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URANUS 52 N

A 25 Cr Super Duplex stainless steel with PREN 40

URANUS 52N+ (UR 52N+) is a super duplex stainless steel with 25% Cr and a PREN value higher than 40. The minimum guaranteed yield strength is 550 MPa which allows the designer to reduce weight. The molybdenum and nitrogen additions have been optimized in order to obtain the best corrosion resistance properties even for heavy plates. High nitrogen content improves the structure stability particularly in HAZ. Its corrosion resistance is much better than UR B6/N08904 and roughly equivalent to 6 Mo super austenitic alloys. Copper additions increase the corrosion resistance properties, particularly in sulphuric acid media. URANUS 52N+ is a cost efficient grade designed for offshore, marine, phosphoric acid, sulphuric acid applications... as well as pollution control equipments.

STANDARDS

EURONORM ................................ 1. 4507 - X2 Cr Ni Mo Cu N 25.6.3 AFNOR......................................... Z3 CNDU 25.07 AZ ASTM. .......................................... UNS S32550/S32520

CHEMICAL ANALYSIS

Typical values (Weight %)


C < 0.030 Cr 25 Ni Mo N 6.5 3.5 0.25 PREN = [Cr %] + 3.3 [Mo %] + 16 [N %] 40 Others Cu 1.5

MECHANICAL PROPERTIES

Tensile properties - minimum values


C 20 100 250 Rp 0.2 MPa 550 485 400 Rp 1.0 MPa 570 500 420 Rm MPa 770 700 640 F 68 212 500 YS 0.2% KSI 78 70 57 YS 1.0% KSI 83 72 61 UTS KSI 111 102 92 El % 25 25 25

Typical temperature range of use : -50C/+ 270 C (-58F /+518F) For lower temperature applications, please contact us.

06/01/2000 - Uranus 52N - Page 1

Impact strength (KV typical values) -50C (-58F) > 70 J > 30 J -20C (-4F) > 85 J > 40 J 0C (32F) > 90 J > 50 J 20C (68F) > 95 J > 55 J

KV plates (guaranteed) KV weld metal (typical)

Impact values of welds are closely related to the microstructure ( / balance) and the control of chemical analysis (oxygen, nitrogen, nickel) which depend on welding processes and parameters. The best results are obtained for high austenite contents (75-60 %) and low oxygen levels. High nitrogen contents associated with high ferrite levels must be avoided. For more information, please contact us. Hardness values - Typical values HV5 : 250 to 280 HRC < 28

PHYSICAL PROPERTIES

Density : 7,820 kg/m3 - 0.28 lb/in3


Interval Temper C 20-200 20-300 20-500 Thermal expansion x10 K 13.5 14 14.5
-6 -1

Resistivity ( cm) 85 95 100

Thermal conductivity (W.m .K ) 17 18 19


-1 -1

Specific heat (J.kg-1.K ) 450 500 530


-1

20 100 200

68 392 392

Young Shear modulus modulus E G (GPa) (GPa) 200 75 190 73 180 70

STRUCTURE STABILITY

25 Cr super duplex grades are subject to intermetallic phase precipitations (, ...) particularly when improperly heat treated. Higher molybdenum and tungsten additions increase the sensitivity to sigma phase transformation. CLI equipments and heat treatments are optimised in order to control the composition, structure and properties of the products. We use a batch furnace to control time and temperature for each individual plate. This makes CLI duplex quality. The microstructure free of intermetallic phases contributes to an increase of both toughness properties and corrosion resistance properties. Nitrogen additions have been increased compared to the former UR 52N grade (0.180.25%) in order to increase both corrosion resistance properties and structure stability, particularly in HAZ.

UR 35 N UR 47N +
C 1000 800 600 400 200 10 100

UR 45 N

UR 52N

UR 52N +
1000C 1800F Cr Mo W Si

Mo, W, Si M7 C3 carbide, Cr N nitride HAZ phase Cr2 N nitride phase phase 2 M 23 C6 carbide R Phase
phase phase (Cu ) ' phase G. phase...

UNS S32760

DTS 25 NWCu
F 1830 1470 1110 750 390 time

Cr, Mo, Cu, W 300C 600F

1000 0.1 1 10

10000

(sec.)

Cr, Mo, Cu, W

100 hour

Time

Possible precipitations in super duplex stainless steels

Uranus 52N - 06/01/2000 - Page 2

Heat treatment : UR 52N+ is delivered in the solution annealed and water quenched conditions (1080/1120C - 1976/2018F). The chemical analysis and heat treatment are optimised in order to reach a 50% / 50% microstructure.

