Professional Documents
Culture Documents
217
40 1
5) 6) 7)
Porte 8)
) (Ta, In )
(1,277 / 5 )
Au 10 kg/ 13.4 /
()
()
(JOGMEC) 2) 3)
82%
1, 2)
e-waste
4)
2008. 2. 7
2009. 3. 31
* ()
* ()
11) 12)
305 - 8506 16 - 2
()
13)CD
5 14)
218
5576%
15) 16)
Basel
Action Network 17)e-waste
18)
19)
40
2
2. 1
IC )
1998
(Fujitsu FMW
2. 2
(Table 1)
4 (HDD, CPU
IC Ta
(FDD), CD
(CDD)) 2
13 g
HDD 2 Fig. 2
Al
HDD (
) (()
(Al
0.51 g (Yamato
Table 1
219
Low
Pressed by
Weight oil pump temperature
ashing
(g)
No Yes No Yes
Outside plastics
Outside metal
Aluminum Inside pin
capacitor Inside metal
Inside fabric
Inside plastics
0.2434
0.2394
0.1025
0.1953
0.1601
0.0499
mL 1 % HNO 3
Ceramic capacitor 1)
0.0054
Film capacitor
0.6624
Tantalum capacitor
0.6177
Pin
Resistor Metal cap
(Large 2)) Coating
Core
0.2930
0.3030
0.0050
0.6980
Resistor (Small)
0.0025
Parts
3)
C
a
p
a
c
i
t
o
r
R
e
s
i
s
t
o
r
IC chip
0.7013
Au pin
Solder 4)
Switch
2. 3
Connector
2.3258
Base board
0.1540
(FP )
(Fig. 3)
Pin
0.3227
Surface metal 0.0888
Plastics
3.3923
HNO 3 50
1 cm 2
(Au IC
((1))
=
[ A
1 A ]
Fig. 3
(1)
220
2. 2
()
Ag, Au, Al, As, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, In,
Fig. 4 62.4wt%
Ir, K, La, Li, Mg, Mn, Mo, Na, Nb, Ni, Pb, Pd, Pt, Sb, Sc,
2.7wt%8.5wt%26.4wt% 65.1wt%
Se, Sn, Sr, Ta, Te, Ti, Tl, V, Y, Zr, Zn, Nd ICP-AES
34.9wt%
()
Nd Nd XRF
Fig. 4
Nd 2Fe 14B
()
FeNdB=72271 20)
( 1 )
62.4wt% 73.7wt%
SnPb=6040 Pb Sn
2.7wt% 5.4wt%
21) ()
HDD 7
9 8.5wt% 10.4wt%
2
10.5wt%
Cu 100%
HD
65.1wt% 79.1wt%
26.4wt% 10.5wt%
3. 1
Fig. 4
3. 2
IC
TG-DTA
30%
5 % 1
79.0% 8.6%
12.5%
3. 2
Fig. 4
3. 2. 1
3. 2. 2 4
(CPU CDDFDDHDD)
Table 2
Plastics
Casing
Percent
Weight
Number
of total
(g)
weight
221
70 FDD 18 41
HDD 10 33 153
2.5
2 2
32
0.3
3900
35.3
CPU CDDFDD
HIPS
274
ABS
Top cover
Bottom cover
2060
18.6
HDD 1 10
90
0.8
1,937 g
276
2.5
Metallic plate
370
3.3
276
2.5
736 g
62
44
0.4
Motherboard 1
565
5.1
Circuit Motherboard 2
board Network card
253
2.3
Cu
108
1.0
Memory card
26
0.2
CPU package
251
2.3
Metal
Screw
Table 4 8 9
960 968
Drives CDD 1)
and
FDD 2)
CPU
HDD 3)
338
3.0
463
4.2
IC 153 Au 1,073 1
461
4.2
Cords
104
0.9
1 19 13,000
Copper coil
20
0.2
1146
10.4
Other
1
93
11057 100
IC
()
3. 2. 2 4 (CPU CDDFDD
HDD)
3. 2. 3 8 9
HDD X
3. 2. 4
Table 4
Table 5
3. 2. 1
Table 2 1
(g) (mg/kg)
CPU CDD
3. 2. 3 HDD
FDDHDD 4 2
Al 37%
81% Fe 29%
Table 3
41% Al
Cu Fe Ni Zn
( 2
Fe
CPU CDDFDD
HDD) Table 4
Nd HDD
1 (
79.6 g Nd 23 g
) 13 () 62 () 3
5 % Nd Fe-Nd-B
5 4
Nd
93
Nd
2 4 (CPU 247
22-24)
Table 2 CPU
153 CPU
CDDFDD
2 7 9 CDD 18
222
Table 3
Metal
Number
CDD
Metal
Spacer
6.4
Bottom cover
66.3
Heat sink
Clamp
4.7
47.7
Cover (black)
97.0
13.4
Cover (beige)
50.8
Plastics
FDD
Metal
0.9
10
12.0
0.5
Rubber part
3.4
Box
1.2
Plate
Stick
