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Learning Goal: To understand the quantitative relationships related to ideal (Carnot) engines and the limitations of such
devices imposed by the second law of thermodynamics.
In 1824, Sadi Carnot, a French engineer, introduced a theoretical engine that has been since then called a Carnot engine, the
most efficient engine possible. The following statement is known as Carnot's theorem:
No engine operating between a hot and a cold reservoir can be more efficient than the Carnot engine that
operates between the same two reservoirs.
The Carnot engine operates cyclically, just like any real engine.The Carnot cycle includes four reversible steps: two isothermal
processes and two adiabatic ones.
In this problem, you will be asked several questions about Carnot engines. We will use the following symbols:
: the absolute value (magnitude) of the heat absorbed from the hot reservoir during one cycle or during some time
specified in the problem;
: the absolute value (magnitude) of the heat delivered to the cold reservoir during one cycle or during some time
specified in the problem;
: the amount of work done by the engine during one cycle or during some time specified in the problem;
: the absolute temperature of the hot reservoir; and
: the absolute temperature of the cold reservoir.
Part A
In general terms, the efficiency of a system can be thought of as the output per unit input. Which of the expressions is a good
mathematical representation of efficiency of any heat engine?
ANSWER:
Part B
During the Carnot cycle, the overall entropy ________.
where we have taken all heat exchanged to be positive. Also, the definition of the entropy change when heat is
transferred at a temperature is
ANSWER:
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ANSWER: increases
decreases
remains constant
Part C
Which of the following gives the efficiency of the Carnot engine?
where we have taken all heat exchanged to be positive. Substitute for and in the earlier expression for the efficiency.
Also recall that
ANSWER:
Part D
Consider a Carnot engine operating between the melting point of lead ( ) and the melting point of ice ( ). What is the
efficiency of such an engine?
ANSWER: 0
0.455
0.545
1
infinity
Part E
We have stressed that the Carnot engine does not exist in real life: It is a purely theoretical device, useful for understanding the
limitations of heat engines. Real engines never operate on the Carnot cycle; their efficiency is hence lower than that of the
Carnot engine. However, no attempts to build a Carnot engine are being made. Why is that?
The Carnot cycle contains only reversible processes. To be reversible, a process must allow the system to equilibrate
with its surroundings at every step, which makes it infinitely slow; therefore, the Carnot engine, although the most
efficient, is the least powerful one! Its power is indeed zero, since work is being done at an infinitely slow rate.
Part F
A real heat engine operates between temperatures and . During a certain time, an amount of heat is released to the
cold reservoir. During that time, what is the maximum amount of work that the engine might have performed?
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where we have taken all heat exchanged to be positive. Substitute for and in the earlier expression for the efficiency.
Also recall that
ANSWER:
=
Learning Goal: To understand the meaning and applications of the second law of thermodynamics, to understand the meaning
of entropy, and perform some basic calculations involving entropy changes.
The first law of thermodynamics (which states that energy is conserved) does not specify the direction in which thermodynamic
processes in nature can spontaneously occur. For example, imagine an object initially at rest suddenly taking off along a rough
horizontal surface and speeding up (gaining kinetic energy) while cooling down (losing thermal energy). Although such a
process would not violate conservation of energy, it is, of course, impossible and could never take place spontaneously.
The second law of thermodynamics dictates which processes in nature may occur spontaneously and which ones may not. The
second law can be stated in many ways, one of which uses the concept of entropy.
Entropy
Entropy can be thought of as a measure of a system's disorder: A lower degree of disorder implies lower entropy, and vice
versa. For example, a highly ordered ice crystal has a relatively low entropy, whereas the same amount of water in a much less
ordered state, such as water vapor, has a much higher entropy. Entropy is usually denoted by , and has units of energy
divided by temperature ( ). For an isothermal process (the temperature of the system remains constant as it exchanges heat
with its surroundings), the change in a system's entropy is given by
where is the amount of heat involved in the process and is the absolute temperature of the system. The heat is positive
if thermal energy is absorbed by the system from its surroundings, and is negative if thermal energy is transferred from the
system to its surroundings.
