Professional Documents
Culture Documents
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absorbed 276 J of heat. The initial temperature was 25.0 C. What was the final temperature?
q T T Tf c m T (0.129 J/g C)(4.50 g) Tf 25.0 C 475 C q (276 J) _ __ cm Tf 5.00 Ti 475 C
Practice Problems
pages 519521
_
1000 cal 1 kcal
102 C
after yourself, with a magnitude of one-tenth of a calorie. What conversion factors relate this new unit to joules? To Calories?
Unit X
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
1 cal X
1 cal X
energy in the following examples: two separated magnets; an avalanche of snow; books on library shelves; a mountain stream; a stock-car race; separation of charge in a battery.
Two separated magnets illustrate potential energy. In a snow avalanche, positional potential energy is changing to kinetic energy. Books on a shelf illustrate positional potential energy. As water races down a mountain stream, positional potential energy is changing to kinetic energy. In a stock-car race, chemical potential energy is being changed to kinetic energy. The separation of charge in a battery illustrates electrical potential energy.
0.0001 Calorie
from 25.0C to 78.8C, how much heat has been absorbed by the ethanol? Refer to Table 15.2.
q q c m T 34.4 g 53.8C 4.52 103 J 2.44 J/(g C)
heated from 25.0C to 40.0C. In the process, the substance absorbed 5696 J of energy. What is the specific heat of the substance? Identify the substance among those listed in Table 15.2 on page 520.
q c c m T (155 g)(40.0 25.0C) 2.45 J/(g C) q (5696 J) _ ___ m T
The specific heat is very close to the value for ethanol. Solutions Manual Chemistry: Matter and Change Chapter 15
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5.50 g of aluminum is heated from 25.0 C to 95.0 C. The specific heat of aluminum is 0.897 J/(g- C).
q q q cm T (0.897 J/(g C))(5.50 g)(95.0 C 345 J 25.0 C)
gold, iron, and silver were left to sit in the Sun at the same time and for the same length of time. Use Table 15.2 on page 520 to arrange the four metals according to the increase in their temperatures from largest increase to smallest.
The temperature change is inversely proportional to the specific heat: aluminum, iron, silver, gold.
Practice Problems
page 525
25.6 J of heat as its temperature increased 1.18 C. What is the specific heat of the metal?
q c m c T 90.0 g 1.18 C 25.6 J c
0.241 J/(g C)
from 20.0 C to 46.6 C as it absorbs 5650 J of heat. What is the mass of the sample?
q c m T m 26.6 C 5650 J m 4.184 J/(g C)
heat of a substance in order to calculate how much heat is gained or lost by the substance as a result of a temperature change.
The specific heat of a substance tells you the number of joules that are lost or gained for every degree change in temperature and for every gram of the substance.
50.8 g
103 g granite boulder (cgranite 0.803 J/(g C)) as its temperature changes from 10.0 C to 29.0 C?
q q q c m T 2.00 103 g 19.0 C 0.803 J/(g C) 30,500 J
namics, and explain how the system is related to the surroundings and the universe.
The system is the particular part of the universe that contains the reaction or process that is being studied. The surroundings are everything in the universe except the system. Thus the universe is the system and its surroundings. Solutions Manual
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unknown substance if a 2.50 g sample releases 12.0 cal as its temperature changes from 25.0 C to 20.0 C.
q c cm T q 12 cal)(4.184 J/cal) _ (__ m T (2.50 g)( 5.0 C) 4.02 J/(g C)
which are distinguished by an abrupt change in slope. Indicate how the absorption of heat changes the energy (kinetic and potential) of the water molecules.
From 20 C to 0.0 C, the water molecules in ice gain kinetic energy as shown by the temperature rise. While the temperature remains at 0.0 C, the water molecules gain potential energy as the ice melts to liquid water in an endothermic process. As the temperature rises from 0.0 C to 100 C, the water molecules again gain kinetic energy. At 100 C, the water molecules gain potential energy in an endothermic process as they evaporate to water vapor.
you could follow to determine the specific heat of a 45-g piece of metal.
Put a known mass of water into a calorimeter and measure its temperature. Heat a 45-g metal sample to 100 C in boiling water. Put the heated metal sample into the water in the calorimeter and wait until the temperature of the water is constant. Measure the final temperature of the water. Assume no heat is lost to the surroundings. Calculate the specific heat of the metal by equating the quantity of heat gained by the water to the quantity of heat lost by the metal.
through each region of the graph (180 g H2O 10 mol H2O, Hfus 6.01 kJ/mol, Hvap 40.7 kJ/mol, c 4.184 J/(g- C)). How does the length of time needed to pass through each region relate to the amount of heat absorbed?
