4541/1 CHEMISTRY FEB 2012 1 HOUR Name: _________________________________________ Class: 5 AL-JABAR

SMK DATO SHAMSUDIN NAIN RANTAU MID YEAR EXAM 2012

CHEMISTRY FORM 5 PAPER 1

1 Hour and 15 minutes

DO NOT OPEN THIS PAPER UNTIL YOU ARE ASKED TO DO SO 1. 2. This paper consists of 50 questions. Answer ALL questions.

3. You are allowed to use scientific calculator.

Section A Answer all questions 1. Which substance is an element? A. Air C. Carbon B. Steam D. Naphthalene 2. What is the definition of a mole? A. The volume occupied by 6.02 x 1023 particles B. The atomic mass of a substance which consist of 6.02 x 1023 atoms C. The molecular mass of a substance which consist of 6.02 x 1023 molecules D. The quantity of a substance which has the same number of particles as the number of atoms in 12.00 g of carbon-12 3. The diagram shows the change of state of matter.

Which of the following is process X? A. melting C. freezing B. boiling D. condensation 4. Which of the following scientists discovered proton? A. Neils Bohr C. James Chadwick B. J. J. Thomson D. Ernest Rutherford 5. The nucleus of an atom contains A. electrons only C. both protons and neutrons B. neutrons only D. both protons and electrons 6. Which of the following is the empirical formula of C6H12O6? A. CHO C. C2H4O2 B. CH2O D. C6H12O6 7. The following equation represents a reaction. Cu(OH)2 (s) +2HNO3 (aq) Cu(NO3)2 (aq) + 2H2O (l) What are the reactants in this equation? A. Copper(II) nitrate and water B. Copper(II) nitrate and nitric acid C. Copper(II) hydroxide and nitric acid D. Copper(II) hydroxide and copper(II) nitrate

8. Which of the following elements are in Group 18 in the Periodic Table of Elements? A. Helium and krypton C. Oxygen and krypton B. Hydrogen and oxygen D. Helium, hydrogen and oxygen 9. The following elements are in Group 17 in the Periodic Table of Elements except A. bromine C. helium B. chlorine D. iodine 10. Which of the following substances is made up of ions? A. Sulphur B. Naphthalene C. Sulphur trioxide D. Potassium chloride 11. An atom that receives an electron forms A. a cation C. an ionic bond B. an anion D. a covalent bond 12. What is the meaning of covalent bond? A. A bond formed when metal atoms contribute electrons to each other to achieve a stable electron arrangement. B. A bond formed when non-metal atoms share electrons to achieve a stable electron arrangement. C. A bond formed by weak Van der Waals forces between the non-metal atoms. D. A bond formed when a metal atom transfer an electron to a non-metal atoms. 13. Which of the following is an example of electrolyte? A. Sugar solution C. Solid sodium chloride B. Molten naphthalene D. Molten lead(II) bromide 14. Which of the following is true about electrolytes? A. Elements that conduct electricity in molten state B. Compounds that conduct electricity in solid state C. Elements that conduct electricity in solid or molten state D. Compounds that conduct electricity in molten state or aqueous solution 15. Which of the following is not the function of electrolysis in daily lives? A. Prevention of corrosion B. Generation of electrical energy C. Electroplating metals D. Extraction of metals 16. A hydrocarbon is a chemical compound consisting of A. carbon and oxygen only B. carbon and hydrogen only C. carbon, hydrogen and oxygen only D. carbon, hydrogen, oxygen and nitrogen only

17. What is the product formed when ethane is burned in air? A. Ethane and water B. Carbon and hydrogen C. Carbon dioxide and water D. Carbon dioxide and hydrogen 18. The chart shows the classification of carbon compounds.

X is A. carbon dioxide B. ethanoic acid

C. methanol D. glucose

19. Which of the following is a saturated hydrocarbon? A. Alkane C. Alcohol B. Alkene D. Carboxylic acid 20. What is the general formula for an alkane? A. CnH2n C. CnH2n+1OH B. CnH2n+2 D. CnH2n+1COOH 21. Which of the following is the structural formula of an unsaturated hydrocarbon?

22. Which statement is correct about alkanes? A. Undergo polymerization reaction B. Undergo hydrogenation reaction C. Undergo substitution reaction D. Undergo hydration reaction 3

23. Propane and propene are members of different homologous series. Which of the following is the general formulae representing the two compounds? Propane Propene Propane Propene A. CnH2n CnH2n+2 C. C2nHn+2 CnH2n+1 B. CnH2n+2 CnH2n D. CnH2n+1 CnH2n+2 24. Which process has the highest rate of reaction? A. rusting C. combustion B. respiration D. photosynthesis 25. Which of the following explains the meaning of effective collision? A. The collision where its energy is less than the activation energy B. The collision that has a low energy C. The collision which takes place before a reaction D. The collision that causes a reaction 26. Which factor does not affect the rate of reaction? A. Size of the solid reactant B. Volume of the reactant C. Concentration of the reactant D. Temperature of the reactant 27. The diagram shows an experiment to study the particle theory of matter.

