCF
H2S752x240 120n.DCF
H2S752x110 240n.DCF
Switch settings
DCF-file
Aspect ratio
1.167
1.167
1.167
all OFF
H2S752x484 90i.DCF
H2S752x240 180n.DCF
H2S752x110 360n.DCF
Switch settings
DCF-file
program files\dataphysics\sca20\dcf\
In the subdirectories double or triple, you will find the necessary DCF files.
Before you start to measure must close and restart the software.
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OCA
Weight: 0.5 kg
Installation See chapter 4.1.2Installation of the dosing bay and dosing units page 17.
7.6.2 SD-DM
Single direct dosing unit New version of the SD-D. Used for dosing the test liquids
without a dosing tube (directly). On it a manual (MS) or electronic syringe unit ES can be
adapted. For use with the OCA devices without master electronics (OCA 5/10/15+) you can
adapt the direct electronic syringe unit ES/2-D.
Features of the SD-DM:
Weight: 0.8 kg
A
B
C
The electronic syringe unit ES can be mounted on three different positions in the SD-DM:
Upper position (A) For use with the longer captive bubble needles SNC.
Figure 190: SD-DM
Middle position (B) For use with the standard needles SNS or SNP.
Lower position (C) For use with the shorter disposable needles SNP-D.
OCA Manual
page 109
7.6.3 SD-DE
Single direct dosing unit for use with an E-MD Used for dosing the test liquids without a
dosing tube (directly). On it a manual (MS) or electronic syringe unit ES can be adapted.
For use with the OCA devices without master electronics (OCA 5/10/15+) you can adapt
the direct electronic syringe unit ES/2-D.
Features of the SD-DE:
Weight: 0.8 kg
7.6.4 LIA-MD
Liquid Injection unit Used for dosing liquids inside an existing drop to detect the
interfacial tension.
Features of the LIA-MD:
Weight: 0.9 kg
Glass cell Made of special optical glass for measuring the interfacial tension between
two fluids according to the Pendant and Captive (GC20) Drop method. For temperatures
up to 70 C, you can use the standard cells GC 10 and GC 20. For temperatures in the
range of 70 350 C you must use the special cells GC 10HT and GC 20HT made of
temperature inert glass.
Dimensions:
GC 10 and GC 10HT: 20 x 20 x 20 mm (Inner-L x W x H)
GC 20 and GC 20HT: 40 x 20 x 20 mm (Inner-L x W x H)
page 110
OCA
Installation If any other sample stage adapter is already installed, take it apart from the
Vacuum-connector
Adjustment screw
sample stage. Tilt the dosing unit to prevent the needles from damaging. Position the SP
100 over the sample stage. Guide the two pins on the bottom of the SP 100 into the two
corresponding holes of the sample stage.
Operation Place the sample onto the SP 100. With the adjustment screw, you can adjust
the size (size A, B or complete) of the suction area by turning the screw in or out.
7.6.6.2 FSC-80
Film sample clamp (Parallel clamping jaws) For fixing of flexible samples like films,
paper, leafs
Technical data:
Size: 100 x 80 mm
Installation If any other sample stage adapter is already installed, take it apart from
the sample stage. Tilt the dosing unit to prevent the needles from damaging. Lay the
FSC 80 onto the sample stage.
Operation Clamp the sample into the both parallel clamping jaws A and fix it with
the four knurled screws. To stretch the sample, turn the knurled screw B clockwise.
7.6.6.3 FSH-30
Film sample holder (Ring) For fixing of flexible samples, like films, textile .
Technical data:
Size: 40 x 15 mm
Installation If any other sample stage adapter is already installed, take it apart from the
sample stage. Tilt the dosing unit to prevent the needles from damaging. Lay the FSH 30
onto the sample stage.
Operation Clamp the sample between the both rings to stretch the sample.
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8 Maintenance
8.1 General
The OCA is continuously rated.
However, in spite of this, we recommend a regular maintenance once a year
by a service engineer from DataPhysics or the respective representation.
Internal work on the unit must only be done when the power
supply is disconnected and the mains cable has been pulled out!
