Ethanol Data - Wikipedia

Ethanol (data page) - Wikipedia, the free encyclopedia
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http://en.wikipedia.org/wiki/Ethanol_(data_page)
Ethanol (data page)

From Wikipedia, the free encyclopedia
This page provides supplementary chemical data on ethanol.
Contents
1 Material Safety Data Sheet
2 Structure and properties
3 Thermodynamic properties
4 Spectral data
5 Vapor pressure of liquid
6 Density of ethanol at various temperatures (kg/l or g/cm3)
7 Properties of aqueous ethanol solutions
8 Boiling points of aqueous solutions
9 References
Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material
Safety Datasheet (MSDS) for this chemical from a reliable source and follow its directions.
SIRI (http://www2.siri.org/msds/index.php)
Science Stuff (http://www.sciencestuff.com/msds/C1156.html)
Mallinckrodt Baker (http://www.jtbaker.com/msds/englishhtml/p6735.htm) .
Structure and properties

Structure and properties
Index of refraction, n25
1.361
Dielectric constant, r
24.3 0 at 25 C
Bond strength
Bond length
Bond angle
Magnetic susceptibility[1] 5.8107 (cgs units, volume)

Surface tension
22.39 dyn/cm at 25C
Viscosity[2]
6.285 mPas at 50C

4.656 mPas at 40C
3.530 mPas at 30C
2.731 mPas at 20C
2.419 mPas at 15C
2.151 mPas at 10C
1.920 mPas at 5C
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1.720 mPas at 0C
1.546 mPas at 5C
1.394 mPas at 10C
1.261 mPas at 15C
1.144 mPas at 20C
1.040 mPas at 25C
0.949 mPas at 30C
0.794 mPas at 40C
0.670 mPas at 50C
0.570 mPas at 60C
0.487 mPas at 70C
0.452 mPas at 75C
Thermodynamic properties
Phase behavior
Triple point
150 K (123 C), 0.00043 Pa
Critical point
514 K (241 C), 63 bar
Std enthalpy change

of fusion, fusHo
+4.9 kJ/mol
Std entropy change

of fusion, fusSo
+31 J/(molK)
Std enthalpy change

of vaporization, vapHo
+38.56 kJ/mol
Std entropy change

of vaporization, vapSo
109.67 J/(molK)
Molal freezing point constant
1.99 C kg/mol
Molal boiling point constant
1.19 C kg/mol
Solid properties
Std enthalpy change
of formation, fHosolid
277.7 kJ/mol
Standard molar entropy,

Sosolid
? J/(mol K)
Heat capacity, cp
? J/(mol K)
Liquid properties
Std enthalpy change

of formation, fHoliquid
277.38 kJ/mol
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Soliquid
159.9 J/(mol K)
Enthalpy of combustion, cHo 1370.7 kJ/mol

Heat capacity, cp
112.4 J/(mol K)
Gas properties
Std enthalpy change

of formation, fHogas
235.3 kJ/mol

Sogas
283 J/(mol K)
Heat capacity,[3][4] cp
78.28 J/(mol K) at 90C

87.53 J/(mol K) at 110-220C
Heat capacity ratio,[3][4]

= cp/cv
1.13 at 90C
van der Waals' constants[5]
a = 1217.9 L2 kPa/mol2
b = 0.08407 liter per mole
Spectral data
UV-Vis
max
? nm
Extinction coefficient,
?
IR
(liquid film)
Wave number transmittance
22%
880 cm1
[6]
Major absorption bands
1048 cm1
6%
1089 cm1
19%
1275 cm1
52%
1329 cm
44%
1384 cm1
32%
1418 cm1
33%
1650 cm
26%
1926 cm1
62%
2899 cm1
12%
2930 cm
13%
2977 cm1
4%
NMR
Proton NMR
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Carbon-13 NMR
http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/IMG.cgi?fname=CDS00245&imgdir=cdsW;
Other NMR data

MS
Masses of
main fragments
Vapor pressure of liquid

P in mm Hg 1
T in C
10
40
100
400
760
1520 3800
31.3 2.3 19.0 34.9 63.5 78.4 97.5
7600
15200 30400 45600
126.0 151.8 183.0
218.0
242.0
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.
Log10 of ethanol vapor pressure vs. temperature. Uses formula:
Ethanol vapor pressure vs. temperature. Uses

formula:
from
Lange's Handbook of Chemistry 10th ed.
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Density of ethanol at various temperatures (kg/l or g/cm3)

