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in metal bonding
Bonding to Enamel
Rods made up of millions of crystals crystal orientation within a rod varies in a regular pattern.
*Adsorption adhesion
Chemical bonding to HA or collagen Ionic,covalent, hydrogen van der Waals Precipitation of substances onto tooth surface that resins can attach to (mechanical or chemical)
Diffusion adhesion
Enamel is Anisotropic
isotropic - same in all directions anisotropic - depends on direction
Properties of enamel
very hard, high compressive strength
Composite (isotropic)
Enamel (anisotropic)
Bonding to enamel
Stronger bonding to rod ends Weaker bonding to sides of rods
etching gel
Etching Patterns
Type II pattern
Type I pattern
definition of pattern
2 6
Dentin Bonding
92
50 vol% HA (less mineral) 25 vol% collagen 25 vol% water includes tubules-(more water)
Enamel
Smear plugs
remove alter
1.2 - 4.5 % by volume 0.2-1.9% linear 2.8 - 7.3 MPa force Depends on how well it is bonded
White Lines ?
Enamel Cracks
Result from shrinkage stress 50X
20X
700X
From what?
Adept Report (2000):6(3) 1-16
C-Factor
What is it?
Ratio of bonded surface/free surface High C-Factor = high shrinkage stress Low C-Factor =low shrinkage stress
Reduce C-Factor and you reduce shrinkage stress Reduce shrinkage stress and you improve margin integrity
Step 1: Total etch (35% H 3PO4) Smear layer removed Surface dentin demineralized Dentin vulnerable to desiccation Step 2: Hydrophilic Primer applied Re-wets dentin Establishes Hybrid layer Step 3: Adhesive Composite placement
Limitations: Too many steps dentin moisture variable some sensitivity reported
Step 1: Total etch (35% H 3PO4) Smear layer removed Surface dentin demineralized Dentin vulnerable to desiccation Step 2: Primer/Adhesive mixture applied Re-wets dentin (not as effective) Establishes Hybrid layer Composite placement
Limitations: Too many steps dentin moisture variable most sensitivity reported
Keep dentin moist Water, Gluma, dentin primers, multiple adhesive layers,
Smear layer modified Surface dentin demineralized Hybrid layer developed More Complete seal and better penetration
Composite placement Lower sensitivity reported Concerns about stability Seal does not appear to be as good
Hybrid layer developed Composite placement Lower sensitivity reported Concerns about stability Seal does not appear to be as good