Standard Subject Marks Time Date

11 B 100 150 min. 26/10/2012

1. How many orbitals can be possible when the value of (n + l) is more than 4 and less than 6? (A) 9 (B) 16 (C) 12 (D) 10 2. Choose the correct increasing order of paramagnetic character. (A) Fe < Cr < Mn < Cu (B) Cu < Fe < Mn < Cr (C) Mn < Fe < Cu < Cr (D) Mn < Cr < Fe < Cu 3. Which substance is oxidised in the following reaction? V + H 2 O H 4 V 6 O 17 + H 2 (A) V (B) H 2 O (C) Both V and H2O (D) H4V6O17 4. Which of the following property, is not possessed by ionic hydrides? (A) Ionic hydrides are formed by the exchange of electrons between metal and dihydrogen. (B) Their density is lower than that of metal from which they are formed. (C) Their melting points and boiling points are high. (D) They liberate H 2 gas by vigorous (violent) reaction with H 2 O. 5. How many -bonds and -bonds are present in ethene? (A) 5 -bonds and 1 -bonds (B) 1 -bonds and 5 -bonds (C) 4 -bonds and 2 -bonds (D) 4 -bonds and 1 -bonds 6. What is the correct electronic configuration of strontium? (A) [Ne]3s 2 (B) [Ar]4s 2 2 (C) [Kr]5s (D) [Xe]6s 2 7. Choose the substance in which the sum of the oxidation number of the constituent elements is not equal to zero? (A) S 8 (B) CrO-2 4 (C) CH2=CH2 (D) KNO3 8. Mention the number of molecules and the number of valence electrons in 40 g methane. (A) 24.088 1024 and 19.27 1025 (B) 15.055 1023 and 12.044 1024 (C) 24.088 1024 and 24.088 1025 (D) 15.055 1023 and 15.055 1024 9. The number of inner shells filled with electrons in Ba, Be, Sr, Mg are respectively .. (A) 5, 1, 4, 2 (B) 4, 5, 2, 1 (C) 5, 2, 3, 1 (D) 6, 2, 3, 5

(D) 127 Xe (C) , 54 11. Which statement is correct about the complex Fe4[Fe(CN)6]3? (A) There are 4Fe atoms in all which possess same oxidation number. (B) The oxidation number of Fe outside square bracket is +2. (C) The oxidation number of Fe of complex ions is +3. (D) The oxidation number of complex ions is -4. 12. What will be the number of electron having subsidiary quantum number l = 1 and l = 2 in ground state of Cr atom? (A) 12 and 4 (B) 12 and 5 (C) 16 and 4 (D) 16 and 5 13. Alkali metals are characterized by .. (A) Smallest ionization energy compared to that of any other group of periodic table (B) Extreme hardness (C)Very high melting point (D) Formation of predominantly covalent compounds 14. Mention the compound which is not a metal hydride? (B) ScH 2 (A) LaH 3 (D) SbH 3 (C) NbH 15. Which statement is not correct? (A) Elements of group-I can be detected by flame test. (B) The all elements of group-I are silvery white metals but due to formation of a layer of hydroxide on its surface, their surface become dull. (C) K on heating with adequate amount of O 2 gives peroxide. (D) For group-I, size of their ions are smaller than their size of atoms. 16. How many electrons can be filled in all the orbitals having value of n + l = 5? (A) 10 (B) 6 (C) 2 (D) 18 17. In But-1-ene molecule, carbon has which type of hybridization? (A) sp 3 (B) sp 2 3 2 (C) sp and sp (D) sp

10. An element having mass number 127, contain 39.62% more neutrons than the protons, mention the symbol of the element. (B) 127 Sb (A) 127 K 51 39

