SAFETY DATA SHEET

COMPOUND CHEMICAL FERTILIZER SUPERAGRO grade NPK 15:15:15

in accordance with DSTU GOST 30333:2009
Date: 04 February 2011 Version:1.1 page 1/7

1 Chemical product identification and information about manufacturer 1.1 Substance identification Trade name compound chemical fertilizer SUPERAGRO Synonyms EINECS name lecular formular State Registration Certificate: Registration number according to Regulation () No.1907/2006 (REACH) NPK fertilizer EC unavailable unavailable

No. 01665 01-2119455044-46-0091; 01-2119490974-22-0042; 01-2119488166-29-0044; 01-2119463277-33-0048

1.2 Application spheres Granulated holding nitrogen, phosphorus and potassium compound fertilizer. Is applied on soils of all types for general application and in rows, to nourish during vegetation, under all agricultural crops: in the event of grain crops sowing, under technical crops, when soil re-digging in autumn and spring, under perennial fruit trees when planting or for nutrition purposes in early spring and after flowerage, in hotbeds and greenhouses. May be utilized to prepare fertilizer mixtures. 1.3 Company/manufacturer identification Manufacturer Address Responsible person for manufacture and release of the goods to circulation E-mail: Manufacturers Special Representative for registrational obligations under () No.1907/2006 (REACH) Regulation lephone /telefax

Public Joint-Stock Company SUMYKHIMPROM Kharkivska str., Sumy, Ukraine, 40012 Deputy Chairman of the Board Manufacturing Director Mr. V.M.Volkov stand@sumykhimprom.org.ua OSTHEM GERMANY GmbH Hamburg, Erdmann str. 10,22765 Germany E-mail: ebinal@afkem.com and nasdala@afkem.com +49 40 5300 300/ +49 40 5300 30 33

1.4 Emergency telephone for handling the substance issues If the emergency medical aid is necessary, turn to your local medical establishments

+38(0542) 683-550, +38(0542) 674-260 24 hours

SAFETY DATA SHEET

COMPOUND CHEMICAL FERTILIZER SUPERAGRO grade NPK 15:15:15
in accordance with DSTU GOST 30333:2009
Date: 04 February 2011 Version:1.1 page 2/7

2 Hazard (hazards) identification Apply individual protection measures to protect respiratory organs, skin, eyes. Avoid direct contact with the product, do not take meals and do not smoke at the workplace, keep personal hygiene measures. The personnel should be subjected to preventive and periodical medical examination. Production premises should be equipped with running cold drinking water supply, ventilation, sanitary and personal service rooms with hot water supply. The production premises should be equipped with first-aid kit, holding the medicines for first aid to the injured persons. As per the impact on organism, is related to hazard class 4 in accordance with GOST 12.1.007. The given product is not classified as dangerous one as per Directives 67/548/EEC and 1999/45/. Is not listed in Annex to Council Regulation No. () 304/203 or in priority list (as indicated in Directive () No. 793/93 on evaluation and risks management as per the available substances). 3 Composition/information on components Chemical name % by weight Ammonium Sulphate Potassium Chloride Ammonium Phosphate bibasic Ammonium Phosphate monobasic Carbonyldiamide (urea) 28-40 23-27 10-23 5-16 2-6

CAS No. 7783-20-2 7447-40-7 7783-28-0 7722-76-1 57-13-6

EINECS No. 231-984-1 231-211-8 231-987-8 231-746-5 200-315-5

Classification/marking

4 First aid measures Impact symptoms: inhalation respiration obstruction; contact with skin xerodermia, blushing; ingress in eyes weak irritative action, lacrimation. General measures: rest, warm, comfortable body position, fresh air access, unrestricted breathing conditions. In the event of ingestion: allow to drink 6-8 glasses of potassium permanganate weak solution, cause vomiting or rinse the stomach. Turn for medical aid. In the event of contact with skin: rinse with clean running water. In the event of ingress in eyes: rinse with clean drinking water, drip with dicaine or albucid. Turn for medical aid. 5 Fire safety measures and means Fire and explosion safety: fire and explosion safe substance. Fire fighting measures: adequate to the type of combustive substances, available in burning area. Dangerous products of thermal destruction: ammonia, phosphorus, nitrogen and sulphur oxides. Special fire preventing safety measures: not required.

