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International Atomic Energy Agency
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Natural Uranium & Natural Thorium are the basic raw materials for nuclear fuels
IAEA
Neutrons
Neutrons
Neutrons
Th232
Th233 -
Pa233 -
U233
Neutrons
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Formation of Plutonium (Pu) and Minor Actinides (Np, Am & Cm) isotopes in reactor
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LMFR MAGNOX
PWR
BWR
RBMK
VVER
AGR
SS clad (U,Pu)O 2
Water -cooled nuclear power reactors are most common in the world today. Except, Magnox all operating reactors use Uranium Oxide Fuel Pellets and to a limited extent mixed Uranium plutonium Oxide (MOX) pellets. Mixed uranium Plutonium oxide (MOX)
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Pebble Bed coated particle fuels embedded in spherical shape Germany, South Africa, China
COATED RTICLES
COMPACTS
FUEL ELEMENTS
2. Fuel particles (dry or wet route) for vibratory compacted fuel pins
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Environment Friendly:
Zero emission of CO2, SO2 & NOx does not contribute to global warming, climate change and acid rain
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Thermal Power stations burn Carbon and Hydrocarbon Fossil Fuels (Coal , Oil or Natural Gas) to heat water and produce steam that run the turbine and generate electricity.
The released CO2 greenhouse gas cause global warming and climate change . Other released pollutants cause Global Environmental Degradation
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Spent Fuel
(1 % U235 + 94 % U238 + 1 % Pu239 (~0.1 % MA) + 4 % FPs)
Reactor Light Water cooled Reactor (LWR) U235 + 0n1 U238 or Fission Products (FPs) + 3 0n1 + 200 MeV + 0n1 U239 Np239 Pu239
Reactor
Liquid Metal Cooled Fast Breeder/ Burner Reactor
Pu239
+ 0n1 U238
In LMFBRs you than IAEAPu content incan produce(isbreed) more Pu from U238Freshyou consumeThe Spent Fuel more than Pu content in Fuel
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MILITARY APPLICATION
URANIUM
Reprocessed Uranium [RepU: 0.8 1.1% U-235] from reprocessing spent fuel from
thermal reactors Re-enrichment & use as LEU fuel in LWRs Use in CANDU reactor [DUPIC (Direct Utilization of PWR Spent Fuel In CANDU] Blanket material for LMFR
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Disposal
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Number of Years Uranium Resources will last assuming uranium consumption of ~ 66,500 tons / year ( corresponding to the year 2006 when 2663 TWh nuclear electricity was generated) Reactor/Fuel cycle Using only Identified Resources Current technology Fast reactors with closed IAEA fuel cycle and recycling. 100 >2 500 Using Total Conventional Resources 300 >8 000 Using Total Conventional and Unconventional Phosphate Resources > 675 ~20 000
Distribution of Identified Uranium resources Worldwide (Is the supply secure?) Total Identified Resources: 5.55 Mt (2007)
Canada 8% USA 6%
China 1% India 1%
Niger 5%
Brazil 6%
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Other techniques (~2%) Open Pit Mining (24%) ISL mining Well Field
From Plant To Plant
Production Well
Monitor
Upper Clay
Ore Horizon
Submersible Pump
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Uranium Deposit
Lower Clay
Process Flowsheet in Uranium Milling Plant & Statistics of Mining methods and World Uranium Production
Open pit mining Crushing & grinding Underground mining
Leaching
Tailings disposal
Extract U in liquor
3 16 21 23 4 100
USA 4%
Canada 23%
Drying
Australia 21%
Uranium oxide concentrate, U3O8 (yellowcake) contains IAEA approximately 85% by weight of uranium
Africa 16%
Others 3%
The objective of IAEA Uranium Production Site Appraisal Team (UPSAT) is to assist to improve the Operation & Safety of Uranium Production Sites , in Member States( on request) by peer review involving international experts.