Using the idea of entropy, the second law can be stated as follows:
The entropy of an isolated system may not decrease. It either increases as the system approaches equilibrium, or stays
constant if the system is already in equilibrium.
Any process that would tend to decrease the entropy of an isolated system could never occur spontaneously in nature. For a
system that is not isolated, however, the entropy can increase, stay the same, or decrease.
Part A
What happens to the entropy of a bucket of water as it is cooled down (but not frozen)?
ANSWER: It increases.
It decreases.
It stays the same.
Presumably, the bucket is not isolated: Heat must be transferred to another object, which is most likely at a lower
temperature than that of the bucket.
Part B
What happens to the entropy of a cube of ice as it is melted?
ANSWER: It increases.
It decreases.
It stays the same.
Part C
What happens to the entropy of a piece of wood as it is burned?
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ANSWER: It increases.
It decreases.
It stays the same.
When a solid object is turned into a gas, the degree of disorder increases, so the entropy increases.
Part D
An object at 20 absorbs 25.0 of heat. What is the change in entropy of the object?
ANSWER:
=
Part E
An object at 500 dissipates 25.0 of heat into the surroundings. What is the change in entropy of the object? Assume
that the temperature of the object does not change appreciably in the process.
Express your answer numerically in joules per kelvin.
ANSWER:
=
Part F
An object at 400 absorbs 25.0 of heat from the surroundings. What is the change in entropy of the object? Assume
that the temperature of the object does not change appreciably in the process.
Express your answer numerically in joules per kelvin.
ANSWER:
=
Part G
Two objects form a closed system. One object, which is at 400 , absorbs 25.0 of heat from the other object,which is at
500 . What is the net change in entropy of the system? Assume that the temperatures of the objects do not change
appreciably in the process.
Express your answer numerically in joules per kelvin.
ANSWER:
=
Note that the net entropy change is positive as the heat is transferred from the hotter object to the colder one. If heat were
transferred in the other direction, the change in entropy would have been negative; that is, the entropy of the system
would have decreased. This observation, not surprisingly, is in full accord with the second law of thermodynamics.
Learning Goal: To understand that a heat engine run backward is a heat pump that can be used as a refrigerator.
By now you should be familiar with heat engines--devices, theoretical or actual, designed to convert heat into work. You should
understand the following:
1. Heat engines must be cyclical; that is, they must return to their original state some time after having absorbed some heat
and done some work).
2. Heat engines cannot convert heat into work without generating some waste heat in the process.
The second characteristic is a rigorous result even for a perfect engine and follows from thermodynamics. A perfect heat engine
is reversible, another result of the laws of thermodynamics.
If a heat engine is run backward (i.e., with every input and output reversed), it becomes a heat pump (as pictured schematically ).
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Work must be put into a heat pump, and it then pumps heat
from a colder temperature to a hotter temperature , that is,
against the usual direction of heat flow (which explains why it is
called a "heat pump").
The heat coming out the hot side of a heat pump or the heat
going in to the cold side of a refrigerator is more than the work
put in; in fact it can be many times larger. For this reason, the ratio
of the heat to the work in heat pumps and refrigerators is called the
coefficient of performance, . In a refrigerator, this is the ratio of
heat removed from the cold side to work put in:
In a heat pump the coefficient of performance is the ratio of heat exiting the hot side to the work put in:
Take , and to be the magnitudes of the heat emitted and absorbed respectively.
Part A
What is the relationship of to the work done by the system?
ANSWER:
=
Part B
Find , the heat pumped out by the ideal heat pump.
ANSWER:
=
Part C
A heat pump is used to heat a house in winter; the inside radiators are at and the outside heat exchanger is at . If it is a
perfect (i.e., Carnot cycle) heat pump, what is , its coefficient of performance?