Coil cover
6.4
Coil
2.0
70
16.0
4.5
31
0.2
102.6
Supporting plate
97.6
Polyimide tape
13.1
9.0
Complex part
4.4
Plastic parts
4.9
2.5
Cover
249.6
Metal part
24.3
21.8
Stick
Spring, screw
41
0.1
8.6
21
5.1
Supporting plate
108.3
Core of coil
10.6
25.4
0.2
Circuit board
Complex
Contact part
Plastics
Urethane
1.3
219.8
79.6
Metal
HDD
Neodymium magnet
Disk
Screw
Circuit board
Complex
Plastics
Plastics
247.2
435
461.4
8.8
33
29.4
21
6.0
46.3
Spindle motor
45.7
Magnetic head
22.2
Copper wire
Cords
96.6
Circuit board
Total (g)
25.5
Screw
Complex
Weight (g)
Circuit board
Plastics
Total
Top cover
459.1
89.5
Wire coating material
82.4
Clamp
43.6
Fan
83.5
Bottom cover
275.6
Screw
Circuit board
3.8
764.0
215.5
1126.9
223
Table 4
Electronic part
Weight
(g/1part)
Mother
board 1
Mother
board 2
Aluminum (large)
Aluminum (medium)
Aluminum (small)
Capacitor
Film
Ceramic
Small
Large
Resistor Small - 1
Small - 2
Large
Medium-thin
IC chip
Medium-thick
Medium-bulky
Small
Au pin
Large
Solder
Medium
Small
Switch
Connector
4.085
0.991
0.475
1.269
0.218
0.006
1.614
0.003
0.008
5.428
1.195
1.721
1.163
0.406
0.00002
0.082
0.007
0.002
0.882
1
23
34
12
0
0
400
0
340
16
2
2
0
0
60
372
20
1132
4385
1
5
0
29
5
0
0
75
0
64
9
0
0
0
0
20
0
12
1006
272
0
9
1
3
17
0
8
61
13
69
5
2
0
0
3
8
103
0
132
321
0
0
0
0
0
0
0
32
0
142
0
0
0
0
0
10
336
0
0
566
0
0
0
0
0
0
0
61
0
38
0
0
0
0
0
6
262
0
56
1055
0
0
0
8
0
0
0
110
0
130
10
1
0
0
0
19
0
0
14
538
0
0
0
0
1
0
0
14
2
34
0
0
0
0
0
2
0
0
53
87
0
1
0
0
0
0
0
66
0
75
1
1
0
3
0
14
0
0
0
300
0
4
6804
1501
746
1086
1478
830
194
464
Table 5
Network Memory
CPU
card
card (2)
24
74
35
960
0
8
819
15
892 948
41
6
2
3 153
3
139
1073 1073
32
2393 9949
7524
1
1
19
19
13103
Metals contents (g) of the hard disk drive (HDD) and total metal content in four components
Ag
Au
Urethane
Top cover (white)
Bottom cover (black)
Neodymium magnet
Metal
Accessory of spindle motor
Disk
Screw
Circuit board
From Tables 3, 4
Metal (ring)
Metal (plate)
Magnet (ring)
Sleeve
Spindle motor
Spindle
Metal (small ring)
Ball bearing
Complex
part
Copper wire
Core of coil
Supporting part
Metal (spindle)
Magnetic head
Wire
Contact
Plastic
Third step
0
0
0
0
0
0
0.087
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.013
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
138
0
0
0
5.8
0
0
0
0
0.014 0.47
0
9.5
0
4.7
0
0.98
0
11
0
0.080
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ag
0.087
190
0.045
183
0.105
242
0.014
31
Au
0.013
28
0.008
34
0.012
49
0.001
2.8
Pd
Al
0.014
171
30 370000
0.013
154
53 620000
0.024
5.4
98 13000
0.003
105
7.5 230000
Plastic
HDD
Pd
Al
Cu
Fe
Zn
Sn
Pb
Nd
0
1.3
0
0
0
1.6
0.004
0.070
0
0.040
0
0.041
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.60
0
0
0