The more heat required, the longer the time in the region. For the region 20 C to 0.0 C, use the equation: q c m T q 4.184 J/(g C) 180 g 1.5 104 J or 15 kJ For the region at 0.0 C, Heat absorbed 20 C 6.01 kJ/mol 10 mol 60 kJ
pages 529533
Problem-Solving Lab
page 531
Hfus
6.01 kJ/mol
For the region 0.0 C to 100 C, use the equation: q c m T q 4.184 J/(g C) or 75 kJ 180 g 100 C 7.5 10 4J
Hvap
40.7 kJ/mol
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look like? Ethanol melts at 114 C and boils at 78 C. Sketch ethanols curve from 120 C to 90 C. What factors determine the lengths of the flat regions of the graph and the slope of the curve between the flat regions?
From 120 C to 114 C the curve rises linearly. At 114 C it becomes horizontal for a time and then rises linearly again until it reach 78 C where it becomes horizontal again. After a time the curve rises again to 90 C. The lengths of the flat regions depend on the amount of ethanol being heated and the amount of heat being added with time. Those factors and the specific heat of the substance determine the slope of the upward curve between the flat regions.
C2H5OH(l) Hcomb
3O2(g) 1367
0 2CO2(g) + 3H2O(l)
8O2(g) 0 5CO2(g)
6H2O(l)
Practice Problems
page 532
286 kJ 1 mol _ _
17.03 g NH3
1 mol NH3
376 kJ
Enthalpy
be burned in order to liberate 12,880 kJ of heat? Refer to Table 15.3 on page 529.
m 1 mol CH 891 kJ __ _
4
A H C
31. Interpreting Scientific Illustrations The
12,880 kJ
16.04 g CH4
4
1 mol CH4
4
m m
reaction A 0 C is shown in the enthalpy diagram at right. Is the reaction exothermic or endothermic? Explain your answer.
The reaction is exothermic because the product (C) has a lower enthalpy than the reactant (A).
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Practice Problems
pages 537541
H for the
following reaction. 2CO(g) 2NO(g) 0 2CO2(g) N2(g) H ? a. 2CO(g) O2(g) 0 2CO2(g) H 566.0 kJ
b. N2(g)
equations produces each of the following reactions. You do not need to look up and include H values. a. 2NO(g) O2(g) 0 2NO2(g)
Formation of NO: N2 Formation of NO2: N2 O2
0 2NO 0 2NO2
O2(g) 0 2NO(g) H
180.6 kJ
2O2
Add the first equation to the second equation reversed. 2CO(g) 2NO(g) 2CO(g) O2(g)
NO is a reactant in the problem, so add the reversed NO formation equation to the NO2 formation equation: 2NO 2NO N2 O2 2O2
0 2CO2(g)
O2(g)
H H
566.0 kJ 180.6 kJ
0 N2
O2
2NO2
0 N2(g)
b. SO3(g)
H2(g) SO3(g) H2O(l) SO3(g)
S(s)
2O2(g) 2
1789 kJ. Use this and reaction a to determine H for Reaction b. 4Al(s) 3MnO2(s) 0 2Al2O3(s) 3Mn(s) H 1789 kJ a. 4Al(s) 3O2(g) 0 2Al2O3(s) H 3352 kJ
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
0 S(s) 0 H2(g)
H2O(l)
3 _ O (g)
2
1 _ O (g) 2
2
0 H2SO4(l)
3O2(g) 0 2Al2O3(s)
3352 kJ
O2(g) 0 MnO2(s) H
O2(g) 0 MnO2(s) H for equation b. H
Table R-11 on page 975, to calculate H for the following reaction. 4NH3(g)
H H
rxn rxn
rxn
?
x kJ
6H2O(l)
4Hf (NO3)
Add the Equation a to Equation b reversed and tripled. 4Al(s) 3O2(g) 0 2Al2O3(s) 3O2(g) H H 3352 kJ 3x kJ 3Mn(s)
36. Determine
H comb butanoic acid, C3H7COOH(l) 5O2(g) 0 4CO2(g) 4H2O(l). Use data in Table R-11 on page 975 and the following equation. 4C(s) 4H2(g) 534 kJ O2(g) 0 C3H7COOH(l) H
4Hf (CO2)] 4( 394 kJ)] ( 534 kJ)
Because the direction of Equation b was changed, H for equation b x 3352 1789 521 kJ 3
__
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tions, a and b, combine to form the equation for the reaction of nitrogen oxide and oxygen. The product of the reaction is nitrogen dioxide: 1 NO(g) O (g) 0 NO2(g) Hrxn 2 2 58.1 kJ
The enthalpy of the reaction under standard conditions (1 atm and 298 K) equals the sum of the standard enthalpies of formation of the products minus the sum of the standard enthalpies of formation of the reactants.
a. b.
91.3 kJ ?
