equation after quencher

C + (1/2)O2 = CO H2
C + 2H2 = CH4 CO
S + H2 = H2S CO2
H2 + (1/2)O2 = H2O CH4
CH4 + 2O2 = CO2 + 2H2O H2S
CH4 + (3/2)O2 = CO +2H2O N2

Product specification MW density H2 produce

H2 95% purity 2 1608.928
CO 1% 28 22524.99
CO2 1% 44 35396.41
N2 2% 28 22524.99
CH4 1% 16 12871.42
H2S Less than 1 ppm 34 27351.77

P 2060 kPa
T 308 K
R 0.008314 m3.kPa/mol.K
assume ideal gas

stream 1 mass mw mole stream 2 mass

C 59500000 12 4958333 C 59500000
H2 7700000 2 3850000 H2 7700000
S 2800000 32 87500 S 2800000
70000000 8895833 70000000

stream 4 mass mw mole stream 5 mass

H2O(v) 52500000 18 2916667 O2 81200000
N2 4270000
85470000
* at stream 40 - 1000000 kg of K2CO3 solution

Stream Table
Stream Number 1 2 3 4 5 6
Temperature (°C) 37.8 50 200 20 210
Pressure (kPa) 206.9 206.9 206.9 4140 4140 4140
Vapor fraction 0 0 0
Mole flow (kmol/h) 8895833 8895833 8895833 2916667 2690000 2690000
Mass flow (kg/h) 70000000 70000000 70000000 52500000 85470000 85470000
Component mass flow (kg/h)
Carbon (liquid) 59500000 59500000 59500000 0 0 0
Hydrogen (liquid) 7700000 7700000 7700000 0 0 0
Sulfur (liquid) 2800000 2800000 2800000 0 0 0
Oxygen (gas) 0 0 0 0 81200000 81200000
Nitrogen (gas) 0 0 0 0 4270000 4270000
Water vapor 0 0 0 52500000 0 0
Carbon dioxide (gas) 0 0 0 0 0 0
Carbon monoxide (gas) 0 0 0 0 0 0
Water (liquid) 0 0 0 0 0 0
Hydrogen (gas) 0 0 0 0 0 0
Methane 0 0 0 0 0 0
Hydrogen sulfide 0 0 0 0 0 0
Carbon (gas) 0 0 0 0 0 0
fter quencher input 600000000
47.60% C 0.85
42.10% H2 0.11
8.30% S 0.04
0.10% O2 1.16 0.95 purity
0.50% N2 0.061 0.05
1.40% H2O(v) 0.75

heavy oil feedstock x

0.85x + 0.11x + 0.04x + 1.16x +0.061x +0.75x 600000000
2.971 x = 207970000
x = 70000000

mass of material input MW mole

1000000 m3/day C 59500000 kg/hr 12 4958333
67038647 kg/hr H2 7700000 kg/hr 2 3850000
S 2800000 kg/hr 32 87500
O2 81200000 kg/hr 32 2537500
N2 4270000 kg/hr 28 152500
H2O(v) 52500000 kg/hr 18 2916667

carbon used 58450000

carbon suspension 1050000 87500 kmol/hr

mw mole stream 3 mass mw mole stream 7

12 4958333 C 59500000 12 4958333.3 O2
2 3850000 H2 7700000 2 3850000 N2
32 87500 S 2800000 32 87500 H2O(v)
8895833 70000000 8895833.3

mw mole stream 6 mass mw mole stream 8

32 2537500 O2 81200000 32 2537500 CO
28 152500 N2 4270000 28 152500 CO2
2690000 85470000 2690000 CH4
H2
H2S
N2
C
 H2O

7 8 9 10 11 12 13 14 15
210 1300 250 50
4140 4140

5606667 33780831 7870924 25909906 7783424.1 87500 12954953 12954953 38695.789

1.38E+08 6E+08 1.34E+08 4.66E+08 132571683 1050000 233189158 2.33E+08 1315656.8

0 0 0 0 0 1050000 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
81200000 0 0 0 0 0 0 0 0
4270000 4270000 4270000 0 4270000 0 0 0 0
52500000 4.66E+08 0 4.66E+08 0 0 233189158 2.33E+08 0
0 28263828 28263828 0 28263828 0 0 0 0
0 91230561 91230561 0 91230561 0 0 0 0
0 0 0 0 0 0 0 0 0
0 7367789 7367789 0 7367788.8 0 0 0 0
0 123828.4 123828.4 0 123828.38 0 0 0 0
0 1315677 1315677 0 1315676.6 0 0 0 1315656.8
0 1050000 1050000 0 0 0 0 0 0
 COMBUSTOR
mole balance
n1 3258234.3 3995833.3