What is the efficiency of a heat pump in terms of the heats in and out? Use the expression for the efficiency of the
heat pump and the expression that you found involving the work done on the system, , and the outside heats, and
.
Give your answer in terms of and .
ANSWER:
=
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ANSWER:
=
Part D
The heat pump is designed to move heat. This is only possible if certain relationships between the heats and temperatures at
the hot and cold sides hold true. Indicate the statement that must apply for the heat pump to work.
ANSWER: and .
and .
and .
and .
Part E
Assume that you heat your home with a heat pump whose heat exchanger is at , and which maintains the baseboard
radiators at . If it would cost $1000 to heat the house for one winter with ideal electric heaters (which have a
coefficient of performance of 1), how much would it cost if the actual coefficient of performance of the heat pump were 75%
of that allowed by thermodynamics?
You are given that the cost of is $1000. You also have an equation for in terms of the temperatures:
% .
Set this equal to and solve for the monetary value of , the amount of external energy input the pump requires.
You can measure energies in units of currency for this calculation.
Keep in mind that when calculating an efficiency of a thermodynamic device you need to use temperature in kelvins. That is,
.
ANSWER:
Cost = dollars
This savings is accompanied by more initial capital costs, both for the heat pump and for the generous area of baseboard
heaters needed to transfer enough heat to the house without raising , which would reduce the coefficient of
performance. An additional problem is icing of the outside heat exchanger, which is very difficult to avoid if the outside
air is humid and not much above zero degrees Celsius. Therefore heat pumps are most useful in temperate climates or
where the heat can be obtained from a groundwater that is abundant or flowing (e.g., an underground stream).
Part A
The thermodynamic processes that occur in nature ____________.
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Only infinitely slow, or quasi-equilibrium, processes can be reversible; such processes exist only in the imaginations of
scientists.
Any process occurring in a closed system either increases the entropy (disorder) of the system or leaves it
constant. For irreveresible processes, the entropy increases; for the reversible ones, the entropy remains
constant.
Part B
According to the second law of thermodynamics, it is impossible for ____________.
The ideal engine follows a reversible cycle--therefore, an infinitely slow one. If the work is being done at the infinitely
slow rate, the power of such an engine is zero.
It is impossible to construct a cyclical heat engine whose sole effect is the continuous transfer of heat
energy from a colder object to a hotter one.
This statement is known as Clausius statement of the second law. Note the word "sole." Of course, it is possible to
construct a machine in which a heat flow from a colder to a hotter object is accompanied by another process, such as
work input.
Part C
If the coefficient of performance of a refrigerator is 1, which the following statements is true?
ANSWER: The temperature outside equals the temperature inside of the refrigerator.
The rate at which heat is removed from the inside equals the rate at which heat is delivered outside.
The power consumed by the refrigerator equals the rate at which heat is removed from the inside.
The power consumed by the refrigerator equals the rate at which heat is delivered to the outside.
Part D
To increase the efficiency of an ideal heat engine, one must increase which of the following?
Part E
How would you increase the coefficient of performance of an ideal refrigerator?
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The efficiency of an ideal/Carnot refrigerator that absorbs heat from a reservoir at a temperature , and releases
heat to another reservoir at a temperature , with a work input , is
From this equation, you can see that decreasing and/or increasing lead to an increase in the efficiency .
Part F
Why must every heat engine have a cold reservoir?
ANSWER: Because it is impossible for even a perfect engine to convert heat entirely into mechanical work.
Because the cold reservoir keeps the engine from overheating.
Because the cold reservoir keeps the engine from overcooling.
Because the cold reservoir increases the power of the engine.
It is impossible to construct a cyclical heat engine whose sole effect is absorption of energy from the hot
reservoir and the performance of the equal amount of work.
This statement is known as the Kelvin-Planck statement of the second law. Note the word "sole."