1 _ N (g) 2
2
O2(g) 0 NO2(g) H
What conclusion can you draw about the stabilities of the compounds listed relative to the elements in their standard states? Recall that low energy is associated with stability.
All compounds listed in Table 15.5 are more stable than their constituent elements.
c. NO(g) 0 1 N2(g)
2
_
2
1 _ O (g) 2
2
Hf
91.3 kJ
Hf (b)
H for the reaction NO(g) O(g) 0 NO2(g) H ? given the following reactions. Show your work. a. O2(g) 0 2O(g) H 495 kJ
b. 2O3(g) 0 3O2(g)
427 kJ O2(g) H
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
33.2 kJ
c. NO(g)
it is used to determine H
rxn.
Hesss law says that if two or more equations add up to an overall equation, the H rxn of the overall equation is the sum of the H rxn values of the equations that were combined. The H rxn of a reaction can be determined by choosing equations that contain the species in the overall equation, reversing the equations if necessary, and multiplying them and their H rxn values by whatever factors are necessary. Then add the H rxn values to obtain the value for the overall equation.
Reverse b and change the sign of 3O2(g) 0 2O3(g) H 427 kJ Reverse a and change the sign of 2O(g) 0 O2(g) H 495 kJ
Add the three equations and their H values: 2NO(g) 2O(g) 0 2NO2(g) H 466 kJ This is the equation and H for 2 moles of NO reacting. Divide the equation and H by 2: NO(g) O(g) 0 NO2(g) H 233 kJ
to determine H
H
rxn
rxn
Hf (products)
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data below to draw a diagram of standard heats of formation similar to Figure 15.15 on page 538, and use your diagram to determine the heat of vaporization of water at 298 K. Liquid water: Hf Gaseous water: Hf 285.8 kJ/mol 241.8 kJ/mol
Ssystem is positive because the systems entropy increases. Entropy increases when a solid or liquid dissolves to form a solution.
d. C10H8(l) 0 C10H8(s)
Ssystem is negative because the systems entropy decreases. Solid particles have less freedom to move around than liquid particles.
Students diagrams will show a line representing liquid water at 285.8 kJ/mol below 0.0 kJ and a line representing gaseous water 241.8 kJ/mol below 0.0 kJ. The heat of vaporization is the energy difference between the two lines or 241.8 kJ ( 285.8 kJ) 44.0 kJ
for the following reaction. Fe(s) Zn2 (aq) 0 Fe2 (aq) Zn(s)
Ssystem
The states of the two reactants are the same on both sides of the equation, so it is impossible from the equation alone to predict the sign of Ssystem.
0 Hf (kJ/mol)
273 K,
Hvap
44.0 kJ/mol
spontaneous reaction
b.
Hsystem Ssystem
Ssystem Gsystem Gsystem
535 K,
0.0552 kJ/K
Practice Problems
pages 545548
Gsystem
nonspontaneous reaction
Ssystem is negative because the systems entropy decreases. There are more gaseous reactant particles than product particles.
Hsystem Ssystem
Ssystem Gsystem Gsystem Gsystem
388 K,
0.0552 kJ/K
b. NH3(g) 0 NH3(aq)
Ssystem is negative because the systems entropy decreases. Aqueous particles have less freedom to move around.
c. CH3OH(l) 0 CH3OH(aq)
Solutions Manual
nonspontaneous reaction
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d.
Hsystem Ssystem
Ssystem Gsystem Gsystem Gsystem
165 K,
0.0557 kJ T Ssystem
The systems entropy increases. The system consists of the sugar and tea. Randomness or disorder increases as sugar molecules, which were originally locked into position in the solid structure of the sugar cube, disperse throughout the tea.
Hsystem 20.5 kJ, T 298 K, and Ssystem 35.0 J/K is spontaneous or nonspontaneous.
Ssystem Gsystem 10.1 kJ 35.0 J/K 20.5 kJ 0.0350 kJ/K (298 K)( 0.0350 kJ/K)
nonspontaneous reaction
Hsystem 144 kJ and 36.8 J/K for a reaction, determine Ssystem the lowest temperature in kelvins at which the reaction would be spontaneous.
Gsystem Hsystem T Ssystem
For the reaction to be spontaneous: Gsystem < 0: Hsystem T Ssystem < 0 H T>_
system
outline the section. Under each heading, summarize the important ideas discussed.
Students outlines chould include all important ideas expressed in the Section Summary.
Ssystem
T>
Writing in Chemistry
page 549
complete combustion of 1 mol octane (C8H18), a component of gasoline, and 1 mol ethanol 5471 kJ/mol; Hcomb ( Hcomb of C8H18 1367 kJ/mol). Which releases of C2H5OH the greater amount of energy per mole of fuel? Which releases more energy per kilogram of fuel? Discuss the significance of your findings.