CORROSION RESISTANCE

General corrosion UR 52N+ performs particularly well in sulphuric and phosphoric acid solutions, even in presence of chlorides. The duplex microstructure which provides high mechanical properties explains why the alloy behaves particularly well in abrasioncorrosion conditions (agitators, screws, rakes...). Mixed acids are often associated with chlorides and in pollution control equipments. Due to high chromium, molybdenum and copper additions, UR 52N+ behaves well in scrubber systems. In Pulp and Paper industries, UR 52N+ is used in the most severe conditions encountered for example in digester (resistant to hot wall problems), chips presteaming vessels or in some bleaching equipments.

Boiling curve

Corrosion rate mg/dm/24 h


212

100

80C (176F) 85C (185F)

100
Temperature (C)

80

176

Temperature (F)

S32520

60
N08904 N08926

140

10

40

316

104
S31803 316

URB6 UR52N UR47N + UNS UR52N + 904L S32550 S32750 S32760 S32550
100 68

20

20

40

60
H 2SO 4 (% wt)

80

Corrosion rate in 10% H2SO4 + 500 ppm Claerated, at 80C and 85C (176F and 185F)

Corrrosion rate (mdd) 300

Medium : NaCl 30g/l + Fe2 (SO4)3 0,1 % - pH = 2 aerated T = 60C Test duration 15 days

Medium : P205 : 30% - H 2 SO4 : 2% - F- 0,2% - H 2 SiF6 1,5% Fe3+ 0.35% - Al3+ 0.26%

Corrosion rate (mdd) 100


0 ppm F1000 ppm F-

80 60 40

80C (176F) 110C (230F)

200

100
No Corrosion

20 0 UR B6 UR 52N + UR B28 UR SB8 N 08904 S32550 N 08028 N08932 Phosphoric acid production Effect of the attack temperature on the corrosion rate

0 316L 317LNM UR45N

N08904 UR 52N

Pollution control equipments Effects of fluoride contents on the uniform corrosion rate

Chloride concentration (ppm) 2000 1600 1200 800 400 UR 52N +

UR B6 UR 45N 317 LNM 317 LN 316 LN 316L

Corrosion rate (mdd) 80 70 60 50 40 30 316L 20 10 0


20 UR 45N

304L

White liquor : NaOH : 125 g/l Na2S : 50 g/ll Na2/So4 : 16 g/l Na2CO3 : 27 g/l Sulfidity : 21 % H2S bubbling

20 68

60 140

80 176

120 216

(C) (F)

UR 52N +
40 60 80 100

Chloride concentration (g/l)

Safe use limits of stainless steels versus chloride content and temperature in 54 % P205

Heat transfer (solution 140C - Sample 80C) Pulp and Paper industry Corrosion rate versus chloride content in Kraft media

Uranus 52N - 06/01/2000 - Page 3

Chloride level F- (ppm) 6


0

1 g/l
400 1000 0

5 g/l
400 1000 0

30 g/l
400 1000 0

300 g/l
400 1000

UR 45N +
UNS 31803 - PREN 35

4 pH 2 UNS 32550/S32520 UR 52N+

UNS 32550/S32520 UR 52N+ UNS 08926 - UR B26

N06022 - H.C22

N10276 - H.C276

MATERIAL GUIDE FOR USING IN FGD EQUIPMENTS - 60C (140F) Based on extensive tests results

Pitting and crevice corrosion The minimum PREN value of 40 also explains why the alloy is highly resistant to pitting corrosion and crevice corrosion. The alloy behaves much better than 904L and is, for pitting corrosion resistance, nearly equivalent to 6 Mo super grade. In some cases, the crevice corrosion resistance is slightly higher than 6 Mo alloys due to the 25% Cr additions.
mV/SCE 1000 800 600 400 200 UR 35N UR B6 904L 316 UR 52N UR 52N+ NaCl 30 g/l
Repassivation potential (1 mA/cm)
mV/SCE

1000 800 600 400 200 0 -200 UNS S31803 UR B6 904 L

UNS S32550 UNS S32520

C 20 40 60 80 100 F 70 105 140 175 210 Pitting potential taken from polarization curves for different stainless steels

20 40 60 80 100 C 70 105 140 175 210 F Repassivation potential in 15% NaCl solution CO2 saturated