Data obtained from Lange's Handbook of Chemistry, 10th ed.
3C
0.80374 16C 0.79283 29C 0.78182
4C
0.80290 17C 0.79198 30C 0.78097
5C
0.80207 18C 0.79114 31C 0.78012
6C
0.80123 19C 0.79029 32C 0.77927
7C
0.80039 20C 0.78945 33C 0.77841
8C
0.79956 21C 0.78860 34C 0.77756
9C
0.79872 22C 0.78775 35C 0.77671
10C 0.79788 23C 0.78691 36C 0.77585

11C 0.79704 24C 0.78606 37C 0.77500
12C 0.79620 25C 0.78522 38C 0.77414
39C 0.77329 40C 0.77244
Properties of aqueous ethanol solutions

Data obtained from Lange's Handbook of Chemistry, 10th ed. The annotation, d aC/bC, indicates density of
solution at temperature a divided by density of pure water at temperature b.
grams
ethanol
% wt
% vol
d
d
d
d
d
d
freezing
per 100
ethanol ethanol
10C/4C 20C/4C 25C/4C 30C/4C 20C/20C 25C/25C temp.
cc
15.56C
0.0
0.99973
0.99823
0.99708
0.99568
1.00000
1.00000
1.0
0.99785
0.99636
0.99520
0.99379
0.99813
0.99811
2.0
0.99602
0.99453
0.99336
0.99194
0.99629
0.99627
2.5
0.0
0.0
3.13
0.99363
3.0
4.0
5.00
3.97
4.8
6.00
4.76
5.0
5.05
6.0
6.30
1C
0.99426
0.99275
0.99157
0.99014
0.99451
0.99447
0.99258
0.99103
0.98984
0.98839
0.99279
0.99274
0.98971
0.99098
5.00
0.98938
0C
2C
0.98817
0.98670
0.99113
0.99106
0.98656
0.98507
0.98955
0.98945
0.98930
0.98946
0.98780
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6.8
8.47
0.98658
3C
7.0
0.98801
0.98627
0.98500
0.98347
0.98802
0.98788
8.0
0.98660
0.98478
0.98346
0.98189
0.98653
0.98634
9.0
0.98524
0.98331
0.98193
0.98031
0.98505
0.98481
0.98393
0.98187
0.98043
0.97575
0.98361
0.98330
0.98267
0.98047
0.97897
0.97723
0.98221
0.98184
10.0
12.40
9.84
11.0
11.3
14.0
11.11
0.98006
5C
12.0
0.98145
0.97910
0.97753
0.97573
0.98084
0.98039
13.0
0.98026
0.97775
0.97611
0.97424
0.97948
0.97897
13.78
17.00
13.49
6.1C
14.0
0.97911
0.97643
0.97472
0.97278
0.97816
0.97757
15.0
0.97800
0.97514
0.97334
0.97133
0.97687
0.97619
0.97199
0.96990
0.97560
0.97484
15.02
18.50
14.68
16.0
16.4
0.97511
0.97692
20.2
0.97336
17.0
0.97583
17.5
21.5
18.0
22.10
18.8
23.1
0.97387
0.97259
7.5C
0.97062
0.96844
0.97431
0.97346
0.97194
17.54
0.97473
0.97129
8.7C
0.96923
0.96697
0.97301
0.97207
0.97024
9.4C
19.0
0.97363
0.96997
0.96782
0.96547
0.97169
0.97065
20.0
0.97252
0.96864
0.96639
0.96395
0.97036
0.96922
20.01
24.50
20.3
24.8
19.44
0.96863
0.96823
10.6C
21.0
0.97139
0.96729
0.96495
0.96242
0.96901
0.96778
22.0
0.97024
0.96592
0.96348
0.96087
0.96763
0.96630
22.11
27.00
21.43
0.96578
12.2C
23.0
0.96907
0.96453
0.96199
0.95929
0.96624
0.96481
24.0
0.96787
0.96312
0.96048
0.95769
0.96483
0.96329
24.2
29.5
25.0
30.40
26.0
0.96283
24.12
14.0C
0.96665
0.96168
0.95895
0.95607
0.96339
0.96176
0.96539
0.96020
0.95738
0.95422
0.96190
0.96018
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26.7
32.4
0.95914
27.0
28.0
33.90
26.90
29.0
29.9
36.1
30.0
36.20
16.0C
0.96406
0.95867
0.95576
0.95272
0.96037
0.95856
0.96268
0.95710
0.95410
0.95098
0.95880
0.95689
0.96125
0.95548
0.95241
0.94922
0.95717
0.95520
0.95400
0.95977
0.95382
0.95067
0.94741
0.95551
0.95345
31.0
0.95823
0.95212
0.94890
0.94557
0.95381
0.95168
32.0
0.95665
0.95038
0.94709
0.94370
0.95207
0.94986
33.0
0.95502
0.94860
0.94525
0.94180
0.95028
0.94802
33.8
28.73
18.9C
40.5
0.94715
23.6C
34.0
0.95334
0.94679
0.94337
0.93986
0.94847
0.94613
35.0
0.95162
0.94494
0.94146
0.93790
0.94662
0.94422
35.04
41.90
33.25
0.94486
36.0
0.94986
0.94306
0.93952
0.93591
0.94473
0.94227
37.0
0.94805
0.94114
0.93756
0.93390
0.94281
0.94031
38.0
0.94620
0.93919
0.93556
0.93186
0.94086
0.93830
0.94431
0.93720
0.93353
0.92979
0.93886
0.93626
0.94238
0.93518
0.93148
0.92770
0.93684
0.93421
39.0
46.3
40.0
40.04
47.40
37.61
0.93510
41.0
0.94042
0.93314
0.92940
