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• SECTION 1
Sections:
Section 1
2+ 2+ +
Q. 1 A solution contains Zn and Cu ions, each at 0.02M. If the solution is made 1 M in H3O and
solution is saturated with H2S, which would precipitate?
-7
K1 for H2S is 1 × 10
-14
K2 for H2s is 1 × 10
-23 -37
Ks.p. of ZnS is 1 × 10 and that of CuS is 8 × 10
3. both precipitate
4. no precipitation occurs
0 out of 4 marks
Correct Answer: 1
Solution:
(1)
-11 3
Q. 2 Ks.p. of CaF2 is 3.2 × 10 M . It is least soluble in
1. water
2. 0.1 M Ca(NH2)2
3. 0.1 M HNO3
4. 0.1 M NaF
0 out of 4 marks
Correct Answer: 4
Solution:
(4)
Q. 3 What is the pH of solution obtained by mixing 50 ml of 0.1 M acetic acid with 25 ml of 0.1 M NaOH?
-5
Ka of CH3COOH is 2 × 10
1. 4.20
2. 4.76
3. 5.24
4. 7
0 out of 4 marks
Correct Answer: 2
Solution:
Ans. (2)
Q. 4 A 200.0 ml sample of H3PO3 requires 22.50 ml of 0.1250 M NaOH for complete neutralization. What
is the molarity of H3PO3solution?
1. 0.014 M
2. 0.028 M
3. 0.007 M
4. 0.005 M
0 out of 4 marks
Correct Answer: 3
Solution:
Ans. (3)
1. 20% V/V
2. 6.07 W/V
3. 20% W/V
4. 6.07 V/V
-1 out of 4 marks
Correct Answer: 2
Solution:
(2)
Q. 6 The molarity of a solution of H2O2 is 2. The volume strength of this solution will be
1. 11.2 volume
2. 10 volume
3. 22.4 volume
4. 5.6 volume
1. 36.5
2. 32
3. 18.25
4. 63.5
Q. 8 What is the normality of 0.30 M H3PO4 (tribasic acid ) in the following reaction ?.
- -2
H3PO4 + 2OH HPO4 + 2H2O
1. 0.30 N
2. 0.60 N
3. 0.90 N
4. 0.15 N
1. 1.79
2. 3.58
3. 60.68
4. 6.86
Q. 11 For the conversion of 0.240 g NaH2PO4 in a solution to monohydrogen phosphate, 21.4 ml NaOH
solution is needed. The molarityof NaOH solution will be
1. 0.093
2. 0.93
3. 0.087
4. 0.083
-1 out of 4 marks (content provider)
Correct Answer: 1
Solution:
Ans. (1)
Number of moles of NaH2PO4 = 0.24/120 0.24/120 45= 0.02 moles .
For this reaction , since it goes from di to mono hydrogen , 'n' factor = 1
So number of equivalents used = 0.02 = Number of moles of NaOH
Molarity of NaOH = 0.02*1000/21.4 = 0.093
Q. 12 22.7 ml of N/10 Na2CO3 solution neutralizes 10.2 ml of dilute H2SO4. Then the volume of water that
1. 245 ml
2. 484.6 ml
3. 480 ml
4. 490.2 ml
Q. 13 50 g of 8% by mass NaOH is mixed with 100 g of 8% by mass of HCl, the resulting solution is
1. acidic
2. basic
3. neutral
4. strongly basic
Q. 14 How many moles of FeCr2O4 can be oxidized completely by 1 mole of KMnO4 in acidic medium?
1. 7
2. 5
3.
4.
-1 out of 4 marks (content provider)
Correct Answer: 4
Solution:
Ans. (4)
Cr2O72- + 6 Fe2+ + 14H+ -->> 2 Cr3+ + 6 Fe3+ + 7 H2O
Fe goes from +2 to +3 hence it's 'n' factor = 1
Cr goes from +3 to + 6 and since there are 2 atoms of Cr per molecule , it's 'n' factor = 2*3 =
