Appendix 1

A.I.I

THE TREBBLE-BISHNOI EQUATION OF STATE

We consider the Trebble-Bishnoi EoS for a fluid mixture that consist of N c components. The equation was given in Chapter 14.
A. 1.2 Derivation of the Fugacity Expression

The Trebble-Bishnoi EoS (Trebble and Bishnoi, 1988a;b) for a fluid

mixture is given by equation 14.6. The fugacity, fj, of component j in a mixture is given by the following expression for case 1 (i > 0)
K bd _ _ _ j = l n ( X j p ) + (Z-l)-\nZ-Bm\ I+ ykX-V>
U Ir, /Y

(A.I.I)

where (A.I.2) '

403

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404

Appendix 1

X =

ad/n

bd

r|6d

am

bm

(A. 1.3)

(A. 1.4)
Z2+(Bm+Cm)Z-(BmCm+D2J
05

(A. 1.5)

1=1

= Q a n d X = In

2Z + B m ( u - 0 ) 2Z+Bm(u+0)

ifi>0

(A.1.6a)

y B mn

-n

ifi<0

(A.1.6b)

u=l+c m /b m c m b m +c2m +4d2m

(A. 1.7) (A. 1.8)

6bm c, -6 b H cm +2cm c, +8d,,,d, -^^m_ m d - d m m d m d

(A. 1.9)

amP
R2T2

(A.l.lOa)

RT

(A. 1.1 Ob)

'm

RT

(A.l.lOc)

RT

(A.l.lOd)

where am, bm, cm and dm are given by Equations 14.7a, b, c and d respectively. The quantities ad, bd, c d , dd and u^ are given by the following equations
Copyright 2001 by Taylor & Francis Group, LLC

Appendix 1

405

_a(amn2L-

(A. 1.1 la)

(A.I. lib)

(A.I.lie)

dnj

(A.I.lid)

ae
on.

(A.I.lie)

_a(u)
Also

(A.l.llf)

(A.I.12)

A.I.3

Derivation of the Expression for

Differentiation of Equation A 1.1. with respect to Xj at constant T, P and x, for i=l,2,...,N c and i^j gives 51nf:

bd

9Z

, (Z-l) db d

b d 5bm

-FX,+FX2

(A.I.13)

Copyright 2001 by Taylor & Francis Group, LLC

406

Appendix 1

where

RT
FX,=-

(A. 1.14)

RT FX -, =

A j 9x j

ox j

ox j J

A I <9x j

A ox j

(A.I.15)

A number of partial derivatives are needed and they are given next,

(A.I.16)
5X:

5X

n am oxj

5b

m
(A.I.17)

!MzBm+0,B^

+ un0dBm -enudBm)

Bmn6d
OX ,-

.58

-- uu , n9 d T ~ ~ u ^ ~n ud
ox j ox j

du

9nu,

ae

(A.I.18)

ox j

oX

OX;

OX,

(A.I.19)

-c,

SB,,

Copyright 2001 by Taylor & Francis Group, LLC

Appendix 1

407

SA m

P Sam R T2
2

3Bm <9x j 5D m 3x

P 5b m
RT ox j

(A.1.20a)

5Cm 9x

P 9cm RT ox

P Sd m RT <9x

(A.1.20b)

If T>0 then A, is given by equation A. 1.6a and the derivative is given by

oA
vg

9g

9h
ox

g-h

( g - h ) Sg , 9h h) 2

(A. 1.2 la)

+h

where g = 2Z + B m u, h = Bra0 and

- + R - + , + ts,_ +, U ox j ox j ox j
5u 5Bm

ox j

oh
^
OTj

= "m B,

59

If T is negative then A. is given by equation A.I .6b and the derivative is given by

2h

Sg

g Sh

(A. 1.2 Id)

In addition to the above derivatives we need the following

OU

SI C"V

dc

Sx"

b m I oXj

b m 9xj

(A. 1.22)

m/ /bmj

flfCm/
| 2

OX,

bm

OXj

(A. 1.23)

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408

Appendix 1

nu

A.

SQ

oQ
Oc <5xj

(A.1.25a)

where
Q A = 6 b m c d - 6 b d c m + 2 c m c d + 8d m d c

(A.1.25b)

QB =

(A.1.25c)

(A.1.25d)

5 d C ) "^ +c d 5bm b d am c r 'in ~T D ~ c

OX j

OX j

OX j

(A.1.25e) - + d,

5c

(A.1.25f) + 163-d,
5d

OX

-+2b2m

OX

Copyright 2001 by Taylor & Francis Group, LLC

Appendix 1

409

56 1 9r . = i f t > 0
oX 26 SX

(A.1.25h)

or

= - it T is negative
OX : 29 OX ;

59

1 5r

(A.1.251)

Copyright 2001 by Taylor & Francis Group, LLC