0.92558
0.93479
0.93212
42.0
0.93842
0.93107
0.92729
0.92344
0.93272
0.93001
43.0
0.93639
0.92897
0.92516
0.92128
0.93062
0.92787
44.0
0.93433
0.92685
0.92301
0.91910
0.92849
0.92571
45.0
0.93226
0.92472
0.92085
0.91692
0.92636
0.92355
0.91868
0.91472
0.92421
0.92137
45.31
53.00
46.0
46.3
28.7C
42.07
0.92406
0.93017
53.8
0.92257
0.92193
33.9C
47.0
0.92806
0.92041
0.91649
0.91250
0.92204
0.91917
48.0
0.92593
0.91823
0.91429
0.91028
0.91986
0.91697
49.0
0.92379
0.91604
0.91208
0.90805
0.91766
0.91475
50.0
0.92162
0.91384
0.90985
0.90580
0.91546
0.91251
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50.16
58.0
46.04
0.91349
51.0
0.91943
0.91160
0.90760
0.90353
0.91322
0.91026
52.0
0.91723
0.90936
0.90524
0.90125
0.91097
0.90799
53.0
0.91502
0.90711
0.90307
0.89896
0.90872
0.90571
54.0
0.91279
0.90485
0.90079
0.89667
0.90645
0.90343
55.0
0.91055
0.90258
0.89850
0.89437
0.90418
0.90113
0.89621
0.89206
0.90191
0.89833
55.16
63.0
50.00
56.0
56.1
0.90220
0.90831
63.6
0.90031
0.90008
41.0C
57.0
0.90607
0.89803
0.89392
0.88975
0.89962
0.89654
58.0
0.90381
0.89574
0.89162
0.88744
0.89733
0.89423
59.0
0.90154
0.89344
0.88931
0.88512
0.89502
0.89191
60.0
0.89927
0.89113
0.88699
0.88278
0.89271
0.88959
60.33
68.0
53.98
0.89038
61.0
0.89898
0.88882
0.88466
0.88044
0.89040
0.88725
62.0
0.89468
0.88650
0.88233
0.87809
0.88807
0.88491
63.0
0.89237
0.88417
0.87998
0.87574
0.88574
0.88256
64.0
0.89006
0.88183
0.87763
0.87337
0.88339
0.88020
65.0
0.88774
0.87948
0.87527
0.87100
0.88104
0.87783
66.0
0.88541
0.87713
0.87291
0.86863
0.87869
0.87547
67.0
0.88308
0.87477
0.87054
0.86625
0.87632
0.87309
68.0
0.88071
0.87241
0.86817
0.86387
0.87396
0.87071
69.0
0.87839
0.87004
0.86579
0.86148
0.87158
0.86833
70.0
0.87602
0.86766
0.86340
0.85908
0.86920
0.86593
71.0
0.87365
0.86527
0.86100
0.85667
0.86680
0.86352
71.9
78.3
0.86311
51.3C
72.0
0.87127
0.86287
0.85859
0.85426
0.86440
0.86110
73.0
0.86888
0.86047
0.85618
0.85184
0.86200
0.85869
74.0
0.86648
0.85806
0.85376
0.84941
0.85958
0.85626
75.0
0.86408
0.85564
0.85135
0.84698
0.85716
0.85383
76.0
0.86168
0.85322
0.84891
0.84455
0.85473
0.85140
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77.0
0.85927
0.85079
0.84647
0.84211
0.85230
0.84895
78.0
0.85685
0.84835
0.84403
0.83966
0.84985
0.84650
79.0
0.85422
0.84590
0.84158
0.83720
0.84740
0.84404
80.0
0.85197
0.84344
0.83911
0.83473
0.84494
0.84157
81.0
0.84950
0.84096
0.83664
0.83224
0.84245
0.83909
82.0
0.84702
0.83848
0.83415
0.82974
0.83997
0.83659
83.0
0.84453
0.83599
0.83164
0.82724
0.83747
0.83408
84.0
0.84203
0.83348
0.82913
0.82473
0.83496
0.83156
85.0
0.83951
0.83095
0.82660
0.82220
0.83242
0.82902
86.0
0.83697
0.82840
0.82405
0.81965
0.82987
0.82646
87.0
0.83441
0.82554
0.82148
0.81708
0.82729
0.82389
88.0
0.83181
0.82323
0.81888
0.81448
0.82469
0.82128
89.0
0.82919
0.82062
0.81626
0.81186
0.82207
0.81865
90.0
0.82654
0.81797
0.81362
0.80922
0.81942
0.81600
0.82386
0.81529
0.81094
0.80655
0.81674
0.81331
92.0
0.82114
0.81257
0.80823
0.80384
0.81401
0.81060
93.0
0.81839
0.80983
0.80549
0.80111
0.81127
0.80785
94.0
0.81561
0.80705
0.80272
0.79835
0.80848
0.80507
95.0
0.81278
0.80424
0.79991
0.79555
0.80567
0.80225
96.0
0.80991
0.80138
0.79706
0.79271
0.80280
0.79939
97.0
0.80698
0.79846
0.79415
0.78981
0.79988
0.79648
98.0
0.80399
0.79547
0.79117
0.78684
0.79688
0.79349
99.0
0.80094
0.79243
0.78814
0.78382
0.79383
0.79045
0.79784
0.78934
0.78506
0.78075
0.79074
0.78736
91.00
100.0
94.00
100.0
74.62
79.39
114.3
C
grams
ethanol
% wt
% vol
d
d
d
d
d
d
freezing
per 100
ethanol ethanol
10C/4C 20C/4C 25C/4C 30C/4C 20C/20C 25C/25C temp.
cc
15.56C
Boiling points of aqueous solutions

