TECHNICAL DATA SHEET

TDS-776 Edition: March 11, 2011 Original Date: November 8, 2010

Sensomer* CT-400 Polymer

Product Description:
Sensomer CT-400 polymer is a naturally derived, multifunctional polymer for use in hair care formulations providing improved deposition, distinctive sensory and enhanced conditioning. When used in shampoos, Sensomer CT-400 polymer deposits silicone more efficiently and conditions hair more effectively than standard cationic conditioning polymers. The improved efficiency of the polymer allows formulators to reduce the amount of silicone and cationic polymer needed to produce formulations that generate smooth, silky, healthy looking hair that is alluring to the eye and to the touch. Sensomer CT-400 polymer is a cationic derivative of cassia gum, a galactomannan with a long history of use in Ayurvedic medicine to treat skin ailments, indigestion and pain.

INCI Designation:
Cassia Hydroxypropyltrimonium Chloride

Benefits:
Very efficient silicone deposition aid Good surfactant compatibility to generate formulations with medium clarity Generates high levels of coacervation Highly substantive polymer Enhances comb properties of hair in both the wet and dry stage Generates clean and fresh wet sensory Leaves dry hair feeling soft and conditioned Effective frizz control to leave hair looking smooth and silky Enhances viscosity of anionic surfactantbased formulations Enhances foam richness to generate a long lasting creamy foam in surfactant-based formulations Versatility to provide enhanced conditioning for a wide variety of hair types

Typical Properties:
Properties as Supplied
Appearance Average Charge Level Cationic Charge Density 1 Dispersion Viscosity 2 Dispersion Turbidity
1 2

Light tan powder 4.0% N 3.0 meq/g 100 - 750 mPas 0 - 18 NTU

Applications:

Note: A dispersion is 1.0% polymer solids in water

Brookfield RVT @ 20 rpm, 25C, 1 minute, spindle #5 DRT-100B Turbidimeter (HF Scientific), NTU

Conditioning shampoos Hair treatments Smoothing shampoos Body washes Hair conditioners Facial cleansers

Due to the high charge density of these naturally derived polymers, best results are obtained when surfactant concentration is >12%.

Lubrizol Advanced Materials, Inc. / 9911 Brecksville Road, Cleveland, Ohio 44141-3247 / TEL: 800.379.5389 or 216.447.5000
The information contained herein is believed to be reliable, but no representations, guarantees or warranties of any kind are made as to its accuracy, suitability for particular applications or the results to be obtained therefrom. The information is based on laboratory work with small-scale equipment and does not necessarily indicate end product performance. Because of the variations in methods, conditions and equipment used commercially in processing these materials, no warranties or guarantees are made as to the suitability of the products for the application disclosed. Full-scale testing and end product performance are the responsibility of the user. Lubrizol Advanced Materials, Inc. shall not be liable for and the customer assumes all risk and liability of any use of handling of any material beyond Lubrizol Advanced Materials, Inc.s direct control. THE SELLER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Nothing contained herein is to be considered as permission, recommendation, nor as an inducement to practice any patented invention without permission of the patent owner.

For further information, please visit www.personalcare.noveon.com

Lubrizol Advanced Materials, Inc. is a wholly owned subsidiary of The Lubrizol Corporation * Trademark owned by The Lubrizol Corporation Copyright 2011 / The Lubrizol Corporation

TDS-776 Sensomer CT-400 Polymer

Page 2 of 3

Chemistry:
Sensomer CT-400 polymer is a cationic derivative of cassia gum. Cassia gum is a natural, vegetable-based carbohydrate based on mannose and galactose sugars and is a member of the galactomannan family of polysaccharides. The cassia gum used to produce Sensomer CT-400 polymer is based on a combination of cassia tora and cassia obtusifolia which grow wild in tropical zones around the world. Cassia gum is modified with the quaternary ammonium compound, hydroxypropyl trimethylammonium chloride, to generate Sensomer CT-400 polymer. The chemical identity of the polymer is 2-hydroxypropyl-3-trimethylammonium chloride cassia. The combination of cationic charge and unique molecular structure provides Sensomer CT-400 polymer with its unique deposition characteristics and distinctive sensory.

