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    This book has been specially written to provide valuable practice at answering Multiple Choice Questions. It is arranged topically and follows the lastest GeE 'a' level Chemistry (H2) syllabus closely. 'Helps' are available at the end of every question to assist you when difficulties are encountered in attempting to answer the questions.

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    This book has been specially written to provide valuable practice at answering Multiple Choice Questions. It is arranged topically and follows the lastest GeE 'a' level Chemistry (H2) syllabus closely. 'Helps' are available at the end of every question to assist you when difficulties are encountered in attempting to answer the questions.

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    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
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    93 views9 pages

    97

    Uploaded by

    Ramsha Siddiqui
    This book has been specially written to provide valuable practice at answering Multiple Choice Questions. It is arranged topically and follows the lastest GeE 'a' level Chemistry (H2) syllabus closely. 'Helps' are available at the end of every question to assist you when difficulties are encountered in attempting to answer the questions.

    Copyright:

    Attribution Non-Commercial (BY-NC)
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    of 9
    To provide an idea about what this book contains, only few pages taken randomly from the book are shown here. Multiple Choice Questions are generally tricky problems. The incorrect choices given are usually quite similar to the | correct one. Consequently, many students play ‘guessing game’ when they run into questions that they are unsure | of. With believe that wth good training and comprehensive | preparation, students should be able to overcome this prob- | lem rather than leaving it to chance. This constitutes the | reason for the publication of this book This book has been specially written to provide valuable practice al answering multiple choice questions. It is ar- ranged topically and follows the lastest GCE ‘A level Chem- istry (H2) syllabus closely, Most importantly, it aims to cover most, if not, all the important and frequently ex- amined questions. ‘Helps’ is available at the end of every question to assist you when difficulties are encountered in attempting to answer the questions. This book also reveals the insight into the topics involved and hence, enhances your overall knowledge of the con- cepts. Therefore, even if you are able to arrive at the cor- rect answer, we suggest that you still read through ‘Helps’ to ensure that you understand thoroughly the methods working out the answers. KSChua ‘The author Section A Section B Section C PHYSICAL CHEMISTRY Topic 1 : Atoms, Molecules and Stoichiometry --—~ Topic 2 : Atomic Structure ~ Topic 3 : Chemical Bonding Topic 4 : The Gaseous State -— Topic 5 : Chemical Energetics. Topic6 : Topic? : Topic 8: INORGANIC CHEMISTRY Topic 9 : The Periodic Table : Chemistry Periodicity - Topic 10: Group II Topiett : Group Vil ——~ Topic 12 : An Introduction to the Chemistry of Transition Elements Topie 13 : Nitrogen and Sulphur ORGANIC CHEMISTRY Topic 14: Introductory Topics Topic 15 : Hydrocarbons Topic 16 : Halogen Derivatives ~ 217-230 Topic 17 : Hydroxy Compounds 231 - 243 Topic 18 : Carbonyl Compounds. 