Vinayaka Missions University,Directorate of Distance Education Salem India

BACHELOR OF SCIENCE IN CHEMISTRY 3 Yr. GENERAL CHEMISTRY AND QUANTUM CHEMISTRY(1030231) UNIT - 01 AUFBAN PRINCIPLE - HUND`S RULE AND ELECTRONIC CONFIGUATIONS OF ELEMENTS STABILITY OF HALF FILLED AND COMPLETELY FILLED - ORBITAL - SHAPES OF S, P, D AND FORBITAL - S, P, D AND F BLOCK ELEMENTS - CLASSIFICATION AND CHARACTERISTIC PROPERTIES. UNIT - 02 PERIODICITY OF PROPERTIES - DEFINITION AND PERIODICITY OF THE FOLLOWING PROPERTIES - ATOMIC RADII - IONIC RADII - IONISATION POTENTIAL - ELECTRON AFFINITY AND ELECTRONEGATIVITY (NO DETERMINATION) LANTHANIDE CONTRACTION - INERT - PAIR EFFECT AND DIAGONAL RELATIONSIP WITH EXAMPLES. UNIT - 03 PRINCIPLES OF INORGANIC ANALYSIS - PRINCIPLES OF ACID BASE EQUILIBRIA COMMONION EFFECT AND SOLUBILITY PRODUCT AND THEIR APPLICATIONS IN QUALITATIVE ANALYSIS REACTIONS INVOLVED IN THE SEPARATION AND IDENTIFICATION OF CATIONS AND ARNIONS IN THE ANALYSIS - SPOT TEST REAGENTS - ALUMINON - CUPFERON - DMG THIOUREA - MAGNESON AND NESSLER`S REGRENT SEMIMICRO TECHNIQUES. UNIT - 04 TYPES OF SOLVENTS - PROTIC AND APROTIC SOLVENTS - AQUEOUS AND NON AQUEOUS SOLVENTS - LIQUID AMMONIA AS A SOLVENT - BASIC CONCEPTS OF BONDING IN ORGANIC CHEMISTRY HYBRIDIZATION AND GEOMETRY OF MOLECULES METHANE - ETHANE - ETHYLENE - ACETYLENE AND BENZENE - ELECTRON DISPLACEMENTS EFFECTS - CLEAVAGE OF BONDS - HOMOLYTIC AND HETEROLYTIF FISSION OF CARBON - CARBON BOND - REACTION INTERMEDIATES - CARBOCATIONS CARBOANIONS AND FREE RADICAL - THEIR STABILITY. UNIT - 05 NAMENCLATURE OF ORGANIC COMPOUNDS - IUPAC RECOMMENDATIONS FOR NAMIC SIMPLE ALIPHATIC - ALICYCLIC AND AROMATIC COMPOUNDS - ALKANES - MECHANISM OF FREE RADICAL SUBSTITUTION IN ALKANES. UNIT - 06 ALKENES - GNERAL METHODS OF PREPARATION PROPERTIES OF ALKENES ELECTROPHILIC AND FREE RADICAL ADDITION - ADDITION REACTIONS WITH HYDROGEN - HALOGENS - HYDROGEN HALIDE (MARK OWNIKOFFS RULE) HYDROGEN BROMIDE (PEROXIDE EFFECT) SULPHURIC ACID - WATER - HYDROBORATION OZONOLYSIS - HYDROXYLATION WITH KMNO4 - ALLYLIC SUBSTITUTION BY NBS. UNIT - 07 QUANTUN CHEMISTRY PLANK`S THEORY - PHOTO ELECTRIC EFFECT - COMPTON EFFECT - DE BROGLIE`S RELATIONSHIP HEISENBERG`S UNCERTAIMTY PRINCIPLE - SCHRODINGER WAVE EQUATION (NO DERIVATION) - SIFNICANCE OF WAVE FUNCTIONS - PROBABILITY

DISTRIBUTION OF ELECTRONS - RADIAL PROBABILITY DISTRIBUTION CURVES. UNIT - 08 GASEOUS STATE - GAS LAWS FROM THE KINETIC THEORY OF GASES - TRANSPORT PROPERTIES - VISCOSITY - THERMAL CONDUCTIVITY - DIFFUSION - MAZWELL`S DISTRIBUTION OF MOLECULAR VELOCITIES (NO DERIVATION) - MEAN - RMS - MOST PROBABLE - VELOCITY EQUI PARTITION OF ENERGY. UNIT - 09 HEAT CAPACITY - MOLECULAR BASIS - VIRIAL EQUATION OF STATE - BOYLE TEMPERATURE - COEFFICIENT OF COMPRESSIBILITY AND THERMAL EXPANSION. UNIT - 10 LIQUID STATE - SURFACE TENSION - EFFECT OF TEMPERATURE ON SURFACE TENSION - PARACHOR - DEFINITION AND APPLICATIONS ONLY - VISCOSITY - EFFECT OF TEMPERATURE - EFFECT OF PRESSURE. UNIT - 11 SOLID STATE - ELEMENTS OF SYMMETRY - CRYSTAL SYSTEMS - MILLER INDICES - UNIT CELL - SPACE LATTICE - BRAVAIS LATTICES. UNIT - 12 MESOMORPHIC STATE - LIQUID CRYSTALS - CLASSIFICATION AND MOLECULAR ARRANGEMENT.