18. Select the option showing elements in an increasing order of negative electron gain enthalpy of the following pairs: (i) Br, Cl (ii) F, Cl (iii) O, S (iv) S, Se (A) Br, F, O, S (B) Cl, F, S, Se (D) Cl, Cl, S, S (C) Cl, F, O, S 19. Which one of the following pairs of ions make water hard? (A) Sodium and bicarbonate (B) Magnesium and chlorine (C) Potassium and sulphate (D) Ammonium and chloride 20. The decrease in the solubilitites of MCO 3 of while going down a Mggroup is due to (A) Decrease in hydration energies of M +2 ions. (B) Interionic attractions (C) Decrease in lattice energies of MCO 3(s) (D) Increase in hydration energies of M +2 cations. 21. The compound which is not isomeric with diethyl ether is . (A) Butanone (B) Butan-1-ol (C) 3 o -Butyl alcohol (D) n-propyl methyl ether 22. Which substance is a strong reducing agent? (B) Cl (A) Cl2 (D) Cl2O3 (C) ClO 2 23. Which of the following conclusions is correct about Rutherfords -particles scattering experiment? (A) Mass and energy are related with each other (B) Mass of atom and positive electric charge are concentrated in small nucleus (C) Nucleus contains neutrons (D) Atom is electrically neutral 24. After complete filling of which orbital, the electron enters into 4f orbital? By which name these elements are known? (A) 4p, Innertransition elements (B) 4p, Transition elements (C) 4d, Innertransition elements (D) 6s, First innertransition elements 25. 1, 2-butadiene has (A) Only sp 2 hybridized carbon atoms (B) Only sp hybridized carbon atoms (C) Both sp and sp 2 hybridized carbon atoms (D) sp, sp 2 and sp 3 , all three types of hybridized carbon atoms.

26. Mention the number of moles and number of molecules in 2800 millilitre of NO2 respectively at STP. (A) 5.75 and 3.46 1024 (B) 0.125 and 3.46 1024 (C) 0.125 and 7.53 1022 (D) 5.75 and 7.53 1023 27. Which relation showing the volume is correct for the isoelectronic species K+ and Cl obtained from K (Z = 19), Cl (Z = 17)? (A) rK+ = rCl (B) rK+ > rCl (C) rK+ = 1.36rCl (D) rK+ = 0.73rCl 28. From the following statements, select the option showing correct answer. (i) During the reaction, oxidation number of oxidizing agent is decreased. (ii) During the reaction, oxidation number of reducing agent is decreased. (iii) During the reaction, oxidation number of oxidizing agent is increased. (iv) In a redox reaction, the oxidation number of reactants do not change. (A) FTTT (B) TFFF (C) TFTT (D) FTFF 29. Which statement is incorrect for H2O2? (A)It turns blue litmus red. (B)It reacts with Na 2 CO 3 and liberates CO 2 gas. (C)It can neutralize NaOH. (D)It works both as an oxidizing agent and a reducing agent. 30. The proportion of calcium in human body is .per day. (A) 4.0 gram (B) 4000 milligram (C) 400 milligram (D) 0.4 gram 31. What will be the wavelength of carbon dioxide molecule moving with a velocity 440 m s-1? (Molecular mass of CO 2 = 44 g mol -1 ) (A) 3.42 10 30 m (B) 2.063 10 11 m (C) 2.063 10 30 m (D) 2.063 10 11 m 32. Which has the highest electronegativity? (A) Cl (B) Na (C) Mg (D) P 33. Hydrogen peroxide cannot be easily concentrated because .. (A) It does not mix with water (B) It has high boiling point (C) It has highly volatile character (D) It decomposes at boiling point