The verification of the measuring is possible using the optical contact angle standards:
OCAS/HW
OCAS/YL
OCAS/PD
If the unit has a fault, please turn to the service departments of our representations or to
ourselves directly at:
DataPhysics Instruments GmbH
Raiffeisenstrae 34
D-70794 Filderstadt
Tel. ++49 (711) 770556-0
Fax ++49 (711) 770556-99
email info@dataphysics.de
Do not use any chemical products like strong solvents or acids to clean the
housing, in particular, the switches, lamps and sockets. Make sure that no
liquids get into the inside of the housing (for example by means of the
connecting sockets on the side of the OCA electronic housings). This leads to
the destruction of the unit and can lead to a hazardous short circuit.
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OCA
Move the sample table down and away from the illumination.
Open the 4 screws (A) (metric hex 2.0) on the inner lid. Remove the lower screws
first.
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9 Technical data
Technical data valid for all devices of the OCA series:
(L x W x H)
100 x 100 mm
(L x W)
160 x 160 mm 1)
0.. 180
Size of device
(L X W x H)
Weight
18 kg / 20 kg 1)
Power supply
Environmental specifications
Temperature
Operating
0 to 40 C
Non-operating
-10 to 60 C
Operating
10% to 80%
Non-operating
10% to 90%
26C
1) OCA L
Optics
Measuring methods
Optics
Measuring methods
Temperature measuring
2 x Pt100-inputs for -60 ... +450 C (Pt100 optional), 0.1 K resolution; accuracy: 1/3
DIN IEC 751 ( 0.03 %), class B
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OCA
110-2...2103 mN/m
tension
Optics
Video system
High performance image processing system with 132 Mbytes/s data transfer rate
(compatible to European-standard CCIR and US-standard RS-170)
Measuring methods
110-2...2103 mN/m
tension
Optics
Video system
High performance image processing system with 132 Mbytes/s data transfer rate
(compatible to European-standard CCIR and US-standard RS-170)
Measuring methods
Temperature measuring
2 x Pt100-inputs for -60 ... +450 C (Pt100 optional), 0.1 K resolution; accuracy: 1/3
DIN IEC 751 ( 0.03 %), class B
OCA Manual
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Additional technical data valid for OCAH 200 and OCA 230:
110-2...2103 mN/m
tension
Optics
Video system
high performance image processing system with 132 Mbytes/s data transfer rate
(compatible to European-standard CCIR and US-standard RS-170)
Measuring methods
60, 120 or 240 images/s digitizing speed (optional 90, 180 or 360 images/s)
Temperature measuring
2 x Pt100-inputs for -60 ... +450 C (Pt100 optional), 0.1 K resolution; accuracy: 1/3
DIN IEC 751 ( 0.03 %), class B
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OCA
10 Terms of Guarantee
DataPhysics guarantees the faultless functioning of this unit provided it is used and serviced appropriately and is connected and handled in accordance with these operating
instructions.
The guarantee is for two years from the date of delivery.
The place of the guarantee fulfilling is the respective representative or DataPhysics in
Filderstadt.
All guarantee and damage claims of the customer are forfeited if he has improperly
treated the supplied unit or has supplemented or worked on it or given it to a third party
for subsequent reconditioning without our prior approval.
DataPhysics entire liability and your exclusive remedy shall be at DataPhysics option,
either a) return of the price paid or b) repair or replacement of the unit that does not
meet DataPhysics limited guarantee and is returned to DataPhysics together with a copy
of the receipt. This limited guarantee is void if failure of the unit has resulted from accident, abuse, or misapplication. Any replacement delivery will only be warranted by DataPhysics for the remainder of the original guarantee period or 30 days, whichever is longer.
DataPhysics disclaims all further warranties with respect to the unit, and the accompanying manuals and written materials.
DataPhysics and its suppliers shall not be liable for any damages whatsoever (including,
without limitation, damages for loss of business profits, business interruption, loss of
business information, or other pecuniary loss) arising from the use or inability to use this
DataPhysics product, even if DataPhysics has been advised of the possibility of such damages. In any case, DataPhysics entire liability shall be limited to the amount actually paid
by you for this product. This limitation does not apply to damages, which were caused by
DataPhysics on intent or by gross negligence. Likewise, claims remain unaffected which
are based on mandatory legal rules regarding product liability.
Furthermore, the guarantee conditions of the " General conditions of supply for products
and services of the electrical industry" of the Zentralverband Elektrotechnik- und Elektronikindustrie (ZVEI) e. V., Stresemannallee 19, D-60596 Frankurt am Main apply.
