Material Balance for the Tannery Wastwater Treatment Plant

Basis(day)
1.0000
Basis(Hours)
INITIAL CHARACTERIZATION OF WASTEWATER POLLUTION LOAD GENERATED
Components
Mass in Kg
SS
116.0000
COD
188.0000
BOD
68.0000
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water

67.5000
7.0000
5.0000
15.0000
170.0000
81.0000
15.0000
637.0000
24094.6574

TOTAL EFFLUENT
Initial Flowrate, kg/hr
Initial Flowrate, L/hr

25464.1574
1061.0066
1065.6164

SCREENING
Components
SS
COD
BOD
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water

Mass in Kg
116.0000
188.0000
68.0000
67.5000
7.0000
5.0000
15.0000
170.0000
81.0000
15.0000
637.0000
24094.6574

TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr
EQUALIZATION
Components
SS
COD
BOD

Effluent Composition
2.3200
188.0000
68.0000
67.5000
7.0000
5.0000
15.0000
170.0000
81.0000
15.0000
12.7400
24094.6574
24726.2174
1030.2591
1034.7634

Effluent Composition
2.3200
188.0000
68.0000

Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water

67.5000
7.0000
5.0000
15.0000
170.0000
81.0000
15.0000
12.7400
24094.6574

TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr

24726.2174
1030.2591
1034.7634

FLOTATION CELL
Components
SS
COD
BOD
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr
FLOCCULATOR
Components
SS
COD
BOD
Cr6+
S2NH3-N
TKN
ClSO42Fats

Effluent Composition
0.0464
3.7600
1.3600
67.5000
7.0000
5.0000
15.0000
170.0000
81.0000
0.3000
12.7400
24094.6574
24458.3638
1019.0985
1023.5540

Effluent
0.0269
2.4816
1.3600
8.7750
7.0000
5.0000
15.0000
170.0000
81.0000
0.3000

Solid Effluents
Water

Basis (day)
Molar Masses

12.7400
24094.6574

7.0000

Basis (hr)
30.0260
96.0700
34.0860
61.0180
116.0100
103.0340
32.0700
18.0160

COD+BOD
SO42H2S
HCO3CrO42Cr(OH)3
S
H2O

FERMENTOR-BIOREACTOR 1
Amount of BOD+COD, kg
Amount of SO42- used, kg
Amount H2S produced, kg
Amount HCO3- prod, kg
Amount CrO42- used, kg
Amount Cr(OH)3 prod, kg
Amount S prod, kg
Amount H2O prod, kg
Amount H+ used, kg
Amount of SRB, L/hr
TOTAL ENTERING FLOWRATE, L/hr

3.8416
6.1457
0.2423
7.8068
0.5497
0.4882
0.4559
0.0854
0.0096
14.5863
160.4494

FERMENTOR-BIOREACTOR 4
Components

Amount of BOD+COD, kg

SS
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
Cr(OH)3
HCO3S
Total, kg
Flowrate, kg/hr
Flowrate, L/hr

0.0081
6.5761
7.0000
5.0000
15.0000
170.0000
56.4171
0.3000
12.7400
24094.9989

Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount

of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount

of BOD+COD, kg
of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

1.9530
31.2272
1.5957
24402.8160
145.2549
145.8899

FERMENTOR-BIOREACTOR 6
Components
SS
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
Cr(OH)3
HCO3S
Total, kg
Flowrate, kg/hr
Flowrate, L/hr
FERMENTOR-BIOREACTOR 8

0.0081
5.4766
7.0000
5.0000
15.0000
170.0000
44.1257
0.3000
12.7400
24095.1696
2.9294
46.8408
2.0516
24406.6418
145.2776
145.9128

Components
SS
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water

0.0081
4.3772
7.0000
5.0000
15.0000
170.0000
31.8343
0.3000
12.7400
24095.3404

Cr(OH)3
HCO3-

3.9059
62.4543

S
Total, kg
Flowrate, kg/hr
Flowrate, L/hr

of BOD+COD, kg
of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

2.5075
24410.4676
145.3004
145.9357

Basis(days)

FLOCCULATOR
Components
SS
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
HCO3-

Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount

1.0000

Effluent
0.0047
0.4976
7.0000
5.0000
15.0000
170.0000
25.6886
0.3000
12.7400
24095.4257
9.1339

