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CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education

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CHEMISTRY
Paper 1 Multiple Choice

0620/01
May/June 2003 45 minutes

Additional Materials:

Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the answer sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question, there are four possible answers A, B, C, and D. Choose the one you consider correct and record your choice in soft pencil on the separate answer sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 20.

This document consists of 18 printed pages and 2 blank pages.

BR (PW) S41678/1 CIE 2003

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2 1 The diagram shows how to obtain pure water from seawater. Where do water molecules lose energy?

water out

water in seawater pure water

Bunsen flame

A solid metal is heated until it turns to vapour. The graph shows the temperature of the metal during this process. Which part of the graph shows the melting of the metal?

2200 temperature/C 500 A 25 time C

Some chemical compounds are purified by recrystallisation. What can be used to test the purity of the crystals? A B C D melting point colour of crystals size of crystals solubility

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3 4 What could be the melting point and boiling point of water containing a dissolved impurity? melting point / oC A B C D +3 +3 3 3 boiling point / oC 96 104 96 104

Which number in the table is 1? particle electron neutron proton charge A C D relative mass B 1 1

What is the electronic structure of an atom with a proton number 5 and a nucleon number 11? A 1, 8, 2 B 2, 8, 1 C 2, 3 D 3, 2

What changes when an ion is made from an atom? A B C D the number of electrons only the number of neutrons only the number of protons only the number both of protons and of neutrons

Strontium, Sr, is a metal that forms an ionic chloride SrCl2. Sulphur, S, is a non-metal that forms a covalent chloride SCl2. Which compound is likely to have the higher melting point (m.p.) and which is more soluble in water? more soluble in water SrCl2 SCl2 SrCl2 SCl2

higher m.p. A B C D SrCl2 SrCl2 SCl2 SCl2

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4 9 The relative atomic mass of oxygen is 16 and that of hydrogen is 1. This means that (i) of oxygen has the same mass as (ii) of hydrogen. Which words correctly complete the gaps? gap (i) A B C D an atom an atom a molecule a molecule gap (ii) thirty-two molecules eight molecules sixteen atoms eight atoms

10 The diagram shows a model of a molecule containing carbon, hydrogen and oxygen.

How many atoms of each element are in the molecule? carbon A B C D 1 2 2 6 hydrogen 6 5 6 2 oxygen 2 1 1 1

11 Water is formed when 48 g of oxygen combine with 6 g of hydrogen. What mass of oxygen combines with 2 g of hydrogen? A 12 g B 16 g C 96 g D 144 g

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5 12 The diagram shows how aluminium is manufactured by electrolysis. anode (+ve)

cathode (ve) aluminium oxide dissolved in cryolite

molten aluminium

What are the anode and cathode made of? anode A B C D aluminium aluminium graphite graphite cathode aluminium graphite aluminium graphite

13 A student sets up the apparatus shown. The bulb does not light.

bulb

electrode water

After the student adds substance X to the water, the bulb lights. What is X? A B C D calcium carbonate carbon copper(II) sulphate ethanol
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6 14 The following elements have radioactive isotopes. Which element is used as a source of energy because of its radioactivity? A B C D carbon hydrogen iodine uranium

15 When hydrogen is passed over a heated metal oxide, the metal and steam are formed. metal oxide excess of hydrogen burning

hydrogen

heat What happens to the hydrogen and to the metal oxide? hydrogen A B C D oxidised oxidised reduced reduced metal oxide oxidised reduced oxidised reduced

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7 16 When hydrated copper(II) sulphate is heated in the apparatus shown, solid X and liquid Y are produced. hydrated copper(II) sulphate

heat cold water liquid Y

Which changes are noticed when liquid Y is added to cold solid X? colour change A B C D blue to white blue to white white to blue white to blue heat change heat given out heat taken in heat given out heat taken in

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8 17 A solution of hydrogen peroxide releases oxygen slowly at room temperature. hydrogen peroxide water + oxygen The diagrams show the effect of adding blood to the solution.

blood

bubbles produced slowly before adding blood after adding blood

bubbles produced rapidly

What could be the reason for the observed change? A B C D Blood contains an enzyme. Blood contains water. The hydrogen peroxide becomes more concentrated. The hydrogen peroxide is neutralised by blood.

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9 18 A liquid X reacts with solid Y to form a gas. Which two diagrams show suitable methods for investigating the speed of the reaction? 1 stopper 2 cotton wool

X Y balance balance

X Y

3 stopper

4 cotton wool

X Y A B C D 1 and 3 1 and 4 2 and 3 2 and 4

X Y

19 Which substance does not form copper(II) sulphate with warm, dilute sulphuric acid? A B C D copper copper(II) carbonate copper(II) hydroxide copper(II) oxide

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10 20 Which test method and gas are correctly linked? test method A B C D a lighted splint a glowing splint damp litmus paper limewater gas oxygen hydrogen chlorine ammonia

21 Water is added to a test-tube containing dilute sulphuric acid of pH 4. What could be the pH of the resulting solution? A 8 B 6 C 4 D 2

22 Magnesium, on the left of Period Two of the Periodic Table, is more metallic than chlorine on the right of this Period. Why is this? Magnesium has A B C D fewer electrons. fewer protons. fewer full shells of electrons. fewer outermost electrons.

