DATA ENTRY FOR FUEL GAS COMBUSTION:(19 components maximum) Gas Page 1

ENTER RUN ID IN NEXT LINE BELOW:

EXAMPLE FUEL GAS RUN 12/04/97
Entry values in blue MUST be a number or a 0 MORE ENTRIES:
FUEL GAS ENTRIES: GROSS HT. RELEASE (GHR), BT 200,000,000
COMPONENTS MOL % AMBIENT TEMP., DEG F 77
H2 9.00 REL. HUMIDITY, % 60
C1 64.00 EXCESS COMB. AIR, % 12.00
C2 14.00 AIR PREHEAT TEMP., DEG F 77
C2= 5.50
C3 3.00 CALCULATED VALUES:
C3= 0.00 AIR PREHEAT TEMP., DEG K 298.15
C4 0.00 MOL % O2 IN DRY FLUE GAS 2.469
C4= 0.00 FUEL, LBS/1OO MOLS 1,843.2
C5 0.00 AVG. FUEL MOL WT 18.432
C5= 0.00 FUEL, BTU/100 MOLS 41,363,002
C6 0.00 AVG. FUEL HHV, BTU/LB 22,441
H2S 0.60 AVG. FUEL HHV, BTU/SCF 1,090.0
COS 0.00 FUEL, LBS/HR 8,912
CO 0.00 FUEL, SCF/HR 183,483
CO2 0.00 FUEL, MOLS/HR 483.524
O2 0.00 AIR SAT. PRESS., PSIA 0.4588
N2 0.00 LBS H2O/LB DRY AIR 0.0119
H2O 3.90 COMBUSTION PRODUCTS, MOLS/HR:
NH3 0.00 N2 0.000
100.00 CO2 541.547
SO2 2.901
H2O 979.619
STOICH. O2 REQD., MOLS/HR 1034.258
NOTES: COMBUSTION AIR, MOLS/HR:
-- 1 SCF is a standard cubic foot at 60 deg F O2 1158.369
and 1 atmosphere N2 4357.672
-- Mols are pound-mols H2O 105.245
-- APH is Air Preheat, Btu/hr WET FLUE GAS, MOLS/HR:
-- Hv is heat of vaporization of water at 298 deg CO2 541.547
-- GHR is gross heat release (HHV), Btu/hr N2 4357.672
O2 124.111
SO2 2.901
H2O 1103.722
TO CALCULATE THE FLAME TEMPERATURE: APH, BTU/HR 10,154
Hv, BTU/HR 18,532,440
The adiabatic flame temperature is automatically GHR-Hv+APH, BTU/HR 181,477,714
calculated as follows: TRIAL T, DEGREES K 2,165.87
N*H for CO2 13,567,344
(1) The TRIAL T in cell E47 must be set at a value of a N*H for N2 62,934,433
least 1,500 to 2,000 and then press ENTER. N*H for O2 1,923,435
(2) Click on TOOLS and then on SOLVER. Then, in th N*H for SO2 68,921
Solver Parameters dialogue box, click on Solve andN*H for H2O 22,326,819
the adiabatic flame temperature will be calculated HEAT IN - HEAT OUT 0
and displayed in E47. Finally, click on OK.
(3) Cell E53 should then have a value of 0.
Gas Flame Temp

2174.9237403

Page 2
Gas Combustion

2165.8656871

Page 3
EXAMPLE FUEL GAS RUN 12/04/97 Gas Page 2

FUEL GAS DATA: HHV

MW Btu/lb lb-mols/hr mol %
H2 2.016 ### 43.517 9.000
C1 ### ### 309.455 ###
C2 ### ### 67.693 ###
C2= ### ### 26.594 5.500
C3 ### ### 14.506 3.000
C3= ### ###
C4 ### ###
C4= ### ###
C5 ### ###
C5= ### ###
C6 ### ###
H2S ### 7,119 2.901 0.600
COS ### 3,915
CO ### 4,348
CO2 ### 0
O2 ### 0
N2 ### 0
H2O ### 0 18.857 3.900
483.524 ###