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Enrichment Cascades
NatU 1000 kg
UF6
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Capacity 120 500 500 10 800 1 800 1 050 3 500 5 1 000 4 000 7 000 3 000 4 000 11 300
48 575
Status Commissioning In operation In operation In operation In operation In operation In operation In operation In operation In operation In operation In operation In operation In operation
MTSWU/year
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Total Capacity
74 562
tHM/year
Commercially Operating Conversion Plants (UF6/Refined Uranium Oxide to UO2 Powder ready for Pettetizing)
Country Argentina Brazil Canada France India Pakistan United Kingdom United Kingdom Facility Complejo Fabril Cordoba Fabrica de Combustivel Nuclear Cameco - Port Hope (UO2) TU2 Cogema NFC - Hyderabad (UOP) Islamabad BNFL Springfields OFC IDR UO2 Line BNFL Springfields Enr. U Residue Recovery Plant Capacity 150 120 2 800 350 450 0 550 65 Status In operation In operation In operation In operation In operation In operation In operation In operation
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Total Capacity
4 485
tHM/year
Yellow Cake
UO 2 Powder
UO 2 Fuel Pellets
PHWR (CANDU)
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Country Argentina Canada Canada China India India Korea, Republic of Pakistan Romania
Facility Ezeiza - Nuclear Fuel Manufacture Plant Peterborough Facility Zircatec Precision Ind. - Port Hope Candu Fuel Plant NFC - Hyderabad (PHWR) NFC - Hyderabad (PHWR)-2 CANDU Fuel Fabrication Plant (2) Chashma Pitesti Fuel Fabrication Plant (FCN)
Capacity 160 1 200 1 200 200 270 300 400 20 200 3 950
Status In operation In operation In operation In operation In operation In operation In operation In operation In operation tHM/year
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Low enriched Uranium Dioxide Powder Handling & Granulation Facility ( operations inside glove box)
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Cold-Pelletization, High Temperature Sintering and Centerless Grinding of Uranium Oxide Fuel Pellets
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Centreless Grinding of Sintered Pellets Shrinkage of Pellets after Sintering
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Zircon Sand
EB Welded Electrode
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LMFR MAGNOX
PWR
BWR
RBMK
VVER
AGR
SS clad (U,Pu)O 2
Water -cooled nuclear power reactors are most common in the world today. Except, Magnox all operating reactors use Uranium Oxide Fuel Pellets and to a limited extent mixed Uranium plutonium Oxide (MOX) pellets. Mixed uranium Plutonium oxide (MOX)
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Current Capacity of Fabrication of Zirconium Alloy Clad, Low Enriched Uranium Oxide Fuel for Light Water Reactors Worldwide (MTU/year) (Powder, Pellet and Assembly)
Country Belgium Brazil China France Germany India Japan Operator AREVA NP EU INB-Resende Jianzhong AREVA NP EU AREVA NP EU NFC-Hyderabd NFI-Kum/Tok MNF-TokaiMur NFI-Kum/Tok JNF-Yokosuka
K a z a to m p ro m T V E L -E le /N o v T V E L -E le /N o v S o u th K o re a S p a in Sweden U .S .A . K N F C -D a e je o n E N U S A -J u z b a d W e s tS E -V a s W e s tU S -C o lu m AREVA NP US AREVA NP US G N F -W ilm in g t W e s tU K -S p rin
Facility Dessel FCN Resende Jianzhong Romans Lingen Fab Hyderabad Kumatori Tokai MNF Tokai NFI Yokosuka
U lb a E le m a s h N o v o s ib irs k D a e je o n Juzbado V a s te ra s C o lu m b ia F a b L y n c h b u rg R ic h la n d W ilm in g to n S p rin g f ie ld s M T U /Y e a r
Pellet 700 120 400 820 650 48 360 440 250 620
1000 850 150 600 400 530 1500 0 700 1100 440 11678
Assembly 700 240 450 820 650 48 284 440 250 750
0 785 1000 600 400 400 1500 700 700 1100 0 11817
K a z a k h s ta n R u s s ia
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U n ite d K in g d o m T o ta l
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Country France France India India India Russian Federation United Kingdom United Kingdom
Facility La Hague - UP2-800 La Hague - UP3 Plutonium Plant, Trombay Prefre-2, Kalpakkam Prefre-1, Tarapur RT-1, Combined Mayak BNFL B205 Magnox Reprocessing BNFL Thorp Total Capacity
