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CHM 403 Advanced Inorganic Chemistry

Welcome to the course website for fall 2011.

Course Documents and Notes

Lecture Syllabus Lab Syllabus Peer Review Forms Magnetic Suceptibility Handout Point Group Flow Chart Diamagnetic Corrections Inorganic References Nomenclature of Inorganic Compounds

Lecture Notes
Lecture Notes 1 Lecture Notes 3 Lecture Notes 4 Lecture Notes 5 Lecture Notes 6 Lecture Notes 7 Lecture Notes 8 HSAB Lecture Lecture Notes 9 Jahn-Teller Exercise Molecular Orbitals of Oh Complexes Lecture Notes 10 Lecture Notes 11

Lab Experiments
Experiment 1 Preparation and Properties of Hexamminechromium(III) Nitrate Experiment 2 The Synthesis and Characterization of Nickel(II) Complexes Experiment 3 Nickel(II) Complexes of Schiff-Based Ligands Experiment 4 Tris-bipyridine and 1,10-phenanthroline complexes of Iron(II) and Ruthenium(II) Experiment 5 Reaction Rates in Transition Metal Complexes Experiment 6 Synthesis and Characterization of a metal-arene complex: (Mestylene)tricarbonylmolbdenum(0),

Exercises
What you remember from general chemistry? Crystal Field Theory Problem Set

Homework Problems
Chapter 1: 6,7,19,21,28,29,30; Chapter 3: 8,14,15,22,23; Chapter 4: 10, 14, 16, 18, 22, 24 Chapter 7: 19, 20, 24; Chapter 19: 7,12,13,14,16,17,18,19; Chapter 20: 3,5,8,9,11,12,15,16,18,20,24

Articles
How to Read an Inorganic Chemistry Article - Assignment Article 1. The Lanthanide Contraction Revisited (J. Am. Chem. Soc., 129 (36), 11153 -11160, 2007) Article 2. High-Energy-Density Materials: Synthesis and Characterization of N5+[P(N3)6],etc... (Angew. Chem. Int. Ed. Engl. 2004, 43, 4919-4924) Article 3. Multiple Mixed-Valence Behavior in trans,trans-[(tpy)(Cl)2OsIII(-1,3N3)OsIII(Cl)2(tpy)]+. An Azido Bridge from the Reaction between trans-[OsVI(tpy)(Cl)2(N)]+ and NH3 (J. Am. Chem. Soc., 125 (10), 2828 -2829, 2003)

Article 4. Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers (Science, 2005, 310, 844-847) Article 5. Synthesis of the P-cluster inorganic core of nitrogenases (J Am Chem Soc. 2003 Apr 9;125(14):4052-3) Article 6. Synthesis, characterization and reactivity of a trinuclear copper(II) thiocyanurate complex: A spin-frustrated molecular propeller. (Inorganic Chemistry Communications 10 (2007) 631635)

General Links
CHEMINFO Chemical Information Sources, is designed to help people find and learn how to use chemical information resources MDB: the Metalloprotein Database and Browser at The Scripps Research Institute RasMol - Viewer program for proteins Reciprocal Net - The Reciprocal Net Site Network is a distributed database for crystallographic information Bioinorganic Systems Metal Complex Formula Finder - enter the metal and ligands and the finder calculates possible formulas. NMR Coupling Constant Calculator

Links
Useful Chemistry Calculators Click the link below if you don't have Adobe Reader

Click on the textbook to go to the publisher's site for Chemistry

Course Topic Links Quantum Mechanics

The Orbitron Effect of Nuclear Charge on Radial functions - Excel

Simple Bonding Theory

Shapes of Molecules - nice site with animations VSEPR Page - with practice problems VSEPR Tutorial Molecular Geometry Tutorial VSEPR examples

Symmetry and Group Theory

Group-Theory Tutorial - Illustrates Groups and Tests Knowledge 3D Molecular Symmetry - Probably the best site for illustrating symmetry elements. Requires Shock Wave Symmetry - nicely illustrated symmetry operations and pt. groups Molecular Symmetry - This site is really helpful in learning about symmetry elements (need to download plug-in) Point Group Form - Answer the Questions about your molecule and you are lead to the Point Group. Spreadsheet to Reduce Representations 3D Excercises in Point Group Symmetry - great site for visualizing symmetry operations Symmetry and Point Groups Tutorial - well constructed site Character Tables and others A Nice Symmetry Site

Assigning Spectra - Tutorial on Using Group Theory to explain IR and Raman Spectroscopies

Copyright (c) Michael Prushan 2009

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Bioinorganic Chemistry of Other Metals

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Chemistry / Biochemistry Curriculum Powerpoint Presentation - Slide 1

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Chemistry / Biochemistry Curriculum Powerpoint Presentation - Slide 1

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