0.082
0.002
0
0
0
0
0
0
0
0
0
0.15
0
0
0
0
0.39
0
0
0.007
0.047
0.005
0
0
0
0
0
0
0
0
Ni
Zn
Cu
Fe
18.1
133 36.27
3.0
39000 290000 79000 6600
8.3
7.4 0.65 0.004
34000 30000 2700
17
24
91
1.7
33
55000 210000 4000 76000
15
299 1.25 2.65
32000 650000 2700 5800
Sn
0.68
1500
1.7
6900
1.5
3400
0.50
1100
Pb
Nd
23
0.60
1300 50000
1.1
4500
0.94
2200
0.30
650
0
55
4.1
1.0
0
55
0.012 0.012
0
0.029
0
3.0
9.30
0.24
0.29
0.100
0.13
0.049
0
2.7
0.047 0.035
0.18
1.3
0
0.84
0.002 0.48
4
0
0
3.5
0
2.7
0.074 6.0
0.000 0.85
0
0
Ni
4.5
0
0
0
27
1.4
0
0
0
2.8
0
0
0
0
0
0
0
0.53
0
0
0
0
23
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
224
Table 5 CPU
Table 6
( Al 62%) 70%CDD
9 Ag 0.79 gAu
37%Fe 29%) Cu
17.8 g
34 %
Pd 0.16 g Cu 153 g
Table 4 9
Ag, Au, Pd 1
2 2 9
Ag
Ag, Au, Pd
3. 2. 3
1.7
1 2
1 2 1
6 2 4 1
40%
8 10
1,937 g (736 g) 7
Pd Pb
Table 6
Metals content of the electronic parts of the nine circuit boards in one PC
Electronic parts
Capacitor
Ag
Au
Pd
Aluminum (large)
0.065 34000
560
2400
0.93
Aluminum (medium)
0.056
36000
180
730
1.5
55
6.5
0.18
Aluminum (small)
5300
28
130
0.53
12
0.96
1.6
0.03
0.5
Film
Ceramic
0.063
0.4
450
0.036
160
Small
Large
Resistor
Small - 1
Small - 2
Large
Medium - thin
IC chip
Medium - thick
Medium - bulky
0.048
120
1.2
36
5.0
20
5.9
1.2
0.002
5.4
1.2
5.4
0.1
19
3900
21
0.004
0.5
26
0.065
0.1
1300
3.3
0.3
46
130
0.7
130
62
1.2
0.1
Zn
0.80
Sn
27
20
130
56
80
4.7
0.006
0
180
Pb
0.11
0
35
210
0.25
310
22
32
65
1.6
10
0.14
1300
91
94
7900
2100
190
1600
1000
10100
6700
7200
4800
0.002
0.62
97
210
0.21
4.8
0.086
110
9960
1100
0.17
0.11
23
Medium
Small
Switch
Connector
3.1
0.8
3900
Ni
209
8.7
Large
(mg/circuit boards)
11
7700
0.7
1.7
Base board
890
0.23
30
Total
3.8
Fe
0.020
150
Au pin
800
Cu
27
Small
Solder
Al
2.5
190
8.8
25
32
19
15000
153000
494
1700
47
8500
4200
794
143
186
91000
187000
10000
3100
198
27900
17800
225
89025,000 mg/kg
7) (Pb7,100 mg/kg)
0.018, 0.18%
Ta Ta
Ta
18.7, 1.8%
510 mm
Table 8 31 Ca Al
23 mm
3,900 mg/kg
IC
Ta
Zr Mo mg/kgCo, Nb Cd
Ta
25)
Ta
9 kg
3. 2. 4
(2006 )
Table 7 1
Ag, Au, Pd
Cu Nd Sb
() Sn Pb
Ag, Au, Pd
Table 7
Component and part
Casing
Plastics HIPS
ABS
Metals Top cover
Bottom cover
CDD top cover
CDD bottom cover
Weight (g) Ag
Au
Pd
Al
Cu
Fe
Ni
Zn
Nd
Sn
273.60
Sb
Pb
0.00
1.35
32.17
3900.00
3900
11.70
2060.00
2000
6.18
90.25
90
0.27
275.56
270
0.83
Small plate
77.70
77
0.23
Large plate
0.00
0.88
276.46
280
0.92
Screw
60.00
Circuit Motherboard 1
board Motherboard 2
564.50
0.35
0.067 0.089
58
77.1
3.99
1.21
0.1
0.06
253.02
19
46.7
0.75
1.01
0.0
0.01
Network card
108.43
7.1 20.4
3.80
0.14
0.1
0.01
1.5
0.00 1.05
Memory card
25.95
0.4
0.16
0.08
0.0
0.00
0.8
0.00 0.56
7.36
0.65
0.00 1.09
Drives
etc
30
5.0
1.7
1.5
0.00 0.94
300
1.25
2.7