You have now seen three different statements of the second law. Understanding the equivalence of these three statements
is important. However, it is not a trivial matter: Your textbook and discussions should help you to get a better grasp of
this equivalency.
A Carnot Refrigerator
Description: A mix of conceptual and quantitative questions about ideal refrigerators.
The ideal Carnot engine operates cyclically, just like any real engine.The Carnot cycle includes four reversible steps: two
isothermal processes and two adiabatic ones. If the Carnot cycle is reversed, a Carnot refrigerator is created. This theoretical
device has the highest coefficient of performance among all refrigerators operating between given inside and outside
temperatures.
: the (positive) amount of heat delivered to the "outside" during one cycle or during some time specified in the
problem;
: the (positive) amount of heat absorbed from the "inside" during one cycle or during some time specified in the
problem;
: the amount of external work input during one cycle or during some time specified in the problem;
: the absolute temperature of the outside; and
: the absolute temperature of the inside.
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In general terms, the performance of a system can be thought of as the output per unit input. The coefficient of performance
of any refrigerator can be represented mathematically as
Part A
What is the coefficient of performance of the Carnot refrigerator?
where we have taken all heat exchanged to be positive. Substitute for and in the earlier expression for the efficiency.
Also recall that
ANSWER:
Part B
Imagine an ideal (Carnot) refrigerator that keeps helium in its liquid state, at a temperature of about 4.00 . The refrigerator,
with the helium container inside, is in a laboratory where the temperature is about 294 . Because of the imperfection of the
insulation, 2.00 of heat is absorbed by the refrigerator each hour. How much electrical energy must be used by the
refrigerator to maintain a temperature of 4.00 inside for one hour?
Use the formula you found in Part A to determine for this refrigerator.
ANSWER:
=
The refrigerator, i.e., the helium in it, absorbs 2.00 of heat every hour. For the helium to be maintained at the same
temperature, the same amount of heat must be removed from it also. Therefore .
ANSWER:
=
When the temperature difference is great, and is very low, the coefficient of performance is also very low, and the
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refrigerator requires a great deal of energy input to do the job. This partially explains why it is so expensive to produce
and maintain liquid helium. In this example, 145 of energy is required to extract only 2 from the refrigerator.
However, when the temperature difference is not so great, the refrigerators become much more efficient, as illustrated by
the next problem.
Part C
Imagine an ideal (Carnot) refrigerator that keeps soda bottles chilled to a temperature of about 280 . The refrigerator is
located in a hot room with a temperature of about 300 . Because of the imperfect insulation, 5.00 of heat is absorbed by
the refrigerator each hour. How much electrical energy must be used by the refrigerator to maintain the temperature of 280
inside for one hour?
Use the formula you found in Part A to determine for this refrigerator.
ANSWER:
=
ANSWER:
=
When the temperature difference is small, and is not too low, the refrigerator requires very little energy input: In our
example, it uses less than 0.4 to exhaust 5 from the refrigerator.
Part A
What is the sign of the change in entropy of the gas after one complete cycle?
ANSWER: positive
zero
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negative
In an ideal Carnot engine, where each process is reversible, the change in entropy of the gas and the change in entropy of
the surroundings are each exactly zero after each complete cycle. However, let us investigate what happens in a real process.
During the isothermal expansion, an amount of heat energy flows into the gas at a temperature . This results in an
increase in the gas's entropy of
However, heat energy will naturally flow into the gas from the surroundings only if there is a (slight) temperature difference
between the gas and the surroundings.
Part B
In a real isothermal expansion, the temperature of the surroundings must be________the temperature of the gas.
Part C
Because of this temperature difference, the magnitude of the entropy lost by the surroundings is ________ the magnitude of
entropy gained by the gas during a real isothermal expansion.
This is positive because the heat energy flows into the gas.