Which of the following is the best explanation of the observation in the experiment? A. Agar dissolves copper(II) sulphate B. Copper(II) sulphate is an ionic compound C. Particles in copper(II) sulphate are minute and discrete D. The attractive force between agar and copper(II) sulphate particles is strong 28. Diagram 1 shows the inter-conversion of the states of matter of a substance. Steam

Ice Which inter-conversion involves the release of energy? A. steam ice C. ice water B. water steam D. ice steam

Water

29. Atom X has a proton number 9 and the nucleon number is 19. Which of the following symbols is for atom X?

30. Diagram 2 shows the set-up of apparatus to determine the empirical formula of magnesium oxide.

Which of the following statements is true for the lifting and closing of lid quickly and occasionally during heating? A. To avoid the pressure in the crucible dish B. To avoid the crucible dish from cracking C. To avoid the white fumes from escaping D. To avoid water vapour from entering the crucible dish 31. Diagram 4 shows reaction between lithium and water.

Lithium reacts with water to produce solution that A. turns red litmus paper blue. B. turns blue litmus paper red. C. no visible change in the colour of the litmus paper. D. no visible change in the colour of the red litmus paper. 32. Which statement is true about the reaction of a magnesium atom with fluorine to form magnesium fluoride? [Proton number: F=9, Mg=12] A. one magnesium atom donates one electron to one fluorine atom B. one magnesium atom donates two electrons to two fluorine atoms C. one magnesium atom shares one electron with one fluorine atom D. one magnesium atom shares two electrons with two fluorine atoms 5

33. Which of the following represents the electron arrangement for the compound sodium chloride, NaCl?

34. Element M and element L are located in Group 1 and Group 16 in the Periodic Table respectively. Element M reacts with element L to form a compound. What is the chemical formula of the compound? A. ML C. M2L B. ML2 D. M2L3 35. Diagram 4 shows the structural formula of an organic compound.

What is the IUPAC name for this compound? A. 2-pentene B. 2-methylbut-1-ene C. 2-methylbut-2-ene D. 3-methylbut-3-ene 36. The equation below represents the combustion of ethane in excess oxygen.

What is the value of a, b, c and d?

37. Which of the following is incorrect about the conversion of unsaturated fats to saturated fats? A. The boiling point of the oil increases B. Physical state changes from liquid to solid C. Relative molecular mass of the oil molecule increases D. Intermolecular forces become weaker 38. Magnesium reacts with acid to produce hydrogen gas, H2. Which solution would give the highest initial rate of reaction? A. 100 cm3 of 1.0 mol dm-3 of nitric acid, HNO3 B. 100 cm3 of 1.0 mol dm-3 of hydrochloric acid, HCl C. 100 cm3 of 1.0 mol dm-3 of sulphuric acid, H2SO4 D. 100 cm3 of 1.0 mol dm-3 of ethanoic acid, CH3COOH 39. The rate of reaction for the decomposition of hydrogen peroxide decreases with time because A. product of reaction decreases B. temperature of hydrogen peroxide decreases C. volume of hydrogen peroxide decreases D. concentration of hydrogen peroxide decreases 40. The diagram shows an electrochemical cell.

What is the energy conversion involved? A. Electrical energy heat energy B. Chemical energy electrical energy C. Electrical energy chemical energy D. Chemical energy heat energy 41. Which of the following statements is true about isotopes I. They have the same chemical properties. II. They have different physical properties. III. They have the same number of valence electrons. IV. They have different numbers of neutrons. A. I, II and III only C. II, III and IV only B. I, III and IV only D. I, II, III and IV and ?

42. The electron arrangement of atom U is 2.8.1 and atom V is 2.8.7. What is the molar mass of a compound formed when atom U combines with atom V? A. 152.5 g mol-1 B. 94.0 g mol-1 C. 81.5 g mol-1 D. 58.5 g mol-1 43. The equation shows a precipitation reaction of potassium phosphate.

The corresponding values of a, b, c and d are A. 1, 6, 3, 2 B. 2, 3, 6, 1 C. 6, 2, 1, 3 D. 3, 1, 2, 6 44. Diagram 3 shows six elements in Period 4 of the Periodic Table of Elements. Which of the following is not true about the elements?

A. B. C. D.

They have a high melting point They do not conduct heat They are able to form coloured compounds They are able to show different oxidation number in their compounds

45. Diagram 2 shows the positions of elements T, W, X, Y and Z in the Periodic Table. T, W, X, Y and Z are not the actual symbols of elements.

Which of the following pairs of elements react to form an ionic compound? I. X and Z III. T and Y II. T and Z IV. W and Y A. I and II C. II and IV B. I and III D. III and IV 46. Diagram 7 shows the electrolysis of 0.5 mol dm-3 silver nitrate solution using carbon electrodes.

Which half equation represents the reactions at the anode and the cathode?

47. The diagram shows the structural change caused by the vulcanization of material P.

Which of the following statements are true about the diagram? I. Q is harder than P II. Q is easily oxidised compared to P III. Q is more elastic than P IV. Q is more heat resistible than P A. I and III only C. I, III and IV only B. II and IV only D. I, II, III, IV 48. In an experiment, 100 cm3 of 1.0 mol dm-3 hydrochloric acid reacts with excess magnesium to produce hydrogen gas. The graph of the volume hydrogen gas against time is drawn and curve X is obtained.

If the experiment is repeated using another solution, which solution will produce curve Y? A. 50 cm3 of 1.0 mol dm-3 nitric acid C. 25 cm3 of 1.0 mol dm-3 sulphuric acid B. 50 cm3 of 1.0 mol dm-3 ethanoic acid D. 25 cm3 of 1.0 mol dm-3 hydrochloric acid 9

49. Which of the following is the correct apparatus set-up for the preparation of an ester?

50. An experiment is carried out to study the rate of reaction between marble and hydrochloric acid to produce carbon dioxide gas. Which of the following graphs represents the two experiments?

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