SAFETY DATA SHEET

COMPOUND CHEMICAL FERTILIZER SUPERAGRO grade NPK 15:15:15
in accordance with DSTU GOST 30333:2009
Date: 04 February 2011 Version:1.1 page 3/7 6 Accidents and emergency situations, and their consequences, prevention and liquidation means. Avoid dust formation. Apply respiratory organs, eyes and skin individual protection measures. Premises mechanical ventilation, utilization of dust and gas purifying equipment, equipment in pressurized version. In the event of casual substance discharge: collect in dry manner, preventing dust formation. After cleaning, rinse the residues with water and detergents, avoid the product ingress in sewage system, surface and soil waters. 7 Chemical products storage rules and handling when loading/unloading Avoid aerosol formation when handling. Apply respiratory organs, eyes and skin individual protection means. Store in covered warehouses, excluding atmospheric precipitations or soil water ingress, or goods contamination. Prevent the product ingress into surface and soil waters. 8 Dangerous impact control measures and individual protection means 8.1 Parameters, subjected to mandatory control: Work zone air: TLV dust 5 mg/m3 (hazard class IV) Atmospheric air: Approximately Safe Level of Impact (ASLI): none. Water in water objects of economic and drinking, community and household assignments - Calcium Phosphate (in terms of 4)- 3,5 mg/dm3 (as per SanPiN No.4630-88 Sanitary Rules and Norms for Surface Waters Protection against Contamination) - Ammonium Salt (in terms of NH4+)- 0,5 mg/dm3 (as per Generalised List of Threshold Limit Values (TLV) and Approximately Safe Levels of Impact (ASLI) of dangerous substances for fishery water pools. Approved by Head of Glavryba of Minrybkhoz of the USSR on August 9th, 1990. No.12-04-11) 8.2 Methods of determination (principle, sensitivity, NTD per each method) Work zone air: - Methodological Guidelines for Measuring the Aerosols Concentration of Predominately Fibrogenous Action. -1988 Measuring the Aerosols Concentration of Predominately Fibrogenous Action. No. 443687 dated 18.11.87. Parameter measuring range from 0,5 TLV to 10 TLV, relative accuracy 25%. Water in water objects of economic and drinking, community and household assignments - No. 081/12-0106-03 Surface, underground and recycling waters. Measuring methods for mass concentrations of ammonium-ions with photo colorimetric method with Nesslers reagent. Measuring range from 0,1 mg/dm3 to 50 mg/dm3, relative accuracy (20-9)%. - No. 081/12-0005-01 Surface and purified sewage waters. Measuring methods for mass concentrations of dissolved orthophosphates with photometric method. Measuring range from 0,05 mg/dm3 to 100 mg/dm3, relative accuracy (15-10)%. 8.3 Information about individual protection measures for personnel: Respiratory organs protection In product manufacture apply anti-dust respirator, type U-2, Rostok or other masks of disposal or short-term action, regulated by norm NF EN 149 2001. Protective cloths, shoes etc. In product manufacture apply protective suit, protective helmet (in accordance with typical allowance norms or regulated by European norm EN 397), protective shoes yuft shoes or regulated by

SAFETY DATA SHEET

COMPOUND CHEMICAL FERTILIZER SUPERAGRO grade NPK 15:15:15
in accordance with DSTU GOST 30333:2009
Date: 04 February 2011 Version:1.1 page 4/7