Data obtained from CRC Handbook of Chemistry 44th ed., p2391
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Weight % ethanol
BP C
Weight % ethanol
BP C
liquid
vapor
liquid
vapor
78.1
95.5
95.5
78.2
91
92
86.5
18
71
78.4
85
89
87.0
17
70
78.6
82
88
87.5
16
69
78.8
80
87
88.0
15
68
79.0
78
86
88.5
13
67
79.2
76
85
89.0
12
65
79.4
74
85
89.5
11
63
79.6
72
84
90.0
10
61
79.8
69
84
90.5
10
59
80.0
67
83
91.0
57
80.2
64
83
91.5
55
80.4
62
82
92.0
53
80.6
59
82
92.5
51
80.8
56
81
93.0
49
81.0
53
81
93.5
46
81.2
50
80
94.0
44
81.4
47
80
94.5
42
81.6
45
80
95.0
39
81.8
43
79
95.5
36
82.0
41
79
96.0
33
82.5
36
78
96.5
30
83.0
33
78
97.0
27
83.5
30
77
97.5
23
84.0
27
77
98.0
19
84.5
25
75
98.5
15
85.0
23
74
99.0
<1
10
85.5
21
73
99.5
<1
86.0
20
72
100.0
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Azeotropic mixture. See azeotrope (data) for more azeotropes of ethanol.
References
1. ^ NMR-002: Sample Devices and Magnetic Susceptibility (http://nmr.chem.umn.edu/ResReports/NMR002.html)
2. ^ "Pure Component Properties" (http://www.cheric.org/research/kdb/hcprop/cmpsrch.php) (Queriable database). Chemical
Engineering Research Information Center. http://www.cheric.org/research/kdb/hcprop/cmpsrch.php. Retrieved 12 May
2007.
3. ^ a b Lange's Handbook of Chemistry 10th ed, pp 1525-1528
4. ^ a b CRC Handbook of Chemistry and Physics 44th ed. pp 2582-2584
5. ^ Lange's Handbook of Chemistry 10th ed, pp 1522-1524
6. ^ "Spectral Database for Organic Compounds" (http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng)
(Queriable database). Advanced Industrial Science and Technology. http://riodb01.ibase.aist.go.jp/sdbs/cgibin/cre_index.cgi?lang=eng. Retrieved 9 June 2007.
Linstrom, P.J.; Mallard, W.G. (eds.) NIST Chemistry WebBook, NIST Standard Reference Database Number
69. National Institute of Standards and Technology, Gaithersburg MD. http://webbook.nist.gov
Except where noted otherwise, data relate to standard ambient temperature and pressure.
Disclaimer applies.
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Ethanol Data - Wikipedia

