Material Safety Data Sheet according to 1907/2006/EC, Article 31

Revised on: 09.02.2010 Printed: Page: 08.03.2010 1/7

Trade name: Cleaning electrolyte

1.

Identification of the substance/preparation and of the company/undertaking Product details: Item number: 42,0411,8015 42,0411,8052 Use of the substance/preparation Electrolytic solution Manufacturer/Supplier: Fronius International GmbH Fronius Strae 5 A-4642 Sattledt, Austria Tel.: +43 (0)7242 2410 Fax: +43 (0)7242 241 8799 Office to contact for information: TSI (TechSupport International) Tel.: +43 (0)7242 241 3440 Fax: +43 (0)7242 241 3930 e-mail: welding.techsupport@fronius.com www.fronius.com Office hours: Mon - Thurs: 08:00 16:30 Fri: 08:00 12:00

Emergency hotline: Austrian Anti-Poison Center +43 (0)1 406 4343

2.

Possible hazards Information concerning particular hazards for humans and the environment: C R 34 Causes burns

3.

Composition/information on the ingredients Chemical characterization: Aqueous solution Dangerous constituents: Name on Phosphoric acid CAS No. 7664-38-2 EC No. 231-633-2 Concentration >=60% <70% INDEX No. 015-011-00-6 ClassificatiC, R 34 Note B

Other information: See section 16 for the exact wording of the R phrases listed above.

Cleaning electrolyte

Material Safety Data Sheet according to 1907/2006/EC, Article 31

Revised on: 09.02.2010 Printed: Page: 08.03.2010 2/7

4.

First-aid measures General information: Take the affected workers out of the danger area and lie them down. Take off all contaminated clothing immediately. After inhalation: If the worker loses consciousness, move him/her into the recovery position and seek medical advice. Supply fresh air to the area. After skin contact: Wash off immediately with copious amounts of water for at least 15 minutes. If skin irritation continues, consult a doctor. After eye contact: Rinse immediately with copious amounts of water, including underneath the eyelids. Seek medical advice immediately. After swallowing: Rinse mouth with water and drink plenty of water. If swallowed, do not induce vomiting. Consult a doctor.

5.

Fire-fighting measures Suitable extinguishing agents: Use fire-fighting measures and sprinklers that suit the environment. The product itself is not flammable. Particular fire-fighting dangers: Hydrogen is produced in reactions with metals, increasing the risk of an explosion. Decomposes when heated. Phosphorus oxide vapours are poisonous when inhaled. Special protective equipment for firefighters: In the event of a fire, wear self-contained breathing apparatus. Wear protective clothing. Other information: Use water spray to cool sealed containers close to source of fire. Collect contaminated fire-fighting water separately. Must not enter drains or sewers.

6.

Accidental release measures Person-related safety precautions: Use personal protection equipment. Avoid skin and eye contact. Do not inhale gas/smoke/vapour/aerosol. See section 8 for information about personal protective equipment. Measures for environmental protection: Do not allow to enter drains, sewers or surface water. If surface water or the drains are polluted, inform the relevant authorities. Avoid water ingress underground. If contaminated water enters the ground, inform the relevant authorities. Measures for cleaning/collecting: Ensure adequate ventilation. This product and its container must be disposed of as hazardous waste. Add alkalis, lime or ammonia to neutralise acidic waste. Use inert absorbent material.

Cleaning electrolyte

Material Safety Data Sheet according to 1907/2006/EC, Article 31

Revised on: 09.02.2010 Printed: Page: 08.03.2010 3/7

Other information: See the relevant section concerning disposal of absorbent material. 7. Handling and storage Handling: Information for safe handling: Keep container tightly closed. Handle and open container with care. Avoid aerosol formation. Information for fire and explosion protection: This product is not flammable. Hydrogen is produced in reactions with metals increasing the risk of an explosion. Storage: Conditions required for storage rooms and vessels: Keep in a place with acid-resistant ground. Keep in the original container. Information for storing in one common facility: Incompatible with bases. Keep away from food, drink and animal feedingstuffs.

8.

Exposure controls and monitoring/personal protective equipment Components with limit values that require monitoring in the workplace: Phosphoric acid (CAS no.: 7664-38-2) MAC: 1 mg/m3, MAC STEL: 2 mg/m3, Peak limit: 4x15 minutes/shift TWA: 1 mg/m3, STEL: 2 mg/m3, Personal protective equipment: Respiratory protection: Use respiratory protection equipment with a suitable filter in case aerosols or vapours occur. Combined filter: B-P2 Protection of hands: Wear suitable protective gloves. The exact breakthrough time is obtained from the glove manufacturer and must be observed. Please follow the manufacturer's instructions with regard to permeation, breakthrough time and special working conditions (mechanical loading and contact time). Protective gloves must be replaced as soon as you notice the first signs of wear and tear. Material Butyl rubber Polychloroprene Polyvinyl chloride Material thickness 0.5 mm 0.5 mm 0.5 mm Penetration time >= 8 hrs >= 8 hrs >= 8 hrs

MAC (AT) MAC (AT) EU ELV EU ELV

Cleaning electrolyte

Material Safety Data Sheet according to 1907/2006/EC, Article 31

Revised on: 09.02.2010 Printed: Page: 08.03.2010 4/7

Eye protection: Wear close-fitting safety goggles. Body protection: Wear protective clothing. Hygiene measures: Remove all contaminated or soaked clothing immediately. Do not inhale gas/smoke/vapour/aerosol. Avoid skin and eye contact. Keep away from food, drink and animal feedingstuffs. When using do not eat, drink or smoke. Always wash hands before breaks and after finishing work. Wash hands. Technical safety measures See safety measures in sections 7 and 8.

