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SDS (Sodium Dodecyl Sulfate)

Safety Data Sheet


Version 1.1 Revision date11/29/2011/LM-IA

SECTION 1. Product and company identification


Substance name CAS No. Product code Formula Synonyms : SDS (Sodium Dodecyl Sulfate) : 151-21-3 : DG092 : C12H25NaO4S : AI3-00356 / akyposal SDS / aquarex ME / aquarex methyl / avirol 101 / avirol 118 conc / berol 452 / carsonol SLS / carsonol SLS paste B / carsonol SLS special / casonol SLS pasta B / conco sulfate WA / conco sulfate WA1200 / conco sulfate WA-1200 / conco sulfate WA1245 / conco sulfate WA-1295 / conco sulfate WAG / conco sulfate WAN / conco sulfate WAS / conco sulfate WN / cycloryl 21 / cycloryl 31 / cycloryl 580 / cycloryl 585N / dehydag sulfate GL emulsion / dehydag sulphate GL emulsion / detergent 66 / dodecyl alcohol,hydrogen sulfate,sodium salt / dodecyl sodium sulfate / dodecyl sulfate sodium / dodecyl sulfate sodium salt / dodecylhydrogensulfate sodium salt / dreft / duponal / duponal WAQE / duponol / duponol C / duponol ME / duponol METHYL / duponol QX / duponol WA / duponol WA dry / duponol WAQ / duponol WAQA / duponol WAQE / duponol WAQM / EMAL 0 / EMAL 10 / emersal 6400 / empicol LPZ / empicol LS 30 / empicol LX / emulsifier n 104 / finasol osr(sub 2) / gaedinol / hexamol SLS / incronol SLS / irium / jordanol SL-300 / lanette wax S / lauryl sodium sulfate / lauryl sulfate sodium / lauryl sulfate sodium salt / maprobix neu / maprofix 563 / maprofix LK / maprofix WAC / maprofix wac LA / melanol CL / melanol CL 30 / monododecyl sodium sulfate / monogen Y 100 / montopol la paste / n-dodecyl sulfate sodium / neutrazyme / nikkol SLS / odoripon AL 95 / orvus WA paste / P and G emulsifier 104 / perklankrol ESD 60 / perlandrol L / perlankrol L / product n 161 / product n 75 / quolac EX-UB / rewopol NLS 30 / richonol A / richonol AF / richonol C / SDS (= sodium dodecyl sulphate) / silfopon WA 1 special / silfopon WA 2 / sinnopon LS 100 / sinnopon LS 95 / sintapon L / sipex OP / sipex SB / sipex SD / sipex SP / sipex UB / sipon LS / sipon LS 100 / sipon LSB / sipon PD / sipon WD / SLS (= sodium lauryl sulfate) / sodium dodecyl sulfate / sodium dodecyl sulphate / sodium lauryl sulfate, powder / sodium lauryl sulphate / sodium monododecyl sulfate / sodium monolauryl sulfate / sodium Ndodecyl sulfate / solsol needles / standapol 112 conc / standapol NLS 90 / standapol WA-AC / standapol WAQ / standapol WAQ special / standapol WAS100 / steinapol NLS 90 / stepanol ME / stepanol ME DRY / stepanol ME DRY AW / stepanol methyl / stepanol METHYL DRY AW / stepanol T28 / stepanol WA / stepanol WA paste / stepanol WA-100 / stepanol WAC / stepanol WAQ / sterling WA paste / sterling WAQ-CH / sterling waq-cosmetic / sulfetal L 95 / sulfopon WA3 / sulfopon WAL / sulfotex WA / sulfotex WALA / sulfuric acid monododecyl ester sodium salt / sulfuric acid monododecyl ester,sodium salt / sulfuric acid,monododecyl ester,sodium salt / swascol 1P / swascol 3L / swascol 4L / syntapon L / syntapon L pasta / tarapon K12 / texapon DL conc / texapon K12 / texapon K-1296 / texapon L100 / texapon V HC / texapon V HC powder / texapon Z high conc. needles / texapon ZHC / trepenol WA / TVM 474 / ultra sulfate SL-1 / WAQE (= sodium dodecyl sulfate) / witcolate A / witcolate A powder / witcolate C : G-Biosciences/ Geno Technology, Inc. 9800 Page Avenue St. Louis, MO 63132-1429, USA Tel.1-800-628-7730 http://www.GBiosciences.com : Chemtrec 1-800-424-9300 (USA/Canada), +1-703-527-3887

Company identification

Emergency number

SECTION: 2. Hazards identification


2.1. Emergency Overview : Solid Appearance Colour Odour SDS (Sodium Dodecyl Sulfate) ( \f )151-21-3 : Crystalline solid. Powder. Flakes : White to light yellow : Mild odour. Characteristic odour

2.2. OSHA Regulatory Status No additional information available 2.3. Potential health effects Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : AFTER INHALATION OF DUST: Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Headache. Dry/sore throat. : Red skin. Tingling/irritation of the skin. Blue/grey discolouration of the skin. ON CONTINUOUS EXPOSURE/CONTACT: Dry skin. Cracking of the skin. : Irritation of the eye tissue. : Nausea. Diarrhoea. Irritation of the gastric/intestinal mucosa.