The change in entropy for the surroundings, which are at temperature , is given by
This is negative because the heat energy flows out of the surroundings. Also note that the temperature of the surroundings
must be slightly higher than the temperature of the gas in order for heat to flow from the surroundings into the gas.
Part D
Because of this difference in entropy change, the net entropy change of the entire system is ________ during a real isothermal
expansion.
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If the two terms have opposite signs, the term of larger magnitude will determine the sign of the total change in entropy. An
object's change in entropy is positive when heat energy flows into the object in question and negative when heat energy
flows out of it. Determine whether heat flows into or out of the gas and the surroundings to determine the signs of and
, respectively.
ANSWER: positive
negative
zero
Because there is no heat flow during an adiabatic process, there is no entropy change for either the gas or the surroundings.
(This is an approximation, but we can wrap the gas sample in lots of insulation to isolate it from the surroundings.)
During the isothermal compression, an amount of heat energy flows out of the gas at a temperature . This results in a
decrease in the gas's entropy of magnitude . However, heat energy will naturally flow out of the gas into the
surroundings only if there is a (slight) temperature difference between the gas and the surroundings.
Part E
In a real isothermal compression, the temperature of the surroundings must be ___________ the temperature of the gas.
Part F
Because of this temperature difference, the magnitude of the entropy gained by the surroundings is __________ the magnitude
of entropy lost by the gas during a real isothermal compression.
Complete the sentence above.
Part G
Because of this difference in entropy change, the net entropy change of the entire system is ________ during a real isothermal
compression.
Complete the sentence above.
ANSWER: positive
negative
zero
Therefore, although the net entropy change of the gas is still zero after a real Carnot-like cycle, the net entropy change of
the entire system is positive, because during both the isothermal expansion and compression phases the net change in
entropy of the system was positive. This is unavoidable and a manifestation of the second law of thermodynamics.
Part A
When the partition is removed, the gas expands and fills both compartments. How many moles of gas were initially
contained in the lower compartment if the entropy change of the gas in this free-expansion process is 17.28 ?
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When the partition is removed, the gas expands freely and no work is done. Thus the velocities of the gas molecules are
unaffected. However, now each molecule has a bigger volume in which it can move and the number of possible positions of
each molecule has increased. By considering the change in volume of the gas after the expansion, you can determine the
number of possible microscopic states. This information allows you to determine the change in entropy of the gas as a
function of the number of moles in the gas, and finally to find the number of moles in the gas.
Hint A.2 Find the number of possible microscopic states of a gas after a free expansion
Consider a thermally insulated box such as the one described in the introduction. Assume that the smaller compartment
contains molecules of gas, whereas the other is evacuated. When the partition is removed the gas expands and occupies
the entire box. The number of microscopic states of the system when the gas initially occupies a volume is . Find the
number of microscopic states when the gas occupies the entire box (volume ).
ANSWER:
=
Hint A.3 Find the microscopic expression for the change in entropy of a gas
Consider a gas that undergoes a thermodynamic process such that the gas is taken from an initial macroscopic state, where
the possible microscopic states are , to a final macroscopic state characterized by possible microscopic states. What is
the change in entropy of the gas after this process?
Express your answer in terms of some or all of the variables , , and the Boltzmann constant .
ANSWER:
=
Now, combine this result with the expression for the number of possible microscopic states of a gas after a free
expansion and solve for the number of molecules. Note that the problem asks for the number of moles of the gas, so
you need to express the number of molecules in terms of the number of moles. Remember that the Boltzmann constant
can be expressed in terms of the gas constant and Avogadro's number.
Recall the relation , where is the gas constant, is the Boltzmann constant, and is Avogadro's number.
ANSWER:
1.89
Part A
What is the net change in entropy of the system from the time of mixing until the moment the ice completely melts?
The heat of fusion of ice is .
Note that since the amount of ice is relatively small, the temperature of the water remains nearly constant throughout the
process. Note also that the ice starts out at the melting point, and you are asked about the change in entropy by the time it just
melts. In other words, you can assume that the temperature of the "ice water" remains constant as well.
