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These are the questions, which are prepared to be reviewed during the CHEM 1007 final exam review

sessions. 1. Coniine, a toxic substance isolated from poison hemlock, contains only carbon, hydrogen and nitrogen. Combustion analysis of a 5.024 mg sample yields 13.90 mg of CO2 and 6.048 mg of H2O. What is the empirical formula of coniine? 2. Calcium levels in blood can be determined by adding oxalate ion to make solid calcium oxalate (CaC2O4), followed by dissolving the solid in aqueous acid to form oxalic acid (H2C2O4). The oxalic acid is finally titrated with KMnO4, as in the UNBALANCED equation in acid: H2C2O4(aq) + MnO4-(aq) + H+(aq) CO2(g) + Mn2+(aq) + H2O(l) How many mg of Ca2+ as present in 10.0 mL of blood if 21.08 mL of 0.000988 M KMnO4 solution is needed for the titration? 3. Cisplatin [Pt(NH3)2Cl2], a compound used in cancer treatment, is prepared by reaction of ammonia with potassium terachloroplatinate (K2PtCl4): K2PtCl4 + 2NH3 2KCl + Pt(NH3)2Cl2 How many grams of cisplatin are formed from 55.8 g of K2PtCl4 and 35.6 g of NH3 if the reaction takes place in 95% yield based on the limiting reactant? 4. A 48.02g sample contains only solid NaCl and CaCl2. The entire 48.02 gram sample was dissolved in enough water to make 1.000 liter of solution. Finally 20.00 ml of this solution was combined with excess 0.5000M AgNO3 solution and 2.433g of solid AgCl was precipitated. What is the percent by mass of NaCl in the original solid solution? 5. Complete the following table Total Nodes Radial Nodes 3 1 3 6 7 0 3 Angular Nodes Orbitals in Subshell 1 4p 2 9 3 Name of Subshell

6. Acrylonitrile (below) is used as the starting material for making acrylic fibers. CH3 H2CCCN (a) Predict values for all bond angles in acrylonitrile. (b) What is the hybridization of each carbon atom? (c) How many sigma bonds and pi bonds are in acrylonitrile?

7. Use molecular orbital theory to describe the bonding of NO+, NO, and NO-. What is the bond order of each? Label each species with paramagnetic or diamagnetic? 8. For the following molecules, draw all the reasonable Lewis structures, predict the shape about the central atom using VSEPR theory and predict all the bond angles. Make sure to assign all formal charges and show all resonance structures. (a) ClO3-, (b) SCl2, (c) SCl4, (d) BrCl5, (e) SeF6, (f) CF2Cl2 9. A mixture of Ar and N2 gases has a density of 1.413 g/L at 1 atm and 0C. What is the mole fraction of each gas? 10. An unknown gas is found to diffuse through a porous membrane 2.92 times more slowly than H2. What is the molecular mass of the gas? 11. Consider separate 1.00 mole samples of O2(g), He(g), and H2(g), each at 25 C and 1.00 atm, in identical in 1.0L containers. (a) Which gas has the greatest root mean square velocity? (b) Which gas imparts the highest momentum to the container walls with each collision? (c) Which gas has the most impacts per second on the container walls? (d) On the same set of axes, make a rough plot of the number of molecules or atoms vs. particle speed for the three gases. 12. Draw the electron distribution in d-orbitals and determine if each of the following compounds is paramagnetic or diamagnetic. (a) [Mn(CN)6]3- (b) [Fe(CN)6]4- (c) [FeF6]4- (d) [Zn(NH3)4]2+ 13. The complex ion [Cu(NH3)6]2+ is blue in aqueous solution. Estimate the crystal field splitting energy (in kJ/mole) for this ion. Given violet light ~ 450nm, blue light ~ 500nm, green light ~ 550nm, yellow light ~600nm, orange light ~650nm, and red light ~ 700nm. 14. Consider the -bonding network of the species below. For each species sketch all the -bonding orbitals and draw and energy diagram representing each -bonding orbital with a line. Use arrows to represent electrons and label each -bonding orbitals as bonding, antibonding or nonbonding. 15. Determine the kinds of intermolecular forces that are present in each of the following elements or compounds. (a) Kr, (b) NCl3, (c) SiH4, (d) HF, (e) N2, (f) NH3, (g) CO, (h) CCl4 16. Arrange the following in order of increasing vapor pressure and explain your reasoning. (a) CH3CH2Cl, (b) CH4, (c) CH3CH3, (d) CH3CH2OH

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