CorrigExercicesdecalorimtrie

Exercice7:
=200J/K;eau:m1=0,4kg,1=30C;glace:m2=0,1kg,2=0C;quilibre:eq=10C
Q1:chaleurcdeparleau30C
QF:chaleurreueparlaglacepourfondre
Q2:chaleurreueparlaglacefondue
Qcalo:chaleurreueparlecalorimtre
Principedeschanges:
Q1 + QF + Q2 + Qcalo = 0
m1 c eau ( eq 1 ) + m2 LF + m2 c eau ( eq 2 ) + ( eq 1 ) = 0
LF =

m1 c eau ( eq 1 ) + m2 c eau ( eq 2 ) + ( eq 1 )
m2
0,4kg 4186

=
= 3,3310 5

J
J
J
(10C 30C) + 0,1kg 4186
(10C 0C) + 200 (10C 30C)
kgC
kgC
K
0,1kg

J
kg

Exercice8:

mgl=250g=0,25kg; i = 20C ; f = 0C ;P=500W

Etape1:latempraturedelaglacemontede20C0C:
Chaleurncessairepourlaugmentationdetemprature: Q1 = mgl c gl = mgl c gl ( f i )

Etape2:laglacefondtempratureconstante
Chaleurncessairelafusion: Q2 = mgl LF

Chaleurtotalereueparlaglacejusquelleacompltementfondue:Q=Q1+Q2
Noussavons(voirex.5):

P=

Q
Q mgl cgl ( f i ) + mgl Lf
t=
=
t
P
P
J
J
0,25kg 2100
( 0C + 20C) + 0,25kg 3,3105
kgC
kg
=

500W
= 186 s

Pendantlestr=300s186s=114srestantes,latempraturedeleaufondueaugmente,elle
Q
reoitlachaleurQeau: P = eau Qeau = P t r
tr
Enplus,nousavons: Qeau = mgl c eau ( f ,eau i,eau ) ,donc:

mgl c eau ( f ,eau

i,eau ) = P t r f ,eau =

P tr
500W 114s
=
= 54,5C
mgl c eau 0,25kg 4186 J
kgC

Exercice9:
tape1:augmenterlatempraturedelaglacede18C0C
Q1=mcglace=2kg2100Jkg1K118K=7,56104J
tape2:transformerlaglace0Ceneau0C(fusion)
Q2=mLF=2kg3,33105Jkg1=6,66105J
tape3:augmenterlatempraturedeleaude0C100C
Q3=mceau=2kg4186Jkg1K1100K=8,37105J
tape4:transformerleauliquide100Cenvapeurdeau100C(vaporisation)
Q4=mLV=2kg23105Jkg1=4,6106J
Total:QT=Q1+Q2+Q3+Q4=6,18106J(=6,18MJ)