C 80 70 60 50 40 30 20 10 0

DUPLEX Ask Us Guaranteed

SUPER-AUSTENITICS

F 175 140 105 70

C 80 70 60 50 40 30 20 10 0

DUPLEX Ask Us Guaranteed

SUPER-AUSTENITICS

F 175 140 105 70

UR 35N S32304

UR 45N S31803

316L

UR B6 904L

UR 52N+ S32520

Test ASTM G48A PITTING in a 6% FeCl3 solution

Test ASTM G78 CREVICE in a 6% FeCl3 solution

C 60 40

11,5% H2SO4 + 1,2% HCl + 1% FeCl3 + 1% CuCl2 UR52N+ UR45N 317LNM

Crevice area % 80

Medium - Cl- 4000ppm + CaS04 7% Fe (SO 4)3 0,7% : pH = 1 aerated T = 60C Test duration 15 days

140
60

UR 52N+ S32520

UR 35N S32304

UR 45N S31803

UR B26 08926

105

40

0 ppm F400 ppm F-

20

316

70

20

0
316 L 317 LNM UR 45N N08904 UR 52N +

GREEN DEATH - CRITICAL PITTING TEMPERATURE

Pollution control equipments Crevice corrosion test on samples fitted with multi-crevice washers - effect of fluoride content

Uranus 52N - 06/01/2000 - Page 4

UR B26 08926

316L

UR B6 904L

Stress corrosion cracking resistance The stress corrosion resistance properties of URANUS 52N+ is excellent in high temperature chloride containing solutions as well as in sour gas applications.

FABRICATION
300 200

UR 52N + 570 Super duplex No cracking

MPa 500 400

Rp 0.2 % Stress threshold

UR 45N UR 35N

390 300 200

100 AISI 304/316 0

210 100 32 10 Cl- (%) 0 304L 316L UR52N 904L Stress corrosion cracking in chloride media : 300 g/l NaCl - T = 110C - pH = 1 Threshold stress without crack after 1 month Chloride (mg/l)
Austenitic Duplex UR45N UR47N UR52N 1000000

0.001

0.1

Constant-strain tests in autoclave Above the curve, SCC occurs. Open circles means no SCC for UNS 32550/UR 52N+

SCC resistance
10 20 30 40

316L

170 HE URB6

MR 01-75 limits for 22 Cr and 25 Cr duplex


100000 CRACKING S 31803 UR 45N 10000 NO CRACKING S 32550 UR 52N + NO CRACKING

CRACKING

Loss of ductility

1000 0.01 0.1 1 10 100

Slow strain rate tests (10-6/sec) in NaCl, 40% pH=2 (HCl), 110C - Elongation in air - Elongation in corrosive medium

Hydrogen Sulphide (psi) Suggested limits for Duplex and Super duplex stainless steels

Cold forming Due to its higher mechanical properties, the cold forming of UR 52N+ requires more strength than austenitic grades. For cold deformations higher than 20 %, an intermediate heat treatment is required (solution annealing 1080/1120C (1976/2018F) + water cooling). Detailed guidelines for cold forming of unwelded and welded plates are available upon request. Hot forming Between 1150C and 1000C (2102 and 1832F). After hot forming, a new solution annealing heat treatment in the range 1080/1120C (1976/2018F) + water cooling is necessary. Pickling Same conditions as for 316L grade, but the pickling time is at least twice that of 316L grade. An increase of the temperature of the pickling bath reduces the pickling time.

Uranus 52N - 06/01/2000 - Page 5

WELDING

URANUS 52N+ can be welded using the following processes : SMAW, GTAW (with filler), GMAW, PAW (with filler). The welding procedures are similar to those of other duplex stainless steels : - no pre-heating, - heat input between 0.5 KJ/mm and 2 JK/mm is recommended (depending on the process and on the thickness of the plate). Precise welding parameters for each type of process and thicknesses are available on request. - interpass temperature less than 150C (302F) and preferably less than 120C (248F) - no PWHT, except solution annnealing at 1080/1120C (1976/2048F) + water cooling. As in welded conditions, the ferrite ratio in the heat affected zone should be lower than 70% between 20 to 60% for the weld metal ; for SMAW, FCAW and SAW weld metal aim for the lower part of the range (20 to 40%). In order to control the structure and properties, over alloyed filler materials are recommended (nickel and/or nitrogen additions). Excessive dilutions must be avoided. Filler materials and shielding gases guaranteeing PREN > 40 have been developed (wire, metallic cored wire, electrodes) - a list of tested filler materials is available on request.
CRITICAL PITTING TEMPERATURE ON WELDED STRUCTURE - ASTM G48A CORROSION CRITERIA : > 10 mg WEIGHT LOSS GRADE FILLER 316L UR 45 N 316 L 22 Cr duplex