mole mass
C balance (kmol/h) mole% mw (kg/hr)
CO n1 3258234.3 41.861195 28 91230561
CO2 0.1971496 n1 642359.74 8.2529196 44 28263828
CH4 0.0023753 n1 7739.2739 0.0994328 16 123828.4

H balance
CH4 7739.2739
H2 3683894.4 3683894.4 47.329997 2 7367789
H2S 38696.37 38696.37 0.4971638 34 1315677

N2 152500 152500 1.9592919 28 4270000

7783424.1 1.33E+08

H2O 466378317 kg/hr 4.66E+08

carbon suspension 1050000 kg/hr 1050000
6E+08

mass mw mole stream 9 mass mw mole

81200000 32 2537500 WASTE HEAT BOILER
4270000 28 152500 output
52500000 18 2916666.7 CO 91230561 28 3258234.3
1.38E+08 5606666.7 CO2 28263828 44 642359.74
CH4 123828.38 16 7739.2739
mass mw mole H2 7367788.8 2 3683894.4
91230561 28 3258234.3 H2S 1315676.6 34 38696.37
28263828 44 642359.74 N2 4270000 28 152500
123828.4 16 7739.2739 C 1050000 12 87500
7367789 2 3683894.4 133621683 7870924.1
1315677 34 38696.37 stream 10 mass mw mole
4270000 28 152500 out H2O 466378317 18 25909906
1050000 12 87500 600000000
4.66E+08 18 25909906
6E+08 33780831

16 17 18 19 20 21 22 23 24
35

20699682 20699682 10349841 10349841 10349841 10349841 33310793 19942390 19897390

3.64E+08 364445185 182222592 182222592 182222592 182222592 591445185 3.53E+08 353219076

0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
4270000 4270000 2135000 2135000 2135000 2135000 4270000 2562000 2562000
2.33E+08 233189158 116594579 116594579 116594579 116594579 4.60E+08 2.43E+08 2.43E+08
28263828 28263828 14131914 14131914 14131914 14131914 28263828 9.42E+07 9.42E+07
91230561 91230561 45615281 45615281 45615281 45615281 9.12E+07 5.47E+06 5.47E+06
0 0 0 0 0 0 0 0 0
7367789 7367788.8 3683894.4 3683894.4 3683894.4 3683894.4 7367788.8 7930673 7930673.3
123828.4 123828.38 61914.191 61914.191 61914.191 61914.191 123828.38 74297.03 74297.03
19.73515 19.735149 9.8675743 9.8675743 9.8675743 9.8675743 19.735149 11.84109 11.841089
0 0 0 0 0 0 0 0 0
stream 11 mass mw mole
QUENCHER stream 13 mass
output out
CO 91230561 28 3258234 H2O 233189158
CO2 28263828 44 642359.7
CH4 123828.4 16 7739.274 stream 14
H2 7367789 2 3683894 H2O 233189158
H2S 1315677 34 38696.37
N2 4270000 28 152500
1.33E+08 7783424 stream 16 mass
SCRUBBER
stream 12 mass mw mole output
C 1050000 12 87500 CO 91230561
1.34E+08 CO2 28263828
 CH4 123828.38
H2 7367788.8
H2S 19.735149
N2 4270000
131256026
H2O 233189158
364445185
stream 15 mass
H2S reduce 1315656.8
365760842