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where is the amount of heat involved in the process and is the absolute temperature of the system. The heat is
positive if thermal energy is absorbed by the system from its surroundings, and is negative if thermal energy is transferred
from the system to its surroundings.
Express your answer numerically in joules per kelvin. Use two significant figures in your answer.
ANSWER:
As you would expect, in this spontaneous process the net change in entropy is positive: The entropy increases. This is
evident not just from the calculation but also from the fact that a crystal becomes liquid and hence the degree of disorder
increases.
Part A
Which of the following conditions should be met to make a process perfectly reversible?
ANSWER: Any mechanical interactions taking place in the process should be frictionless.
Any thermal interactions taking place in the process should occur across infinitesimal temperature or
pressure gradients.
The system should not be close to equilibrium.
Part B
Based on the results found in the previous part, which of the following processes are not reversible?
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first law of thermodynamics, which violate the second law of thermodynamics, and which of the remaining engines has the
highest thermal efficiency. (conceptual)
As part of your job at the patent office, you are asked to evaluate the six designs shown in the figure for innovative new heat
engines.
Part A
Which of the designs violate(s) the first law of thermodynamics?
Give the letter(s) of the design(s) in alphabetical order, without commas or spaces (e.g., ACD).
ANSWER: CF
Part B
Which of the remaining designs violate(s) the second law of thermodynamics?
An engine with thermal efficiency greater than that given by the above equation violates the second law of thermodynamics.
Give the letter(s) of the design(s) in alphabetical order, without commas or spaces (e.g., ABD).
ANSWER: BD
Part C
Which of the remaining designs has the highest thermal efficiency?
ANSWER: device A
device E
Part A
Rank these refrigerators on the basis of their performance coefficient.
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conservation of energy, the energy deposited in the hot reservoir is the sum of the work done on the refrigerator and the
energy removed from the cold reservoir.
A good refrigerator (with a large performance coefficient) will remove a large amount of heat energy from the cold reservoir
for a small amount of work input.
ANSWER:
View
Part B
The six refrigerators are placed in six identical sealed rooms. Rank the refrigerators on the basis of the rate at which they raise
the temperature of the room.
ANSWER:
View
Part A
Rank these engines on the basis of the change in entropy of the gas during the isothermal expansion phase of the cycle.
ANSWER:
View
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Part B
Rank these engines on the basis of the change in entropy of the gas during one complete cycle.
ANSWER:
View
Part A
Air conditioners operate on the same principle as refrigerators. Consider an air conditioner that has 7.00 of refrigerant
flowing through its circuit each cycle. The refrigerant enters the evaporator coils in phase equilibrium, with 54.0 of its mass
as liquid and the rest as vapor. It flows through the evaporator at a constant pressure and when it reaches the compressor 95
of its mass is vapor. In each cycle, how much heat is absorbed by the refrigerant while it is in the evaporator? The heat of
ANSWER:
=
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Now calculate the heat needed to transform this amount of refrigerant to vapor. Recall that the heat of vaporization is
defined as the amount of heat required to vaporize a unit mass of a given substance.
ANSWER:
=
Part B
In each cycle, the change in internal energy of the refrigerant when it leaves the compresser is 1.20!10 5 . What is the work
done by the motor of the compressor?
ANSWER:
=
Part C
If the direction of the refrigerant flow is inverted in an air conditioner, the air conditioning unit turns into a heat pump and it
can be used for heating rather than cooling. In this case, the coils where the refrigerant would condense in the air conditioner
become the evaporator coils when the unit is operated as a heat pump, and, vice versa, the evaporator coils of the air
conditioner become the condenser coils in the heat pump. Suppose you operate the air conditioner described in Parts A and B
as a heat pump to heat your bedroom. In each cycle, what is the amount of heat released into the room? You may assume
that the energy changes and work done during the expansion process are negligible compared to those for other processes
during the cycle.