34. The correct order of C-C bond length is (A) C 2 H 6 > C 2 H 4 > C 6 H 6 > C 2 H 2 (B) C 2 H 2 < C 2H 4 < C 6 H 6 < C 2 H 6 (C) C 2 H 4 < C 2 H 6 < C 6 H 6 < C 2 H 2 (D) C 2 H 2 < C 6 H 6 < C 2 H 6 < C 2 H 4 35. Select option showing correct answer. Zn + CuSO 4 ZnSO 4 + Cu (1) Red coloured copper is dissolved in a solution. (2) When Zn rod is immersed in a solution of CuSO 4 rust from its surface is removed. (3) Due to reduction of Cu +2 ions from the solution by Zn atoms from the zinc rod, red coloured copper is deposited on Zn rod. (4) Blue colour of the solution becomes more intense blue. (A) FFTT (B) FFTF (C) TFTF (D) TFFT 36. What is the percentage proportion of potassium and oxygen atoms in caustic potash respectively? (A) 69.64% and 28.57% (B) 28.57% and 69.64% (C) 69.64% and 17.85% (D) 71.43% and 28.57% 37. From the following, which is the correct equation? 393 K (A) 2CaSO 4 .2H 2 O 2CaSO 4 + 2H 2 O (B) 2CaSO 4 .2H 2 O 2(CaSO 4 ).H 2 O + 3H 2 O 393 K (C) 2CaSO 4 .2H 2 O 2CaO + 2SO 3 + 2H 2 O 393 K (D) 2CaSO 4 .2H 2 O 2CaSO 4 .H 2 O + H 2 O 38. Which of the following has an equal number of -bonds and -bonds? (A) But-1, 3-diene (B) Benzene (C) Tetracyano ethylene (D) ethyne 39. What is the composition of compounds obtained by combination of magnesium and phosphorus with fluorine? (A) MgF 2 , PF 3 (B) MgF 2 , PF 3 , PF 5 (C) MgF 2 , P 2 F 4 (D) Mg 2 F 2 , PF 5 40. The energies of two radiations are 25 eV and 50 eV respectively. Mention the relation between their wavelengths. (A) 1 = 2 2 (B) 1 = 4 2 1 (C) 1 = 2 (D) 1 = 2 2

41. If the strength of H 2 O 2 for sale in market is 8.32% w/v, then what will be the strength by volume and concentration in molarity of this solution respectively. (A) 28.5 and 2.74 (B) 2.44 and 27.4 (C) 27.447 and 15 (D) 27.4 and 2.447 42. Choose the wrong statement from the following. (A) Ethyne molecule is linear and its bond angle is 180 o . (B) Ethyne has one -bond and two bonds between two carbon atoms. (C) Bond length of ethane is shorter than that of ethyne. (D) In ethene, -bond between two carbon atoms is formed by the overlapping of 2p z orbital of each carbon. 43. Select the correct option possessing statements True and False. (a) Ionization enthalpy increases from top to bottom in the same group. (b) Electronic configuration in the outermost shell remain same for the elements of the same group. (c) Chemical properties remain same as their electronic configuration is same. (d) Number of elements in all the periods are same. (A) FTTF (B) TFTT (C) TTTF (D) TTFF 22 44. When 36.132 10 molecules are removed from a vessel containing 240 g of NaOH, the number of NaOH left out in the vessel are (A) 6.022 1022 (B) 0 (C) 10 (D) 32.5 1023 45. Mention the compound in which all CC bond lengths are identical. (A) But-2-yne (B) But-1, 3-diene (C) 1, 3-pentadiene (D) Pent-2-yne 46. Which group contains only electrophiles? (A):NH 3 , CN , OCH 3 (B) CH 3 OH, AlCl 3, NH 2
+

(C) AlCl3, NO+ , SO3 H 2 (D) H + , Br , H 2 O

47. Zn + HNO3 Zn(NO3)2 + NO + H2O For the above reaction, by checking the validity of the following statements select the option showing correct answers. (1) Production of Zn(NO 3 ) 2 from Zn is an oxidation of Zn by HNO 3 . (2) Balanced redox reaction of the given equation is Zn + 3HNO 3 Zn(NO 3 ) 2 + NO + H 2 O (3) For the reduction of HNO 3 is NO, 3e are needed for each HNO 3 molecule. (4) Reaction can be shown in ionic form as, 3Zn + 2 NO3 + 8H + 3Zn +2 + 2NO + 4H 2 O (A) TFFT (B) TFTT (C) TTTT (D) FFTT 48. Find out the correct choice with reference to 38 40 +2 36 17 A , 17 B , 20 C components. (Element or ion) 36 38 (A) 17 A and 17 B are isotopes. The number of e in their orbit is not same. (B) A and B are isotopes. In both of then number of neutron in addition to number of e is not same. (C) B and C are not isotopes but as they one isoelectric and so possess same number of electrons. (D) The mass numbers A = n + P of B and C are same and so can be considered isobaric. 49. In which reactions from the following same gas is produced? (i) 2NaHCO 3 (ii) Na 2 CO 3 + 2HCl (iii) CaO + 3C (iv) CaCO 3 + H 2 SO 4 (A) (i), (ii), (iii) (B) (i), (ii), (iv) (C) (ii), (iii), (iv) (D) (i), (iii), (iv) 50. If 440 gram solute is present in 6 litre solution of H2O2, then how many litres of O2 gas will it produce at STP? (A) 24.16 L (B) 22.8 L (C) 30.16 L (D) 25.8 L 51. 2NH 4 Cl + Ca(OH) 2 NH 3 + CaCl 2 + H 2 O show mole relation between NH 3 , CaCl 2 and H 2 O in the product? (A) 1:2:1 (B) 2:1:2 (C) 2:1:1 (D) 1:1:2