25 26 27 28 29 30 31 32

13324317 13324317 33221707 12611111 12611111 12611111 12611111.1111111 22960952

236578071 236578071 5.90E+08 2.27E+08 2.27E+08 2.27E+08 2.27E+08 409222593

0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0
1708000 1708000 4270000 0 0 0 0 2135000
1.65E+08 1.65E+08 4.08E+08 2.27E+08 3.44E+08
57181467 57181467 1.51E+08 0 0 0 0 14131914
7.30E+06 7.30E+06 1.28E+07 0 0 0 0 45615281
0 0 0 2.27E+08 2.27E+08 2.27E+08 0 0
5032385.4 5032385.4 12963059 0 0 0 0 3683894.4
49531.353 49531.353 123828.4 0 0 0 0 61914.191
7.8940594 7.8940594 19.73515 0 0 0 0 9.8675743
0 0 0 0 0 0 0 0
 stream 17 mass mw mole
SCRUBBER
output
CO 91230561.06 28 3258234.323
CO2 28263828.38 44 642359.736
CH4 123828.3828 16 7739.273927
H2 7367788.779 2 3683894.389
H2S 19.73514851 34 0.580445545
N2 4270000 28 152500
131256026.3
H2O 233189158.4 18 12954953.25
364445184.8 20699681.55

stream 17 mole MW mass

H2O 10000000 18 180000000

mw mole stream 18 mole mw mass

CO conversion 90 % 0.9
18 12954953 consumption of CO 2932410.891 0.1

CO 325823.4323 28 9123056.106
18 12954953 CO2 3574770.627 44 157289907.6
CH4 7739.273927 16 123828.3828
H2 6616305.281 2 13232610.56
mw mole H2S 0.580445545 34 19.73514851
N2 152500 28 4270000
H2O 20022542.35 18 360405762.4
28 3258234.3 30699681.55 544445184.8
44 642359.74
 16 7739.2739 stream 19 mass mw mole
2 3683894.4 CO 9123056.106 28 325823.4323
34 0.5804455 CH4 123828.3828 16 7739.273927
28 152500 H2S 19.73514851 34 0.580445545
N2 4270000 28 152500
18 12954953 H2O 360405762.4 18 20022542.35
20699682 373922666.6 20508605.64
mw mole
34 38695.789 stream 20 mass mw mole
CO2 157289907.6 44 3574770.627
H2 13232610.56 2 6616305.281

33 34 35 36 37 38 39 40

20593471 20593471 20593471 20593470.79 20593470.79 20593470.79 7347921.439 36227.61

362488912 362488912 362488893 362488892.7 362488892.7 362488892.7 41129165.52 1000000

0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0
4270000 4270000 4270000 4270000 4270000 4270000 4270000 0
0 0
1.51E+08 1.51E+08 151359727 151359727.2 151359727.2 151359727.2 11000000 0
1.28E+07 1.28E+07 12772278 12772278.41 12772278.41 12772278.41 12772278.41 0
1.81E+08 1.81E+08 1.81E+08 1.81E+08 1.81E+08 1.81E+08 0 400000
12963059 12963059 12963059 12963058.73 12963058.73 12963058.73 12963058.73 0
123828.38 123828.38 123828.38 123828.3828 123828.3828 123828.3828 123828.3828 0
19.735149 19.735149 0.0002171 1.519606E-09 4.558819E-15 4.558819E-21 4.558819E-21 0
0 0 0 0 0 0 0 0
stream 18 mass mw mole stream 19 mass mw mole
SCRUBBER SCRUBBER
output output
CO 45615281 28 1629117 CO 45615281 28 1629117
CO2 14131914 44 321179.9 CO2 14131914 44 321179.9
CH4 61914.191 16 3869.637 CH4 61914.191 16 3869.637
H2 3683894.4 2 1841947 H2 3683894.4 2 1841947
H2S 9.8675743 34 0.290223 H2S 9.8675743 34 0.290223
N2 2135000 28 76250 N2 2135000 28 76250
65628013 65628013
H2O 116594579 18 6477477 H2O 116594579 18 6477477
182222592 10349841 182222592 10349841