FUEL GAS RATE, SCF/hr 183,483

FUEL GAS RATE, lbs/hr 8,912
AVERAGE MW 18.43
AVERAGE HHV, Btu/lb 22,441
AVERAGE HHV, Btu/SCF 1,090.0
HEAT RELEASE (HHV), Btu/hr ###

COMBUSTION AIR DATA:

AMBIENT TEMPERATURE, degrees F 77
AMBIENT RELATIVE HUMIDITY, % 60
AIR PREHEAT TEMPERATURE, degrees F 77
SPECIFIED EXCESS COMBUSTION AIR, % 12.00
CALCULATED COMBUSTION AIR, lbs/hr:
N2 122,071
O2 37,067
H2O 1,896
Total air 161,034

CALCULATED COMBUSTION AIR, SCF/hr 2,133,109

CALCULATED H2O CONTENT, lbs/lb of dry air 0.0119
CALCULATED ADIABATIC FLAME TEMPERATURE, de 3,439

NOTES:
-- 1 SCF is a standard cubic foot at 60 deg F and 1 atmosphere
-- 1 lb-mol is 379.47 SCF
-- Dry air mol wt is 28.850 (79 mol % N2, 21 mol % O2)
-- Atmospheric pressure is 14.696 psia
EXAMPLE FUEL GAS RUN 12/04/97 Gas Page 3

WET FLUE GAS (WFG):

MW lb-mols/hr lbs/hr mol %

CO2 ### 541.55 23,833 8.834

N2 ### ### 122,071 71.088
O2 ### 124.11 3,971 2.025
SO2 ### 2.90 186 0.047
H2O ### ### 19,884 18.005
### 169,946 ###

TOTAL SCF/MM Btu of heat release 11,631

TOTAL SCF/hr of wet flue gas ###
AVERAGE MW 27.72
SO2, ppmv 473.3
WATER DEWPOINT, degrees F at 1 atmosphere 136.6

DRY FLUE GAS (DFG):

MW lb-mols/hr lbs/hr mol %

CO2 ### 541.55 23,833 10.774

N2 ### ### 122,071 86.699
O2 ### 124.11 3,971 2.469
SO2 ### 2.90 186 0.058
### 150,062 ###

TOTAL SCF/MM Btu of heat release 9,537

TOTAL SCF/hr of dry flue gas ###
AVERAGE MW 29.86
SO2, ppmv 577.2

NOTES:
-- 1 lb-mol is 379.47 SCF
-- 1 SCF is a standard cubic foot at 60 deg F and 1 atmosphere
-- 1 MM is one million or 1,000,000
-- 1 ppmv is one part per million by volume
DATA ENTRY FOR LIQUID FUEL COMBUSTION: Oil Page 1

ENTER RUN ID IN NEXT LINE BELOW:

EXAMPLE FUEL OIL RUN 12-04-97
Entry values in blue must be a number or a 0

ENTRIES: CALCULATED:
FUEL GRAVITY, deg API 15.5 FUEL SP.GR., LBS/GAL 8.0164
FUEL HHV, Btu/gal 150,000 FUEL HHV, BTU/LB 18,712
FUEL FIRED, gal/hr 5000 FUEL HHV, MMBTU/BBL 6.300
WT % Sulfur in fuel 0.75 FUEL FIRED, LBS/HR 40,082
WT % Nitrogen in fuel 0.55 GROSS HT. RELEASE (GHR), BTU 750,000,000
C/H RATIO BY WEIGHT 8.06
AMBIENT TEMP., deg F 75
REL HUMIDITY, % 70 AIR SAT. PRESS., PSIA 0.4292
EXCESS COMB. AIR, % 15 LBS H2O/LB DRY AIR 0.0130
AIR PREHEAT TEMP., D 400
AIR PREHEAT TEMP., DEG K 478
MOL % O2 IN DRY FLUE GAS 2.880
NOTES:
1 MM is one million or 1,000,000 FUEL, MOLS/HR:
1 gal is one U.S. gallon or 3.785 liters S 9.38
1 bbl is one barrel or 42 U.S. gallons or 159 liter N2 7.87
Mols are pound-mols H2 2166.78
APH is Air Preheat, Btu/hr C 2930.04
Hv is water's heat of vaporization at 298 deg K, COMBUSTION AIR, MOLS/HR:
O2 4626.23
N2 17403.42
H2O 459.53

