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h-kataura@aist.go.jp
SWCNT
SWCNT n,m
n-m 3 K SWCNT
SWCNT
2,3
1 ............................................... 2
1-1 ..................................................................... 2
1-2SWCNT ........................................................ 2
1-3SWCNT ..................................................... 3
2SWCNT ............................................................... 3
2-1 .......................................................... 4
2-2.................................................................. 4
2-3 ....................................................... 4
2-4.................................................................. 5
3SWCNT PERIPUTOS ............. 6
3-1 ............................................................................ 6
3-2 ............................................................................ 7
3-2-1 ....................................................... 7
3-2-2.................................................... 8
3-3 ............................................................................ 8
4 .......................................................................... 10
5 .......................................................................... 10
4,5
sp2 SWCNT
SWCNT
SWCNT
ITO
1SWCNT (8,3)-SWCNT
1
1-1
1-2SWCNT
SWCNT 15
1993 Iijima
SWCNT1993
SWCNT
Iijima SWCNT
Ni Y
SWCNT
SWCNT
SWCNT
SWCNT
1
6
SWCNT
SWCNT
1200
SWCNT 7
SWCNT
SWCNT
KK
SWCNT
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10.12.14 11:37:43 AM
Deposition, CVD 2
CVD
SWCNT Scanning
SWCNT HiPco
CoMoCAT 9SWCNT
SWCNT
CVD
SWCNT
Maruyama
SWCNT
Hata
10
SWCNT
SWCNT 2
1 SWCNT
11
1
SWCNT
1-3SWCNT
SWCNT
CVD SWCNT
SWCNT
SWCNT
1 /g
FeNiCoMoY
30 /g
SWCNT SWCNT
SWCNT
sp2
SWCNT
SWCNT
SWCNT
SWCNT
SWCNT
SWCNT
SWCNT
SWCNT
SWCNT
SWCNT
Multi-Wall Carbon Nanotube, MWCNT
MWCNT
MWCNT
SWCNT
SWCNT MWCNT
2SWCNT
SWCNT
2 SWCNT SEM
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2-1
SWCNT
SWCNT
TGA
SWCNT
SEM Transmission Electron
Microscope, TEMSEM m
SWCNT
SEM
SWCNT SWCNT
TEM SEM
1 SWCNT SWCNT
TEM
3SWCNT
TEM
12
SEMTEM
2-3
SWCNT 1
van Hove
1
SWCNT
2-2
SWCNT 13 4
SWCNT CO2
3 SWCNT
TGA SWCNT
300 500
SWCNT
SWCNT
SWCNT
4 SWCNT
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10.12.14 11:37:46 AM
1.0 nm SWCNT
1100 nm
SWCNT 1 Es11700 nm
Es SWCNT 500 nm 1
22
EM11 Es33Es44EM22
SWCNT
SWCNT
SWCNT
2-4
SWCNT
6
CVD SWCNT
633 nm He-Ne
SWCNT ES22
ES11
SWCNT
SWCNT
14ES11
ES11
SWCNT
SWCNT
ES22
2
5 SWCNT
SWCNT
15
SWCNT
3
1 150 300 cm-1
Radial Breathing ModeRBMRBM
RBM
RBM SWCNT
SWCNT
RBM SWCNT
SWCNT
10% Dnm=248 /
Rcm-1 D SWCNT
R RBM
5SWCNT SWCNT
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10.12.14 11:37:48 AM
1593 cm-1
G G Graphite
sp2
SWCNT
SWCNT
G
SWCNT
3 1350 cm-1
sp2 DefectD
SWCNT SWCNT
D SWCNT
D
G D SWCNT
SWCNT
3SWCNT
PERIPUTOS
3-1
SWCNT
TGA
1000
SWCNT
633 nm He-Ne
RBM 1.0 nm
SWCNT 2
1 SWCNT
ES 6
1 100
SWCNT
SWCNT 2
SWCNT
7 SWCNT
22
488 nm Ar
+
488 nm EM11
SWCNT SWCNT
SWCNT LO G
Breit-Wigner-Fano BWF
SWCNT G
SWCNT
SWCNT
8PERIPUTOS
SWCNT
PERIPUTOS
16
PERIPUTOS "Purity Evaluated by Raman Intensity of Pristine and