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Ethanol Data - Wikipedia

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Ethanol (data page) - Wikipedia, the free encyclopedia

Ethanol (data page)

This page provides supplementary chemical data on ethanol.

Material Safety Data Sheet

Structure and properties

Magnetic susceptibility[1] 5.8107 (cgs units, volume)

22.39 dyn/cm at 25C

6.285 mPas at 50C

Ethanol (data page) - Wikipedia, the free encyclopedia

150 K (123 C), 0.00043 Pa

514 K (241 C), 63 bar

Std enthalpy change

Std entropy change

Std enthalpy change

Std entropy change

Molal freezing point constant

Molal boiling point constant

Standard molar entropy,

Std enthalpy change

Ethanol (data page) - Wikipedia, the free encyclopedia

Standard molar entropy,

Enthalpy of combustion, cHo 1370.7 kJ/mol

Std enthalpy change

Standard molar entropy,

78.28 J/(mol K) at 90C

Heat capacity ratio,[3][4]

van der Waals' constants[5]

Major absorption bands

Ethanol (data page) - Wikipedia, the free encyclopedia

Other NMR data

Vapor pressure of liquid

31.3 2.3 19.0 34.9 63.5 78.4 97.5

15200 30400 45600

126.0 151.8 183.0

Log10 of ethanol vapor pressure vs. temperature. Uses formula:

Ethanol vapor pressure vs. temperature. Uses

Ethanol (data page) - Wikipedia, the free encyclopedia

Density of ethanol at various temperatures (kg/l or g/cm3)

0.80374 16C 0.79283 29C 0.78182

0.80290 17C 0.79198 30C 0.78097

0.80207 18C 0.79114 31C 0.78012

0.80123 19C 0.79029 32C 0.77927

0.80039 20C 0.78945 33C 0.77841

0.79956 21C 0.78860 34C 0.77756

0.79872 22C 0.78775 35C 0.77671

10C 0.79788 23C 0.78691 36C 0.77585

Properties of aqueous ethanol solutions

Ethanol (data page) - Wikipedia, the free encyclopedia

Ethanol (data page) - Wikipedia, the free encyclopedia

Ethanol (data page) - Wikipedia, the free encyclopedia

Ethanol (data page) - Wikipedia, the free encyclopedia

Boiling points of aqueous solutions

Ethanol (data page) - Wikipedia, the free encyclopedia

Ethanol (data page) - Wikipedia, the free encyclopedia

Azeotropic mixture. See azeotrope (data) for more azeotropes of ethanol.

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