Formulating Guidelines:
Formulation Tips: Recommended use level: 0.10 - 0.25 wt% TS High levels of anionic surfactants preferred (>10 - 12 wt% TS) o Amphoteric surfactants (i.e., CAPB) and salt levels varied to adjust viscosity and clarity (if desired) At lower levels of anionic surfactants (<12 wt% TS) compatibility can be improved by: o Higher levels of amphoteric surfactant (CAPB) and salt o Use of lower levels of Sensomer CT-400 polymer Use of small particle size silicone leads to higher levels of silicone deposition than large particle size silicone For formulations requiring use of high levels of Sensomer CT-400 polymer dispersions (2 wt% TS or more), dispersion preparation time can be optimized with use of: o Citric acid o Carriers such as glycerin or betaine Recommended Order of Addition for Shampoo via Pre-Addition: 1. Disperse the Sensomer CT-400 polymer in water 2. Add betaine (CAPB) 3. Add anionic surfactants (SLES or others) 4. Add EGDS (Heat to 65 - 70C), then cool 5. Add silicone emulsion and any other ingredients (fragrance, dye, mica, etc.) 6. Add salt to desired viscosity 7. Adjust pH as needed Recommended Order of Addition for Shampoo via Post Addition:
Please note: This process is recommended when Carbopol polymer is used for shampoo formulation.

Storage and Handling:

Packaging: Polyethylene lined, heavy duty paper bags with a net weight of 20 kilograms. Shelf Life: Two years from date of manufacture. Storage Conditions: Store in a dry, clean place away from direct heat or sparks. Material Handling:

Keep bags of product sealed until needed. Keep partially used bags in a humidity controlled room to prevent moisture uptake. Avoid creating dust. Maintain good housekeeping procedures. Sensomer CT-400 polymer is freeze/thaw stable. Consult the product MSDS for additional safety and handling information.

Formulations Available:
Please see http://www.lubrizol.com/ PersonalCare/Formulations for formulations.

1. Disperse Carbopol polymer in water 2. Add anionic surfactants 3. Add silicone emulsion, and any other ingredients (fragrance, dye, mica, etc.) 4. Add betaine 5. Add dispersion of Sensomer CT-400 polymer in water 6. Add salt to desired viscosity 7. Adjust pH as needed

TDS-776 Sensomer CT-400 Polymer

Page 3 of 3

Regulatory Status:
Sensomer CT-400 polymer qualifies as polymer exempt from TSCA, EINECS and ELINCS registration. All monomers used in Sensomer CT-400 polymer are listed on EINECS. As supplied, Sensomer CT-400 polymer complies with the European Union Cosmetics Directive 76/768/EEC, 7th Amendment. It is not classified as a carcinogenic, mutagenic or reproductive toxicant (CMR). Additional regulatory information is available on the material safety data sheet.

Other Literature Available:

Product Brochure (TDS-774) Temporary Product Specification Test Procedure Regulatory Status Summary Material Safety Data Sheet (MSDS) Toxicological Summary Reprint of article, Cassia Derivatives Improve Hair Conditioning, published in HAPPI Magazine, December, 2010 Reprint of summary of presentation to the TRI Applied Hair Science Symposium, Use of Statistical Modeling to Predict the Effect of Formulation Composition on Coacervation and Conditioning Sensory Performance of Cationic Cassia Polymers, to be published in the Journal of Cosmetic Science, March, 2011 (available May, 2011)

Toxicology:
Toxicology studies performed with chemical compositions representative of Sensomer CT-400 polymer demonstrate the polymer has an excellent toxicity profile. It is recommended for all types of personal care formulations. A complete summary of toxicological effects is available upon request.

Source and Genetically Modified Organisms:

Sensomer CT-400 polymer is prepared solely from plant and synthetic materials. No animal products are used at any point in the processing or handling of this product. Sensomer CT-400 polymer does not contain genetically modified plant material. A TSE-GMO certificate is available upon request.

Other General Information:

The U.S. Tariff code for Sensomer CT-400 polymer is 1302.39.0090. The CAS number is considered proprietary.