244 - 263 Topic 19 : Carboxylic Acids and Derivatives, Topic 20 : Nitrogen Compounds peo ton A Physical Chemisrry Atoms, Molecules & Stoichiometry wpic 1 Atoms, Molecules & Stoichiomenry chemistry MCO wis HAps You should rey 10 awsuer ov your own belone seeking HELPS Section A Qi ‘A sample of 0.025 mol of the chloride of an element Z ‘was dissolved in distilled water and the solution made up to 300 cm’, 12.5 em’ of this solution reacted with 25 cm’ of 0.1 mol dm” silver nitrate solution, What is the most likely formula of the chloride? a ze 2 Za Cc Zc D ZCh Help Silver(!) nitrate reacts with chloride ion to give silver(|) chloride precipitate Ag'(aq) + Cr'(aq) —> AgCl(s) Amount of Ag* used = concentration x volume 25 = 0.4 (mot dm") x (2-9 (dim? {mol dm’) (G55) (dm?) 28x10" mol Since 1 mole of Ag’ react with 1 mole of Cl-, amount of OF present in 125 om? =25x10" mol 25x10 25 =01 mol Since 0.025 mole of the compound contain 0.1 mole of chloride, 1 mole of the compound therefore contain > 4 mol of chloride. Amount of Cl present in $00 ¢m* 500 The formula of the compound is ZCl,. Q2 Complete combustion of a hydrocarbon gave 0.352 g of carbon dioxide and 0,072 g of water, Which one of the following formulae could correctly represent this hydro- carbon? = [ H. 1.0; C, 12.0; 0, 16.0. ] cH H-CH=CH; on“ Help The empirical formula of the hydrocarbon Is C,H,. The empirical formulae of the compounds are A: CH, B: C,H, C= C,H, D: CH, E: CH. ae Q3 In the absence of a catalyst, ammonia burns in an excess of ‘oxygen to produce steam and nitrogen. What is the volume of oxygen remaining when 60 cm’ of ammonia is burnt in 100 cm? of oxygen, all volumes being measured at the same temperature and pressure? A 25cm* D 45cm’ B 35cm’ E 55cm C 40cm’? Help ANH,(9) + 30,(g) ——> 2N,(g) + GH,O(g) Sn? ot oautae 26048 en? ot, +. Volume of excess O, = 100-45 ~ 55 em? ae Q4 A sample of 10 dm? of polluted air is passed through lime ‘water so that all the carbon dioxide present is precipitated as calcium carbonate. The mass of calcium carbonate formed is 0.05 g. What is the percentage, by volume, of carbon dioxide in the air sample? [Relative atomic masses: €, 12; 0, 16; Ca, 40; 1 mol of gas under experimental conditions has a volume of 24 dm3.] 13 topic 1 Atoms, Molecules & Stoichiometry A 03% D 03% B 0.05% © 012% Help Ca(OH},(aq) + CO,(g) —> CacO,(s) + HO 0.05 H+i243x16 =50%10-* mol Volume of CO, =5.0 x10 x 24 = 12x10? om? 412x102 10 Amount of CaCO, precipitated = . % by volume of CO, = x100 =012 anne Q5 A sample of 2.00 g of iron({I}) sulphate, FexSO«)s, dissolved in water to give 100 cm? of aqueous solution, What is the concentration of SO4?~ ions? [The relative formula (molecular) mass of Fe(SO4)s is 400.] A 15x 10° mol dm B 5x10? moldm? 15X10? mol dm> D 5x 107 mol dm E 15x 107 mol dm” Help 1 mole of Fe,(SO,). gives 3 moles of SO, fons. O6 What volume of oxygen is required for the complete combustion of a mixture of $ cm’ of CHa and 5 em’ of OH? A Sem’ D 20cm" Bo 10cm? E 25cm! C 1Sem’ chemistry MEO win HAPS. Help Chi4(g) + 20,(g) —> CO,(g) + 2H,0(0) CaH,(9) + 30p(9) ——> 2C0,(g) + 2H,O(4) Volume of O, required to burn 5 em? of CH, =2x5=10cm? Volume of ©, required to burn 5 cm? of CoH, =3x5= 150m? Total volume of O, required =10415 =25 em? hes Q7 In which one of the following reactions does hydrogen behave as an oxidising agent? Hy + Ch = 2HC1 C3Hy + Ha = C3He G:HsCHO + Ha — Nz + 3H: 2NHy 2Na + Ha — 2NaH C:H;CHOH moe Help ‘An oxisising agent decreases its oxidation state since itis being reduced. In (E), H changes its oxidation state from Oto -1. In this case, Hp oxidises the highly reactive Na by gaining an electron trom a Na atom to form H- Na —> Nat +0 oe oH +e O8 The relative atomic mass of chlorine is 35.5. Which one, of the following is the mass spectrogram of chlorine? Lb me ae 14 topic 1_Aroms, Molecules & Stoichiometry