Professional Documents
Culture Documents
Polishing of wastewater before discharging Nitrogen control (removal of ammonium ion from
wastewaters)
Purification of acids and bases to reuse them Removal of radioactive contaminants in the nuclear
industry
PIERO M. ARMENANTE NJIT
Recovery of metals from mixed rinsewaters Removal of chromates from cooling water circuits Recovery, purification and re-use of spent acids
from metal pickling and etching processes
+
CH=CH2
Polymerization
- CH - CH2- CH - CH2- CH - CH2- CH - CH2-
Sulfonation
SO3H
SO3H
- CH - CH2-
b g + 2H RSO Ca
2 4
d i + 2OH SO
+ 2
b g + 2H RCOO Ca b g R NH SO
3 2 4
+ 2 OH
A+ a + x Ax + + b B B
with: a = b subscript x = subscript identifying the ionic species adsorbed on the resin the equilibrium relationship takes the form:
+b
KB =
AX A
+a
q C = C q BX
A A
B B
bC g q = bC g q
A A B B
KB
dC i q = dC i q
Ca H Ca 2 + 2 H+
bC g q = bC g q
A A B B
dC i q = dC i q
Ca Ca 2 + H+ H
SO42- > I- > NO3- > CrO42- > BrPIERO M. ARMENANTE NJIT
Separation
V dC = K Ap C C * dt
where: V = volume of wastewater (m 3)
b g
K = mass transfer coefficient between ion exchange particles and wastewater (m/s) Ap = cumulative surface area of ion exchange particles (m2) C = ionic pollutant concentration (g/L) C* = concentration of ionic pollutant in equilibrium with concentration q in the particle at time t (g/L)
PIERO M. ARMENANTE NJIT
1 t = K ap
z
C
where: a = surface area of particles/liquid volume This equation can be integrated if the equilibrium isotherm is known and by knowing that the mass balance at a generic time, t, is given by:
V (Co C ) = B (q q o )
"o"
indicates
initial
evaluated
Then:
1 t K ap
z
C
dC ' 1 Co = ln Co C ' K ap C
This equation can be used to approximately estimate the time required for the pollutant concentration in the wastewater to drop to a desired level.
PIERO M. ARMENANTE NJIT
F G H
I J K
where: q So = saturation capacity of the ion exchanger for a specific ion = amount of pollutant adsorbed in the bed/maximum amount of pollutant that could be adsorbed in the bed (at full capacity)
F G H
I F J G K H
I J K
B+ Z -
B+ Y-
can be reverted to the left (with consequent release of Ca++ ions) if a strong acid is passed through the bed Other concentrated solutions other than acids or bases can be used as regenerating solutions (e.g., NaCl). In such a case the regenerated resin will be loaded with the resulting ion (e.g., Na + instead of H+)
PIERO M. ARMENANTE NJIT