TO CALCULATE THE FLAME TEMPERATURE: APH, BTU/HR 50,556,106

Hv, BTU/HR 40,991,192
The adiabatic flame temperature is automatically GHR-Hv+APH, BTU/HR 759,564,914
calculated as follows: TRIAL T, DEGREES K 2,305.89
N*H for CO2 80,145,956
(1) The TRIAL T in cell E35 must be set at a value of N*H for N2 272,756,337
least 1,500 to 2,000 and then press ENTER. N*H for O2 10,095,988
(2) Click on TOOLS and then on SOLVER. Then, in t N*H for SO2 242,970
Solver Parameters dialogue box, click on Solve and N*H for H2O 58,739,257
the adiabatic flame temperature will be calculated HEAT IN - HEAT OUT 0
and displayed in E35. Finally, click on OK.
(3) Cell E41 should then have a value of 0.
Oil Flame Temp

2305.8058324

Page 7
EXAMPLE FUEL OIL RUN 12-04-97 Oil Page 2

LIQUID FUEL DATA:

GRAVITY, lbs/gal 8.016

GRAVITY, degrees API 15.5

SULFUR CONTENT, wt % 0.75

NITROGEN CONTENT, wt % 0.55

C/H RATIO, by weight 8.06

FUEL RATE, lbs/hr 40,082

FUEL RATE, gals/hr 5,000.0

HHV, Btu/lb 18,712

HHV, Btu/gal 150,000
HHV, MM Btu/bbl 6.300

HEAT RELEASE (HHV), Btu/hr 750,000,000

COMBUSTION AIR DATA:

AMBIENT TEMPERATURE, degrees F 75

AMBIENT RELATIVE HUMIDITY, % 70
AIR PREHEAT TEMPERATURE, degrees F 400
SPECIFIED EXCESS COMBUSTION AIR, % 15.00
CALCULATED COMBUSTION AIR, lbs/hr:
N2 487,522
O2 148,035
H2O 8,278
643,835

CALCULATED COMBUSTION AIR, SCF/hr 8,533,966

CALCULATED H2O CONTENT, lbs/lb of dry air 0.0130
CALCULATED ADIABATIC FLAME TEMPERATURE, 3,691

NOTES:
-- Atmospheric pressure is 14.696 psia
-- Dry air mol wt is 28.850 (79 mol % N2, 21 mol % O2)
-- 1 MM is one million or 1,000,000
-- Molecular Weights:
C 12.011
H2 2.016
O2 31.999
S 32.060
N2 28.013
H2O 18.015
EXAMPLE FUEL OIL RUN 12-04-97 Oil Page 3

WET FLUE GAS (WFG):

MW lb-mols/hr lbs/hr mol %

CO2 44.010 2,930.04 128,951 12.426

N2 28.013 ### 487,742 73.838
O2 31.999 603.42 19,309 2.559
SO2 64.059 9.38 601 0.040
H2O 18.015 2,626.31 47,313 11.138
### 683,916 ###

TOTAL SCF/MM Btu of heat release 11,931

TOTAL SCF/hr of wet flue gas 8,948,067
AVERAGE MW 29.00
SO2, ppmv 397.6
WATER DEWPOINT, degrees F at 1 atmosphere 118.8

DRY FLUE GAS (DFG):

MW lb-mols/hr lbs/hr mol %

CO2 44.010 2,930.04 128,951 13.983

N2 28.013 ### 487,742 83.092
O2 31.999 603.42 19,309 2.880
SO2 64.059 9.38 601 0.045
### 636,603 ###

TOTAL SCF/MM Btu of heat release 10,602

TOTAL SCF/hr of dry flue gas 7,951,461
AVERAGE MW 30.38
SO2, ppmv 447.5

NOTES:
-- 1 lb-mol is 379.47 SCF
-- 1 SCF is a standard cubic foot at 60 deg F and 1 atmosphere
-- 1 MM is one million or 1E6
-- 1 ppmv is one part per million by volume
 DATA ENTRY FOR SOLID FUEL COMBUSTION: Solid Page 1