stream 21 mole mw mass stream 24 mass

CO conversion 80 % 0.8 CO 1824611
consumption of CO 260658.7 0.2 CH4 123828.4
H2S 19.73515
CO 65164.69 28 1824611 N2 4270000
CO2 260658.7 44 11468985 H2O 3.56E+08
CH4 7739.274 16 123828.4 3.62E+08
H2 260658.7 2 521317.5
H2S 0.580446 34 19.73515 stream 25 mass
N2 152500 28 4270000 CO 912305.6
H2O 19761884 18 3.56E+08 CH4 61914.19
20508606 3.74E+08 H2S 9.867574
N2 2135000
 stream 22 mass mw mole CO2 5734492
CO2 11468985 44 260658.7 H2 260658.7
H2 521317.5 2 260658.7 H2O 1.78E+08
11990302 521317.5 1.87E+08

stream 23 mass mw mole stream 28 mass

CO 1824611 28 65164.69 CO 912305.6
CH4 123828.4 16 7739.274 CH4 61914.19
H2S 19.73515 34 0.580446 H2S 9.867574
N2 4270000 28 152500 N2 2135000
H2O 3.56E+08 18 19761884 CO2 5734492
3.62E+08 19987288 H2 260658.7
H2O 1.78E+08
1.87E+08

41 42 43 44 45 46 47 48

3189993.8 10055556
140359727 1.81E+08

0 0
0 0
0 0
0 0
0 0
0 0
140359727 0
0 0
0 1.81E+08
0 0
0 0
0 0
0 0
 stream 28 mass mw mole
H2O 2.27E+08 18 12611111

stream 20 mass mw mole stream 21 mass mw mole

SCRUBBER SCRUBBER
output output
CO 45615281 28 1629117 CO 45615281 28 1629117
CO2 14131914 44 321179.9 CO2 14131914 44 321179.9
CH4 61914.191 16 3869.637 CH4 61914.19 16 3869.637
H2 3683894.4 2 1841947 H2 3683894 2 1841947
H2S 9.8675743 34 0.290223 H2S 9.867574 34 0.290223
N2 2135000 28 76250 N2 2135000 28 76250
65628013 65628013
H2O 116594579 18 6477477 H2O 1.17E+08 18 6477477
182222592 10349841 1.82E+08 10349841

mw mole stream 31 mass mw mole stream 30 mass

28 65164.69 H2O 2.67E+08 18 14821413 CO 1368458
16 7739.274 CH4 92871.29
34 0.580446 stream 32 mass mw mole H2S 14.80136
28 152500 H2O 2.67E+08 18 14821413 N2 3202500
18 19761884 CO2 87246692
19987288 H2 7007293
stream 26 mass mw mole H2O 2.67E+08
mw mole CO 456152.8 28 16291.17 3.66E+08
28 32582.34 CH4 30957.1 16 1934.818
16 3869.637 H2S 4.933787 34 0.145111 stream 33 mass
34 0.290223 N2 1067500 28 38125 H2O 2.67E+08
28 76250 CO2 81512200 44 1852550
 44 130329.4 H2 6746635 2 3373317 stream 34 mass
2 130329.4 H2O 88928476 18 4940471 H2O 2.67E+08
18 9880942 1.79E+08 10222689
10254303 stream 35 mass
stream 29 mass mw mole CO 1368458
mw mole CO 456152.8 28 16291.17 CH4 92871.29
28 32582.34 CH4 30957.1 16 1934.818 H2S 14.80136
16 3869.637 H2S 4.933787 34 0.145111 N2 3202500
34 0.290223 N2 1067500 28 38125 CO2 87246692
28 76250 CO2 81512200 44 1852550 H2 7007293
44 130329.4 H2 6746635 2 3373317 98917830
2 130329.4 H2O 88928476 18 4940471
18 9880942 1.79E+08 10222689
10254303
 stream 29 mass mw mole
H2O 2.27E+08 18 12611111

