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Crude Oil
Crude Oil
Crude Oil Characterization Boiling Point Curve API Gravity Sulfur Content Nitrogen Content Metals (Nickel/Vanadium) Conradson Carbon Residue (CCR) PONA Analysis (Paraffins/Olefins/Naphthenes/Aromatics) Viscosity Curve Carbon/Hydrogen Ratio
HIBERNIA - SUMMARY OF MAJOR CUTS Whole Crude TBP Temp At Start, C TBP Temp At End, C TBP Temp At Start, F TBP Temp At End, F Yield at Start, vol% Yield at End, vol% Yield of Cut (wt% of Crude) Yield of Cut (vol% of Crude) Gravity, API Specific Gravity Sulfur, wt% Mercaptan Sulfur, ppm Nitrogen, ppm Hydrogen, wt% Viscosity @ 40 C (104 F), cSt Viscosity @ 50 C (122 F), cSt Viscosity @ 100 C (212 F), cSt Viscosity @ 135 C (275 F), cSt Total Acid Number, mg KOH/g Cetane Index, ASTM D976 Diesel Index Characterization Factor (K Factor) Research Octane Number, Clear Motor Octane Number, Clear Paraffins, vol% Naphthenes, vol% Aromatics, vol% Molecular Weight Heptane Asphaltenes, wt% Micro Carbon Residue, wt% Ramsbottom Carbon, wt% Vanadium, ppm 35.8 0.8458 0.36 1030 16.1 5.20 3.50 0.929 0.0276 0.11 15.9 15.4 1.07 0.938 0.563 0.438 0.02 37 61 11.8 34.2 51.2 30.4 18.4 143 14.6 1.73 1.47 0.797 0.591 0.03 46 57 11.8 Light Naphtha 10 80 55 175 1.6 7.3 4.5 5.7 81.0 0.6660 0.0003 1 Medium Naphtha 80 150 175 300 7.3 21.3 12.6 14.0 53.9 0.7632 0.0007 2 Heavy Naphtha 150 200 300 400 21.3 30.9 8.9 9.6 48.6 0.7857 0.0080 2 Kero 200 260 400 500 30.9 41.6 10.4 10.7 40.7 0.8218 0.0231 3 Atm Gas Oil 260 340 500 650 41.6 56.7 15.1 15.1 35.2 0.8489 0.154 3 51 14.0 4.06 3.26 1.46 0.994 0.04 52 56 11.9 Light VGO 340 430 650 800 56.7 69.9 13.8 13.2 28.9 0.8821 0.391 3 600 13.3 13.3 9.79 3.29 2.00 0.10 46 12.0 Heavy VGO 430 570 800 1050 69.9 86.6 18.0 16.6 23.5 0.9127 0.499 1600 12.6 64.9 11.0 5.16 0.22 Vacuum Resid 570 End 1050 End 86.6 100.0 15.6 13.4 13.0 0.9791 1.07 4200 Atm Resid 340 End 650 End 56.7 100.0 47.3 43.3 21.6 0.9240 0.656 2200
0.00
0.01
11.9
12.1
12.0
12.0
310
441
7.05 %
3.4 %
1.1 %
0.61 %
0.00 %
Refinery
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Crude Oil
Crude Distillation
Middle Distillates
Conversion
Gas Oils Residuals
Byproduct Recovery
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Crude Oil
Crude Distillation
Middle Distillates
Conversion
Gas Oils Residuals
Byproduct Recovery
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Crude Oil
Distillation Conversion
Gas Oils Residuals
Byproduct Recovery
Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Crude Oil
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Naphtha Distillate
Crude Oil
Middle Distillates
Conversion
Gas Oils
Gas Oil
Residuals
Residual
Byproducts
Byproduct Recovery
Off Gas
Chemical Feedstock
Straight-Run Naphtha Straight-Run Kerosene Straight-Run Product Diesel AGO
Naphtha Distillate
Crude Oil
Middle Distillates
Conversion
Gas Oils
Gas Oil
ATB
Vacuum Tower
HVGO
Byproducts
VTB (Vac Resid)
Byproduct Recovery
Off Gas
Chemical Feedstock
Straight-Run Naphtha Straight-Run Kerosene Straight-Run Product Diesel AGO
Naphtha Distillate
Crude Oil
Middle Distillates
Conversion
Gas Oils
Gas Oil
ATB
Vacuum Tower
HVGO
Byproducts
VTB (Vac Resid)
Byproduct Recovery
Chemical Feedstock
Straight-Run Naphtha Straight-Run Kerosene Straight-Run Product Diesel AGO
Crude Oil
Middle Distillates
Conversion
Gas Oils
ATB
Vacuum Tower
HVGO
Byproducts
VTB (Vac Resid)
Byproduct Recovery
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Crude Oil
Conversion
Gas Oils Residuals
Byproduct Recovery
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Crude Oil
Conversion
Gas Oils Residuals
Byproduct Recovery
Crude Oil
Middle Distillates
Provide net volumetric gain (Volume Swell) Diesel Product Finishing Conversion units are the Economic Drivers of Fuel Oil the Refinery Gas Oils Lube / Specialty Oil
Residuals Primary Conversion Modes are Hydrogen Addition and Carbon Rejection Byproduct Recovery
Byproducts
Crude Oil
Fluid Catalytic Cracking Unit (FCCU or Cat Cracker) Middle Distillates Product Alkylation Unit (HF or H2SO4) Finishing Hydrocracker (MHC OilsFull Conversion) Gas or