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SDS (Sodium Dodecyl Sulfate)


Safety Data Sheet
2.4. Potential environmental effects No additional information available

SECTION: 3. Composition/information on ingredients


Name
SDS (Sodium Dodecyl Sulfate)

CAS No.
151-21-3

%
100

4.1. First aid procedures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. : Wash immediately with lots of water. Soap may be used. Do not apply (chemical) neutralizing agents. Take victim to a doctor if irritation persists. : Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. : Rinse mouth with water. Do not induce vomiting. Call Poison Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital.

First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion

4.2. Note to physicians No additional information available

SECTION: 5. Firefighting measures


5.1. Flammable properties Fire hazard : DIRECT FIRE HAZARD. Literature reports direct fire hazard. In finely divided state: increased fire hazard. INDIRECT FIRE HAZARD. Heating increases the fire hazard. Reactions involving a fire hazard: see "Reactivity Hazard". : DIRECT EXPLOSION HAZARD. Its dust is explosive with air. INDIRECT EXPLOSION HAZARD. Dust cloud can be ignited by a spark. : On burning: release of toxic and corrosive gases/vapours (sulphur oxides, carbon monoxide carbon dioxide). Reacts with (strong) oxidizers: (increased) risk of fire. : Water spray. Alcohol-resistant foam. Polymer foam. ABC powder. Carbon dioxide. : Dilute toxic gases with water spray. Take account of environmentally hazardous firefighting water. Use water moderately and if possible collect or contain it. : Heat/fire exposure: compressed air/oxygen apparatus.

Explosion hazard Reactivity 5.1. Extinguishing media Suitable extinguishing media 5.3. Protection for firefighters Firefighting instructions Protection during firefighting

SECTION: 6. Accidental release measures


6.1. Personal precautions 6.1.1. For non-emergency personnel : Gloves. Face-shield. Protective clothing. Dust cloud production: compressed air/oxygen apparatus. Dust cloud production: dust-tight suit. : Mark the danger area. Prevent dust cloud formation. No naked flames. Wash contaminated clothes.

Protective equipment Emergency procedures

6.1.2.

For emergency responders

No additional information available 6.2. Environmental precautions Prevent soil and water pollution. Prevent spreading in sewers. 6.3. Methods for containment For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to select material of containers. Plug the leak, cut off the supply. Dam up the solid spill. Knock down/dilute dust cloud with water spray. Do not use compressed air for pumping over spills.

6.4. Methods for clean up Methods for cleaning up : Stop dust cloud by covering with sand/earth. Scoop solid spill into closing containers. Carefully collect the spill/leftovers. Powdered: do not use compressed air for pumping over spills. See "Material-handling" for suitable container materials. Clean contaminated surfaces with an excess of water. Wash clothing and equipment after handling.

6.5. Other information No additional information available


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SDS (Sodium Dodecyl Sulfate)


Safety Data Sheet
6.6. Spill or leak statements by type of chemical No additional information available

SECTION: 7. Handling and storage


7.1. Handling Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Do not discharge the waste into the drain. Powdered form: no compressed air for pumping over. Avoid raising dust. Keep away from naked flames/heat. Finely divided: spark- and explosionproof appliances. Finely divided: keep away from ignition sources/sparks. Observe normal hygiene standards. Keep container tightly closed. Carry operations in the open/under local exhaust/ventilation or with respiratory protection.

7.2. Storage Storage temperature Heat-ignition Prohibitions on mixed storage Storage area Special rules on packaging Packaging materials : < 38 C : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. : KEEP SUBSTANCE AWAY FROM: oxidizing agents. : Store in a dry area. Keep container in a well-ventilated place. Keep out of direct sunlight. Meet the legal requirements. : SPECIAL REQUIREMENTS: closing. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers. : SUITABLE MATERIAL: cardboard. glass. plastics.

SECTION: 8. Exposure controls/personal protection


8.1. Exposure guidelines No additional information available 8.2. Engineering controls No additional information available 8.3. Personal protective equipment (PPE) Materials for protective clothing : GIVE EXCELLENT RESISTANCE: No data available. GIVE GOOD RESISTANCE: No data available. GIVE LESS RESISTANCE: No data available. GIVE POOR RESISTANCE: No data available. : Gloves. : Face shield. In case of dust production: protective goggles. : Protective clothing. In case of dust production: head/neck protection. In case of dust production: dustproof clothing. : Dust production: dust mask with filter type P2.