C2H5OH(l) 3O2(g) 0 2CO2(g) 1367 kJ/mol C8H18(l) 25/2O2(g) 0 8CO2(g) 5471 kJ/mol 3H2O(l) 9H2O(l) Hcomb Hcomb
nonspontaneous reactions.
A reaction occurs spontaneously only when the temperature, entropy change within the system, and energy exchanged between the system and surroundings cause the entropy of the universe to increase.
Octane releases the greater amount of energy per mol. 1 mol of ethanol 1 mol of octane 46.07 g/mol 114.23 g/mol
1367 kJ 1000 g _ _ _ 1 mol 1 mol 46.07 g 1 kg 29,670 kJ/kg ethanol 1000 g 5471 kJ 1 mol _ _ _ 114.23 g 1 mol 47,890 kJ/kg octane 1 kg
or decrease when you dissolve a cube of sugar in a cup of tea? Define the system, and explain your answer.
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Chapter 15 Assessment
pages 552555
Mastering Problems 62. Nutrition A food item contains 124 nutritional Calories. How many calories does the food item contain?
124 Calories 1000 calories __ 1 Calorie 124,000 calories
Some is converted to work to move pistons in the engine; much is released as heat.
compare with the calorie? What is the relationship between the Calorie and a kilocalorie?
One nutritional Calorie equals 1000 calories. One nutritional Calorie equals 1 kilocalorie.
additive to gasoline. The combustion of 1 mol of ethanol releases 1367 kJ of energy. How many Calories are released?
1367 kJ 1000 J 1 cal 1 Calorie _ _ _ 4.184 J 1000 cal 1 kJ 327 Calories
65. To vaporize 2.00 g of ammonia 656 calories are 58. What quantity has the units J/(g C)?
specific heat
required. How many kilojoules are required to vaporize the same mass of ammonia?
656 cal 4.184 J 1 kJ _ _ 1 cal 1000 J 2.74 kJ
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absorbed 250 joules of heat as its temperature changed from 25.0 C to 78.0 C. What is the specific heat of the alloy?
T c c 78.0 C 25.0 C m T 25.0 g 0.189 J/g C 53.0 C 53.0 C q 250 J _ __
H, is negative. What does this indicate about the chemical potential energy of the system before and after the reaction?
The systems chemical potential energy is less after the reaction than before the reaction.
Section 15.2
Mastering Concepts 68. Why is a foam cup used in a student calorimeter rather than a typical glass beaker?
The foam cup is better insulated than a glass beaker, so that a minimal amount of heat is transferred into or out of the calorimeter.
Mastering Problems 74. How many joules of heat are lost by 3580 kg granite as it cools from 41.2 C to 12.9 C? The specific heat of granite is 0.803 J/(g C).
T 41.2 C ( 12.9 C) 54.1 C 106 g)(54.1 C)
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Products
Enthalpy
qgranite
H = 233 kJ
Reactants The reaction is endothermic because the enthalpy of the products is 233 kJ higher than the enthalpy of the reactants.
qgranite
measuring 20.0 m 12.5 m is filled with water to a depth of 3.75 m. If the initial temperature is 18.4 C, how much heat must be added to the water to raise its temperature to 29.0 C? Assume that the density of water is 1.000 g/mL.
Change the dimensions of the pools water from meters to centimeters. 20.0 m 3.75 m 2.00 3.75 103 cm; 12.5 m 102 cm 1.25 103 cm; 103 cm)
volume of water (2.00 103 cm)(1.25 (3.75 102 cm) 9.38 108 cm3 9.38 108 mL mass of water 9.38 108 g q T q c m (29.0 C T 18.4 C) 10.6 C 108 g)(10.6 C) (9.38
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at 25.0 C is placed in a wok, 3.34 kJ of heat is required to heat it to a temperature of 196.4 C. What is the specific heat of canola oil?
3.34 kJ T q c c m Tf m T 1000 J _ 1 kJ Ti 3340 J 25.0 C 171.4 C
body.
Your body is cooled as it supplies the heat required to vaporize water from your skin.
q 3340 J _ __
placed in 125 g of cold water in a calorimeter, the temperature of the alloy decreases by 106.1 C while the temperature of the water increases by 10.5 C. What is the specific heat of the alloy?
q c m T; qwater qalloy
Mastering Problems 83. Use information from Figure 15.24 to calculate how much heat is required to vaporize 4.33 mol of water at 100 C? Phase Changes for Water H2O(g) Hvap = +40.7 kJ
Enthalpy
4.184 J/(g C) 125 g 10.5 C calloy 58.8 g 106.1 C calloy calloy (4.184 J/g C)(125 g)(10.5 C) ___ (58.8 g)(106.1 C) 0.880 J/(g C)
Section 15.3
Mastering Concepts 79. Write the sign of Hsystem for each of the following changes in physical state.
a. C2H5OH(s) 0 C2H5OH(l)
Hsystem is positive. q q mol
4.33 mol
b. H2O(g) 0 H2O(l)
Hsystem is negative.
c. CH3OH(l) 0 CH3OH(g)
Hsystem is positive.
during a frosty night. If an average of 11.8 g of water freezes on each orange, how much heat is released?