0.00
0.5
0.00 0.30
130
36.53
3.0
23.08
0.7
0.00
0.0
0.00
91
FDD
461.82
14.9
HDD
457.18
18.2
Copper coil
Total (g)
Metal concentration of PC 1) (mg/kg)
20.00
20.0
0.02 8.89
0.03 4.60
0.02
5.5 23.6
7.5
0.01
87.8
14
0.0
503.60
454.00
0.00
16.6
1.73 33.2
CPU package
CDD
Others Cords
8.3
14.5
0.01 0.60
0.67 1.96
1061.60
11416.36
0.79
69
0.143 0.19
13
17
420
320
7200
57
76.6
23.2
2000
28
2.09
2500 183
20
1800
226
Table 8
(thousand : PC)
Element
Concentration (mg/kg)
Ca
3900
Ba
270
Mg
140
Na
130
Mn
88
Ti
45
39
Sr
24
La, Zr
12
Mo
11
Co
2.5
Private hoarding
Private hoarding
760
Total waste
PCs
Export
3080
7470
Domestic
3630
760
1850
Landfill
310
700
1490
Nb
2.0
Cd. Te
1.5
20%
V, Sc, Ga
1.1
As, Be, Bi, Hf, In, Ir, Li, Pt, Rh, Ru, Se,
Ta, Tl, Y
PC 100%
PC
2)
(Cu, Ag, Au, Pd)
3. 3
Pd)
Fig. 5(c)
()
()
Fig. 6 Fig. 7
Table 9
Pd
113 (
26)
123
Fig. 5
227
Fig. 6
Fig. 7
3. 3. 1
Cu
(Fig. 5(c)) 2)
(41 ton)
1.4%
Ag
2)
5.9 ton
1,177 Cu
3,800 ton
0.6 ton
Ag 1.17 ton
3. 3. 3 Au
3. 3. 2
Ag
1,243 ton (
1.2%
Au 1.05 ton
11
228
0.5 ton
1.7
3. 3. 4
Pd
Pd 50 ton 22
3)
ton 7 ton
Pd 60% 100%
2)
32% Ag
Au Pd
Pd 1.4 ton
1,177 (2004 )
0.69 ton
747
3. 3. 5
Pb
Pb 21.9 ton
95% 2) 16 ton
235 ton
g/)
Pb 1.8%
()
Pb 149 ton
40
1 )
(2004)
pdf
2 ) ()
2006 (2007)
3)
4
pp. 537 - 571 (2007)
1)
1 ()
4 ) 3R
(2007)
5)
6 %
71
2)
6)
Ag
IC Au IC
Pd IC Cu
Ag,
12
Ipp. 42 - 44 (2000)
8)
Scheidegger and S. Kytzia : Key Drivers of the E-waste
Vol. 1992 Page 55 II. 1 - 55. II. 9 (1993), Vol. 1993 Page
Processing in the Informal Sector in Dehli, Environmental Impact Assessment Review, Vol. 25, Issue 5, pp.
472 - 491(2005)
9)
10)
Asia, p. 44 (2002)
18)
E-waste 20
20) ()
(2007)
21)
(1998)
13)
14)
18 pp. 83 - 87 (2000)
23)
7 1 pp. 35 - 41 (1994)
pp. 41 - 43 (2001)
25) ()ICP
ICP Chapter 2
p. 41 (2008)
26) ()20062009
p. 40 (2006)
I. 8 (1994)
16)
12
15)
JIS C
60068-2-20
12)
11)
229
27) ()IT
p. 23
(2006)
13
230
Abstract
In this study, we determined the amount of metal in one desktop personal computer (PC) as a case
study of electronic and electrical waste (e-waste). Using a three-step process, we dismantled the PC. We
then analyzed the metal content of each part. The circuit boards contained 0.794 g of Ag, 0.143 g of Au, 0.186
g of Pd, 91 g of Al, 187 g of Cu, and 17.8 g of Pb. In total, the PC contained 0.79 g of Ag, 0.143 g of Au, 0.19 g of
Pd, 420 g of Al, 320 g of Cu, 7200 g of Fe, 77 g of Zn, 23 g of Nd, and 20 g of Pb. We also evaluated the
maximum recoverable amount of metal (M-max) from waste PCs in Japan per year and determined that
the M-max for Au, Ag and Pd are 1.1, 5.9, and 1.4 t per year, respectively.
Key words : electronic and electrical waste, metal resources, hazardous metal, maximum recoverable
amount of metal
14