Residuals Delayed Coker
Byproduct Recovery
Fluid Catalytic Cracking Unit (FCCU) Cracks Gas Oil feeds into Gasoline and Naphtha valuable byproducts Crude Oil Uses finely Middle Distillates powdered catalyst to crack feedstocks to products Product Finishing Gasoline product has high (85-87) octane
Gas Oils
Products may or may not meet sulfur specs Residuals depending on feed quality Byproduct Recovery Conversion is based on Carbon Rejection
Conversion LPG
Light Ends Naphtha
Reactor Main Fractionator FCC Wet Gas
Chemical Feedstock
Fractionator Overhead Heavy Cat Naphtha (HCN) Light Cycle Oil (LCO)
Naphtha Distillate
Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil
Crude Oil
Regenerator Air AGO Gas Oil LVGO HVGO Other Gas Oil Residual
Middle Distillates
Product Finishing
Byproduct Recovery
Riser
Gas Oils
Clarified Slurry Oil (CSO)
Residuals
(Decant Oil)
Byproducts
Conversion LPG
Light Ends Naphtha
Reactor Main Fractionator FCC Wet Gas
Chemical Feedstock
Fractionator Overhead Heavy Cat Naphtha (HCN) Light Cycle Oil (LCO)
Naphtha Distillate
Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil
Crude Oil
Regenerator Air AGO Gas Oil LVGO HVGO Other Gas Oil Residual
Middle Distillates
Product Finishing
Byproduct Recovery
Riser
Gas Oils
Clarified Slurry Oil (CSO)
Residuals
(Decant Oil)
Byproducts
Conversion LPG
Light Ends Naphtha Middle Distillates
FCC Wet Gas
Chemical Feedstock
Fractionator Overhead
Naphtha Distillate
Crude Oil
Gas Oils
Gas Oil
Residuals
Residual
Byproduct Recovery
Conversion
Wet Gas Compressor FCC Dry Gas FCC C3s FCC C4s Light Cat Naphtha (LCN)
LPG Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil
Crude Oil
Middle
FCC Gas Plant Distillates Plant) (Unsat Gas (Cat Light Ends Unit) Product
Finishing
Gas Oils FCC C4s FCC C3s Gas Oil B/B Olefins P/P Olefins C4 Olefins C3 Olefins ResidualsRefinery Butylenes Refinery Grade Propylene
Residual
Byproduct Recovery
Conversion
Wet Gas Compressor FCC Dry Gas FCC C3s FCC C4s Light Cat Naphtha (LCN)
LPG Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil
Crude Oil
Middle
FCC Gas Plant Distillates Plant) (Unsat Gas (Cat Light Ends Unit) Product
Finishing
Gas Oils FCC C4s FCC C3s B/B Olefins P/P Olefins C4 Olefins C3 Olefins ResidualsRefinery Butylenes Refinery Grade Propylene
Byproduct Recovery
Crude Oil
Fluid Catalytic Cracking Unit (FCCU or Cat Cracker) Middle Distillates Product Alkylation Unit (HF or H2SO4) Finishing Hydrocracker (MHC OilsFull Conversion) Gas or
Residuals Delayed Coker
Byproduct Recovery
Converts light end byproducts from FCCU to Naphtha gasoline blending components
Jet Fuel / Kerosene Uses strong acid (HF or H2SO4) as catalyst to Middle Distillates Crude Oil convert feedstocks to products Product Diesel Finishing Gasoline product has very high (94-97) octane Fuel Oil
Gas Oils
Conversion LPG
Light Ends
Propane
Naphtha
Reactors
Crude Oil
Naphtha
Middle Distillates
Recycle Isobutane
Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Product Finishing
Alkylate
Byproduct Recovery
Naphtha
Reactors
Crude Oil
Middle Distillates
Recycle Isobutane
Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Product Finishing
Alkylate
Byproduct Recovery
Crude Oil
Fluid Catalytic Cracking Unit (FCCU or Cat Cracker) Middle Distillates Product Alkylation Unit (HF or H2SO4) Finishing Hydrocracker (MHC OilsFull Conversion) Gas or
Residuals Delayed Coker
Byproduct Recovery
LPG
Converts Gas Oil and other low-value Refinery Chemical Feedstock streams to diesel and gasoline Gasoline Naphtha Uses hydrogen and solid catalyst to convert Jet Fuel / Kerosene Middle to products feedstocksDistillates Crude Oil Product Diesel Finishing Gasoline product has medium (80-85) octane - Fuel Oil makes good CCR feedstock Gas Oils Lube / Specialty Oil Diesel product has excellent cetane properties Residuals Byproducts Products will meetRecovery specs Byproduct low-sulfur Conversion is based on Hydrogen Addition
Conversion LPG
Full Conversion
Fuel Gas HCU LPG Lt Naphtha Hvy Naph Lt Distillate HCU Diesel Fractionation
Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Crude Oil
Middle Distillates
Hydrogen AGO Coker GO HVGO/LVGO Gas Oil HDS/HDN Reactors Hydrocrkg Reactors Separators
Product Finishing
Gas Oils
Unconverted Oil Residuals
Residual
Byproduct Recovery
Conversion LPG
Partial (MHC) Conversion
Fuel Gas HCU LPG Lt Naphtha Hvy Naph Lt Distillate HCU Diesel Fractionation
Crude Oil
Middle Distillates
Hydrogen AGO Coker GO HVGO/LVGO Gas Oil HDS/HDN Reactors Hydrocrkg Reactors Separators
Product Diesel Finishing FCC Feed Fuel Oil Lube / Specialty Oil Byproducts
Residual
Byproduct Recovery
Fuel Gas HCU LPG Lt Naphtha Hvy Naph Lt Distillate HCU Diesel Fractionation
Recycle Compressor
Crude Oil
Middle Distillates
Hydrogen AGO Coker GO HVGO/LVGO HDS/HDN Reactors Hydrocrkg Reactors Separators
Product Diesel Finishing FCC Feed Fuel Oil Lube / Specialty Oil Byproducts
Byproduct Recovery
Crude Oil
Fluid Catalytic Cracking Unit (FCCU or Cat Cracker) Middle Distillates Product Alkylation Unit (HF or H2SO4) Finishing Hydrocracker (MHC OilsFull Conversion) Gas or
Residuals Delayed Coker
Byproduct Recovery
LPG Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Cracks Residual feeds into Gasoline, Diesel and other byproducts Naphtha Uses high temperature (thermal cracking) to Middle Distillates crack feedstocks to products Product Finishing Coker liquid products all require downstream processing to meet specifications Gas Oils Petroleum coke Residuals can be high-value (Anode Grade) or low-value (Fuels Grade) Byproduct Recovery Conversion is based on Carbon Rejection
Crude Oil
Conversion LPG
Light Ends Naphtha
Coke Middle Drums Main Fractionator Fuel Gas Coker Gas Coker LPG Plant Coker Naphtha Coker Distillate (Coker Diesel)
Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Naphtha Distillate
Crude Oil
Distillates
Product Finishing
Gas Oils
Gas Oil Heater
Residuals
Residual Vacuum Btms
Recycle
Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Crude Oil
Distillates
Product Finishing
Gas Oils
Heater
Residuals
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Crude Oil
Byproduct Recovery
Conversion LPG
Light Ends Naphtha Middle Distillates
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Naphtha Distillate
Crude Oil
Gas Oils
Gas Oil
Residuals
Residual
Byproduct Recovery
Conversion LPG
Light Ends
Light Ends
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil
Naphtha Distillate
Crude Oil
Gas Oils
Gas Oil
Residuals
Residual
Byproduct Recovery
Conversion LPG
Light Ends
Alkylation
Light Ends
Chemical Feedstock Gasoline Jet Fuel / Kerosene Product Finishing Diesel Fuel Oil Lube / Specialty Oil Byproducts
Naphtha Distillate
Naphtha
Hydrocracker
Crude Oil
Middle Distillates
FCCU
Gas Oil
Vac Btms
Residual
Byproduct Recovery
Conversion LPG
Light Isobutane
Propane N-Butane Ends Alkylate
Light Ends
Alkylation
Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Clarified Slurry Oil
Naphtha Distillate
Crude Oil
Middle Distillates
FCC Feed
FCCU
FCC C3s FCC C4s Lt Cat Naphtha Hvy Cat Naphtha Light Cycle Oil
Gas Oil
Vac Btms
Residual
Byproduct Recovery
Conversion
Light Ends
Alkylation
Crude Unit Off Gas Alky Propane/n-Butane HCU LPG FCC C3s SR Naphtha Alkylate Lt/Hvy Hydrocrackate Lt/Hvy Cat Naphtha Coker Naphtha SR Kerosene SR Diesel HCU Diesel Light Cycle Oil Coker Distillate
LPG Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Naphtha
Naphtha
Hydrocracker
Crude Oil
Distillate
Middle Distillates
FCCU
Product Finishing
Gas Oils
Gas Oil
Residuals
Residual
Delayed Coker
Byproduct Recovery
Conversion
Light Ends
Alkylation
Product Finishing
Crude Unit Off Gas Alky Propane/n-Butane HCU LPG FCC C3s SR Naphtha Alkylate Lt/Hvy Hydrocrackate Lt/Hvy Cat Naphtha Coker Naphtha SR Kerosene SR Diesel HCU Diesel Light Cycle Oil Coker Distillate
LPG Chemical Feedstock Gasoline Jet Fuel / Kerosene Diesel Fuel Oil Lube / Specialty Oil Byproducts
Naphtha
Naphtha
Hydrocracker
Crude Oil
Distillate
Middle Distillates
FCCU
Gas Oils
Gas Oil
Residuals
Residual
Delayed Coker
Byproduct Recovery