11.8 g H2O q q mol 1 mole H O __
2
18.0 g
d. NH3(l) 0 NH3(s)
Hsystem is negative. Solutions Manual
0.656 mol
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burned in a barbecue grill to release 4560 kJ of heat? The Hcomb of propane is 2219 kJ/mol.
mol Hcomb 4560 kJ __ 2219 kJ/mol 2.055 mol
H for a thermochemical equation change when the amounts of all substances are tripled and the equation is reversed?
H is tripled, and its sign is changed.
0.0 Hf (kJ/mol)
Al(s), Cl2(g)
90.60 g
ated when 5.00 kg of coal is burned if the coal is 96.2% carbon by mass and the other materials in the coal do not react in any way? Hcomb of carbon 394 kJ/mol.
mcarbon mcoal 0.962 1000 g _ 1 kg 4810 g 401 mol C 1000 g (5.00 kg)(0.962)(_) 1 kg mol C q q mol 4810 g C Hcomb ( 394 kJ/mol C) 158,000 kJ
-704
AlCl3 (s)
1 mol _ 12.0 g C
equation for the formation of 1 mol of aluminum chloride (a solid in its standard state) from its constituent elements in their standard states.
Al(s) 3 _ Cl (g) 0 AlCl (s) 2
2 3
704 kJ
401 mol C
1255 g
2830 kJ
5.66 kJ/mol) liberates 5.66 kJ of heat as it solidifies at its melting point. What is the mass of the sample?
Mass mass of 1 mol ammonia 17.03 g
H H
rxn rxn
1343.9 kJ
Section 15.4
Mastering Concepts 89. For a given compound, what does the standard enthalpy of formation describe?
Standard enthalpy of formation describes the change in enthalpy when one mole of the compound in its standard state is formed from its constituent elements in their standard states.
ical equations to produce the thermochemical equation for the reaction C(s, diamond) 0 C(s, graphite). What is H for the reaction? a. C(s, graphite) O2(g) 0 CO2(g) H 394 kJ
b. C(s, diamond)
O2(g) 0 CO2(g) H
396 kJ
Reverse Equation a, and add to Equation b. CO2(g) 0 C(s, graphite) C(s, diamond) O2(g) H H H 394 kJ 396 kJ 2 kJ
O2(g) 0 CO2(g)
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Mastering Problems 92. Use standard enthalpies of formation from Table R-11 on page 975 to calculate H rxn for the following reaction. P4O6(s) 2O2(g) 0 P4O10(s)
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the following two generic reactions to calculate H for the reaction 2A B2C3 0 2B A2C3. What is H for the reaction?
2A 2B 3 _C 2 3 _C 2
2
0 A2C3 0 B2C3
H H
1874 kJ 285 kJ
spontaneous (a negative value for Gsystem). On the other hand, reaction b has fewer moles of gas on the products side, which means entropy decreases as products form. But because Hsystem is negative for this reaction, it will tend to be spontaneous at lower temperatures.
Reverse the second equation and change the sign of its H value. Add the resulting equation to the first equation. Add the H values. The resulting thermochemical equation is 2A B2C3 0 2B A2C3 H 1589 kJ
the entropy of the surroundings. Does the enthalpy change for such a reaction increase or decrease Gsystem? Explain.
The heat released by an exothermic reaction increases the entropy of the surroundings. Such a reaction decreases Gsystem because Hsystem is negative in the equation G system H system T S system.
Section 15.5
Mastering Concepts 95. Under what conditions is an endothermic chemical reaction in which the entropy of the system increases likely to be spontaneous?
Such a reaction is likely to be spontaneous only at higher temperatures.
Mastering Problems 99. Calculate Gsystem for each process, and state if the process is spontaneous or nonspontaneous. a. Hsystem 145 kJ, T 293 K, Ssystem 195 J/K
Ssystem G G
system system
195 J/K H
system
0.195 kJ/K T S
system
CO2(g).
