Nmero MSDSPF 47

MSDS - ESBR 1000 SERIES - EMULSION STYRENE BUTADIENE RUBBER -

Data 06/03/2002 Rev 3 Emitente Elcio Motta Aprov. Ricardo Matte

HISTRICO DE ALTERAES
Rev - Data - Histrico 0 - 04/07/2000 - Emisso Original 1 - 18/10/2000 - Alterao do CAS Number 2 - 28/03/2001 - Excluso da ESBR 1009 3 - 05/03/2002 - Incluso da ESBR 1009 Aprovao Ricardo Matte

SECTION I - PRODUCT IDENTIFICATION

PRODUCT NAME: PETROFLEX ESBR SERIES 1000 -Emulsion Styrene Butadiene Rubber SERIE SPECIFICATION : ESBR 1006 - ESBR 1009 - ESBR 1027 - ESBR 1028 CHEMICAL NAME: Styrene Butadiene Copolymer (ESBR 1006 - ESBR 1027 - ESBR 1028) e Divinylbenzene - ButadieneStyrene Terpolymer (ESBR 1009) CAS RN: 9003-55-8 PRODUCT DESCRIPTION: Butadiene-styrene copolymer (ESBR 1006 - ESBR 1027 - ESBR 1028) and terpolimer of butadiene-styrene and divinylbenzene (ESBR 1009) produced by hot emulsion polymerization using fatty-acid soaps as emulsifier. Coagulated by saltacid method. A non-staining antioxidant is used. PRODUCER: PETROFLEX INDSTRIA E COMRCIO S/A - BRASIL TRIUNFO PLANT Via de Contorno, 920 Complexo Bsico Plo Petroqumico Triunfo - RS CEP 95.853-000 Brazil phone.: 51 457-1144 ; fax: 51 457-1109

SECTION II - COMPOSITION
CHEMICAL FAMILY: Synthetic elastomer CHEMICAL FORMULA : (CH2-CH=CH-CH2-CH2-CH)nC6H5

SECTION IIl - EXPOSURE LIMITS

BRASIL L.T
ppm NC mg/m3 NC ppm NC

V.M
mg/m3 NC

LIMITES DE EXPOSIO OSHAEUA ACGIHEUA TWA TLV/TWA TLV/STEL

ppm NC mg/m3 NC ppm NC mg/m3 NC ppm NC mg/m3 NC

NIOSHEUA IDLH
ppm NC mg/m3 NC

NFPA 704 HAZARD SIGNAL: 4 - Extreme 3 - High 2 - Moderate 1 - Slight 0 - Insignificant

Health -1 Flammability - 1 Reactivity - 0 Special - NA

1 1 0

SECTION IV - HEALTH INFORMATION

INGESTION: No hazard in normal industrial use . INHALATION: Negligible hazard at ambient temperature. SKIN CONTACT: No hazard in normal industrial use. Exposure to hot material may cause thermal burns. EYE CONTACT : Particulates may scratch eye surface and cause mechanical irritation. CHRONIC / OTHERS: NA TOXICOLOGY DATA: NA

SECTION V - FIRST AID

EYE: This product is an inert solid. If in eye, remove as one would any foreign object. INGESTION: NA INHALATION: NA SKIN: No hazard in normal use industrial at ambient temperature. For hot product , immediatly immerse in or flush the affected area with large amounts of cold water to dissipate heat.

SECTION VI - FIRE AND EXPLOSION HAZARD

CLASSIFICATION: Solid fuel. FLASH POINT (C): ND IGNITION TEMPERATURE (C): 320 LOWER EXPLOSIVE LIMIT (%): ND UPPER EXPLOSIVE LIMIT (%): ND FIRE FIGHTING: extinguisher agents: foam, water spray, dry chemical foam and CO2. SPECIAL PROCEDURES: take all fuel material away from the surrounding area; extinguish fire in the wind direction. FIRE AND EXPLOSION HAZARD: may quickly burn introducing flame. TOXIC SUBSTANCES PRODUCED BY COMBUSTION: CO

SECTION VII - SPILL CONTROL PROCEDURES

LAND AND WATER SPILL: Recover spilled material and place in suitable containers for recycle or disposal.Consult an expert on disposal of recovery material and ensure conformity to local disposal regulations.

