Chem 400 Exercise #7

Name: ___________________________

Boyles Law (P1V1 = P2V2) 1. A sample of nitrogen gas (N2) has a volume of 0.250 mL at a pressure of 0.967 atm. What will the volume be if the pressure is increased to 1.65 atm? 2. If a sample of oxygen gas (O2) has a volume of 800.0 mL at a pressure of 98.7 kPa and a temperature of 30.C, what pressure will be required to compress the oxygen sample to 500.0 mL, keeping the temperature constant? 3. An aerosol spray can has a volume of 0.15 L. It is designed so that it can deliver 1000 times the original volume (or a new volume of 150 L) to a new pressure equal to 1.0 atm. What is the original pressure in atm? 4. A 500.00 mL flask was evacuated (all air removed) and 235 mL of H2 gas under a pressure of 2.56 atm was forced into it. What is the new pressure of the H2 gas? Charles Law (V1/T1 = V2/T2) 5. A sample of propane gas (C4H10) has a volume of 13.47 L at 25C and 1 atm pressure. What volume will it occupy at 50.C and 1 atm pressure? 6. A sample of neon gas occupies 100.0 mL at 100.0C. The sample is then heated to 200.0C. What is the new volume of neon (pressure remains constant)? 7. A sample of chlorine gas (Cl2) gas occupies 95.7 mL at -11.5C. Heating at constant pressure changes its volume to 146.4 mL. What is the new temperature in Kelvin and in Celsius? Gay-Lussacs Law (P1/T1 = P2/T2) 8. A steel bomb having a volume of 575 cm3 is filled with air at 28C and 0.85 atm. If the bomb was filled with 575 cm3 of air at 2.0 atm of pressure, what is the temperature of the air? 9. A sealed glass vessel with a 50.0 L volume is filled with argon gas at 22C and 1.0 atm. If the vessel is heated to 225C, what is the new pressure of the argon gas? 10. A glass ampule is filled with helium gas and is sealed at a pressure of 1.0 atm and 25C. If the ampule is stored in a -80C freezer, what is the new pressure of helium within the ampule? Avogadros Law (V1/n1 = V2/n2 or V1/N1 = V2/N2) 11. A balloon is filled to a volume of 5.8 L with 2.5 moles of helium gas. If 1.4 L of helium is added to the balloon, how many moles of helium gas are now in the balloon? How many moles of helium were added to the original 2.5 moles? 12. A balloon is filled to a volume of 1.6 L with 0.5 moles of helium gas. If 1.4 moles of helium are added to the balloon, what is the new volume? Mixed Laws Problems (P1V1/T1 = P2V2/T2) 13. At STP, the volume of a sample of O2 gas is 24.7 L. What will the volume be if the temperature is raised to 39C and the pressure is raised to 5.4 atm? 14. At STP, the volume of a sample of H2 gas is 9.6 L. If the temperature is lowered to -56C and the volume is increased to 10.4 L, what is the new pressure?

Chem 400 Exercise #7 p. 1

Chem 400 Exercise #7

Name: ___________________________

15. A 1 mol sample of radon gas is at STP. If the pressure is increased to 25 atm and the volume is decreased to 17.8 L, what is the new temperature of the 1 mol sample? Daltons Law of Partial Pressure and Mole Fractions (Ptotal = p1 + p2 + p3 +... and X1 = n1/ntotal and p1 = X1Ptotal where X1 is the mole fraction of gas 1, n1 is the # of moles of gas 1, ntotal is the total # of moles in the gas mixture, p1 is the partial pressure of gas 1, and Ptotal is the total pressure) 16. If a sample of oxygen gas is collected over water at a pressure of 0.921 atm and 23C, what is the partial pressure of the oxygen gas? 17. A mixture of gases exerting a pressure of 1.11 atm consists of 0.20 mol of O2 gas, 0.3 mol of H2 gas, and 0.7 mol of CO2 gas. What is the partial pressure of the O2 gas, the H2 gas and the CO2 gas? 18. 0.5 mol of O2 is added to a cylinder containing 0.7 mol of H2 at 0.6 atm. What is the mole fraction of each gas? What is the partial pressure of O2 and the total pressure of the cylinder? 19. A 150 mL flask was evacuated (all air removed) and into it was forced 50. mL of H2 gas under a pressure of 750 torr; 75 mL of Ar under a pressure of 450 torr; and 100. mL of O2 under a pressure of 350 torr. Determine the partial pressure (in torr) of each of the gases in the 150 mL flask and determine the total pressure of the gas mixture. (See problem #4) 20. The pressure of a sample of nitrogen gas and water vapor is 947 torr at 20C. What is the partial pressure of nitrogen? PV = nRT Problems (R = 0.0821 Latm/molK) and STP (at STP 1 mol = 22.414L) 21. What is the volume of 2.38 mol of radon gas at STP? 22. What is the volume of 35.4 g of helium gas at STP? 23. What is the density of O2 gas at STP? 24. What is the density of C2H2 gas at STP? 25. The density of a gas is 1.43 g/L at STP. Calculate its density under a pressure of 743 torr and 26C. 26. A gas has a density of 3.214 g/L at 728 torr and 24C. What would be its density at STP? 27. Calculate the density of carbon dioxide gas in g/L at 35C and 4.00 atm. 28. What is the pressure of a 2.25 mg sample of hydrogen gas in a 3500. L container at -15.6C? 29. If a 56.8 kL sample of argon is at 1.25 atm and 255C, how many g of argon is this? 30. The air in a persons lungs contains 0.177 mol gas particles at 37C and 1.00 atm. What is the volume of this persons lungs? Stoichiometry Problems Use the following equation (unbalanced) to solve the following problems. CaO(s) Ca(s) + O2(g) 31. What mass of calcium will react with oxygen gas in a 10.500 L container at a pressure of 10.0 atm and 500.C? 32. If 25.7 g of calcium reacts with oxygen gas, how many L of oxygen gas will be consumed at STP? 33. How many g of CaO can be made from 150.0 mL of oxygen gas at 140C and 1.52 atm?
Chem 400 Exercise #7 p. 2

Chem 400 Exercise #7

Name: ___________________________

34. If 1.5 kg of Ca is reacted, how many mL of oxygen gas are required at 85.0C and 5.00 atm?

Vapor Pressure (VP) of Water vs. Temperature Temp (C) VP (torr) Temp (C) VP (torr) 0 4.6 19 16.5 1 4.9 20 17.5 2 5.3 21 18.7 3 5.7 22 19.8 4 6.1 23 21.1 5 6.5 24 22.4 6 7.0 25 23.8 7 7.5 26 25.2 8 8.0 27 26.7 9 8.6 28 28.3 10 9.2 29 30.0 11 9.8 30 31.8 12 10.5 31 33.7 13 11.2 32 35.7 14 12.0 33 37.7 15 12.8 34 39.9 16 13.6 35 42.2 17 14.5 36 44.6 18 15.5 37 47.1

Temp (C) 38 39 40 45 50 55 60 65 70 75 80 85 90 95 100

VP (torr) 49.7 52.4 55.3 71.9 92.5 118.0 149.4 187.5 233.7 289.1 355.1 433.6 525.8 633.9 760.0

Chem 400 Exercise #7 p. 3