EN345 and EN347), protective gloves of alkali resistant rubber or as per EN374-3 , protective goggles (in accordance with typical allowance norms for grades 2-80 or as per CE EN 166). 9 Physical and chemical properties Physical state: granules of light pink colour (as per the customers requirements, may be of other colour). Odor: odorless. Melting point: 1900. Boiling temperature: not rated. Sparkling temperature, ignition temperature, self ignition temperature: incombustible. Vapour pressure: does not form vapour in standard conditions. Density: 1,58 g/cm3 at 20. of water suspension: 6,75 (1:10 suspension in water). Solubility: in water 84,4%. In organic substances (acetone, alcohol) practically insoluble. Distribution factor in octanol-water system: none. 10 Stability and reactivity Stability: the product is stable in due conditions of utilization and storage. Reactivity: the product is chemically inert. Conditions to be avoided: prevent from heating, do not subject to combustion. Under the influence of external heat sources at over 1000, diammonium phosphate and urea, included in the fertilizer, are decomposed with emitting of ammonia gas phase. The product is hygroscopic, absorbs atmospheric moisture from air. Substances, contact with which may cause dangerous reaction: strong oxidizers, strong alkali. Dangerous products of decomposition: ammonia; phosphorus, nitrogen and sulphur oxides. 11 Toxicological information Inhalative action: CL 50 >2000 mg/kg. In clinical picture of acute intoxication prevail the lungs system injury symptoms: obstructed respiration, rhinitis, general sluggishness, adynamy. Threshold concentration Limch is 10 mg/m3. In this event the regenerative functions in central nervous system (CNS), liver, blood were observed. Introduction into stomach: LD50>5000 mg/kg, the clinical picture of acute intoxication was characterized by spasms, hemodynamic syndrome, respiratory distortions. Irritating action Skin : none (rabbit) Eyes: yes (rabbit, weak irritating action in the event of introduction into conjunctival sac). Respiratory roots: yes. Skin-resorptive action: none. Sensibilizing action: none . Embryotoxic action: not found. Gonadotoxic action: not found. Teratogenic action: not found. utagenic action: not found. Carcinogenic action: not found.

SAFETY DATA SHEET

COMPOUND CHEMICAL FERTILIZER SUPERAGRO grade NPK 15:15:15
in accordance with DSTU GOST 30333:2009
Date: 04 February 2011 Version:1.1 page 5/7

12 Information on environmental impact 12.1 Ecotoxicity

Ammonium Sulphate Acute toxicity for Daphnia magna Acute toxicity for fish L50=129mg/l (48hours) L50=420mg/l (Brachydanyo rerio 96 hours) No information found Ammonium Phosphate bibasic L50=40mg/l (96 hours) L50=52 mg/l (Grammarus pseudolimnaeu, 96 hours) No information found Potassium Chloride L50=740mg/l (24 hours) L50=950mg/l (Pimephales promelas, 24 hours) 50=1337mg/l( Nitzschia linearis L50=940mg/l (Physa heterostropha, 96 hours) Ammonium Phosphate monobasic No information found L50=5000 mg/l (Salmo irideus, 24 hours) At concentration near 0.01 mg/l, algae intensive growth is observed No information found Carbonyldiamide 50>10000mg/l (24 hours) L 50>10000mg/l (Leuciscus idus melanotus,48hours) L min>10000mg/l (Scenedesmus quadricauda,168 ) No information found

Toxic impact on algae

Toxic impact on soil invertebrates

No information found

No information found

Disclosed effects on modeled ecosystems: no information found 12.2 Mobility Transformation products in environment: ammonium, sulphates, phosphates, sulphur and nitrogen oxides. 12.3 Stability and dissociation potential Stability in abiotic conditions (1/2)> 30-7 days (highly stable) in terms of ammonium phosphates; (1/2)> 7-1 days (stable) in terms of carbonylamide, ammonium sulphate Biological dissimilation: no information found Biological oxygen demand: no information found Chemical oxygen demand: no information found 12.4 Bioaccumulation property Cumulative factor is not found due to absence of mortal cases among white rats. 12.5 Persistent biocumulative toxis (PBT) properties evaluation results The substance is not persistent boicumulative toxic one. 12.6 Hygienic norms within environmental objects In water (phosphorus anhydride)-5 mg/dm3, In atmospheric air absent, In soil absent. 12.7 Other negative effects Substances, capable to evoke ozone layer deterioration none. Volatility - non volatile. 13 Recommendations on wastes (residues) disposal The product is non-hazardous to be buried in economical or sanitary settlers. No hazardous wastes as per 2000/532/. Upon absence of possibility for recycling or utilizing, wastes and tare should be liquidated in accordance with national and local legal regulations.