SECTION VII HANDLING AND PROTECTION

TEMPERATURE: should be lower than 50C. PRESSURE: 760 mmHg. VENTILATION: Natural. IDENTIFICATION: Non toxic.

SECTION IX - EXPOSURE CONTROL AND INDIVIDUAL PROTECTION

RESPIRATORY PROTECTION: not required . EYES: wear safety glasses. SKIN: where contact may occur with hot material, wear thermal resistant gloves. ADDITIONAL PROTECTIVE MEASURES: NA

SECTION X - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: solid. APPEARANCE: ESBR 1006 - ESBR 1009 - ESBR 1027 - ESBR 1028 -pale yellow, white . BOILING POINT (C): ND MELTING POINT (C): ND MOLECULAR WEIGHT: ND SPECIFIC GRAVITY (WATER=1): 0,94 VISCOSITY: NA VOLATILES (% VOLUME): 0,75 (max.) VAPOR PRESSURE (mm Hg):ND SOLUBILITY IN WATER (20C): Insoluble. SOLUBILITY (g/100g): Soluble in aromatics, alifatics solvents and chlorinated hydrocarbons.

SECTION XI - REACTIVITY DATA

STABILITY: [ X ] - STABLE [ ] - UNSTABLE HAZARDOUS POLYMERIZATION: [ ] - OCCUR [ X ] - WILL NOT OCCUR CONDITIONS TO AVOID INSTABILITY: NA DECOMPOSITION TEMPERATURE: NA THERMAL DECOMPOSITION PRODUCTS: oxides of carbon under burning conditions.

SECTION XII - ENVIRONMENTAL PROTECTION

LEAKAGE AND SPILLAGE : Recover in container for disposal. TREATMENT AND FINAL DISPOSAL : According to applied local enviromental laws. ENVIRONMENTAL IMPACTS : No hazard.

SECTION XIII - DISPOSAL PROCEDURE

DISPOSAL: Place in suitable containers for recycle or disposal. Consult an expert on disposal of recovery material and ensure conformity to local disposal regulations.

SECTION XIV - TRANSPORTATION

UN NUMBER: N.C

LABELING: N.C. HAZARD CLASS: N.C. CLASS/SUBCLASS: N.C. Obs: The classification below is valid only to powder or debris up to 640 micrometers with more than 45% of rubber. In others situations is not classified as hazard product. UN NUMBER: 1345 LABELING: flammable solid HAZARD CLASS: 4,0 CLASS/SUBCLASS: 4/4,1 ADDITIONAL RECOMMENDATIONS: Use labeling according to subclass. Maximum to be transposted without emergency kit 250 kg.

SECTION XV - INFORMATION ON REGULATION

TSCA Inventory Status : All components of this product are listed on the U.S. EPA Toxic Substances Control Act Inventory.

SECTION XVI - ADDITIONAL INFORMATION

ABBREVIATIONS: NA: not applicable; NC.: not classified; ND: not available; ACGIH: American Conference of Governmental Industrial Hygienists. CAS: Chemical Abstract Service. LC50:The concentration in air that causes death in 50% of the animals exposed. LD50: The dose that causes death in 50% of the animals exposed. mg/m3: Milligrams of substance per cubic meter of air; method of expressing the concentration of a substance in air. NFPA: National Fire Protection Association. NIOSH: National Institute for Occupational Safety and Health. OSHA: Occupational Safety and Health Administration. PEL: Permissible Exposure Limits. TLV: Thershold Limit Value. TWA: Time Weighted Average. STEL: Short Term Exposure Limit . IDLH: Immediately Dangerous to life and Health. MSDS: Material Safety Data Sheet. REFERENCE: 1.PETROFLEX, INDSTRIA E COMRCIO S/A - Brasil 2..PR- QUMICA - ABIQUIM, MANUAL PARA ATENDIMENTO DE EMERGNCIAS COM PRODUTOS PERIGOSOS, GUIA NR-32, 1994.
THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT, HOWEVER, PETROFLEX MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THEIR USE THEREOF. PETROFLEX ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.