UR 45 N+ 25 Cr duplex UR 825 UR B6 UR 52N+ UR 52N+ 625 625 25 Cr Duplex Alloy H.C22


20 70 25 75 30 85 35 93 40 45 50 105 113 120 55 60 65 70 CPTC 131 140 150 160 CPTF

Corrosion resistance properties of welded structures are very dependant on welding parameters and surface condition. Avoid oxyde scales or contaminations. Brushed or pickled welds perform better. The best results are obtained for solution annealed welds. The use of nickel based weld consumables allow to increase the corrosion resistance of welded structures (avoid 625 alloys but use Nb free grades like H.C22 or SG Ni Cr 23 Mo 16 or PHYWELD NCM (Nb free 625).

Uranus 52N - 06/01/2000 - Page 6

DESIGN

Cost factor considerations Maximum allowable stresses given by several pressure vessel codes are shown here. The high mechanical properties of URANUS 52N+ allow thickness and, consequently, cost reductions.. We are happy to offer assistance in evaluating potential cost savings related to pressure vessel or structural design and the excellent corrosion resistance properties of UR 52N+. Design stress values (Typical values)
Room temperature (MPa)
Country Code 316 UR 45N 31803 UR B6 904L UR 52N 32550/520
+

Saving factors + UR52N / URB6

USA F UK D

ASME VIII, DIV1 CODAP 90, f.1 BS 5500 ADW 2

108 166 128 128

155 275 289 300

123 176 173 167

190 287 294 327

35 % 38 % 42 % 49 %

COST EFFECTIVENESS ASPECTS Cost including weight saving factors Corrosion resistance PREN = [%Cr] + 3.3 [%Mo] + 16 [%N]

45
UR B26 URB6 317LNM 316 UR 35N UR 76N UR 45N+ UR45N

UR B26 08926

40 35 30 25 50 20
316L UR B6 UR45N 31803 UR 35N 32304

UR 52N+ 32550/520 UR 45N+ 31803

304

20

Corrosion resistance PREN = [%Cr] + 3.3 [%Mo] + 16 [%N]

30

40

200

250

300

350

400 450 500YS 0.2 MPa Mechanical properties

APPLICATIONS

Seawater systems and applications (diving spheres...), Oil and gas Industry including sour gas applications, Petrochemical industry including PVC strippers, Pulp and paper industry (digesters, bleaching towers...), Chemical industry including organic acid applications, Sulphuric acid plants, Phosphoric acid plants, Truck-lorries multipurpose containers, Pollution control equipments (scrubbers), ...

SIZE RANGE
Thickness Width Length

Hot rolled plates 5 to 150 mm 3/16" to 6" Up to 3300 mm Up to 130" Up to 12000 mm Up to 472"

Cold rolled plates 2 to 14 mm 5/64" to 5/8" Up to 2300 mm Up to 90.5" Up to 8250 mm Up to 325"

Clad plates 6 to 150 mm 1/4" to 6" Up to 3300 mm Up to 130" Up to 14000 mm Up to 551"

Other sizes are available on request, including 4100mm (161,5")width plates

Uranus 52N - 06/01/2000 - Page 7

NOTE This technical data and information represents our best knowledge at the time of printing. However, it may be subject to some slight variations due to our ongoing research programme on corrosion resistant grades. We therefore suggest that information be verified at time of enquiry or order. Furthermore, in service, real conditions are specific for each application. The data presented here is only for the purpose of description, and may only be considered as guarantees when our company has given written formal approval.Further information may be obtained from the following address.

For all information : CREUSOT-LOIRE INDUSTRIE, FAFER 56 Rue Clemenceau 266, rue du Chatelet 71202 LE CREUSOT CEDEX - FRANCE B- 6030 MARCHIENNE AU PONT Sales Tel +33 3 85 80 52 16 Tel +32 71 44 18 78 Fax +33 3 85 80 51 77 Fax +32 71 44 19 59 Development CLI-FAFER Tel Fax +33 3 85 80 55 03 +33 3 85 80 59 66

Uranus 52N - 06/01/2000 - Page 8

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