Hand protection Eye protection Skin and body protection Respiratory protection

SECTION: 9. Physical and chemical properties


Physical state Appearance Molecular mass Colour Odour Odour threshold pH pH solution Melting point Solidification point Boiling point Flash point Relative evaporation rate (butylacetate=1) Flammability (solid, gas) Explosive limits Vapour pressure Relative vapour density at 20 C Relative density Density Solubility : Solid : Crystalline solid. Powder. Flakes. : 288.38 g/mol : White to light yellow. : Mild odour. Characteristic odour. : No data available : 6-9 : 1% : 204 C : No data available : No data available : No data available : No data available : No data available : No data available : < 0.1 hPa (20 C) : No data available : > 1.1 : > 1100 kg/m : Soluble in water. Water: 10 g/100ml Ethanol: < 0.1 g/100ml Acetone: < 0.1 g/100ml
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SDS (Sodium Dodecyl Sulfate)


Safety Data Sheet
Log Pow Self ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties VOC content : 1.6 : 248 C : No data available : No data available : No data available : No data available : 0%

SECTION: 10. Stability and reactivity


10.1. Chemical stability On burning: release of toxic and corrosive gases/vapours (sulphur oxides, carbon monoxide - carbon dioxide). Reacts with (strong) oxidizers: (increased) risk of fire. Stable under normal conditions. 10.2. Conditions to avoid No additional information available 10.3. Incompatible materials No additional information available 10.4. Hazardous decomposition products No additional information available 10.5. Possibility of hazardous reactions No additional information available

SECTION: 11. Toxicological information


Information on toxicological effects Acute toxicity SDS (Sodium Dodecyl Sulfate) (151-21-3) LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE (oral) ATE (dermal) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard : Harmful if swallowed. Harmful in contact with skin. 1288 mg/kg < 2000 mg/kg > 580 mg/kg 1288 mg/kg 1100.00000 mg/kg : Causes skin irritation. pH: 6 - 9 : Causes serious eye irritation. pH: 6 - 9 : Not classified : Not classified : Not classified : Not classified : Not classified : Not classified : Not classified

SECTION: 12. Ecological information


12.1 Ecotoxicity Ecology - general Ecology - air SDS (Sodium Dodecyl Sulfate) ( \f )151-21-3 LC50 fishes 1 LC50 other aquatic organisms 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fishes 2 LC50 other aquatic organisms 2 EC50 Daphnia 2 EC50 other aquatic organisms 2
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: Classification concerning the environment: not applicable. : Not dangerous for the ozone layer (Council Regulation (EC) no 1005/2009). 4.62 mg/l (96 Hours; SALMO GAIRDNERI/ ONCORHYNCHUS MYKISS; NOMINAL CONCENTRATION) 0.91 mg/l (48 Hours; CRASSOSTREA SP.; STATIC SYSTEM) 6.3 - 7.8 mg/l (48 Hours; DAPHNIA MAGNA; STATIC SYSTEM) 117 mg/l (96 Hours; SELENASTRUM CAPRICORNUTUM; GROWTH RATE) 7.97 mg/l (96 Hours; BRACHYDANIO RERIO; FLOW-THROUGH SYSTEM) 0.72 mg/l (96 Hours; HOMARUS SP.; LARVAE) 12.6 mg/l (48 Hours; DAPHNIA PULEX) 18 mg/l (168 Hours; LEMNA SP.; FLOW-THROUGH SYSTEM)
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SDS (Sodium Dodecyl Sulfate)


Safety Data Sheet
12.2. 12.2. Persistence and degradability Readily biodegradable in water. test: 81 %, OECD 302B Zahn- Well. SDS (Sodium Dodecyl Sulfate) ( \f )151-21-3 Persistence and degradability 12.3. Bioaccumulation/Accumulation SDS (Sodium Dodecyl Sulfate) ( \f )151-21-3 BCF fishes 1 BCF fishes 2 Log Pow Bioaccumulative potential 12.4. Mobility in environmental media No additional information available 12.6. Other adverse effects No additional information available 3.9 - 5.3 (72 Hours; CYPRINUS CARPIO) 7.15 (PISCES; CHRONIC) 1.6 Slightly bioaccumulative.

SECTION: 13. Disposal considerations


13.1. Waste treatment methods : Dissolve or mix with a combustible solvent. Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber. : Hazardous waste (91/689/EEC). Waste disposal recommendations Additional information

SECTION: 14. Transport information


14.1. Basic shipping description No additional information available 14.2 Additional information Other information State during transport (ADR-RID) Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available : No supplementary information available. : Rail and road transport: not subject to ADR-RID.

SECTION: 15. Regulatory information


15.1. US Federal regulations No additional information available 15.2. International regulations CANADA No additional information available

EU-Regulations No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 4 (Oral) Acute Tox. 4 (Dermal) Skin Irrit. 2 Eye Irrit. 2 Aquatic Acute 1 H302 H312 H315 H319 H400

Full text of H-phrases: see section 16. Classification according to Directive 67/548/EEC or 1999/45/EC Xn; R21/22 Xi; R36/38 Full text of R-phrases: see section 16. 15.2.2.
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National regulations
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No additional information available

SDS (Sodium Dodecyl Sulfate)


Safety Data Sheet
15.3. US State regulations No additional information available

SECTION: 16. Other information


HMIS III Rating No additional information available

SDS US (ANSI) GBiosciences

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