52. Select the proper option for checking True or False about given statements. (a) The order of eg H for F, Cl and Br is F > Cl > Br. (b) Ionic volumes are always smaller than their atomic volume. (c) Number of protons in isoelectronic species remain the same. (d) The effective nuclear positive charge increases when an atom loses electrons. (A) TTTF (B) FFTT (C) FTTF (D) FFFT 53. Select the proper choice for the correct answer with the following two parts with reference to Ni (Z = 28). Column A Column B (1) Electron (a) [Ar]3d 8 4s 2 configuration of ground state of Ni. (2) The values of n (b) [Ar]4p 6 3d 2 and l for the 4s 1 orbitals in which the last electron of Ni enters. (3) Number of (c) n = 4, l = 2 total electrons in M orbit of Ni atom. (d) n = 3, l = 2 (e) 10e (f) 18e (g) n = 3, l = 1 (h) 16e (A) (1) (b), (2) (e), (3) (h) (B) (1) (a), (2) (d), (3) (h) (C) (1) (b), (2) (d), (3) (g) (D) (1) (a), (2) (c), (3) (g) 54. Which of the following is dihydric alcohol? (A) catachol (B) resorcinol (C) ethylene glycol (D) glycerol 55. When 9.033 1025 molecules are removed from a vessel containing 5.475kg of HCl, the number of HCl left out in the vessel are (A) 0 (B) 10 (D) 9 1025 (C) 6.022 1023 56. In which of the following calcium carbonate is used? (i) As antacid drug (ii) Writing chalk on black board (iii) As an abrasive in toothpaste (iv) In chewin gum (v) For whitening the walls of building (vi) In softening of a hard water (A) (i), (iii), (iv) (B) (iv), (v), (vi) (C) (i), (ii), (v), (vi) (D) (ii), (iv), (v), (vi)

57. The first and second ionization enthalpies are given below. Relate the elements according to the given characteristics of elements. (1) The most reactive metal with lowest ionization enthalpy.( eg H) (2) Ionization enthalpy is less than of inert gas but the element is strongly reactive. (3) Inert gas possessing higher ionization enthalpy. ( i H 1 and i H 2 ). (4) i H 1 and i H 2 values for an element which can form MX 2 type halides which has i H 1 and i H 2 values are greater than alkali metals but lower than halogens. iH2 Elements iH1 I 2372 kJ 5251 kJ mole -1 mole -1 II 520 kJ 7300 kJ mole -1 mole -1 III 900 kJ 1760 kJ mole -1 mole -1 IV 1680 kJ 3380 kJ mole -1 mole -1 (A) (1) II, (2) IV, (3) I, (4) III (B) (1) III, (2) IV, (3) II, (4) I (C) (1) II, (2) I, (3) III, (4) IV (D) (1) II, (2) I, (3) IV, (4) III
58. Reaction: P4 +
NO3