145 kJ
(293K)(0.195 kJ/K)
87.9 kJ nonspontaneous
Because a gaseous product is formed, its likely that the systems entropy increases.
b.
be spontaneous at relatively high temperatures? At relatively low temperatures? a. 2NH3(g) 0 N2(g) 3H2(g) Hsystem 92 kJ
b. 2NO2(g) 0 N2O4(g)
232 kJ, T
273 K, Ssystem
270 kJ spontaneous
Hsystem Hsystem
58 kJ
c.
c. CaCO3(s) 0 CaO(s)
CO2(g)
178 kJ
For a spontaneous reaction, Gsystem must be negative as calculated in the expression G system H system T S system. Reactions a and c both have a positive Hsystem. However, both reactions also have more moles of gaseous products than gaseous reactants, which suggests that entropy increases as products form. So, higher temperatures will tend to make these reactions Solutions Manual
84.1 kJ nonspontaneous
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Mixed Review
Heating Curve for Water
100 4
if Hsystem
Ssystem G 0 T H
55.2 J/K.
55.2 J/K T S
4.88 kJ
Temperature (C)
G0system is 8.557 kJ and system is 44.01 kJ, What is S0system for the change? H0
G 8.557 kJ S H T S 44.01 kJ (298 K) S 0.119 kJ/K
__
water to produce the heating curve in Figure 15.26. Identify what is happening in Sections 1, 2, 3, and 4 on the curve.
Section 1: The kinetic energy of the water (ice) is increasing as the temperature rises. Section 2: Potential energy is increasing as the system absorbs energy in the process of melting. Section 3: The kinetic energy of the water is increasing as the temperature rises.
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
sulfide to copper(II) sulfate spontaneous under standard conditions? CuS(s) 2O2(g) 0 718.3 kJ, and S0rxn CuSO4(s). H0rxn 368 J/K. Explain.
G H T S (298 K)( 0.368 kJ/K); G G 718.3 kJ 609 kJ
Yes. The reaction is spontaneous under standard conditions because G0rxn 609 kJ, and a negative G0rxn indicates spontaneity.
Section 4: Potential energy is increasing as the system absorbs energy in the process of evaporating.
28.8 kJ
that occur when a bicyclist coasts down a long grade, then struggles to ascend a steep grade.
As the bicyclist coats down a long grade, potential energy of position is converted to kinetic energy of motion. As the bicycle and rider ascend a steep grade, chemical potential energy and kinetic energy are converted to potential energy of position.
system
T S
system
34.7 kJ T 266 K
28.8 kJ
T (0.0222 kJ/K)
ning to take a thermos of hot soup with you on a hike. Explain why you might fill the thermos with hot water before filling it with hot soup.
The hot water will transfer energy to the thermos in the form of heat, raising the temperature of the thermos to nearly that of the hot soup. Because the temperatures of the thermos and soup are similar, the soup will lose little heat to the thermos when placed inside.
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tion of H2O(l) and H2O(g). Why is it necessary to specify the physical state of water in the following thermochemical equation: CH4(g) 2O2(g) CO2(g) 2H2O(l or g) H = ?
H f for H2O(l) and H2O(g) differ by approximately the enthalpy of vaporization of water. Because water in the liquid state has an enthalpy of formation that differs from that of water in the gaseous state, the enthalpy change for the reaction depends upon the physical states of all reactants and products.
one with a mass exactly twice the mass of the other, are placed in an insulated calorimeter. If the original temperatures of the larger piece and the smaller piece are 90.0 C and 50.0 C, respectively, what is the temperature of the two pieces when thermal equilibrium has been established? Refer to Table R-9 on page 975 for the specific heat of iron.
Let subscript 1 refer to the smaller, cooler piece. Let subscript 2 refer to the larger, hotter piece. Heat lost by the hotter piece cooler piece: q1 q2 T f); T f = final heat gained by
Think Critically 108. Analyze each image in Figure 15.27 in terms of potential energy of position, chemical potential energy, kinetic energy, and heat.
By virtue of its position high on the mountain, the snow has positional potential energy. When the snow slides down the mountain, its positional potential energy changes to kinetic energy of motion. Wood has chemical potential energy stored in its bonds. This energy is being converted to heat, light, and kinetic energy.
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Eliminate the specific heat c from this equation: From the problem statement: m2 = 2m1: m 1(T 1 T f) 2m 1(T 2 T f)
2(T 2
T f)
1 _(50 C 3
material for the preparation of organic phosphorous compounds. Demonstrate how thermochemical equations a and b may be used to determine the enthalpy change for the reaction described by the equation PCl3(l) Cl2(g) 0 PCl5(s). a. P4(s) 6Cl2(g) 0 4PCl3(l) H 1280 kJ
b. P4(s)
methane gas (CH4) or methanal vapor (CH2O), has the greater molar enthalpy of combustion. Explain your answer. (Hint: Write and compare the balanced chemical equations for the two combustion reactions.)