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10.12.14 11:37:49 AM
PERIPUTOS
SWCNT G
1650 G10min
SWCNT
SWCNT
SWCNT
SWCNTPristine-SWCNT
SWCNT
Pristine-SWCNT 219000
G15min 40 %
SWCNT
SWCNT 100
40 %
SWCNT
SWCNT
SWCNT
SWCNT
SWCNT
2 wt.% SC 1
SWCNT
SWCNT
SWCNT
17
SWCNT 100%
100%
100% SWCNT
SWCNT
100 % 100%-SWCNT
100%-SWCNT
SEM SEM
SWCNT
7
HiPco 2 SWCNT
SWCNT SEM
SWCNT SWCNT
3-2
SWCNT
3-2-1
SWCNT
SWCNT 50 mg 2 wt.%
Sodium CholateSC
SWCNT
50 ml 30
RBM
1/2 20 W/cm
8 Pristine-SWCNT 100%-SWCNT
SWCNT 3
SWCNT
15
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CCD
PristineSWCNT100%-SWCNT SC SWCNT
3-3
SWCNT
9 2
HiPco
SWCNT
SWCNT SC
0%-SWCNT
100%-SWCNT
SWCNT
11 SWCNT
10 SWCNT
3-2-2
SWCNT
G
SWCNT 10 mW
CCD
3++++.indd 8
11SWCNT 0% 100%
633nm
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10.12.14 11:37:52 AM
0 % 13
G 0 %
100 %
G
0 % 0 SWCNT
1213
Pristine-SWCNT 13
Pristine-SWCNT G
PERIPUTOS 58 %
12 633 nm
12 SWCNT
633nm
SWCNT
SWCNT
488
nm SWCNT
Pristine-SWCNT
G
14 SWCNT
SWCNT S/N
G SWCNT
Pristine-SWCNT PERIPUTOS 58 %
SWCNT
PERIPUTOS
SWCNT
TGA
SWCNT
13 12 G
TGA
Pristine-SWCNT 100%-SWCNT G
SWCNT
SWCNT
SWCNT
W M SWCNT
0 %
SWCNT
SWCNT 40 % 29 %
12
31 %
G
SWCNT
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4
SWCNT
SWCNT
SWCNT
TGA
SWCNT
SWCNT
SWCNT
SWCNT
5
S. Iijima; T. Ichihashi, Nature, 1993, 363, 603.
R. Saito; M. Fujita; G. Dresselhaus; M. S Dresselhaus, App. Phys. Lett., 1992, 60, 2201.
N. Hamada; S. Sawada; A. Oshiyama, Phys. Rev. Lett., 1992, 68, 1579.
J. W. G. Wildoer; L. C. Venema; A. G. Rinzler; R. E. Smalley; C. Dekker, Nature, 1998,
391, 59.
5 T. W. Odom; J.-L. Huang; P. Kim; C. M. Lieber, Nature, 1998, 391, 62.
6 C. Journet; W. K. Maser; P. Bernier; A. Loiseau; M. L. Chapelle; S. Lefrant; P. Deniard; R.
Leek & J. E. Fischer, Nature, 1997, 388, 756.
7 A. Thess; R. Lee; P. Nikolaev; H. Dai; P. Petit; J. Robert; C. Xu; Y. H. Lee; S. G. Kim; A. G.
Rinzler; D. T. Colbert; G. E. Scuseria; D. Tomanek; J. E. Fischer; R. E. Smalley, Science,
1996, 273, 483.
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Smalley, Chem. Phys. Lett., 1999, 313, 91.
9 S. M. Bachilo; L. Balzano; J. E. Herrera; F. Pompeo; D. E. Resasco; R. B. Weisman, J. Am.
Chem. Soc., 2003, 125, 11186.
10 S. Maruyama; R. Kojima; Y. Miyauchi; S. Chiashi; M. Kohno, Chem. Phys. Lett., 2002,
360, 229.
11 K. Hata; D. N. Futaba; K. Mizuno; T. Namai; M. Yumura; S. Iijima, Science, 2004, 306,
1362.
12 Y. Sato; K. Yanagi; Y. Miyata; K. Suenaga; H. Kataura; S. Iijima, Nano Lett., 2008, 8,
3151.
13 H. Kataura; Y. Kumazawa; Y. Maniwa; I. Umezu; S. Suzuki; Y. Ohtsuka; Y. Achiba, Synth.
Met., 1999, 103, 2555.
14 M. J. O Connell; S. M. Bachilo; C. B. Huffman; V. C. Moore; M. S. Strano; E. H. Haroz; K.
L. Rialon; P. J. Boul; W. H. Noon; C. Kittrell; J. Ma; R. H. Hauge; R. B. Weisman; R. E.
Smalley, Science, 2002, 297, 593.
15 S. M. Bachilo; M. S. Strano; C. Kittrell; R. H. Hauge; R. E. Smalley; R. B. Weisman,
Science, 2002, 298, 2361.
16 D. Nishide; Y. Miyata; K. Yanagi; T. Tanaka; H. Kataura, Phys. Status Solidi B, 2009, 246,
2728.
17 D. Nishide; Y. Miyata; K. Yanagi; T. Tanaka; H. Kataura, Jpn. J. App. Phys., 2009, 48,
015004.