Hint C.2 Find the right expresssion for the first law of thermodynamics
Suppose you have an ideal system that absorbs heat from a cold reservoir and releases heat to a hot reservoir. The
net input of work required by this system for operation is . Which of the following expressions is correct?
ANSWER:
ANSWER:
=
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the bar and the specific heat capacity of the metal. Also determine the total change of entropy given the entropy change of the
bar and discuss the application of the second law of thermodynamics to systems that are not isolated.
An aluminum bar of mass 2.00 at 300 is thrown into a lake. The temperature of the water in the lake is 15.0 ; the
specific heat capacity of aluminum is 900 .
Part A
The bar eventually reaches thermal equilibrium with the lake. What is the entropy change of the lake? Assume that the
lake is so large that its temperature remains virtually constant.
ANSWER:
=
Hint A.2.2 Find the energy change for the aluminum bar
What is the change of heat energy for the metal bar?
ANSWER:
=
ANSWER:
=
ANSWER:
=
Part B
Has the entropy of the aluminum bar decreased or increased?
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ANSWER: Since the entropy change of a system is always positive, we can deduce that the entropy of the aluminum
bar has increased.
Since the final lower temperature of the bar means lower average speed of molecular motion, we can
deduce that the entropy of the bar has decreased.
We don't have enough information to determine whether the entropy of the aluminum bar has decreased
or increased.
Part C
Since the aluminum bar is not an isolated system, the second law of thermodynamics cannot be applied to the bar alone.
Rather, it should be applied to the bar in combination with its surroundings (the lake).
Assume that the entropy change of the bar is -73.5 , what is the change in total entropy ?
ANSWER:
=
Even though the aluminum bar lowers its entropy, the total entropy change of the bar and its surroundings (the water in
the lake) is positive, and the total entropy increases.
Part D
The second law of thermodynamics states that spontaneous processes tend to be accompanied by entropy increase. Consider,
however, the following spontaneous processes:
In all these cases, systems evolve to a state of less disorder and lower entropy, apparently violating the second law of
thermodynamics. Could we, then, consider them as processes occurring in systems that are not isolated?
ANSWER: True
False
All the processes listed above require energy input to occur just as a refrigerator requires electrical energy to run.
Systems can become more ordered and lower their entropy as time passes. However, this can happen only as the entropy
of the environment increases, just as we found out in the case of the hot aluminum bar cooling down in the lake.
A Carnot heat engine uses a hot reservoir consisting of a large amount of boiling water and a cold reservoir consisting of a large
tub of ice and water. In 5 minutes of operation of the engine, the heat rejected by the engine melts a mass of ice equal to
4.15!10 "2 .
Throughout this problem use for the heat of fusion for water.
Part A
During this time, how much work is performed by the engine?
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MasteringPhysics 1/7/09 3:06 PM
Since the amount of ice that melts is known, the heat needed to melt the ice must be equal to the magnitude of the heat
rejected by the Carnot engine. Use the equation for the heat of a phase change to determine this, then think about how this
relates to the heat rejected by the engine.
The equation for ice melting is , where is the heat absorbed by the ice, 4.15!10 "2 is the mass of ice being
melted, and is the heat of fusion for water.
ANSWER:
=
Note the sign used in the equation, and recall that all temperatures should be expressed in kelvins.
ANSWER:
=
ANSWER:
=
As you can see from this problem, it is very important to keep in mind the signs of the heats exchanged in an engine.
When the Carnot engine absorbs heat from a reservoir, the heat will be a positive quantity since the heat is being added to
the engine, before it does any work. Similarly, when the Carnot engine rejects heat to a reservoir, the heat will be a
negative quantity since the heat is lost from the engine. The work done by the engine, by the first law of thermodynamics,
is therefore the sum of all heat changes in the engine.
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