Basis (hours)

GRANULAR ACTIVATED CARBON FILTER

Components
Effluent
SS
0.000028096
Cr6+
0.4976
S20.1400
NH3-N
5.0000
TKN
15.0000
Cl3.4000
SO420.5138
Fats
0.0060
Solid Effluents
0.2548
Water
24095.4257
HCO30.1827
TOTAL, kg
24120.4206
Flowrate, kg/hr
1005.0175
Flowrate, L/hr
1009.4115
NITRIFICATION-DENITRIFICATION
NITRIFICATION 1
Components
SS
0.000028096
Cr6+
0.4976
S20.1400
Cl3.4000
SO420.5138
Fats
0.0060
Solid Effluents
0.2548
Water
24116.5787
HCO30.0103
TOTAL, kg
24121.4012
Flowrate, kg/hr
1005.0584
Flowrate, L/hr
1009.4525

FLOCCULATOR
Components
SS
Cr6+
S2ClSO42Fats
Solid Effluents
Water
HCO3-

Effluent
0.000016296
0.0647
0.1400
3.4000
0.5138
0.0060
0.2548
24137.7317
9.3149

Sludge
0.001376710
6.8600

166.6000
25.1748
0.2940
12.4852
8.9513
220.3666
9.1819
18.3639

NITRIFICATION 2
Components
SS
Cr6+
S2ClSO42Fats
Solid Effluents
Water
HCO3TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr

CHLORINATION TANK
Components
SS
Cr6+
S2ClSO42Fats
Solid Effluents
Water

0.00000489
0.0647
0.1400
4.4000
0.5138
0.0060
0.2548
24137.7317

TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr

24143.1110
1005.9630
1010.3611

24.0000

Density (kg/hr)

GENERATED

nt Composition

Sludge Composition
113.6800

624.2600

737.9400
30.7475

995.6470

Sludge Composition
2.2736
184.2400
66.6400

14.7000

267.8536
11.1606

Sludge
0.0195
1.2784
58.7250

CENTRIFUGE
Components
SS
COD
BOD
Cr6+
S2NH3-N
TKN
ClSO42Fats

Effluent
0.0081
2.4816
1.3600
8.7750
7.0000
5.0000
15.0000
170.0000
81.0000
0.3000

Solid Effluents
Water

12.7400
24094.6574

TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr

24398.3221
1016.5968
1021.0413

168.0000
Entering flowrate, kg/hr
Entering flowrate, L/hr

Components
SS
COD
BOD
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water

0.4882
7.8068

0.4559

nt of BOD+COD, kg

FERMENTOR-BIOREACTOR 2
Components
SS
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water

0.0081
0.0000
0.0000
8.2253
7.0000
5.0000
15.0000
170.0000
74.8543
0.3000
12.7400
24094.74

Cr(OH)3
HCO3-

Total, kg
Flowrate, kg/hr
Flowrate, L/hr

145.2281
145.8630

Cr(OH)3
HCO3S
Total, kg
Flowrate, kg/hr
Flowrate, L/hr

24396.62
145.2180
145.8529

FERMENTOR-BIOREACTOR 5

0.0000

Components
SS
Cr6+

nt
nt
nt
nt
nt
nt
nt
nt

nt
nt
nt
nt
nt
nt
nt
nt
nt

of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

6.1457
0.2423
7.8068
0.5497
0.4882
0.2280
0.0854
0.0096

S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
Cr(OH)3
HCO3S
Total, kg
Flowrate, kg/hr
Flowrate, L/hr
FERMENTOR-BIOREACTOR 7

of BOD+COD, kg
of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

0.0000
6.1457
0.2423
7.8068
0.5497
0.4882
0.2280
0.0854
0.0096

Components
SS
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
Cr(OH)3
HCO3S
Total, kg
Flowrate, kg/hr
Flowrate, L/hr
FERMENTOR-BIOREACTOR 9
Components
SS

nt
nt
nt
nt
nt
nt
nt
nt
nt

of BOD+COD, kg
of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

0.0000
6.1457
0.2423
7.8068
0.5497
0.4882
0.2280
0.0854
0.0096

Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
Cr(OH)3
HCO3S
Total, kg
Flowrate, kg/hr
Flowrate, L/hr