ENTER RUN ID ON NEXT LINE BELOW:

EXAMPLE COAL RUN 12-04-97
Entry values in blue must be a number or a 0
SOLID FUEL ENTRIES: CALCULATED:
COMPONENTS WT % LBS/HR LB-MOLS/HR
C 61.20 57,528 4,789.61
H 4.30 4,042 2,004.96
O 7.40 6,956 217.38
S 3.90 3,666 114.35
N 1.20 1,128 40.27
ASH 12.00 11,280
H2O 10.00 9,400 521.79
100.00 94,000
MORE ENTRIES:
FUEL RATE, LBS/HR 94,000 FUEL RATE, SHORT T/D 94,000
HHV, BTU/LB 11,150 GROSS HEAT RELEASE (GHR), BT ###
AMBIENT TEMP., DEG F 75 AIR SAT. PRESS., PSIA 0.4292
REL. HUMIDITY, % 70 LBS H20/LB DRY AIR 0.0130
AIR PREHT TEMP., DEG F 400 AIR PREHEAT TEMP., DEG K 478
EXCESS COMB. AIR, % 20.00 COMBUSTION AIR, MOLS/HR:
SULFUR TO ASH, % 10.0 O2 6856.622
N2 25793.958
H2O 681.073
MOL % O2 IN DRY FLUE GAS 3.695
TO CALCULATE THE FLAME TEMPERATURE: APH, BTU/HR 74,930,342
Hv, BTU/HR 47,846,495
The adiabatic flame temperature is automatically (GHR-Hv+APH), BTU/HR ###
calculated as follows: TRIAL T, DEG K 2,217.20
N*H for CO2 124,002,919
(1) The TRIAL T in cell H33 must be set at a value of N*H for N2 384,631,008
least 1,500 to 2,000 and then press ENTER. N*H for O2 18,804,237
(2) Click on TOOLS and then on SOLVER. Then in t N*H for SO2 2,527,348
Solver Parameters dialogue box, click on Solve andN*H for H2O 67,358,849
the adiabatic flame temperature will be calculatedHEAT IN - HEAT OUT 0
and displayed in H33. Finally, click on OK.
(3) Cell H39 should then have a value of 0.

SPRAY DRYING: ENTRIES: CALCULATED:

SO2 REMOVAL, % 85.0 AVG. FLUE GAS TEMP., DEG K 373.61
FG TEMP. IN, DEG F 285 FLUE GAS DELTA T, DEG F 145.00
FG TEMP. OUT, DEG F 140 H20 LHV, BTU/LB 1056.34
WATER TEMP. IN, DEG F 65 FLUE GAS SP. HTS., BTU / MOL / DEG F:
CO2 9.9631
N2 6.8736
NOTES: O2 7.0217
-- Short ton = 2000 lbs SO2 9.5643
H20 8.4631
 Solid Flame Temp

2002.5523029

Page 11
EXAMPLE COAL RUN 12-04-97 Solid Page 2

SOLID FUEL DATA:

wt % lbs/hr
C 61.20 57,528
H 4.30 4,042
O 7.40 6,956
S 3.90 3,666
N 1.20 1,128
ASH 12.00 11,280
H2O 10.00 9,400
### 94,000

SOLID FUEL RATE, lbs/hr 94,000

SOLID FUEL RATE, short tons/day #REF!

HHV, Btu/lb 11,150

HEAT RELEASE (HHV), Btu/hr ###

(All of the above data are on a wet fuel basis)

SULFUR REPORTING TO ASH, % 10

COMBUSTION AIR DATA:

AMBIENT TEMPERATURE, degrees F 75

AMBIENT RELATIVE HUMIDITY, % 70
AIR PREHEAT TEMPERATURE, degrees F 400
SPECIFIED EXCESS COMBUSTION AIR, % 20.00
CALCULATED COMBUSTION AIR, lbs/hr:
N2 722,566
O2 219,405
H2O 12,270
Total air 954,241