stream 30 mass mw mole

H2O 2.27E+08 18 12611111

stream 31 mass mw mole

H2O 2.27E+08 18 12611111

stream 32 mass mw mole stream 22 mass mw

SCRUBBER
output
CO 45615281 28 1629117 CO 9.12E+07 28
CO2 14131914 44 321179.9 CO2 28263828 44
CH4 61914.19 16 3869.637 CH4 123828.4 16
H2 3683894 2 1841947 H2 7367789 2
H2S 9.867574 34 0.290223 H2S 19.73515 34
N2 2135000 28 76250 N2 4270000 28
65628014 1.31E+08
H2O 3.44E+08 18 19088588 H2O 4.60E+08 18
4.09E+08 22960952 5.91E+08

start kat sini acap!!!! Stream 35

assume
mw mole stream 27 mass mw mole stream 35
28 48873.51 CO 456152.8 28 16291.17 CO
16 5804.455 CH4 30957.1 16 1934.818 CH4
34 0.435334 H2S 4.933787 34 0.145111 H2S
28 114375 N2 1067500 28 38125 N2
44 1982879 CO2 81512200 44 1852550 CO2
2 3503647 H2 6746635 2 3373317 H2
18 14821413 H2O 3.22E+08 18 17895424 H2O
20476992 4.12E+08 23177643
H2S reduc
mw mole stream 36 mass mw mole assume
18 14821413 CO 456152.8 28 16291.17 stream 36
CH4 30957.1 16 1934.818 CO
mw mole H2S 4.933787 34 0.145111 CH4
18 14821413 N2 1067500 28 38125 H2S
CO2 81512200 44 1852550 N2
mw mole H2 6746635 2 3373317 CO2
28 48873.51 H2O 3.22E+08 18 17895424 H2
16 5804.455 4.12E+08 23177643 H2O
34 0.435334
28 114375 stream 34 mass mw mole H2S reduc
44 1982879 CO 1.28E+07 28 456152.8 assume
2 3503647 CH4 123828.4 16 7739.274 stream 37
5655579 H2S 19.73515 34 0.580446 CO
N2 4270000 28 152500 CH4
CO2 1.51E+08 44 3439994 H2S
H2 12963059 2 6481529 N2
H2O 1.81E+08 18 10055556 CO2
3.62E+08 20593471 H2
H2O

H2S reduc
 60% mass fraction to the second stage and 40% to the first stage

stream mass mw mole stream mass

before conversion before conversion
second stage first stage
CO 5.47E+07 28 1954940.604 CO 3.65E+07
CO2 16958297 44 385415.8416 CO2 11305531
CH4 74297.03 16 4643.564356 CH4 49531.353
H2 4420673 2 2210336.634 H2 2947115.5
mole H2S 11.84109 34 0.348267327 H2S 7.8940594
N2 2562000 28 91500 N2 1708000
7.88E+07 52502411
3258234.34 H2O 2.76E+08 18 15339638.61 H2O 1.84E+08
642359.736 3.55E+08 19986475.61 236578074
7739.273927
3683894.389 stream 23 mass mw mole stream 25 mass
0.580445545 after 90% conversion after 80% conversion
152500 second stage first stage
CO 5.47E+06 28 1.95E+05 CO 7.30E+06
25566064.36 CO2 9.42E+07 44 2.14E+06 CO2 57181467
33310792.68 CH4 74297.03 16 4643.564356 CH4 49531.353
H2 7930673 2 3965336.634 H2 5032385.4
H2S 11.84109 34 0.348267327 H2S 7.8940594
N2 2562000 28 91500 N2 1708000
1.10E+08 71269837
H2O 2.43E+08 18 1.35E+07 H2O 1.65E+08
3.53E+08 19942389.61 236578071