1
2
3
4
14488nm
488nm
G
10
3++++.indd 10
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10.12.14 11:37:54 AM
704113-250MG, 1G
724777-250MG, 1G
704148-250MG, 1G
704121-250MG, 1G
652482-100MG
639230-100MG
652474-100MG
685380-100MG
652490-250MG1G
1, 71.
Reference 1Niyogi, S. et al. Accts. Chem. Res. 2002, 35, 1105. 2Zhao, B. et al. J. Am. Chem. Soc. 2005, 127, 8197. 3Zhao, B. et al. Adv. Funct. Mater. 2004, 14
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1 2
1
2
uchida-kunio@aist.go.jp
s-endoh@aist.go.jp
MWCNT
10
nm 5000
1 .......................................................................... 12
2 .......................................................................... 12
2-1................................................................ 13
2-2 .......................................................................... 13
2-3 .......................................................................... 13
2-4 .......................................................................... 13
2-5 .......................................................................... 14
2-6 ................................................................... 14
3 ................................................................................. 14
3-1 ....................................................................... 14
3-2TEM ......................................... 14
4 .......................................................................... 15
5 .......................................................................... 15
100 nm
MWCNT
MWCNT 450 nm
MWCNT 2
3 MWCNT
1
1990 C60
1991
MWCNT 1
MWCNT MWCNT
1a 1b
0.1 %
2
MWCNT SEM
CNT
CNT
2006 5 NEDO
2000
CVD
MWCNT CVD
NEDO CVD MWCNT
CVD MWCNT
2000
MWCNT 3a MWCNT
1a
SEM
12
3++++.indd 12
1b MWCNT
SEM
20 m
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10.12.14 11:38:03 AM
2-2
300 ml 30 g
120100 ml
5
120 5
3aCVD WCNT 3bCVD MWCNT
TEM
TEM
MWCNT 30 nm MWCNT
3b MWCNT
MWCNT MWCNT
5
MWCNT
MWCNT
MWCNT MWCNT
2-3
MWCNT 2 mm
0.2 ml
20 mm 540 g 250 ml
450 rpm 2 15
2-1
2 30
0.2 ml
MWCNT 2.0 g 50 ml 20
mm 540 g 90 cm3 250
ml MONO
2-4
5 mm
10 4
6 300 ml
5 mm
80 24 0.45
MWCNT 500 ml
m 300 ml
300 ml 120
80 2
0.5
0.1%
7
6MWCNT
400 ml
5 ml 100 ml
80 12 1 m
4
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13
10.12.14 11:38:17 AM
2-5
2-6
Triton X-1000.5
MWCNT CNT
450W 30 MWCNT
MWCNT 10 ml
H-9R
120 5
350 30
3000G
3000G 3 TEM 8
ml Triton-X100 CNT
MWCNT
1 mg/ml
3000G 20000G
20000G 3000 20000G
MWCNT TEM 9a
5 m MWCNT
TEM 9b MWCNT
10 11 TEM
20000G MWCNT
3
3-1
CNT 1 mg/ml 4
12 UPA
4
83000G TEM
12MWCNT
3-2TEM
9aMWCNT TEM
9bMWCNT TEM
10
MWCNT
14
3++++.indd 14
1120000G TEM
13
MWCNT
TEM
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10.12.14 11:38:25 AM
MWCNT
MWCNT
6
MWCNT
NEDO
14MWCNT
4
NEDO
5
5
S. Iijima Nature, 1991, 354, 56.
U.S. Pat. No.5, 1996, 560, 898.
33 , 1995, 167.
3650819 , 2005.
Y. Morimoto et al. "Deposition and biopersistence of inhaled MWCNT in rat lung".
Nanotoxicology 2010, Edinburgh, UK.
6 T. Seto et al. Aerosol Sci. and Technol., 2010, 44, 734.
1
2
3
4
5
www.sigma-aldrich.com/nano-jp
CoMoCAT
724769-25G, 100G
10 - 15 nm 2 - 6 nm 0.1 - 10 m 5 15
ICP TEM
CVD
677248-5G, 25G
BET
698849-1G
CVD
659258-2G, 10G
687804-1EA
687812-1EA
Vacuum Release
CNT MWCNT SEM
SEM 10 m
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Aldrich
2-1
3 3-1
3-2
3-3
4-1
4-2
4-3
24-4
5-1
5-2
5-3
URL
http://www.sigma-aldrich.com/mscatalog-jp
Material Matters
sialjp@sial.com
CoMoCAT and SWeNT are registered trademarks of SouthWest NanoTechnologies, Inc. Graphistrength is a registered trademark of Arkema Inc. Sigma, Aldrich and SigmaAldrich are registered trademarks of Sigma-Aldrich Biotechnology LP and Sigma-Aldrich Co.. Vacuum Release is a trademark of Gel-Pak. Material Matters is a trademark of
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