MATERIAL SAFETY DATA SHEET:

(000000-000000-

- 0011 )

ETCH-KLENZ
|DATE OF ISSUE
| 10/10/2005

PAGE : 1
| SUPERSEDES
| 1/19/1999

|
|

SECTION I - GENERAL INFORMATION

-------------------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME & SYNONYMS
TRADE NAME & SYNONYMS
N/A
ETCH-KLENZ
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL FAMILY:
FORMULA
PHOSPHORIC ACID/GLYCOL ETHER AQUEOUS SOLUTION
X <--MIXTURE
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------MANUFACTURER'S NAME:
CHEMSEARCH, DIV. OF NCH CORPORATION
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------ADDRESS (NUMBER, STREET, CITY, STATE & ZIP CODE)
BOX 152170
IRVING, TEXAS 75015
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------PREPARED BY:
| PRODUCT CODE NUMBER
| EMERGENCY TELEPHONE NUMBER
R STOLLEY/CHEMIST
0011
800-424-9300
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION II - HAZARDOUS INGREDIENTS

THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME (INGREDIENTS):
PHOSPHORIC ACID
HAZARD----->IRR/CORR
| TLV--->3 PPM
1.
| PEL--->3 PPM
2.
|
STEL(TWA)*->NOT EST.
| CAS#-->7664-38-2
|
|
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------ETHYLENE GLYCOL MONOBUTYL ETHER
HAZARD----->TOX\IRR.
| TLV--->20 PPM
1.
| PEL--->25 PPM
2.
|
STEL(TWA)*->NOT EST.
| CAS#-->111-76-2
|
|
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------NONYL PHENOL POLYETHOXYLATE
HAZARD-----> IRRITANT
| TLV--->N/E
1.
| PEL--->N/E
2.
|
STEL(TWA)*->N/E
| CAS#-->9016-45-9
|
|
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION IIA - NON-HAZARDOUS INGREDIENTS

NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NJ TRADE SECRET
REGISTRY # 409363-5129P
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION III - PHYSICAL DATA

BOILING PT. (F)
| 210
| SPEC. GRAVITY (H20=1) | 1.110
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------VAPOR PR. (MM HG)
| 18
| COLOR
| WATER WHITE
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------VAPOR DENSITY
| 0.6
| ODOR
| BUTYL
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------PH. @ 100%
| <1.0
| CLARITY
| TRANSPARENT
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------% VOLATILE BY VOL
| 79
| EVAPORATION RATE
| 0.1
|
| ( BU A/C = 1 )
|
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------H2O SOLUBILITY
| COMPLETE
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------VISCOSITY
| NON-VISCOUS
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET:

ETCH-KLENZ

PAGE : 2

SECTION IV - FIRE AND EXPLOSION HAZARD

FLASH POINT: >200 F
| FLAMMABLE LIMITS
| LEL
| UEL
SETAFLASH
| GLYCOL ETHER
| 0.1%
| 10.6%
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------EXTINGUISHING MEDIA
"ALCOHOL"
DRY
WATER
X <--FOAM
X <--FOAM
X <--CO2
X <--CHEMICAL
X <--SPRAY
<--OTHER
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------SPECIAL FIRE FIGHTING PROCEDURES
FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR.
EXTINGUISHING MEDIA SHOULD BE CHOSEN BASED ON THE NATURE OF THE SURROUNDING FIRE. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------UNUSUAL FIRE AND EXPLOSION HAZARDS
PROLONGED CONTACT WITH REACTIVE METALS, SUCH AS TIN, ZINC, MAGNESIUM AND CHROMIUM CAN CAUSE THE
FORMATION OF FLAMMABLE HYDROGEN GAS WHICH CAN FORM AN EXPLOSIVE MIXTURE WITH AIR.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------NFPA HAZARD RATING (0=INSIGNIFICANT; 1=SLIGHT; 2=MODERATE; 3=HIGH; 4=EXTREME):
3 <--HEALTH
1 <--FLAMMABILITY
1 <--INSTABILITY
<--SPECIAL
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION V - HEALTH HAZARD DATA

