Renel M. Alucilja AENG 204: Advanced Engineering Thermodynamics 1. Prove the maxwell relations 1.

Maxwell # 3 s P = v T T let s = f(v,T)

s v
T

Maxwell relation 1 Equation 1&2

v T
s

T =1 s v

eq.1

T P = v s s

eq.2
v

s v
T

s P

T =1 s v

s v

T =1 P v

Relation 3.

s P = v T T s P

2. Maxwell # 4 v T let f(v,T,P)

=
P

v T
P

T P

P v

=1
T

eq. 1

constant P and constant T relationship between

T P
T

can be derived from 3.

substituting relation 3 to equation 1.

v T v T
P

v s

P v

=1

s P

maxwell relation IV

Assignment 3. Derived Maxwell relation II and IV using Helmholtz and Gibbs function. II.

T v = P s s
Solution:

dh=T dsv dP

enthalpy (1) constant entropy

v= T= v s
IV.

h P h s

(2)

constant pressure

2 h = P s P

T 2 h = P s s P

(3) 2nd order pde 1

sP

(4) 2nd order pde 2

Ps

therefore:

T v = P s s

v T =
P

s P

dg =s dT v dP
s=

Gibb's function (1) Constant Pressure

v=

g T g P
T

(2)

Constant entropy

therefore:

s 2 g = P T T P 2 g = PT P
PT

(3) 2nd order pde 1

v T

(4) 2nd order pde 2

TP

v T

s P