STATES OF MATTER (ASSIGNMENT)

1. A gas is collected in theflask shown here.

Whatis the pressure exertedby the gas if the
atmospheric pressure is735 mmHg?
A) 42 mmHg B) 693 mmHg
C) 735 mmHg D) 777 mmHg
2. A commercial gas cylinder contain 100 litres of helium at a pressure of 11 atm.Howmany
2.5 litres balloones at 1 atm may be filled by the gas in the cylinder
A) 150 B)450 C)500 D)400
3. The density of SO2 at STP is 2.86 kg/m3.then its density at 819
0C
and 2 atm pressure is
A) 0.715 B) 1.43 C) 2.86 D) 4.26kg/m3
4. An open vessel at
0
27 c heated until 2/5 of the air in it has been expelled. Assuming that
the volume of the vessel remains constant. Find the temperature to which the vessel has
been heated?
A)
0
227 C B)
0
477 C C) 750K D)
0
500 C
5. 0.2g of gas X occupies 320 ml but under the same conditions 0.1 g of oxygen occupies
290ml .Molar mass of the gas
A) 64 B)29 C)58 D)45
6. The number of molecules present in one lit flask having nitrogen gas at 27
0
C and
5`
7.6 10 mm

pressure.
1)
15
2.4 10 2)
16
2.4 10
3)
16
4.2 10 4)
16
4.2 10

7. When 4g of agas X is introduced into an evacuated flask at 30
0
Cthe pressure is found to be
1.6 atm.When 12 g another gas is added to the same flask the total pressure is
2.8atm.Molecular weight ratio of the gases
1) 1:4 2) 2:3 3) 1:2 4) 4:1
8. The density of air is 0.0013 g/mL. The vapor density of air will be
(1) 14.23 (2) 14.56 (3) 14.48 (4) 14.65
9. How much should the pressure be increased in order to decrease the volume of a gas by
5% at constant temperature?
(1) 25% (2) 10% (3) 4.26% (4) 5.26%
10. A small bubble rises from the bottom of a lake, where the temperature and pressure are
0
8 C and 6.0atm, to the waters surface, where the temperature is
0
25 C and pressure is
1.0atm. Calculate the final volume of the bubble if its initial volume was 2mL.
A) 14mL B) 12.72mL C) 11.21mL D) 15mL



11. A air column of length 10cm is trapped by a column of Hg 4cm long in a capillary tube
of uniform bore when tube is held horizontally in a room at 1 atm . Length of air column
when the tube is held vertically with open end up
A) 9.5 B)10.52
C) 3.53 D) 4.6
12. A gaseous mixture contains 1 g of H
2
, 4 g of He, 7 g of N
2
, and 10 g O
2
. The gases
having highest and lowest partial pressures respectively are
(1) He, N
2
(2) H
2
, O
2
(3) O
2
, N
2
(4) He, H
2
13. Two flasks X and Y of volumes 250ml and 300ml respectively at the same temperature
are connected by a stop cock of negligible volume. The flask X contains nitrogen gas at a
pressure of 660 torr and the flask Y contains neon gas at a pressure of 825torr. If the stop
cock is opened to allow the two gases to mix, the partial pressure of neon gas and total
pressure of the system will be
(A) 300 torr,700torr (B) 400 torr,700torr (C) 450 torr,750torr (D) 300 torr,750torr
14. A container contains certain gas of mass m at high pressure. Some of the gas has been
allowed to escape from the container and after some time the pressure of gas becomes half
and its absolute temperature 2/3 rd. The amount of gas escaped is
(1) m
3
2
(2) m
2
1
(3) m
4
1
(4) m
6
1

15. Consider three gases at same temperature and pressure having the molar masses M
1
, M
2
and
M
3
; rates of diffusion r
1
, r
2
, r
3
; times of diffusion t
1
, t
2
, t
3
; volumes diffused V
1
, V
2
, V
3
;
masses diffused m
1
, m
2
, m
3
.
LIST I LIST II
A. t
1
: t
2
: t
3
(equal volumes) 1.
3
M :
2
M :
1
M
B. V
1
: V
2
: V
3
(same times) 2.
1
M :
2
M :
3
M
C. r
1
: r
2
: r
3
3.
1
M
1
:
2
M
1
:
3
M
1

D. m
1
: m
2
: m
3
(same times) 4.
3
M
1
:
2
M
1
:
1
M
1

The correct match is
A)A-2,B-3,C-3,D-2 B) A-4,B-3C-1,D-4 C)A-2 ,B-2, C-4,D-2 D) A-3,B-2,C-4,D-1
10cm 4cm
air