PO3 4

N 2 O 3 (Acidic medium) Step 1 Oxi : P 4 x PO3 + ye 4

Red : 2 NO3 + ze N 2 O 3

Step 2 Oxi : P 4 + 4xH 2 O x PO3 + 4 ye + 8xH +

Red : 2 NO3 + ze + 6H + N 2 O 3 +

3H 2 O
Step 3 Redox : P 4 + m NO3 + H 2 O

m N 2 O 3 + 2H + 4 PO + 2 The values at x, y and m in the reaction are respectively. (A) 4, 20, 6, 10 (B) 4, 20, 4, 10 (C) 4, 10, 4, 5 (D) 4, 20, 6, 12
3 4

59. What are the values of (i) velocity (ii) wavelength and (iii) energy respectively for electron in H-atom moving in second orbit at a distance 0.45 A from the nucleus? (A) Velocity = 5.15 10 7 m s 1 Wavelength = 1.41 10 9 cm Energy = -5.45 10 19 J (B) Velocity = 5.824 10 7 m s 1 Wavelength = 2.25 10 7 m Energy = -5.45 10 22 kJ (C) Velocity = 8.533 10 7 m s 1 Wavelength = 2.25 10 3 A Energy = 8.45 10 19 J (D) Velocity = 6.285 10 7 m s 1 Wavelength = 2.25 10 7 m Energy = 5.85 10 19 J 60. The equation of combustion of glucose is as follows: C6H12O6 + 6O2 6CO2 + 6H2O Select choice for correct answer for the reaction with reference to column A and B. A B (i) Volume of STP of CO2 (a) 8.1 gm gas obtained by complete (b) 336 ml combustion of 2.7 gram (c) 0.75 mole glucose. (ii) Moles of O2 necessary (d) 1.35 gm for complete combustion of (e) 4.5 moles 135 gm glucose. (iii) Mass of water obtained (f) 2.016 L by complete combustion of 13.5 gm glucose. (A) (i) (b), (ii) (e), (iii) (d) (B) (i) (b), (ii) (c), (iii) (a) (C) (i) (f), (ii) (c), (iii) (d) (D) (i) (f), (ii) (e), (iii) (a) 61. What will be the volume of 10% volume H2O2 solution reacting with 100 ml KMnO4 solution in acidic medium? (A) 28 ml (B) 56 ml (C) 112 ml (D) 11.2 ml 62. How many ethers are possible for C4H8O? (A) 4 (B) 8 (C) 5 (D) 6

 63. For a reaction KMnO4 + AsO3 3 H3AsO4

+ MnO2 Check the validity of the statements given below: (1) KMnO 4 is reduced to MnO 2 , therefore KMnO 4 is a reducing agent.
(2) In a conversion of AsO3 3 to AsO 3 , 4

oxidation number of As changes from +3 to +5 and KMnO 4 is reduced by it. (3) As there is a change of 3 moles electrons in the conversion of KMnO 4 to MnO 2 , equivalent weight of KMnO 4

Molecular mass (158) = 52.22 3 (4) Half-reaction of formation of H3AsO4

=
from AsO3 3 AsO 3 + 2e . 4

(5) MnO + 5e MnO 2 is a reduction 4 half reaction.

(A) TTTTF (C) FFFFT

(B) TFTFF (D) FTTTF

64. Select the choice having the answer combining the terms in column-I and II. I II (i) What is the total (a) 5.42 1023 number of ions in 200 (b) 1.81 1022 ml 0.3 N Na2CO3? (c) 0.085 (ii) What will be the mole (d) 0.915 fraction of solvent in (e) 0.951 5.2 m aqueous (f) 36.75 gram (g) 137.1 gram solution of glucose? (iii) 2KClO3 2KClO2 (h) 31.95 gram + 3O2. Mol. Mass of (i) 13.71 gram KClO3 is 122.5 g mol1. What mass of KClO2 will be produced if 10.08 L O2 gas is obtained at STP? (iv) How many grams will be the mass of 2.58 1023 dioxygen molecules? (A) (i) (a), (ii) (d), (iii) (f), (iv) (g) (B) (i) (a), (ii) (d), (iii) (h), (iv) (i) (C) (i) (b), (ii) (c), (iii) (h), (iv) (g) (D) (i) (b), (ii) (e), (iii) (f), (iv) (g)