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Agenda
Type of Zn Plating Working Condition Post Treatment (Passivation)
Ammonium based
Alkaline based
Cyanide based Non Cyanide based
Working Condition
Hot Acid Zinc Conventional Zn 35-40g/l 20-30g/l Cl 140-160g/l 75-105g/l H3BO3 20-25g/l 15-20g/l Temp 25-45C 20-30C pH 5,0-5,3 4,5-5,3
Working Condition
Temperature : 20 45o C Current Density : 3A/dm2 (2 6A/dm2) Rack 0.75A/dm2 (0.5 1A/dm2) Barrel Voltage : 3 10 Volt (Rack) 2 3 Volt (Barrel) Filtration : Required Agitation : Required Anode Material : Zinc 99.995%
Working Condition
Cyanide zinc
Low Cyanide
Working Condition
Current Density : 2A/dm2 (1 3A/dm2) Rack 0.75A/dm2 (0.5 1A/dm2) Barrel Voltage : 2 6 Volt (Rack) 6 12 Volt (Barrel) Filtration : Required Current Efficiency : 50 95% Anode Material : Zinc 99.995%
Post Treatment ..
Passivation
Process sequence
Zink Drag out t rinse Drag out t activation Oxide development t passivation Active surface t rinse Active surface t
c /0 .9 /G F U H /0 2 o 3 7 M /F C S 2
structure organic codeposition drag in / out l (katalysts) l cleaning of surface Neutralisation homogene surface brightness ca. 0,1 m Zink is dissolved pH / T / agitation t / replenishment Volvonorm leaching T "cold" T < 60 C demage of layer
Time optimum fast reaction, low viscosity, less diffusion influence wrong colour (reddish) Passivation is too soft Low corrosion protection Influence of diffusion
Agitation
Zinc
Blue Passivation
Color of chromate film is
Higher thickness, more corrosion protection
Final color is
Reduced dip time Lower pH Lower temperature Shorter pull over Lower salt conc.
co/05.90/GMF/ZINK/011E
Longer dip time Higher pH Higher temperature Longer pull over Higher salt conc.