CH 4(g) CH 2O(g) 2O 2(g) 0 CO 2(g) O 2(g) 0 CO 2(g) 2H 2O(l) H 2O(l)
Reverse equation a and divide it by 4, yielding equation c. Equation c: PCl3(l) 0 1/4P4(s) 320 kJ 6/4Cl2(g) H
Divide equation b by 4, yielding equation d. Equation d: 1/4P4(s) 444 kJ 10/4Cl2(g) 0 PCl5(s) H values. 124 kJ H
Methane likely has the greater molar enthalpy of combustion The chemical equations for the two reactions reveal that the combustion of one mole of methane yields one mole of carbon dioxide and two moles of water, whereas the combustion of one mole of methanal yields one mole of carbon dioxide and one mole of water. Because
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Hf(products) for the combustion of methane has the greater value, its likely that methane has the greater molar enthalpy of combustion.
(Chapter 8) a. S2Cl2
disulfur dichloride
Challenge Problem 112. A sample of natural gas is analyzed and found to be 88.4% methane (CH4) and 11.6% ethane (C2H6) by mass. The standard enthalpy of combustion of methane to gaseous carbon dioxide and liquid water is 891 kJ/mol. Write the equation for the combustion of gaseous ethane to carbon dioxide and water. Calculate the standard enthalpy of combustion of ethane using standard enthalpies of formation from Table R-11 on page 975. Using that result and the standard enthalpy of combustion of methane in Table 15.3, calculate the energy released by the combustion of 1 kg of natural gas.
C2H6(g) H0comb 7/2O2(g) 0 2CO2(g) 1599.7 kJ/mol 3H2O(l)
b. CS2
carbon disulfide
c. SO3
sulfur trioxide
d. P4O10
tetraphosphorus decoxide
1.000 kg of natural gas contains 884 g CH4 and 116 g C2H6. 884 g
1 mol _ 55.2 mol CH4 16.0 g 1 mol 116 g C2H6 _ 3.86 mol C2H6. 30.1 g
b. Fe(OH)3
molar mass 55.85 g/mol 3(16.00 g/mol) 3(1.01 g/mol) 106.88 g/mol
(55.2 mol CH4) ( 891 kJ/mol)) (3.86 mol C2H6) ( 1599.7 kJ/mol) 55,400 kJ
Cumulative Review 113. Why is it necessary to perform repeated experiments in order to support a hypothesis? (Chapter 1)
Experiments must be repeated to be sure that they yield similar results each time. Hydrogen bonds
atomic mass of 31 amu. How many protons, neutrons, and electrons are in a neutral phosphorus atom? (Chapter 4)
number of protons 15; number of electrons 15; number of neutrons mass number number of protons 16
20.0 cm3 at 10.0 C. What volume will this sample occupy if the temperature rises to 110 C ? (Chapter 13)
T T V T (383 K)(20.0 cm ) _ _; V2 _ __
1 2 2 1 3
V1
29.1 cm 3
V2
T1
263 K
[Ar]4s13d5? (Chapter 5)
chromium
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dissolving 25.0 g of sodium thiocyanate (NaSCN) )in enough water to make 500 mL of solution? (Chapter 14)
25.0 g
1 mol _ 81.1 g
birds may inadvertently fly into the blades and be destroyed. When windmills are located off shore, fish could be adversely affected by the structures.
0.616M
Document-Based Questions
Cooking Oil A university research group
(Chapter 14)
vapor pressure lowering, boiling point elevations, freezing point elevation
Writing in Chemistry
122. Alternate Fuels Use library and internet
sources to explain how hydrogen might be produced, transported, and used as a fuel for automobiles. Summarize the benefits and drawbacks of using hydrogen as an alternative fuel for internal combustion engines.
Students may write that hydrogen could best be used as an automobile fuel in fuel cells. A large supply of the gas would need to be produced, transported and handled. Much of the technology now used for handling methane and propane gases could be adapted for use with hydrogen. Much of the hydrogen now available is a byproduct of the petrochemical industry. For full-scale use of hydrogen as a fuel for automobiles and for other energy needs, hydrogen would probably be produced by the electrolysis of water using renewable sources of energy such as wind power or solar energy. The only product of the combustion of hydrogen is water, so it is a nonpolluting source of power. However, issues of safe use and handling must be carefully considered.
burned four cooking oils in a bomb calorimeter to determine if a relationship exists between the enthalpy of combustion and the number of double bonds in an oil molecule. Cooking oils typically contain long chains of carbon atoms linked by either single or double bonds. A chain with no double bonds is said to be saturated. Oils with one or more double bonds are unsaturated. The enthalpies of combustion of the four oils are shown in Table 15.7. The researchers calculated that the results deviated by only 0.6% and concluded that a link between saturation and enthalpy of combustion could not be detected by the experimental procedure used.
Data obtained from: http: Heat of Combustion Oils. April 1998. University of Pennsylvania.
source of electrical power. Explain the possible benefits, disadvantages, and limitations of its use.