SAFETY DATA SHEET

COMPOUND CHEMICAL FERTILIZER SUPERAGRO grade NPK 15:15:15
in accordance with DSTU GOST 30333:2009
Date: 04 February 2011 Version:1.1 page 6/7

14 Information for transportation Hints on transportation: the product is transportable by all kinds of vehicles in accordance with transport regulations, active for the given kind of transportation. The cargo is not classified as dangerous one in accordance with international carriage regulation. The marking Prevent from moisturising is mandatory.

15 Information about national and international legislation Information about legislation, regulating the chemical goods circulation Law of Ukraine About Pesticides and Agrochemicals Temporal Procedure of State Sanitary and Hygienic Expertise, Regulation by Ukrainian Health Care Ministry dated 09.10.2000 No. 247 Law of Ukraine About Natural Environment Protection Regulation () No. 1907/2006 (REACH) The given product is not classified as a dangerous one as per Directives 67/548/EEC and 1999/45/EC -

rules

Safety symbols Risk phrases (R phrases) Safety phrases (S phrases) Marking conditions Industrial use

Marking, bearing hazard warning, is mandatory To avoid risk for humans and environment, keep the hints on agricultural application and application in private sector as per consumable norms: winter wheat 250 kg/ha, grain crops -150-200 kg/ha, potato 250-300 kg/ha, sugar beet 450-500 kg/ha, sunflower -200-250 kg/ha.

16 Additional information 16.1 The list of references 1. DSTU GOST 30333:2009 Chemical Product Safety Data Sheet 2. GOST 12.1.007-76 . Dangerous substances. Classification and general safety requirements 3. U U24.1-05766356-045-2002 Compound chemical fertilizer SUPERAGRO. Technical requirements.

SAFETY DATA SHEET

COMPOUND CHEMICAL FERTILIZER SUPERAGRO grade NPK 15:15:15
in accordance with DSTU GOST 30333:2009
Date: 04 February 2011 Version:1.1 page 7/7

4. Toxicological and Hygienic Passport for compound chemical fertilizer NPK, developed by Labour Medicine Institute, attached to Ukrainian Academy of Medical Sciences. 5. Material Safety Data Sheet. No. 11468 (Ammonium Sulphate) 6. Material Safety Data Sheet. No. 12375 (Ammonium Phosphate monobasic) 7. Material Safety Data Sheet. No. 12370 (Ammonium Phosphate bibasic) 8. Material Safety Data Sheet. No. 9234 (Carbonylamide) 9. IUCLID Data Set Potassium chloride (http://www.chem.unep.ch/irptc/sids) 10. Safety rules and the procedure of liquidating the consequences of emergency situations with dangerous cargoes in the event of their transportation by railway vehicles. Regulation by Ukrainian Ministry for Transport and Communications No. 1430 dated 25.11.2008 11. Standards: NF EN 149 2001, CE EN 166, EN 397, EN345 and EN347, EN374-3. 12. Directive by European Community Commission 2001/95 EE dd. 3.12.2001 On goods general safety 13. Directive by European Community Commission 1999/45 dd. 31.05.1999 About approximation of laws, sublegislative and administrative acts of member countries in terms of classification, packing and marking of dangerous substances 14. Chemical safety reports: mmonium Sulphate, mmonium Phosphate bibasic, mmonium Phosphate
monobasic

16.2 Recommendations on training The given document is targeted for personnel, dealing with the product carriage and utilization, with the purpose to learn the safety handling rules. 16.3 Restrictions in use Persons, subjected to the given document delivery, may undertake the independent estimation of the product appropriateness for their own needs. The user bares responsibility for appropriateness check and information integrity for his specific application sphere. The manufacturer will be grateful for sending the information about the product utilization, to undertake the extended risks evaluation, at the address indicated on page 1 .