6
Total 'n' factor for FeCr2O7 = 7
In KMnO4 , Mn goes from + 7 to + 2 , it's 'n' factor = +5
Since the number of equivalents be same ,
1*5 = m*7
M=5/7
Q. 15 A solution of KMnO4 is reduced to MnO2. The normality of solution is 0.6. The molarity is:
1. 1.8 M
2. 0.6 M
3. 0.1 M
4. 0.2 M
Q. 16 500 ml of 0.2M H2SO4 is mixed with 250 ml of 0.1M Ba(OH)2, the resulting normality of solution
(acidic) is
1. 0.2
2. 0.1
3. 0.5
4. 0.25
1. 40 ml
2. 20ml
3. 10 ml
4. 4 ml
1. 0.224V
2. 0.112V
3. 0.056V
4. None of these
Q. 19 0.2 mol of HCl and 0.1 mol of barium chloride were dissolved in water to produce a 500 ml.
-
solution. The molarity of the Cl is
1. 0.06M
2. 0.09M
3. 0.12M
4. 0.80M
Q. 20 0.7g of Na2CO3×xH2O were dissolved in water and the volume was made to 100 ml, 20 ml of this
solution required 19.8 m of N/10 HCl for complete neutralization. The value of
x is:
1. 7
2. 3
3. 2
4. 5
Q. 21 The hydrated salt Na2SO4×nH2O undergoes 55.9% loss in weight on heating and becomes
anhydrous. The value of n will be
1. 5
2. 3
3. 7
4. 10
Q. 22 What volume of 0.1 M H2SO4 will be required to produce 17.0g of H2S by the reaction
5H2SO4 + 8NaI 4Na2SO4 + 4I2 + H2S + 4H2O?
1. 70.0 L
2. 50.0L
3. 25.0 L
4. 5.0 L
Q. 23 How many grams of copper will be replaced in 2 L of a 1.50 M CuSO4 solution if the latter is made
to react with 27.0g of aluminium? (Cu = 63.5, Al = 27.0)
1. 190.50g
2. 95.25g
3. 31.75g
4. 10.65g
3
Q. 24 An aqueous solution of urea containing 18g urea in 1500cm of solution has a density of 1.502
3
g/cm of solution. If the molecular weight of urea is 60, then the molality of solution is
1. 0.2
2. 0.192
3. 0.064
4. 1.2
-1
Q. 25 The solubility of Fe(OH)3 is x mol L . Its Ksp would be
1. 9x3
2. 3x4
3. 27x4
4. 9x4
-22 2-
Q. 26 Ksp of H2S is 1 × 10 . [S ] in a buffer of pH 6 is :
1. 1 × 10-16 M
2. 1 × 10-12 M
3. 1 × 10-10 M
4. 1 × 10-8 M.
2. 50 mL of 1 M CH3COONa + 25 mL of 1 M HCl
3. 50 mL of 1 M CH3COOH + 25 mL of 1 M NaOH
Q. 28 pKa (CH3COOH) is 4.74. x mol of lead acetate and 0.1 mol of acetic acid in one L solution make a
solution of pH = 5.04. Hence, x is :
1. 0.2
2. 0.05
3. 0.1
4. 0.02.
1. 5 × 10-7 M3
2. 5 × 10-4 M2
3. 1 × 10-6 M3
4. 4 × 10-6 M3.
Q. 30 For a sparingly soluble salt AP Bq the relationship of it's solubility product Ksp with its solubility S
is given by:-
1. KSP = SP + q pp qq
2. KSP = Sp + q pq qp
3. KSP = Spq pp qq
4. KSP = Spq pp + q qp + q
- - o
Q. 32 A gas 'X' at 1 atm is bubbled through a solution containing a mixture of 1 MY and 1 MZ at 25 C. If
the reduction potential of Z > Y > X, then
-4 -5
Q. 33 The dissociation constants of two weak acids HA1 and HA2 are 3 × 10 and 1.8 × 10 , respectively.
The relative strength of the acids will be
1. 1:4
2. 4:1
3. 1 : 16
4. 16 : 1
Q. 34 The hydrogen ion concentration and pH of the solution made by mixing 100 ml of 1M HNO3 with
100 ml of 0.8 M KOH, are
1. [H+] = 0.1, pH = 1
2. [H+] = 0.01, pH = 2
3. [H+] = 1 × 10-12, pH = 12
4. [H+] = 1 × 10-7, pH = 7
+
Q. 36 The correct order of increasing [H3O ] in the following aqueous solution is
1. 0.01 M H2S < 0.01 M H2SO4 < 0.01 M NaCl < 0.01 M NaNO2
2. 0.01 M NaCl < 0.01 M NaNO2 < 0.01 M H2S < 0.01 M H2SO4
3. 0.01 M NaNO2 < 0.01M NaCl < 0.01 M H2S < 0.01 M H2SO4
4. 0.01 M H2S , 0.01 M NaCl < 0.01 M NaNO2 < 0.01 M H2SO4
Q. 37 The vapour pressure of a solution of a non-volatile solvent (A) in solvent (B) is 95% of vapour
pressure of solvent at the same temperature. If MB = 0.3 MA where MB and MA are molecular
weights of B and A respectively the weight ratio of solvent and solution are
1. 0.15
2. 0.57
3. 0.2
4. 0.4
o
Q. 38 At 4 C an osmotic pressure rise of 2.6 mm of protein solution was observed which was prepared
3
by dissolving 0.75 g protein in 125 cm of an aqueous solution. If density of solution is 1.0
3
gm/cm the mol wt of protein will be:
1. 9.4 × 105
2. 5.4 × 105
3. 5.4 × 1010
4. 9.4 × 1010
1. 180
2. 90
3. 270
4. 200
Q. 40 Three sparingly soluble salts A2X, AX and AX3 have the same solubility product. Their solubilities
will be in the order