OCA Manual
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11 Appendix
11.1 Requirements of the mains cable
The power supply of the OCA enable operation at a voltage supply with 90 264 Volts
Alternating Current (43 60 Hz).
The mains cable delivered with your OCA may not meet the requirements of the country
in which you are using the system.
You must, without fail, use a mains cable which meets the requirements of
the relevant country or the local Electricity Board.
The following information explains the requirements which are to be taken into account
when choosing a mains cable.
General information
The mains cable must be permitted (authorized) for the country in which it is used.
The mains cable must have the UL release and the CSA certificate
Type SV or comparable
3 phase
The mains plug must be shockproof plug of the type NEMA 5-15P (15A, 125V) or NEMA
6-15P (15A, 250V).
Other countries
The connectors of the mains cable must carry the approval certificate of the respective country (see table below):
BSI (Great Britain)
NEMKO (Norway)
CEBEC (Belgian)
OVE (Austria)
DEMKO (Denmark)
SEMKO (Sweden)
EANSW (Australia)
SETI (Finland)
IMQ (Italy)
SEV (Switzerland)
KEMA (Netherlands)
UTE (France)
VDE (Germany)
The cable must be a three-phase HAR cable of the type HO5VV-F3 with a minimum
phase-diameter of 2.5 mm2 .
The mains cable must have a minimum current-carrying capacity of 20 A, and according to the country, have a nominal voltage of 125 V or 250 V Alternating current.
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OCA
Japan
In Japan, the following cable types and connected loads are required:
All parts of the cable (cable, box, and plug) must have the trademark and the registry
number according to the Japanese Dentori Law.
3.2 mm2
3 phase
The mains plug must be a 2 pin shock-proof plug according to the Japanese Industrial
Standard (15A, 125V).
6 000 005
6 000 006
6 000 007
SNS 052/026; Dosing needle Outer- 0.52 mm; Inner- 0.26 mm; Length
51 mm; viscosity up to 120 mPas (e.g. Dipropylene glycol)
6 000 011
SNS 107/069; Dosing needle Outer- 1.07 mm; Inner- 0.69 mm; Length 51
mm; viscosity up to 3000 mPas (e.g. Glycerin)
6 000 027
SNP 165/119; Dosing needle Outer- 1.65 mm; Inner- 1.19 mm; Length 51
mm; viscosity up to 3000 mPas (e.g. Glycerin)
6 000 028
SNP 277/069; Dosing needle Outer- 2.41 mm; Inner- 1.80 mm; Length 51
mm; viscosity up to 3000 mPas (e.g. Glycerin)
6 000 015
SNC 052/026; Dosing needle Outer- 0.52 mm; Inner- 0.26 mm; Length
50 mm; Width 15 mm; Upwards 7 mm; viscosity up to 50 mPas (e.g.
Diethylene glycol)
8 000 360
DT 300/03; PTFE dosing tube Inner- 0.3 mm; Length 300 mm; For fluids
up to 50 mPas viscosity (e.g. Diethylene glycol)
8 000 431
DT 300/10; PTFE dosing tube Inner- 1.0 mm; Length 300 mm; For fluids
up to 3000 mPas viscosity (e.g. Glycerin)
8 000 432
DT 400/03; PTFE dosing tube Inner- 0.3 mm; Length 400 mm; For fluids
up to 20 mPas viscosity (e.g. Ethylene glycol)
8 000 361
DT 400/05; PTFE dosing tube Inner- 0.5 mm; Length 400 mm; For fluids
up to 150 mPas viscosity (e.g. 1.5-Pentane diole)
8 000 433
DT 400/10; PTFE dosing tube Inner- 1.0 mm; Length 400 mm; For fluids
up to 3000 mPas viscosity (e.g. Glycerin)
8 000 502
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8 000 149
6 000 017
GC 10; Glass cell 20 x 20 x 20 mm (Inner-L x W x H); Glass cell made of special optical glass for measuring the interfacial tension between two fluids
according to the Pendant Drop method; up to 70 C
6 000 021
6 000 018
6 000 022
8 000 136
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EN 50081-1 (1992)
EN 50082-1 (1993)
Diese Erklrung wird verantwortlich fr den Hersteller: / This declaration is given under sole responsibility of: / Cette
dclaration engage le constructeur:
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