Professional Documents
Culture Documents
in
Theory 2012
Name of Student
Problem 1 Heterocyclic compounds
1.1 B, C
Roll No.
18 marks
1.2
F>G>E
1.3
B. 1.4 a)
00
or
m .1
N
+
H
+
H
+ N
H
ar w
O3 S N H N H NO2
b)
HO3 S
ks
H
NO2
.in
+ N
H
1
Theory 2012
or
1.6
N H2
O H5 C2
CHO
1 mole
C. 1.7
2 moles
00
1.9
H N H
m
..
1.8
Yes
.1
H OH N H
ar
ks
N H2
.in
N
N H
S (gives an oxime)
T (C H NO) 9 11
U (C H N) 9 9
V(C9 H7 N)
2.4
B. 2.6
NO3(aq) + 10H+ (aq) + 8e NH4+(aq) + 3H2O Pb2+ (aq) + 2H2O PbO2 + 4H+ (aq) + 4e
2.8
2.9
2.7
.1
00
ar
2.5
0.469 g of copper
ks
.in
3
3.2
(a) (c)
X X
3.3
No
X KI7 /I7
X
Solubility
ar
19
(c)
ks
Solvent n-Hexane Toluene Solubility 13 182
(b) (iii)
00
3.5
Solvent
.1
337
F2 + Br2 2BrF (A) 3BrF Br2(g) + BrF3 (B) 5BrF 2Br2(g) + BrF5 (B) 3.7 BrF3 + SbF5 or BrF5 + SbF5 [BrF2]+[SbF6] [BrF4]+[SbF6] or
.in
Color Bright violet Deep brown 4
3.4
(a)
Theory 2012
Lewis Base F SbF6
3.9
a)
b)
... . . .
F
N S
. . ..
..
F
c)
12 Tetrahedral
d)
3.10
F F F F F F Sb F
F Sb F
3.11
XeO64
.1
00
F
ar
ks
.in
5
4.2
4.3
4.5
4.8
4.9
4.7
(ii)
4.6
(iii)
Br
.1
G [C15H15O]
00
m
H
6
ar
ks
.in
Theory 2012
J (C17H24 O)
4.11
or
4.12
O
4.14
(i)
or
(ii)
.1
X (As per the given structure of P in 4.12)
4.13
(i)
4.15
O O O H
00
and
H
m
CH3
ar
ks
.in
7
5.2
I abs k 3
[H 2 ] [Cl 2 ]
or 2K 1
.[H 2 ]
5.4
B. 5.6
c)
5.7
a)
b)
pka = 3.5
.1
5.5
00
ar
ks
5.3
abs1/2 k 31/2
.in
8
= 0 .1
6.2
pH = 10.08
B. 6.4
H3 N C H2 H3N C H2
COOH C H2
m
C H2
H2 C
ar 00
H2 N H2 C C H2 COO
C H2
6.6
[H 2 N R COO ] [H 3 N + R COOH]
(iii)
6.5
around point B
.1
H2 C
COO
ks
around point D X
= 0.03
6.7
.in
9
6.3
pH 6