Students will note that the wind is not a steady source of energy and there will always be a need for a backup. The advantage of wind power is that it is nonpolluting. Many people, however, object to the presence of large numbers of spinning blades that create sound and disturb the natural beauty of the landscape. Another concern is that flocks of migrating
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that all the energy released is used to heat 1.600 kg of water, initially at 20.0 C, what is the final temperature of the water?
Energy released q c m T 4.184 J/(g C) Ti; 74.4 C Tf 1,600 g 20.0 C; Tf T; T 12.2 g 40.81 kJ/g 498 kJ
ization of cyclohexane a. does not occur at all. b. will occur spontaneously. c. is not spontaneous. d. occurs only at high temperatures.
c
498,000 J 74.4 C T Tf
canola oil would have to be burned to provide the energy to vaporize 25.0 g of water? Hvap 40.7 kJ/mol
25.0 g H2O 1.39 mol 56.6 kJ
1 mol H O _
2
vap,
of cyclohexane at 300 K?
18.02 g
3. When
40.7 kJ/mol
1g _ 41.45 kJ
d slope rise _ (6.00 5.00)kJ/mol __ run (290 300)K 1000 J 0.1 kJ/mol K _ 100 J/mol K 1 kJ 0.1 kJ/mol K
G (kJ/mol)
4.00 3.00 2.00 1.00 0 290 300 310 320 330 340 350
positive ions. negative ions. both positive and negative ions. no ions at all.
3FeO 0 Al2O3 3Fe, what is the mole-to-mole ratio between iorn (II) oxide and aluminum oxide? a. 2:3 b. 1:1 c. 3:2 d. 3:1
d
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G vap is plotted as a function of temperature, the slope of the line equals S vap and the y-intercept of the line equals H vap. What is the approximate standard entropy of the vaporization of cyclohexane? a. 50.0 J/mol-K b. 10.0 J/mol-K c. 5.0 J/mol-K d. 100 J/mol-K
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Presure (kPa)
0 250
260
270
280
290
300
Temperature (K)
2, while element M has an oxidation number of 3. Which is the correct formula for a compound made of elements Q and M? a. Q2M3 b. M2Q3 c. Q3M2 d. M3Q2
c
4.00 10 7 m are not visible to the human eye. What is the energy of a photon of ultraviolet light having a frequency of 5.45 1016 s 1? (Plancks constant is 6.626 10 34 J s.) a. 3.61 10 17 J b. 1.22 10 50 J c. 8.23 1049 J d. 3.81 10 24 J
a (5.45 1016 s
1)(6.626
compound.
Argon already has a full outer energy level (eight valence electrons) and is not likely to form an ion. It does not need to gain or lose any electrons in order to become chemically stable.
chloride? Explain the formation of this ionic compound using the election-dot structures above.
17
10
34
J s)
3.61
10
CaCl2; a calcium atom becomes Ca2 , losing its two valence electrons to two chlorine atoms, which each become Cl .
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Extended Response Use the information below to answer Questions 13 and 14. A sample of gas occupies a certain volume at a pressure of 1 atm. If the pressure remains constant, heating causes the gas to expand, as shown below.
C). How many kilojoules of energy are required to heat 50.0 g of ethanol from 20.0 C to 68.0 C? a. 10.7 kJ b. 8.30 kJ c. 2.44 kJ d. 1.22 kJ e. 5.86 kJ
a cm T (2.44 J/(g C)) q 1kj _ 10.7 kJ (88.0 C)
1000 J
(50.0 g)
1 atm 1 atm
and heated from 20.0C to 662.0C, absorbs 1728 J of heat, what is the specific heat of aluminum? a. 0.131 J/(g C) b. 0.870 J/(g C) c. 0.897 J/(g C) d. 2.61 J/(g C) e. 0.261 J/(g C)
q cm T q (1728 J) _ __ m T (3.00 g) (642.0 C) 0.897 J/(g C)
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
13. State the gas law that describes why the gas in
the second canister occupies a greater volume than the gas in the first canister.
This is Charless law: at a constant pressure, the volume of a given mass of gas is directly proportional to its kelvin temperature.
a temperature of 300.0 K, to what temperature must the second canister be heated to reach a volume of 5.4 L? Show your setup and the final answer. T1 _ V1 T2 _ V2 T2 _ 5.4 L
2.1 L
300.0 K _ 2.1 L
T2 T2
(300.0 K)(5.4 L) __ 770 K Chemistry: Matter and Change Chapter 15 Solutions Manual
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bond? a. carbon and sulfur b. aluminum and magnesium c. copper and sulfur d. magnesium and fluorine e. aluminum and carbon
d
occupies a volume of 5.250 mL. Which metal is it? a. aluminum b. magnesium c. carbon d. copper e. sulfur
9.250 g m _ _ V 5.250 mL b 1.762 g/mL
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