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Multiple recycling of Pu with Minor Actinides (MA) in Liquid Metal-cooled Fast Reactor (LMFR) with Closed Fuel Cycle
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Mixed Uranium Plutonium Oxide (MOX) Fuel Fabrication Facility inside Alpha Tight Glove Boxes (Beta Gamma & Neutron Shielding for Pilot and Industrial Plants
Industrial Facility
Sellafield MOX Plant (SMP) Melox FBFC International - MOX
Status
Commissioning In operation In operation
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415
tHM/year
Flowsheet for Fabrication of Mixed Uranium Plutonium Oxide (MOX) Fuel Pellets by MIMAS Process [ MIMAS: MIcronized MAster Blend]
PuO2 Powder
UO2 Powder
BLENDING-MICRONIZATION
BLENDING
COLD - PELLETIZATION
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Inert atmos Inert atmos good good risk of C14 very little eutectics good Pyroreprocessing limited
Large Good
limited
600
GW(e)
high
400
low history
200
2008 Nuclear power (GWe) Natural U (ktonnes) Conversion UF6 (ktonnes U) Enrichment (MSWU) Fuel fabrication (ktonnes U) MOX fabrication (ktonnes HM) SF discharge (ktonnes HM 373 67 64 46 12 0.2 12 1.5
2030 Low 473 65-80 60-75 55-70 11-13 0.2 11-13 1-2 High 748 100-125 95-120 85-110 17-20 0.5 18-21 4-6
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Summary
Natural uranium and natural thorium are the basic raw materials for nuclear
fuels .
Light water reactors (LWR) account for more than 80% of the operating nuclear
power reactors, followed by pressurized heavy water reactor (PHWR) which contribute to ~ 6% of power reactors. LWRs will dominate the nuclear power worldwide up to 2050 and beyond. The present generation of nuclear power reactors use Uranium-235 as fuel. U-235 is the only fissile material in nature. The LWRs use LEU containing < 5% U-235 and the PHWRs use natural uranium as fuel. The plutonium 239 formed in the reactor by neutron capture reaction of fertile 238 is a man- made fissile material. In operating water cooled reactors , in-situ fission of Pu239 contribute ~ 30% of fission heat energy. Uranium resources are more or less uniformly distributed in the world and are adequate to meet any foreseeable growth scenario of nuclear power
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Summary contd
The operating nuclear power reactors utilize only 1% of the mined uranium
the rest is stored in the form of depleted and reprocessed uranium mostly as U-238. The U-238 could be utilized for breeding plutonium in a fast reactor. Plutonium is the best fissile material for fast reactor.
Natural thorium has no fissile isotopes. Neutron capture reaction with thorium
lead to the formation of man made fissile isotope U-233. Thorium based fuel must contain a fissile isotope ( U-235, Pu-239 or U-233). Though thorium is three times more abundant in nature compared to uranium, thorium based fuels are not likely to be commercialized till the uranium resources are utilized. Thorium 232- uranium 233 fuel cycle is best for thermal neutron reactors.
The fissile isotopes ( e.g. U-235 , Pu-239 , U-233 etc) are dual use materials
having both civil and military applications. Proliferation resistance in nuclear fuel cycle is essential to avoid clandestine diversion of fissile materials for non peaceful purpose
Nuclear Fuel Cycle activities are matured industries in several countries in the
world
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To promote development of nuclear fuel cycle options that are economically viable, safe, environment-friendly, proliferation-resistant and sustainable. To promote information exchange on:
1. 2. 3. 4.
exploration, mining and processing of uranium and thorium design, manufacturing, and performance of nuclear fuels management of spent fuel, including storage & treatment of spent fuel & recycling of plutonium & uranium fuel, and development of advanced and innovative nuclear fuels and fuel cycles.
Through:
1. 2. 3. 4. technical co-operation organizing technical meetings, symposia and coordinated research projects preparation of state -of -the art technical documents maintaining & updating databases on nuclear fuels and fuel cycles
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