THRESHOLD LIMIT VALUE:
NOT ESTABLISHED FOR MIXTURE. SEE SECTION II.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------EFFECTS OF OVEREXPOSURE:
- ACUTE - (SHORT TERM EXPOSURE)
EYE CONTACT: CAUSES SEVERE IRRITATION SEEN AS TEARING, REDNESS, EXCESSIVE BLINKING, SWELLING, AND A
BURNING SENSATION. PROLONGED CONTACT CAN CAUSE CORNEAL DAMAGE.
SKIN CONTACT: CAUSES SEVERE IRRITATION SEEN AS REDNESS, ITCHING AND A BURNING SENSATION. MAY BE
ABSORBED THROUGH THE SKIN WITH EFFECTS AS THOSE FOR INGESTION.
INHALATION: CAUSES RESPIRATORY IRRITATION SEEN AS COUGHING AND SNEEZING. INHALATION OF VAPORS MAY
CAUSE HEADACHE, DIZZINESS, NAUSEA, DROWSINESS, WEAKNESS, APATHY, SLURRED SPEACH, STUTTERING AND A
STAGGERING GAIT.
INGESTION: CAUSES SEVERE IRRITATION TO THE MOUTH AND THROAT AND MAY CAUSE NAUSEA,VOMITING AND
DIARRHEA. INGESTION OF LARGE AMOUNTS MAY PRODUCE SIGNS OF INTOXICATION: DIZZINESS, INCOORDINATION,
DROWSINESS, HEADACHE, NAUSEA, MENTAL CONFUSION, STAGGERING GAIT, SLURRED SPEECH, VOMITING AND
STUPOR. IT MAY ALSO CAUSE KIDNEY AND LIVER DAMAGE AS WELL AS BLOOD ABNORMALITIES. INGESTION AND
SUBSEQUENT VOMITING OF THIS PRODUCT CAN LEAD TO ASPIRATION OF THE PRODUCT INTO THE LUNGS WHICH
CAN CAUSE DAMAGE AND MAY BE FATAL.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------- CHRONIC - (LONG TERM EXPOSURE)
REPEATED OVEREXPOSURE CAN CAUSE KIDNEY, LIVER, TESTES AND SPLEEN DAMAGE. ALSO AFFECTS RED BLOOD
CELLS LEADING TO ANEMIA. MAY CAUSE DEVELOPMENTAL DEFECTS TO FETUSES. MAY CAUSE BLOOD TO BE
PRESENT IN URINE AND ANOREXIA.
TARGET ORGANS: KIDNEYS, LIVER, SPLEEN, BLOOD-FORMING ORGANS, AND TESTES. MEDICAL CONDITIONS
AGGRAVATED BY EXPOSURE ARE PRE-EXISTING RESPIRATORY AND SKIN CONDITIONS SUCH AS ASTHMA,
EMPHYSEMA, AND DERMATITIS. MAY ALSO AGGRAVATE PRE-EXISITING LIVER, KIDNEY, AND BLOOD DISEASES.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------PRIMARY ROUTE OF ENTRY:
X<-- INHALATION
<-- INGESTION
X<-- ABSORPTION
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY & FIRST AID PROCEDURES
INHALATION:
REMOVE FROM THE AREA TO FRESH AIR. SEEK MEDICAL ATTENTION IF RESPIRATORY IRRITATION DEVELOPS OR IF
BREATHING BECOMES DIFFICULT.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT:
IMMEDIATELY RINSE THE EYES WITH WATER. REMOVE ANY CONTACT LENSES AND CONTINUE FLUSHING FOR AT
LEAST 15 MINUTES. HOLD THE EYELIDS APART TO ENSURE RINSING OF THE ENTIRE SURFACE OF THE EYES AND
LIDS WITH WATER. GET IMMEDIATE MEDICAL ATTENTION.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET:

ETCH-KLENZ

PAGE : 3

SECTION V - HEALTH HAZARD DATA (CONTINUED)