24.0000

Sludge
0.0034
3.3299

61.1272

CENTRIFUGE
Components
SS
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr

Effluent
0.0014
0.4976
7.0000
5.0000
15.0000
170.0000
25.6886
0.3000
12.7400
24095.4257
24331.6533
1013.8189
1018.2513

FICATION 2

DENITRIFICATION
Components
SS
Cr6+
S2ClSO42Fats
Solid Effluents
Water
HCO3TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr

0.0000
0.4976
0.1400
3.4000
0.5138
0.0060
0.2548
24116.5787
0.0103
24121.4012
1005.0584
1009.4525

ate, kg/hr
ate, L/hr

Sludge
0.00001
0.4329

62.3380

CENTRIFUGE
Components
SS
Cr6+
S2ClSO42Fats
Solid Effluents
Water

Effluent
0.000004889
0.0647
0.1400
3.4000
0.5138
0.0060
0.2548
24137.7317

TOTAL, kg
Flowrate, kg/hr
Flowrate, L/hr

24142.1110
1005.9213
1010.3192

Sludge
0.0188

60.0417
2.5017
5.0035

EACTOR 2
Amount
0.0081 Amount
7.6755 Amount
7.0000 Amount
5.0000 Amount
15.0000 Amount
170.0000 Amount
68.7086 Amount
0.3000 Amount
12.7400
24094.8281

of BOD+COD, kg
of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

0.0000
6.1457
0.2423
7.8068
0.5497
0.4882
0.4559
0.0854
0.0096

0.9765
15.6136

FERMENTOR-BIORE
Components
SS
Cr6+
S2NH3-N
TKN
ClSO42Fats
Solid Effluents
Water
Cr(OH)3
HCO3-

0.9118

24398.7622
145.2307
145.8657

Total, kg
Flowrate, kg/hr
Flowrate, L/hr

ENTOR-BIOREACTOR 5

0.0081
6.0264

Amount of BOD+COD, kg

7.0000
5.0000
15.0000
170.0000
50.2714
0.3000
12.7400
24095.0843

Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount

of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount

of BOD+COD, kg
of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

2.4412
39.0340
1.8236
24404.7289
145.2662
145.9014

ate, kg/hr

ENTOR-BIOREACTOR 7

0.0081
4.9269
7.0000
5.0000
15.0000
170.0000
37.9800
0.3000
12.7400
24095.2550
3.4177
54.6475
2.2795
24408.5547
145.2890
145.9242

ate, kg/hr

ENTOR-BIOREACTOR 9

0.0081

3.8275
7.0000
5.0000
15.0000
170.0000
25.6886
0.3000
12.7400
24095.4257

Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount

4.3941
70.2611
2.7354
24412.3805
145.3118
145.9471

Sludge
0.0033

64.4637
2.6860
5.3720

of BOD+COD, kg
of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

0.000028096
0.4976
0.1400
3.4000
0.5138
0.0060
0.2548
24137.7317
71.6529
24214.1968
1008.9249
1013.3359

Sludge
0.000011

62.7709
2.6155
5.2309

ERMENTOR-BIOREACTOR 3
omponents
0.0081
7.1258
7.0000
5.0000
15.0000
170.0000
62.5629
0.3000
12.7400
24094.9135

olid Effluents

1.4647
23.4204
1.3677
24400.9031
145.2435
145.8785

owrate, kg/hr
owrate, L/hr

0.0000

Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount
Amount

of BOD+COD, kg
of SO42- used, kg
H2S produced, kg
HCO3- prod, kg
CrO42- used, kg
Cr(OH)3 prod, kg
S prod, kg
H2O prod, kg
H+ used, kg

0.0000
6.1457
0.2423
7.8068
0.5497
0.4882
0.4559
0.0854
0.0096

6.1457
0.2423
7.8068
0.5497
0.4882
0.2280
0.0854
0.0096

0.0000
6.1457
0.2423
7.8068
0.5497
0.4882
0.2280
0.0854
0.0096

0.0000
6.1457
0.2423
7.8068
0.5497
0.4882
0.2280
0.0854
0.0096

For Collection
Cr(OH)3
S

4.3941
2.7354