16. 4gm of sulphur dioxide gas diffuses from a container in 8min. Mass of helium gas
diffusing from the same container over the same time interval is
A) 0.5gm B) 1gm C) 2gm D) 4gm
17. The ratio of mean speeds of a gas at temperatures 173 C, 127 C and 627 C is
(A) 6:3:2 (B) 1:2:3 (C) 3:2:1 (D) 1:4:9
18. Two glass bulbs A and B at same temperature are connected by a very small tube having
a stop-cock. Bulb A has a volume of
3
100cm and contained the gas while bulb B was
empty. On opening the stop-cock, the pressure fell down to 20%. The volume of the bulb
B is
A)
3
100cm B)
3
200cm C)
3
250cm D)
3
400cm
19.
A mixture of hydrogen and oxygen at one bar pressure contain 20% by weight of hydrogen .
Calculate the partial pressure of hydrogen
a) 1.0 b) 0.8 c) 1.2 d) 1.8 bar
20.. Which of the following expressions between the vander waals constant b and the radius
r of spherical molecules is true?
A)
3
4
3
A
b r N t
| |
=
|
\ .
B)
3
4
3
b r t
| |
=
|
\ .
C)
3
4
2
3
A
b r N t
| |
=
|
\ .
D)
3
4
4
3
A
b r N t
| |
=
|
\ .

21. Which of the following expressions of compression factor of a real gas is applicable at
high pressure?
A)
1 /
m
Z a V RT =
B)
1 /
m
Z a V RT = +
C)
1 / Z pb RT = +
D)
1 / Z pb RT =

22. The ratio of Boyle's temperature (Tb) and critical temperature (T
C
)for a gas is
A) 8/27 B) 27/8 C) 1/2 D) 2/1
23. The boiling points of three liquids A,B ,C are 350K , 490 K and 630K respectively.The
correct diagram of graphs representing their vapour pressures against different
temperatures
A)
temperature
p
r
e
s
s
u
r
e
B
A
C
B)
temperature
p
r
e
s
s
u
r
e
A
B
C
C)
temperature
p
r
e
s
s
u
r
e
C
B
A
D)
temperature
p
r
e
s
s
u
r
e
A C
B

24. A gas obeys the equation of state P(V-b)=RT(The parameter b is a constant). The slop for an
isochore will be:
(A) Negative (B) Zero (C) R/(V-b) (D) R/P
25. From the following values of the critical constants. Find out b of the van der Waals
equation for C Tc atm P H
c
= = 7 . 33 ., 4 . 12 :
2
.
(A) 0253 . 0 (B) 0212 . 0 (C) 0174 . 0 (D) 0192 . 0


Explanatory Key
7. Molar ratio= Partial pressure
4 12 1.6 4
:
1.2 3 x y
= =
4 4 4
12 3 3 3
y y
or
x x
= = or
3 3
4
x
y
= OR : 1: 4 x y =
OR
1 1 2 2 1 2
1` 1 2` 2 1` 2`
PV PV P P
or
n T n T n n
= = or
1 1 2 2
1 2
PM P M
W W
= or
1 2
1.6 1.2
4 12
M M
= and
1
2
1: 4
M
M
=
10. The volume of the gas in the bubble remains constant, so that
1 2
n n = . To calculate the
final volume,
2
V

1 2
2 1
2 1
6.0 298
2.0 12.72
1.0 281
P T
V V mL
P T
= = =

11. AWhen open end up the wt of Hg represents an increase in the P of gas of 4cm Hg .
Final pressure =760+40=800mm
P1V1=P2V2 or P1A1l1=P2A2l2 Since area of cross section is constant
P1l1=P2l2 or 760x10= 800xl or l= 9.5 cm
16.
Explanation:
1 2 2 1 2 2
2 1 1 1 2 1
.
;
.
n t M w M M
n t M M w M
= =

1 1 1
2 2
4
;
4 64
w M w
w M
= =


1
1 w gm =

19. Let hydrogen = 20g and oxygen = 80g Number of moles = 20/2+80/32 =10+2.5 = 12.5
PP of hydrogen = 10/12.5x1=100/125 = 0.8 bar
23) Explanation: p(v-b)=RT
RT R
P T
V b V b
| |
= =
|

\ .
Slope =
R
V b

25. We have
0253 . 0
8 4 . 12
0821 . 0 ) 7 . 33 273 (
8
=

+
=

=
C
C
P
R T
b