-------------------------------------------------------------------------------------------------------------------------------------------------------------------------SKIN CONTACT:
WASH AFFECTED AREAS WITH LARGE AMOUNTS OF SOAP AND WATER FOR 15 MINUTES. REMOVE CONTAMINATED
CLOTHING AND SHOES. GET IMMEDIATE MEDICAL ATTENTION. WASH CLOTHING AND CLEAN SHOES BEFORE
REUSE.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------INGESTION:
GIVE 3 TO 4 GLASSES OF WATER, BUT DO NOT INDUCE VOMITING. IF VOMITING OCCURS, GIVE FLUIDS AGAIN. GET
IMMEDIATE MEDICAL ATTENTION IF DISCOMFORT OCCURS.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------NOTES TO PHYSICIAN:
OVEREXPOSURE BY ANY ROUTE MAY PRESENT AN ABNORMAL BLOOD PICTURE CHARACTERIZED BY
ERYTHROPENIA, RETICULOCYTOSIS, GRANULOCYTOSIS, AND LEUKOCYTOSIS. INGESTION AND SUBSEQUENT
VOMITING OF THIS PRODUCT CAN LEAD TO ASPIRATION OF THE PRODUCT INTO THE LUNGS WHICH CAN CAUSE
DAMAGE AND MAY BE FATAL.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION VI - TOXICITY INFORMATION

-------------------------------------------------------------------------------------------------------------------------------------------------------------------------PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY:
IARC <--YES
NTP <--YES
OSHA <--YES
ACGIH <--YES
OTHER <--YES
X<--NO
NTP X<--NO
OSHA X<--NO
ACGIH X<--NO
OTHER X<--NO
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------PHOSPHORIC ACID
EYE-RBT SDT: 119 MG SEVERE IRRITATION
3.
ORL-RAT LD50: 1530 MG/KG
3.
SKN-RBT SDT: 595 MG/24H SEVERE IRRITATION 3.
ORL-HMN(MAN)TDLo: 220 MG/KG
3.
IHL-RAT LC50: > 850 MG/M3/24H
3.
SKN-RBT LD50: 2740 MG/KG
3.
ETHYLENE GLYCOL MONOBUTYL ETHER
SKN-RBT LD50: 220 MG/KG
ORL-RAT LD50: 470 MG/KG
EYE-RBT SDT: 100 MG SEVERE
IHL-RAT LC50: 450 PPM/4H
SKN-RBT (OPEN): 500 MG MILD

3.
3.
3.
3.
3.

NONYL PHENOL POLYETHOXYLATE

SKN-RBT: 500 MG OPEN MILD
3.
EYE RBT: 5 MG SEVERE
3.
ORL-RAT LD50: 1310 MG/KG
3.
SKN-RBT LD50: 2000 MG/KG
3.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION VII - REACTIVITY DATA

-------------------------------------------------------------------------------------------------------------------------------------------------------------------------| X <--STABLE <--UNSTABLE | CONDITIONS TO AVOID
STABILITY
|___________________________________________________________
NONE KNOWN
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------INCOMPATABILITY (MATERIALS TO AVOID):
STRONG OXIDIZERS, REDUCERS AND BASES; PROLONGED CONTACT WITH TIN, ZINC, MAGNESIUM, CHROMIUM AND
NICKEL-PLATE; PHOSPHORUS PENTOXIDE
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------HAZARDOUS DECOMPOSITION PRODUCTS
OXIDES OF CARBON AND PHOSPHOROUS, HYDROGEN GAS WHEN IN PROLONGED CONTACT WITH REACTIVE METALS.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------|
WILL NOT
MAY
| CONDITIONS TO AVOID
HAZARDOUS
| X <--OCCUR
<--OCCUR
POLYMERIZATION
|_______________________________________________________________
N/A
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET:

ETCH-KLENZ

PAGE : 4

SECTION VIII - SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
DIKE AND CONTAIN SPILL IF SAFE TO DO SO. ABSORB WITH AN INERT MATERIAL AND TRANSFER ALL MATERIAL
INTO A PROPERLY LABELED CONTAINER FOR DISPOSAL. WEAR APPROPRIATE PROTECTIVE CLOTHING. USE CARE AS
SPILLS MAY BE SLIPPERY.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD(S):
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS.
------------------------------------------------------------------------------------------------------------------------------------------------------------------------NEUTRALIZING AGENT:
USE SODIUM BICARBONATE OR SODA ASH. ADD CAUTIOUSLY WHILE MIXING. WEAR APPROPRIATE PROTECTIVE
EQUIPMENT.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION IX - SPECIAL PROTECTION INFORMATION