ni acap!!!! Stream 35

H2S 11 ppm H2S 1 ppm

mass mw mole stream 38 mass mw mole
12772278.41 28 456152.8 CO 12772278.41 28 456152.8
123828.3828 16 7739.274 CH4 123828.3828 16 7739.274
0.000217087 34 6.385E-06 H2S 4.558819E-21 34 1.341E-22
4270000 28 152500 N2 4270000 28 152500
151359727.2 44 3439994 CO2 151359727.2 44 3439994
12963058.73 2 6481529 H2 12963058.73 2 6481529
181000000 18 10055556 H2O 181000000 18 10055556
362488892.7 20593471 362488892.7 20593471
19.73493143
H2S 7 ppm assume K2CO3 solution 1000000 kg
mass mw mole stream 40 mass mw mole
12772278.41 28 456152.8 K2CO3 solu 1000000
 123828.3828 16 7739.274 K2CO3 400000 138.204 2894.272
1.519606E-09 34 4.469E-11 H2O 600000 18 33333.33
4270000 28 152500 1000000 36227.61
151359727.2 44 3439994
12963058.73 2 6481529
181000000 18 10055556 stream 43
362488892.7 20593471 K2CO3 solu 183000000
0.000217085 K2CO3 73200000 138.204
H2S 3 ppm H2O 109800000 18
mass mw mole
12772278.41 28 456152.8
123828.3828 16 7739.274
4.558819E-15 34 1.341E-16 stream 44
4270000 28 152500 K2CO3 solu 182000000
151359727.2 44 3439994 K2CO3 72800000 138.204
12963058.73 2 6481529 H2O 109200000 18
181000000 18 10055556
362488892.7 20593471
1.519602E-09
mw mole stream 24 mass mw mole

28 1303293.736 CO 5.47E+06 28 1.95E+05

44 256943.8944 CO2 9.42E+07 44 2.14E+06
16 3095.709571 CH4 74297.03 16 4643.56435643564
2 1473557.756 H2 7930673 2 3965336.65
34 0.232178218 H2S 11.84109 34 0.34826732673267
28 61000 N2 2562000 28 91500
1.1E+08
18 10226425.74 H2O 2.43E+08 18 1.35E+07
13324317.07 3.53E+08 19897389.623041

mw mole stream 26 mass mw mole

28 260658.74 CO 7.30E+06 28 2.61E+05

44 1299578.8 CO2 57181467 44 1299578.8
16 3095.709571 CH4 49531.35 16 3095.7095709571
2 2516192.7 H2 5032385 2 2516192.715
34 0.232178218 H2S 7.894059 34 0.23217821782178
28 61000 N2 1708000 28 61000
71269837
18 9183790.8 H2O 1.65E+08 18 9.18E+06
13324316.98 2.37E+08 13324316.974527

CO2 removed 92.73255

stream 39 mass mw
CO 12772278.4116832 28
CH4 123828.382838284 16
H2S 4.55881930693E-21 34
N2 4270000 28
H2 12963058.73 2
CO2 11000000 44
41129165.5245215

stream 45 mass mw mole stream 42

K2CO3 solutio 182000000 H2O 1.81E+08 18
K2CO3 72800000 138.204
H2O 109200000 18 stream 41

CO2 140359727.2 44
140359727.2

product 183854569.292178
reactant 247038646.543097
H2 produced 613514.258496864 m3/day
88.2090182714049 % purity
stream 27 mass mw mole stream 34 mass mw mole

CO 1.28E+07 28 4.56E+05 CO 1.28E+07 28 4.56E+05

CO2 1.51E+08 44 3.44E+06 CO2 1.51E+08 44 3.44E+06
CH4 123828.3828 16 7739.27393 CH4 123828.383 16 7739.27393
H2 12963058.73 2 6481529.37 H2 12963059 2 6481529.37
H2S 19.73514851 34 0.58044554 H2S 19.7351485 34 0.58044554
N2 4270000 28 152500 N2 4270000 28 152500
181488912.5 181488912
H2O 4.08E+08 18 2.27E+07 H2O 1.81E+08 18 1.01E+07
5.90E+08 33221707 362488912 20593471

stream 33 mass mw mole

CO 1.28E+07 28 4.56E+05
CO2 1.51E+08 44 3.44E+06
CH4 123828.3828 16 7739.27393
H2 12963058.73 2 6481529.37
H2S 19.73514851 34 0.58044554
N2 4270000 28 152500
181488912.5
H2O 1.81E+08 18 1.01E+07
362488912.5 20593471

mole mole%
456152.8 6.207916132
7739.2739 0.10532603
1.3408E-22 1.824773E-27
152500 2.075416854
6481529.4 88.20901827
250000 3.402322712
7347921.4

10055556
3189993.8
3189993.8