9.

Physical and chemical properties General information: Form: Colour: Odour: Safety data: Melting point/range: Boiling point/range: Thermal decomposition: Flashpoint: Risk of explosion: Density: Solubility in water: pH value (concentrate):

Liquid red Odourless

no data available approx. 150C approx. 300C n.a. the product is not explosive. approx. 4.43 g/cm3; 20C fully miscible <1

10. Stability and reactivity Substances to avoid: Alkalis Dangerous products of decomposition: An explosive gas can be produced on contact with different metals, decomposes when heated. Hazardous reactions: Hydrogen is produced in reactions with metals. General information: Does not decompose when stored and used appropriately.

Cleaning electrolyte

Material Safety Data Sheet according to 1907/2006/EC, Article 31

Revised on: 09.02.2010 Printed: Page: 08.03.2010 5/7

11. Toxicological information If swallowed: Phosphoric acid: LD50 rat 1.530 mg/kg This data differs from the classification stipulated by the EU. If inhaled: Phosphoric acid: LC50 rat 1.69 mg/l 1 hr This data differs from the classification stipulated by the EU. Contact with the skin: Phosphoric acid: Rabbits exhibit corrosive effects. OECD Test Guideline 404 Contact with the eye: Phosphoric acid: Rabbits exhibit corrosive effects. Other information: All numerical values for acute toxicity relate to pure substances. If swallowed, it has a strong corrosive effect on the mouth and throat. There is also the danger of perforating the oesophagus and stomach. Take standard safety precautions when handling chemicals.

12. Ecological information Toxicity to fishes: Phosphoric acid: LC50 Gambusia affinis 138 mg/l 96 hours Other ecological information: All numerical values for ecotoxicological effects relate to pure substances. Harmful effects on aquatic organisms due to change in pH. Waste must always be neutralised before it is sent to water treatment plants. Do not allow to enter drains, sewers or surface water.

13. Disposal considerations Product: Do not dispose of together with household waste. Do not empty into drains. Dispose of hazardous waste according to regional and national regulations. Packaging: It is best to empty contaminated packaging. It can then be cleaned and recycled. Dispose of packaging that cannot be cleaned. European waste catalogue: No EWC codes can be defined for this product since it is used by different consumers for different purposes. The EWC code is defined in consultation with the regional disposal company.

Cleaning electrolyte

Material Safety Data Sheet according to 1907/2006/EC, Article 31

Revised on: 09.02.2010 Printed: Page: 08.03.2010 6/7

14. Transport information ADR UN number Class Packaging group Classification code Hazard label Hazard sign ADR 5.2.1.8 sign Shipping name RID UN number Class Packaging group Classification code Hazard label Hazard sign RID 5.2.1.8 sign Shipping name IMDG UN number Class Packaging group Hazard label EMS IMDG 5.2.1.6.3 sign - Classed as hazardous according to 2.9.3 IMDG - Marked "P" according to 2.10 IMDG Shipping name

1805 8 III C1 8 80 no PHOSPHORIC ACID, SOLUTION

1805 8 III C1 8 80 no PHOSPHORIC ACID, SOLUTION

1805 8 III 8 F-A, S-B no no no PHOSPHORIC ACID, SOLUTION

15. Legal regulations Labelling according to EEC directives 1999/45/EG

C Corrosive

Cleaning electrolyte

Material Safety Data Sheet according to 1907/2006/EC, Article 31

Revised on: 09.02.2010 Printed: Page: 08.03.2010 7/7

Risk phrases R 34 Safety phrases S 1/2 S 26 S 30 S 45 S 60 hazardous waste.

Causes burns.

Keep locked up and out of the reach of children. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Never add water to this product. In case of accident or if you feel unwell, seek medical advice immediately (show this label where possible). This material and its container must be disposed of as

Labelling of components as hazardous: Phosphoric acid Austrian regulations Waste code:

52102

Regulation The classification in accordance with the Austrian Chemicals Act (BGBl.I 53/1997) is identical to the classification of the EEC directives. Please note the occupational restrictions in accordance with the Labour Protection Act.

16. Other information The exact wording of the R phrases listed in sections 2 and 3 R 34 Causes burns.

Other information The information found in this material safety data sheet is based on our present knowledge and is intended to describe the product with a view to the safety precautions to take. It provides no assurances with regard to the properties of the product described or product information or specification. Neither does it constitute a contractual legal relationship. The information given in the material safety data sheet are valid for the mentioned product only. It may no longer apply if the product is processed or mixed with other substances. The information in this material safety data sheet cannot be used for new materials. For industrial use only. Avoid exposure - obtain special instructions before use. The information contained in this material safety data sheet is only relevant to safety and does not replace any product information or specification.

Cleaning electrolyte