-------------------------------------------------------------------------------------------------------------------------------------------------------------------------REQUIRED VENTILATION:
LOCAL VENTILATION IS RECOMMENDED TO CONTROL EXPOSURE FROM OPERATIONS THAT CAN GENERATE MISTS
OR VAPORS.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------RESPIRATORY PROTECTION:
A NIOSH/MSHA APPROVED RESPIRATOR IN POORLY VENTILATED AREAS AND/OR FOR EXPOSURE ABOVE THE ACGIH
TLV OR OSHA PEL OR WHERE MISTING EXISTS.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------GLOVE PROTECTION:
NEOPRENE RUBBER OR POLYVINYL ALCOHOL GLOVES SHOULD BE WORN.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------EYE PROTECTION:
CHEMICAL GOGGLES SHOULD BE WORN.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------OTHER PROTECTION:
WEAR PROTECTIVE CLOTHING WHEN HANDLING. A SAFETY SHOWER AND AN EYEWASH STATION SHOULD BE
AVAILABLE.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION X - STORAGE AND HANDLING INFORMATION

-------------------------------------------------------------------------------------------------------------------------------------------------------------------------STORAGE TEMPERATURE
INDOOR
HEATED
REFRIGERATED
OUTDOOR
MAX: 120 F MIN: 35 F.
X
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING & STORING
ALWAYS STORE MATERIAL IN ITS ORIGINAL CONTAINER. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUES WHICH MAY EXHIBIT THE HAZARDS OF THE PRODUCT.
KEEP FROM FREEZING. IF PRODUCT FREEZES ALLOW IT TO SLOWLY WARM TO ROOM TEMPERATURE AND STIR
WELL.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------OTHER PRECAUTIONS
TRACES OF FREE ETHYLENE OXIDE MAY BE PRESENT IN THIS PRODUCT AND COULD ACCUMULATE IN THE
HEADSPACE OF THE CONTAINER. KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL BEFORE USING THE
PRODUCT. FOLLOW THE LABEL DIRECTIONS.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI - REGULATORY INFORMATION
CHEMICAL NAME
C.A.S NUMBER
UPPER % LIMIT
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------PHOSPHORIC ACID
7664-38-2
25
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------GLYCOL ETHERS
N/A
15
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET:

ETCH-KLENZ

PAGE : 5

SECTION XI - REGULATORY INFORMATION (CONTINUED)

-------------------------------------------------------------------------------------------------------------------------------------------------------------------------THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372.
IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE
THE PRODUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK, OR THE PRODUCT IS USED AND LABELED
FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES), OR THE PRODUCT IS USED AND
LABELED FOR MAINTAINING MOTOR VEHICLES.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION XII REFERENCES

1.

THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS AND BIOLOGICAL EXPOSURE
INDICES, ACGIH, 2005.
2. OSHA PEL.
3. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES, CCINFOWEB, 2005.
4. DISSOLVING THE MYTHS ABOUT EGBE AND HEALTH, CMA, GLYCOL ETHER PANEL, 1989.
5. CHEMICAL MANUFACTURERS ASSOCIATION, NOVEMBER 9, 1998.
6. VENDOR'S MSDS.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------* SHORT TERM EXPOSURE LIMIT (TWA) LISTED AS FINAL RULE LIMITS PUBLISHED IN THE FEDERAL
REGISTER/VOL. 54 NO. 12, 1-19-89
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT
FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS
DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
CHEMSEARCH, DIV. OF NCH CORP. ASSUMES NO RESPONSIBILTY FOR PERSONAL
INJURY OR PROPERTY DAMAGE CAUSED BY THE USE, STORAGE OR DISPOSAL OF
THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS
ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE, STORAGE, OR
DISPOSAL OF THE PRODUCT.