chenistay MEO win HApS Hallg ‘The isotopes of Cl are %c| and *9} and they exist in the ratio of 3: 1. Hence 3 1 A, of Cl= (5x38) +1 x37) ae 355 roses Qa A mixture of 10 cm? of methane and 10 em! of ethane was sparked with an excess of oxygen. After cooling 0 where n= 1, 2, 9, 4. room temperature, the residual gas was passed through . . aqueous potassium hydroxide, What volume of gas was |" ll the 4 cases, ©, is in excess. The residual gas + 00, + (n+ 9H,0, absorbed by the alkali? therefore contains CO, and the excess O, at room tem- A Sem D em perature and pressure. B 20cm’ Volume of CO, = 10n om? Cc 25 om Volume of ©, reacted = (103884) om? Help Volume of excess 0, = (7010x2224) om? CHA) + 204{9) —+ CO,(9) + 24,00 + Volume of residual gas Geel) + $0,(g) —> 260,(g) + 3H,0(6) = 100 + (70-10 x 524) = (65 5) om® The gas absorbed by KOH is CO,. Hence, the graph should be a straight line with a negative €O,(g) + 20H"(aq) —+ CO," (aq) + H.0(0) gecko (¥0u may also calculate the volume of residual gas for each Volume of CO, produced by CH, =10 om? ey Volume of CO, produced by GH, =20 em? + Total volume of CO, produced=10+20=30 cm? wen QI1 In which of the following substances does sulphur exhibit its highest oxidation state? D Nas820) Qio ‘Samples of 10 cm? of the first four members of the alkane series are cach mixed with 70 cm! of oxygen. Each is then burned and the total volume, ¥, of residual gas ‘measured again at room temperature and pressure. Which one of the following graphs represents the resus Hel. p that would be obtained? WO B14 ()18 (O12 (125 a ‘dation state of S in SO,Cly. ies wad acl Let x be the oxidatior wo. | 426-2) + 2-4 +6 © : 0} (# Strictly speaking, both Na,S,0,, thiosulphate and % < ie Na,S,O,, tetrathionate also have S exhibiting oxidation = *. =: state of +6. eM, oa ce omy, ca eon came tea 15 topic 1 Atoms, Molecules & Stoichiometry The numbers in parentheses indicate the oxidation states, of S) Q12 A sample of 10.0 cm? of 0.10 mol dm iron(II) sulphate is titrated against 0.025 mol dm potassium manganate( VII) in the presence of an excess of fluoride ions. It is found that 10.0 en of the manganate( V1) solution is required to reach the end-point, What is the oxidation number of the manganese at the end- point? A 2 D +5 BOW c +4 Help Fo 5 Fo™ 4 @ ‘Amount of Fe® = concentration x volume = 0.10 (mol dm ®) x22 (dn?) =1%10 mot Amount of electrons lost = 1310 mol 10 7000 Amount af MnO,” = 0.028 (mol dn") x2 (am) = 25x10 mot For a redox reaction, amount of electrons gained =amount of electrons lost 10° mol 1x10? Amount of electrons gained per mole of MnO,” =< 107 ean 4 25x10" =4 mole Hence, the oxidation state of Mn decreases by 4 units. (Oxidation state of Mn in MnO,” = +7 «+ Final oxidation state of Mn = 7—4= +3 ane 8 ry MCO wes Hats ais Ta an attempt to establish the formula of an oxide of nitrogen, a known volume of the pure gas was mixed with hydrogen and passed over a catalyst at a suitable tempera- ture, 100% conversion of the oxide to ammonia and water was shown to have taken place. Has) catalyst 2400 cm? of the nitrogen oxide, measured at room temperature and pressure (F.t.p), produced 7.20 g of ‘water, The ammonia produced was neutralised by 200 em? of 1.0 mol dm~™ HCl. NiOy XNH3 + yH20 [Molar volume of gas at rt.p. = 24000 cm? mol-!; Ae H, 1; O, 16.) What was the oxidation number of the nitrogen in the nitrogen oxide? a a cow Du Help Amount of #0 = 222 = 040 mot NH(aq) + HCl(ag) —> NH,"(aq) + Cl-faa) ‘Amount of HCI = coneantration x volume 2) 9g 200. ean =1.0 (mol dm »* F000 (om?) =02 mol 2 Amount of NH, =02 mol X__amount of NH, Hence, ~-

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