CALCULATED COMBUSTION AIR, SCF/hr 12,648,362

CALCULATED H2O CONTENT, lbs/lb of dry a 0.0130
CALCULATED ADIABATIC FLAME TEMP., d 3,531

NOTES:
-- Atmospheric pressure is 14.696 psia
-- Dry air mol wt is 28.850 (79 mol % N2, 21 mol % O2)
-- Short ton = 2000 lbs
-- Molecular weights:
C ###
H2 2.016
O2 ###
S ###
N2 ###
H2O ###
EXAMPLE COAL RUN 12-04-97 Solid Page 3

WET FLUE GAS (WFG):

MW lb-mols/hr lbs/hr mol %

CO2 44.010 4,789.61 210,791 13.640

N2 28.013 25,834.23 723,694 73.573
O2 31.999 1,179.00 37,727 3.358
SO2 64.059 102.91 6,593 0.293
H2O 18.015 3,207.82 57,789 9.136
35,113.57 ### 100.000

TOTAL SCF/MM Btu of heat release 12,713

TOTAL SCF/hr of wet flue gas 13,324,546
AVERAGE MW 29.52
SO2, ppmv 2930.9
WATER DEWPOINT, degrees F at 1 atmosphere 111.8

DRY FLUE GAS (DFG):

MW lb-mols/hr lbs/hr mol%

CO2 44.010 4,789.61 210,791 15.012

N2 28.013 25,834.23 723,694 80.970
O2 31.999 1,179.00 37,727 3.695
SO2 64.059 102.91 6,593 0.323
31,905.75 978,804 100.000

TOTAL SCF/MM Btu of heat release 11,552

TOTAL SCF/hr of dry flue gas 12,107,274
TOTAL Ncm/MT of fuel (at 12 vol % CO2 in DFG) 9,517
AVERAGE MW 30.68
SO2, ppmv 3225.5

NOTES:
-- 1 lb-mol is 379.47 SCF
-- 1 SCF is a standard cubic foot at 60 deg F and 1 atmosphere
-- 1 Ncm is a normal cubic meter at 0 deg C and 1 atmosphere
-- 1 Ncm is 37.3244 SCF
-- 1 MT is one metric ton or 2204.6 pounds
-- 1 MM is one million or 1,000,000
-- 1 ppmv is one part per million by volume
EXAMPLE COAL RUN 12-04-97 Solid Page 4

EXIT WET GAS FROM SPRAY DRYING:

MW lb-mols/hr lbs/hr mol %

CO2 44.01 4,789.61 210,791 12.984

N2 28.013 25,834.23 723,694 70.034
O2 31.999 1,179.00 37,727 3.196
SO2 64.059 15.44 989 0.042
H2O 18.015 5,069.70 91,331 13.744
36,887.97 ### 100.00

SPECIFIED SO2 REMOVAL ACROSS SCRUBBER, % 85

SPECIFIED INLET GAS TEMPERATURE, degrees F 285
SPECIFIED OUTLET GAS TEMPERATURE, degrees F 140
SPECIFIED INLET WATER TEMPERATURE, degrees F 65

CALCULATED WATER EVAPORATION, lbs/hr 33,542

TOTAL SCF/hr of wet exit gas 13,997,879

AVERAGE MW 28.86
SO2, ppmv 418.5

WATER DEWPOINT, degrees F at 1 atmosphere 126.4

EXIT DRY GAS FROM SPRAY DRYING:

MW lb-mols/hr lbs/hr mol %

CO2 44.01 4,789.61 210,791 15.053

N2 28.013 25,834.23 723,694 81.193
O2 31.999 1,179.00 37,727 3.705
SO2 64.059 15.44 989 0.049
31,818.27 ### 100.00

TOTAL SCF/min of dry exit gas 201,235

CO2 in dry exit gas, vol % 15.053
O2 in dry exit gas, vol % 3.705

NOTES:
-- See pages 1, 2 and 3
-- The spray drying system removes SO2 from the flue gas by injecting atomized water and lime slurry into
a scrubber/absorber tower where most of the water is evaporated by the hot flue gas and the lime reacts
with the SO2 to form a fine, dry powder which is then removed from the flue gas.