1.

Which of the following structures correspond to the product expected, wh en excess of reacts with in presence of anhydrous (a) (c) Which of the following will be (b) (c) (d) Chlorination of benzene is not (b) (d) easily nitrated possible in the following reaction

2. (a) 3. (a) (b) (c) (d) 4. (a) (c) 5. (1)

. A is (b) (d) In order to complete the reaction a and b will be : (2) : (3) : (4) : (a) 1 (b) 2 (c) 3 (d) 4 The number of secondary hydrogens in 2, 2-dimethyl butane is

6.

(a) 8 (b) 6 (c) 4 (d) 2 7. An alkane (molecular weight 72) forms only one monochlorinated product. Its formula is (a) (b) (c) (d) 8. The poisonous gas that comes out with petrol burning in a car is (a) (c) 9. (a) (b) HCOOH 10. In the above reaction the compound A is (a) Ethylene bromohydrin (b) 1, 2-dibromo ethane (c) Ethanol (d) None of these Read the assertion and reason carefully to mark the correct option out of the op tions given below: (a) If both assertion and reason are true and the reason is the correct expl anation of the assertion. (b) If both assertion and reason are true but reason is not the correct expl anation of the assertion. (c) If assertion is true but reason is false. (c) (d) (b) (d) The reagent X in the reactions

(d) (e) 11. Reason 12. Reason

If the assertion and reason both are false. If assertion is false but reason is true. Assertion : Alkyl halides are soluble in organic solvents. : p-dichlorobenzene possesses low melting point. Assertion : is not a fire extinguisher. : is insoluble in water.

Answers and solutions 1. (d)

2. (a) The presence of an electron-releasing groups (+I group) e.g., etc makes the process of nitration easier. So will be easily nitrated. 3. (b) Reaction is called Gattermann-Koch synthesis, which is carried b y catalyst . 4. (a) 5. (c)

6. (d) 7. (a) The alkane forms only one mono substituted product, it must have only one type of hydrogen atoms. there fore the alkane is 2, 2-dimethyl propane . 8. (d) On petrol burning CO comes out which is so much poisonous gas. 9. (b) Oxy mereuration-demercuration : with mercuricacetate (in THF) fo llowed by reduction with is an example of hydration of alkene according to mar kowni koff s rule. 10. (a) Hence compound A is Ethylene bromohydrin. 11. (c) Due to symmetrical nature and more closer packing p-dichlorobenz ene has highest melting point. 12. (e) is used as a fire extinguisher. The dense, non combustible vap ours cover the burning substance and prevents the availability of oxygen round b urning material.