23 An inert gas X is used to fill weather balloons. Which descriptions of X are correct? number of outer electrons in atoms of X A B C D 2 2 8 8

structure of gas X single atoms diatomic molecules single atoms diatomic molecules

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11 24 A student is asked to complete two sentences. Metallic and non-metallic elements are classified in the (i) This can be used to (ii) the properties of elements. Which words correctly complete the gaps? gap (i) A B C D Periodic Table Periodic Table reactivity series reactivity series gap (ii) measure predict measure predict

25 Which material is an alloy that contains a non-metallic element? A B C D brass haematite manganese steel

26 The table gives information about the reactivity of three metals P, Q and R. metal P Q R reaction with air burns with sparks slowly forms an oxide slowly forms an oxide reaction with steam reaction with dilute hydrochloric acid forms an oxide no reaction no reaction forms hydrogen no reaction forms hydrogen

What is the order of reactivity of P, Q and R? most reactive A B C D P P Q R Q R R Q least reactive R Q P P

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12 27 The bodies of aircraft are often made using aluminium. Which two properties of aluminium make it suitable for this purpose? property 1 A B C D good conductor of electricity good conductor of electricity good conductor of heat strong property 2 good conductor of heat strong low density low density

28 Which raw materials are used in the manufacture of iron? A B C D bauxite and lime bauxite and limestone haematite and lime haematite and limestone

29 In a car industry, approximately 45 000 litres of water are required to produce a single car. This water does not need to be very pure. Which purification methods would be suitable and economic to use? chlorinated A B C D distilled

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13 30 The pie-chart shows the composition of air.

3 2

What are the gases in parts 1, 2 and 3 of the pie-chart? 1 A B C D nitrogen nitrogen oxygen oxygen 2 other gases oxygen other gases nitrogen 3 oxygen other gases nitrogen other gases

31 A steel works and a chemical works are built near to a city. The limestone buildings in the city begin to crumble. Which gas is most likely to cause this damage? A B C D carbon dioxide carbon monoxide oxygen sulphur dioxide

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14 32 Which methods can be used to prevent the rusting of an iron girder of a bridge? coat it with grease A B C D electroplate it paint it

33 A student heats a mixture of ammonium chloride and calcium hydroxide. She tests the gas given off with damp red litmus paper. What is the name of the gas and the final colour of the litmus paper? gas A B C D ammonia ammonia chlorine chlorine colour blue red red white

34 A newspaper article claims that carbon dioxide is formed as follows. 1 2 3 during respiration when calcium carbonate reacts with hydrochloric acid when methane burns in air

Which statements are correct? A B C D 1, 2 and 3 1 and 2 only 1 and 3 only 2 and 3 only

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15 35 The diagram shows how the pH of an industrial waste changes when substance X is added to it.

7 pH

before X is added What is substance X? A B C D coal lime salt water

after X is added

36 The diagram shows a model of an organic compound.

key carbon atom hydrogen atom What is the name of this compound? A B C D ethane ethanoic acid ethanol ethene

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16 37 Bitumen is a substance obtained from the fractional distillation of petroleum. What are the boiling points and the sizes of the molecules in bitumen? boiling points A B C D high high low low sizes of molecules large small large small

38 Which hydrocarbons in the table are members of the same homologous series? hydrocarbon state at room temperature reaction with oxygen aqueous reaction with bromine A B C D 1 and 2 1 and 3 3 and 4 1, 2, 3 and 4 1 gas burns decolourises bromine 2 gas burns no reaction 3 liquid burns decolourises bromine 4 liquid burns no reaction

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17 39 Which of the molecules shown can be polymerised? H A H C H H

H B H C H

H C H H

H C H C H

H C C

H D H C H C

40 Which conditions are necessary to ferment sugar into ethanol? yeast A B C D absent absent present present temperature/ C 30 70 30 70

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18 BLANK PAGE

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19 BLANK PAGE

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DATA SHEET The Periodic Table of the Elements

Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon Nitrogen

Be
5 27 28 6 7 31

N
8

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

9 32 35.5

10 40

23

24

Na
Aluminium Silicon

Mg
13 52 55 56 59 59 64 65 70 14 73

Al Si

P
Phosphorus

S
Sulphur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 75

16 79

17 80

18 84

39

40

45

48

51

K
Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium

Ca
24 96 101 103 106 108 112 25 26 27 28 29 30 31 115

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn

Ga
32

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

Vanadium

19

20

21

22

23

33 119 122

34 128

35 127

36 131

20

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85

88

89

91

93

Rb
Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
42 184 186 190 192 195 197 43 44 45 46 47 48 201

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

Rubidium

Strontium

Yttrium

Zirconium

Niobium

37

38

39

40

41

49 204

50 207

51 209

52

53

54

133

137

139

178

181

Cs
Tungsten Iridium Rhenium Osmium Platinum Gold

Ba
74 77 75 76 78 79

La W Re Os Pt Au

Hf

Ta

Ir

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

Tantalum

55

56

57

72

73

80

81

82

83

84

85

86

226

227

Fr
141 144 150 152

Ra

Ac
157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

140

*58-71 Lanthanoid series 90-103 Actinoid series Pr

Praseodymium Neodymium Promethium

Ce
59 238 60 61 62

Nd

Pm

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

Cerium

58

63

64

65

66

67

68

69

70

71

a = relative atomic mass

232

Key Pa
Protactinium Uranium

X U
92 93

X = atomic symbol
91

Th

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

Thorium

90

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).